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11. 发明授权

US4994523A Impact-resistant resin composition 失效
标题翻译：耐冲击树脂组合物
公开(公告)号：US4994523A
公开(公告)日：1991-02-19
申请号：US299677
申请日：1989-01-23
申请人： Isao Sasaki , Naoki Yamamoto , Akira Yanagase
发明人： Isao Sasaki , Naoki Yamamoto , Akira Yanagase
IPC分类号： C08F285/00 , C08F290/14 , C08F291/00 , C08L25/02 , C08L33/06 , C08L51/00 , C08L51/04 , C08L51/06 , C08L51/08 , C08L83/04 , C08L83/10
CPC分类号： C08L33/06 , C08F285/00 , C08L25/02 , C08L51/04 , C08L51/085 , Y10S525/903
摘要： An impact-resistant resin composition having excellent impact resistance, weather resistance, surface appearance and wear characteristics is disclosed.The resin composition comprises:(A) a compound rubber type graft copolymer wherein at least one vinyl monomers is graft-polymerized onto a compound rubber that has an average particle diameter of 0.08 to 0.6 .mu.m and possesses such a structure that 10 to 90 wt. % of a polyorganosiloxane rubber component and 10 to 90 wt. % of a polyalkyl (meth)acrylate rubber component are entangled in an inseparable fashion, and the total amount of the polyorganosiloxane rubber component and the polyalkyl (meth)arcylate rubber component is 100 wt. %; and(B) a vinyl polymer obtained by polymerizing 70 to 100 wt. % of at least one vinyl monomer selected from the group consisting of aromatic alkenyl compounds, vinyl cyanide compounds, and alkyl (meth)acrylates with 0 to 30 wt. % of other vinyl monomer copolymerizable with them.

12. 发明授权

US4775712A Thermoplastic polyester resin composition 失效
标题翻译：热塑性聚酯树脂组合物
公开(公告)号：US4775712A
公开(公告)日：1988-10-04
申请号：US002922
申请日：1987-01-13
申请人： Isao Sasaki , Akira Yanagase , Masafumi Hongo
发明人： Isao Sasaki , Akira Yanagase , Masafumi Hongo
IPC分类号： C08L51/00 , C08L51/02 , C08L51/08 , C08L67/00 , C08L67/02 , C08L77/00 , C08L83/04
CPC分类号： C08L51/085 , C08L67/02
摘要： A thermoplastic polyester resin composition capable of providing a molded article superior in impact resistance, heat resistance, cold resistance, and weather resistance, which comprises a blend of 10 to 80% by weight of a thermoplastic polyester (A), 5 to 55% by weight of a polyorganosiloxane-based graft copolymer (B) obtained by graft-polymerizing 95 to 10% by weight of at least one vinyl monomer onto 5 to 90% by weight of a polyorganosiloxane rubber which exhibits a degree of swelling of 3.0 to 15.0 measured in toluene at 25.degree. C. and contains a graft-linking agent, 5 to 55% by weight of a thermoplastic polyester elastomer (C), and 0 to 60% by weight of a filler (D), wherein the total amount of the components (A) to (D) is 100% by weight.
摘要翻译：一种能够提供耐冲击性，耐热性，耐寒性和耐候性优异的成型体的热塑性聚酯树脂组合物，其包含10〜80重量％的热塑性聚酯（A），5〜55重量％的热塑性聚酯将95〜10重量％的至少一种乙烯基单体接枝聚合得到的聚有机硅氧烷类接枝共聚物（B）的重量在5〜90重量％的表现出3.0〜15.0的溶胀度的聚有机硅氧烷橡胶的情况下在25℃的甲苯中，含有接枝交联剂，5〜55重量％的热塑性聚酯弹性体（C）和0〜60重量％的填料（D），其中，组分（A）至（D）为100重量％。

13. 发明授权

US4690986A Impact-resistant thermoplastic polyorganosiloxane-based graft copolymer and process for producing same 失效
标题翻译：耐冲击热塑性聚有机硅氧烷基接枝共聚物及其制备方法
公开(公告)号：US4690986A
公开(公告)日：1987-09-01
申请号：US904463
申请日：1986-09-08
申请人： Isao Sasaki , Akira Yanagase , Yasunori Kawachi , Tetsuya Mayuzumi , Toshio Oba , Fumio Okada
发明人： Isao Sasaki , Akira Yanagase , Yasunori Kawachi , Tetsuya Mayuzumi , Toshio Oba , Fumio Okada
IPC分类号： C08F30/00 , C08F30/08 , C08F283/00 , C08F283/12 , C08F290/00 , C08F299/08 , C09D151/08
CPC分类号： C08F283/124 , C09D151/085
摘要： A polyorganosiloxane-based high-impact thermoplastic graft copolymer superior in impact resistance, light resistance, surface gloss and color fastness produced by the emulsion graft polymerization of at least one vinyl monomer on an emulsion-polymerized polyorganosiloxane which consists of90 to 99.8 mole % of an organosiloxane unit represented by the formulaR'.sub.2 SiO.sub.2/2 (I) wherein R' is the same or different and denotes methyl, ethyl, propyl, or phenyl,0.1 to 10 mole % of a unit derived from a graft-linking agent, said unit being represented by the formula ##STR1## wherein; R.sup.2 denotes methyl, ethyl, propyl, or phenyl; n denotes a number of 0, 1, and 2; and p denotes a number of 1 to 6, and0.1 to 10 mole % of a unit derived from a tetrafunctional silane crosslinking agent, said unit being represented by the formulaSiO.sub.4/2 (III),said polyorganosiloxane showing a degree of swelling of 5 to 15 in toluene, andsaid graft copolymer containing said polyorganosiloxane in an amount of 10 to 70% by weight; and a process for producing the said graft copolymer.
摘要翻译：通过在乳液聚合的聚有机硅氧烷上由至少一种乙烯基单体的乳液接枝聚合产生的抗冲击性，耐光性，表面光泽和色牢度优异的基于聚有机硅氧烷的高冲击热塑性接枝共聚物，其由90-99.8摩尔％由式R'2SiO2 / 2（I）表示的有机硅氧烷单元，其中R'相同或不同，表示甲基，乙基，丙基或苯基，0.1-10摩尔％衍生自接枝交联剂的单元，所述单元由式（II）表示，其中： R2表示甲基，乙基，丙基或苯基; n表示0，1和2的数; p表示1〜6的数，0.1〜10摩尔％的来自四官能性硅烷交联剂的单元，所述单元由式SiO 4/2（III）表示，所述聚有机硅氧烷的膨胀度为5 至15，并且所述含有所述聚有机硅氧烷的接枝共聚物的量为10-70重量％; 以及所述接枝共聚物的制造方法。

14. 发明授权

US5219932A Graft copolymers excellent in property to be colored and theremoplastic resin compositions with the same 失效
标题翻译：具有优异性能的GRAFT共聚物和具有相同性质的树脂组合物
公开(公告)号：US5219932A
公开(公告)日：1993-06-15
申请号：US784886
申请日：1991-10-30
申请人： Naoki Yamamoto , Akira Yanagase , Tadashi Iwasaki , Masakazu Itoh
发明人： Naoki Yamamoto , Akira Yanagase , Tadashi Iwasaki , Masakazu Itoh
IPC分类号： C08F285/00 , C08L51/08
CPC分类号： C08L51/085 , C08F285/00 , Y10S525/903
摘要： A thermoplastic resin comprises a graft copolymer obtained by graft-polymerizing one or more kinds of vinyl monomer onto a compound rubber, wherein that compound rubber is obtained by inseparably entangling a polyalkyl(meth)acrylate rubber and a modified polyorganosiloxane rubber, the modification being obtained by radical polymerization of 1 to 15 parts by weight of at least one monomer selected from the group consisting of a polyfunctional unsaturated compound having at least one (meth) acryloyloxy group and a polyfunctional unsaturated compound having a cyanuric acid or isocyanuric acid skeleton in the presence of a polyorganosiloxane rubber.

15. 发明授权

US4877687A Synthetic resin molded article having antistatic property 失效
标题翻译：合成树脂成型体具有抗静电性
公开(公告)号：US4877687A
公开(公告)日：1989-10-31
申请号：US95671
申请日：1987-09-14
申请人： Kiyotaka Azegami , Suehiro Tayama , Naoki Yamamoto , Akira Yanagase , Hiroki Hatakeyama
发明人： Kiyotaka Azegami , Suehiro Tayama , Naoki Yamamoto , Akira Yanagase , Hiroki Hatakeyama
IPC分类号： B29C39/16 , B29C39/20 , B32B27/18 , C08J5/00 , C08J7/04
CPC分类号： C08J7/047 , C08J5/00 , Y10S428/922 , Y10S524/913 , Y10T428/31928 , Y10T428/31935
摘要： A synthetic resin molded article having good antistatic properties is disclosed, which is composed of a body of a synthetic resin (B) having a surface layer which is predominantly comprised of an antistatic polymer (A) and is integral with the body (B). The antistatic polymer (A) mainly composed of units of a quaternary ammonium base monomer of the formula: ##STR1##wherein R.sub.1 is H or methyl, R.sub.2 through R.sub.4 are H, unsubstituted or substituted (C.sub.1-9) alkyl, m is 1-10 and X.sup.- is an anion of a quaternizing agent. The molded article is made by forming a film of the antistatic polymer (A) on the molding surface of a casting mold, casting a polymerizable material to be formed into the synthetic resin (B) as the base material in the casting mold, and polymerizing the polymerizable material to form a body of the synthetic resin (B), simultaneously rendering the film of the polymer (A) integral with the body of the base material.
摘要翻译：公开了一种具有良好抗静电性能的合成树脂模塑制品，其由具有主要由抗静电聚合物（A）组成并与主体（B）成一体的表面层的合成树脂（B）的主体组成。主要由下式的季铵基单体的单元组成的抗静电聚合物（A）：其中R1是H或甲基，R2至R4是H，未取代或取代的（C1-9）烷基，m 是1-10，X-是季铵化剂的阴离子。成型品通过在铸模的成型面上形成抗静电聚合物（A）的膜，将要形成的可聚合材料作为基体材料浇铸在合成树脂（B）中而制成，并且聚合形成合成树脂（B）的主体的可聚合材料，同时使聚合物（A）的膜与基材的主体成一体。

16. 发明授权

US5270375A Polyarylene sulfide resin 失效
标题翻译：聚芳硫醚树脂
公开(公告)号：US5270375A
公开(公告)日：1993-12-14
申请号：US967543
申请日：1992-10-27
申请人： Naoki Yamamoto , Akira Yanagase , Hiroshi Mori , Akira Nakata
发明人： Naoki Yamamoto , Akira Yanagase , Hiroshi Mori , Akira Nakata
IPC分类号： C08L51/08 , C08L81/02 , C08K3/40
CPC分类号： C08L81/02 , C08L51/08
摘要： A polyarylene sulfide resin composition comprising 60-99 parts by weight of a polyarylenesulfide resin (A), 40-1 parts by weight of a polyorganosiloxane graft copolymer (B) prepared by grafting a vinyl monomer on a polyorganosiloxane rubber having a degree of swelling in a range of 3-50 measured using toluene as a solvent and an average particle size in a range of 0.15 .mu.m-0.5 .mu.m and being copolymerized with a graft-linking agent, where the total amount of the (A) component and the (B) component is 100 parts by weight, and 0-150 parts by weight of a reinforcing filler (C). A polyarylene sulfide resin composition according to the present invention is excellent in impact resistance, heat resistance, mechanical strength and moldability and useful for an engineering plastic.
摘要翻译：包含60-99重量份的聚芳硫醚树脂（A）的聚芳硫醚树脂组合物，40-1重量份通过将乙烯基单体接枝在具有膨胀度的聚有机硅氧烷橡胶上制备的聚有机硅氧烷接枝共聚物（B）使用甲苯作为溶剂测定的3-50的范围内，平均粒径在0.15μm〜0.5μm的范围内，并与接枝交联剂共聚，其中（A）成分和（B）成分为100重量份，0-150重量份增强填料（C）。本发明的聚芳硫醚树脂组合物的耐冲击性，耐热性，机械强度和成型性优异，对于工程塑料是有用的。

17. 发明授权

US5179144A Polyester resin compositions 失效
标题翻译：聚酯树脂组合物
公开(公告)号：US5179144A
公开(公告)日：1993-01-12
申请号：US797855
申请日：1991-11-26
申请人： Naoki Yamamoto , Akira Nakata , Atsunori Koshirai , Akira Yanagase
发明人： Naoki Yamamoto , Akira Nakata , Atsunori Koshirai , Akira Yanagase
IPC分类号： C08L51/08 , C08G77/42 , C08G77/442 , C08K5/5435 , C08L67/00 , C08L67/02 , C08L83/04 , C08L83/10
CPC分类号： C08L67/02
摘要： A polyester resin composition obtained by blending 60 to 99 parts by weight of a thermoplastic polyester resin (component A), 1 to 40 parts by weight of a polyorganosiloxane graft copolymer (component B) of 0.08 to 0.6 .mu.m in average particle size obtained by graft-polymerizing one or more kinds of vinyl monomer onto a compound rubber having such a structure that 1 to 99 wt. % of a polyorganosiloxane rubber component and 99 to 1 wt. % of a polyalkyl (meth)acrylate rubber component, the total amount of both the rubber components being 100 wt. %, have been inseparably entangled with each other, the total amount of the components A and B being 100 parts by weight, and 0.01 to 10 parts by weight of an organic silane compound having an epoxy group (component C). The polyester resing composition of the present invention is excellent in impact resistance, particularly impact strength at low temperatures, gives molded products having a good appearance, and also can be used under severer conditions and in a wider range than before.

18. 发明授权

US5086106A Methacrylic resin cast plate having excellent antistatic property 失效
标题翻译：具有优良抗菌性能的甲基丙烯酸树脂板
公开(公告)号：US5086106A
公开(公告)日：1992-02-04
申请号：US423596
申请日：1989-10-17
申请人： Kiyotaka Azegami , Suehiro Tayama , Naoki Yamamoto , Akira Yanagase , Hiroki Hatakeyama
发明人： Kiyotaka Azegami , Suehiro Tayama , Naoki Yamamoto , Akira Yanagase , Hiroki Hatakeyama
IPC分类号： C08F265/06 , C08F299/02
CPC分类号： C08F299/024 , C08F265/06 , Y10S524/91
摘要： A methacrylic resin cast plate having an excellent antistatic property comprises (A) 100 weight parts of a polymer comprising 50 to 100 weight % of methyl methacrylate units and 0 to 50 weight % of copolymerizable monomer units and (B) 0.1 to 20 weight parts of a polymer comprising 20 to 100 weight % of units derived from a monomer having a quaternary ammonium base, which is represented by the formula (I): ##STR1## wherein R.sub.1 is H or CH.sub.3, R.sub.2 through R.sub.4 are H or (Cl-9)alkyl which may have a substituent, m is from 1 to 10 and X.sup.- is an anion of a quaternizing agent,and 0 to 80 weight % of copolymerizable monomer units. The cast plate is obtained by polymerizing methyl methacrylate, a monomer mixture comprising at least 50 weight % of methyl methacrylate and up to 50 weight % of a copolymerizable monomer or a partial polymerization product thereof in the presence of the polymer (B).
摘要翻译：具有优异的抗静电性能的甲基丙烯酸树脂浇铸板包含（A）100重量份的包含50-100重量％甲基丙烯酸甲酯单元和0-50重量％可共聚单体单元的聚合物，和（B）0.1-20重量份包含20-100重量％衍生自具有季铵碱的单体的单元，其由式（I）表示：其中R 1为H或CH 3，R 2至R 4为H或（可具有取代基的C 1〜9）烷基，m为1〜10，X为季铵化剂的阴离子，0〜80重量％的可共聚单体单元。通过在聚合物（B）的存在下聚合甲基丙烯酸甲酯，包含至少50重量％的甲基丙烯酸甲酯和至多50重量％的可共聚单体或其部分聚合产物的单体混合物来获得流延板。

19. 发明授权

US4888388A Polycarbonate resin composition 失效
标题翻译：聚碳酸酯树脂组合物
公开(公告)号：US4888388A
公开(公告)日：1989-12-19
申请号：US246612
申请日：1988-09-20
申请人： Masafumi Hongo , Hideyuki Shigemitsu , Naoki Yamamoto , Akira Yanagase
发明人： Masafumi Hongo , Hideyuki Shigemitsu , Naoki Yamamoto , Akira Yanagase
IPC分类号： C08F285/00 , C08L69/00
CPC分类号： C08L69/00 , C08F285/00
摘要： A polycarbonate resin composition comprising a polycarbonate resin (A) or a mixture (A') of a polycarbonate resin with a saturated polyester resin and/or a polyester elastomer, and a compound rubber type graft copolymer (B) having at least one vinyl monomer graft-polymerized onto a compound rubber composed of from 10 to 90% by weight of a polyorganosiloxane rubber and from 10 to 90% by weight of a polyalkyl (meth)acrylate rubber in a total amount of 100% by weight in an inseparable interlocking fashion and having an average particle size of from 0.08 to 0.6 .mu.m, or a mixture (B') of such a compound rubber type graft copolymer (B) with a vinyl monomer, wherein component (B) or (B') is in an amount such that the compound rubber is from 0.5 to 60% by weight based on the entire resin composition.

20. 发明授权

US5543460A Graft copolymer particles their production and compositions comprising them 失效
标题翻译：接枝共聚物颗粒的生产和组成包括它们
公开(公告)号：US5543460A
公开(公告)日：1996-08-06
申请号：US465130
申请日：1995-06-05
申请人： Naoki Yamamoto , Akira Yanagase , Tadashi Iwasaki , Masakazu Itoh
发明人： Naoki Yamamoto , Akira Yanagase , Tadashi Iwasaki , Masakazu Itoh
IPC分类号： C08F285/00 , C08F291/02 , C08L51/00 , C08L51/04 , C08L51/08 , C08L77/00 , C08L101/00 , C08G77/04
CPC分类号： C08L51/04 , C08F285/00 , C08F291/02 , C08L101/00 , C08L51/003 , C08L51/085 , C08L77/00
摘要： Graft copolymer particles obtained by graft-polymerizing one or more kinds of vinyl monomer onto a compound rubber comprising a polyorganosiloxane component and an alkyl (meth)acrylate rubber component, which graft copolymer particle has a number average particle size of 0.01 to 0.07 .mu.m, the volume of particles larger than 0.10 .mu.m being 20% or less of the whole particle volume, a method for producing the above graft copolymer particle, wherein one or more kinds of vinyl monomer are graft-polymerized onto a compound rubber obtained by polymerizing an alkyl (meth)acrylate rubber component comprising alkyl (meth)acrylate and a polyfunctional alkyl (meth)acrylate with a polyorganosiloxane having a number average particle size of 0.003 to 0.06 .mu.m, the volume of particles larger than 0.10 .mu.m being 20% or less of the whole particle volume, and thermoplastic resin compositions comprising the above graft copolymer and various thermoplastic resins.The present invention provides graft copolymer particles and their thermoplastic resin composition which can give molded products having both excellent pigment colorability and extremely high impact resistance.
摘要翻译：通过将一种或多种乙烯基单体接枝聚合到包含聚有机硅氧烷组分和（甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯）组分的复合橡胶上获得的接枝共聚物颗粒，该接枝共聚物颗粒的数均粒径为0.01至0.07μm，大于0.10μm的粒子的体积为整个粒子体积的20％以下，制造上述接枝共聚物粒子的方法，其中将一种或多种乙烯基单体接枝聚合到通过聚合（甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯橡胶组分和多官能烷基（甲基）丙烯酸酯与数均粒径为0.003至0.06μm的聚有机硅氧烷，大于0.10μm的颗粒体积为20％或整个颗粒体积较小，以及包含上述接枝共聚物和各种热塑性树脂的热塑性树脂组合物。本发明提供接枝共聚物颗粒及其热塑性树脂组合物，其可以得到具有优异颜料着色性和极高抗冲击性的成型体。

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