专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

11. 发明授权

US4080385A Preparation of alkoxy phospholane oxides and sulphides 失效
标题翻译：烷氧基磷脂氧化物和硫化物的制备
公开(公告)号：US4080385A
公开(公告)日：1978-03-21
申请号：US741577
申请日：1976-11-12
申请人： Hans-Dieter Block
发明人： Hans-Dieter Block
IPC分类号： C07F9/6568 , C08G18/02 , C07F9/53
CPC分类号： C08G18/025 , C07F9/65685
摘要： A process for the production of an alkoxy phospholane oxide or sulphide of the formula ##STR1## in which R.sup.1 is an alkyl, alkoxy or aryl radical having up to 14 carbon atoms.R.sup.2, r.sup.3 and R.sup.4 each independently is a C.sub.1 to C.sub.4 alkyl radical, hydrogen, chlorine or bromine,R.sup.5 is an alkyl, alkenyl, alkynyl radical having from 1 to 14 carbon atoms, andX is oxygen or sulphur,Comprising reacting a phospholene oxide or sulphide of the formula ##STR2## with an alcohol of the formulaR.sup.5 -- O -- Hin the presence of an alkaline catalyst, such as sodium methylate. The products catalyze the conversion of isocyanates into carbodiimides with evolution of carbon dioxide.
摘要翻译：制备式“IMAGE”的烷氧基磷酰氧化物或硫化物的方法，其中R 1是具有至多14个碳原子的烷基，烷氧基或芳基。

12. 发明授权

US06951637B2 Method and device for producing globular grains of high-puroty silicon having a diameter of between 50 μm and 300 μm and use of the same 失效
标题翻译：用于生产直径在50μm和300μm之间的高磷硅球形颗粒的方法和装置，并使用它们
公开(公告)号：US06951637B2
公开(公告)日：2005-10-04
申请号：US10433257
申请日：2001-11-06
申请人： Hans-Dieter Block , Udo Kräuter , Peter Schreckenberg
发明人： Hans-Dieter Block , Udo Kräuter , Peter Schreckenberg
IPC分类号： B05B17/06 , C01B33/02 , C01B33/027 , B22D11/01 , B22F9/00 , B28B1/54 , B29B9/00
CPC分类号： C01B33/02 , B05B17/0623 , B22F2999/00 , C01B33/027 , B22F9/08 , B22F2202/01
摘要： The invention relates to a method and a device for producing globular grains of high-purity silicon by atomising a silicon melt (6) in an ultrasonic field (10). Globular grains having a grain size of 50 μm can be produced by means of said method and device and can be used to separate high-purity silicon from silane in the fluid bed. The silicon melt (6) is fed into the ultrasonic field (10) at a distance of
摘要翻译：本发明涉及一种通过在超声波场（10）中雾化硅熔体（6）来生产高纯度硅球颗粒的方法和装置。粒径为50μm的球状颗粒可以通过所述方法和装置制备，并且可用于在流化床中将高纯度硅与硅烷分离。硅熔体（6）相对于场节点以相对于场节点<50mm的距离被馈送到超声场（10）中，并且雾化的硅在接近液相点的温度离开超声场（10）。本发明还涉及根据本发明方法生产的产品或使用本发明的装置作为在流化床中由硅烷生产高纯度硅的颗粒的用途。

13. 发明授权

US06852301B2 Method for producing silane 失效
标题翻译：硅烷的制造方法
公开(公告)号：US06852301B2
公开(公告)日：2005-02-08
申请号：US10450207
申请日：2001-11-21
申请人： Hans-Dieter Block , Leslaw Mleczko , Andreas Bulan , Rainer Weber , Sigurd Buchholz , Torsten Sill
发明人： Hans-Dieter Block , Leslaw Mleczko , Andreas Bulan , Rainer Weber , Sigurd Buchholz , Torsten Sill
IPC分类号： C01B33/04 , C01B33/18
CPC分类号： C01B33/046 , C01B33/043 , C01B33/18
摘要： The invention relates to a method for producing silane (SiH4) by a) reacting metallurgical silicon with silicon tetrachloride (SiCl4) and hydrogen (H2), to form a crude gas stream containing trichlorosilane (SiHCl3) and silicon tetrachloride (SiCl4), b) removing impurities from the resulting crude gas stream by washing with condensed chlorosilanes, c) condensing and subsequently, separating the purified crude gas stream by distillation, d) returning the partial stream consisting essentially of SiCl4 to the reaction of metallurgical silicon with SiCl4 and H2, e) disproportionating the partial stream containing SiHCl3, to form SiCl4 and SiH4 and f) returning the SiH4 formed by disproportionation to the reaction of metallurgical silicon with SiCl4 and H2, the crude gas stream containing trichlorosilane and silicon tetrachloride being liberated from solids as far as possible by gas filtration before being washed with the condensed chlorosilanes. The washing process with the condensed chlorosilanes is carried out at a pressure of 25 to 40 bar and at a temperature of at least 150° C. in a single-stage distillation column and is carried out in such a way that 0.1 to 3 wt. % of the crude gas stream containing trichlorosilane and silicon tetrachloride is recovered in the form of a condensed liquid phase consisting essentially of SiCl4, this liquid phase then being removed from the SiCl4 circuit and expanded to a pressure of 1 bar outside said SiCl4 circuit and cooled to a temperature of 10 to 40° C., whereby dissolved impurities separate out and are then removed by filtration.
摘要翻译：本发明涉及一种通过以下步骤制备硅烷（SiH 4）的方法：a）使冶金硅与四氯化硅（SiCl 4）和氢（H 2）反应，形成含有三氯硅烷（SiHCl 3）和四氯化硅（SiCl 4）的粗气流，b）通过用冷凝的氯硅烷洗涤从所得粗气流中除去杂质，c）冷凝并随后通过蒸馏分离纯化的粗气流，d）将基本上由SiCl 4组成的部分流返回到冶金硅与SiCl 4和H 2的反应中， e）歧化含SiHCl3的部分流，以形成SiCl4和SiH4，以及f）将通过歧化形成的SiH 4返回至冶金硅与SiCl4和H2的反应，将含有三氯硅烷和四氯化硅的粗气流从固体释放至在用冷凝的氯硅烷洗涤之前可能通过气体过滤。冷凝氯硅烷的洗涤过程在单级蒸馏塔中在25至40巴的压力和至少150℃的温度下进行，并以0.1至3重量％含有三氯硅烷和四氯化硅的粗气流的％以基本上由SiCl 4组成的冷凝液相的形式回收，然后将该液相从SiCl4回路除去并在SiCl 4回路外扩张至1巴的压力，并冷却温度为10〜40℃，由此分离出溶解的杂质，然后通过过滤除去。

14. 发明授权

US06843972B2 Method for purifying trichlorosilane 有权
标题翻译：纯化三氯硅烷的方法
公开(公告)号：US06843972B2
公开(公告)日：2005-01-18
申请号：US10416829
申请日：2001-11-06
申请人： Stephan Klein , Hans-Dieter Block , Hans-Joachim Leimkühler , Werner Dick , Johannes-Peter Schäfer
发明人： Stephan Klein , Hans-Dieter Block , Hans-Joachim Leimkühler , Werner Dick , Johannes-Peter Schäfer
IPC分类号： C01B33/107 , A62D3/00
CPC分类号： C01B33/10778
摘要： The invention relates to a method for removing anhydrous acids and hydrohalogens from trichlorosilane by contacting the trichlorosilane with solid bases. The invention further relates to the use of the trichlorosilane so purified in the production of silane and/or super-pure silicon.
摘要翻译：本发明涉及通过使三氯硅烷与固体碱接触来从三氯硅烷中除去无水酸和氢卤素的方法。本发明还涉及在制备硅烷和/或超纯硅中如此纯化的三氯硅烷的用途。

15. 发明授权

US5667759A Method for manufacturing alkali chromates from chromium ore 失效
标题翻译：从铬矿生产铬酸铬的方法
公开(公告)号：US5667759A
公开(公告)日：1997-09-16
申请号：US690420
申请日：1996-07-26
申请人： Rainer Bellinghausen , Heinrich Helker , Paul Strehlow , Hans-Heinrich Moretto , Bernhard Spreckelmeyer , Norbert Lonhoff , Michael Batz , Rainer Weber , Hans Rinkes , Hans-Dieter Block , Uwe Arndt
发明人： Rainer Bellinghausen , Heinrich Helker , Paul Strehlow , Hans-Heinrich Moretto , Bernhard Spreckelmeyer , Norbert Lonhoff , Michael Batz , Rainer Weber , Hans Rinkes , Hans-Dieter Block , Uwe Arndt
IPC分类号： C01G37/14 , C01G37/00
CPC分类号： C01G37/14
摘要： A method for the decomposition of chromium ore in a directly heated revolving tube is described, in which oxygen-containing gases are introduced into the revolving tube by means of below-bed nozzles.
摘要翻译：描述了在直接加热的旋转管中分解铬矿的方法，其中含氧气体通过下床喷嘴引入回转管中。

16. 发明授权

US5096548A Process for the preparation of chromic acid 失效
标题翻译：制备色素的方法
公开(公告)号：US5096548A
公开(公告)日：1992-03-17
申请号：US626076
申请日：1990-12-11
申请人： Norbert Lonhoff , Ludwig Schmidt , Hans-Dieter Block , Rainer Weber
发明人： Norbert Lonhoff , Ludwig Schmidt , Hans-Dieter Block , Rainer Weber
IPC分类号： C25B1/00 , B01J47/12 , C01G37/033 , C25B1/22 , C25B15/08 , C25C1/10
CPC分类号： C01G37/033 , C25B1/22 , C25C1/10
摘要： A process for the production of chromic acid, comprising(a) dissolving ferrochrome in sulphuric acid and mother liquor from the subsequent crystallization of ammonium chrome alum, optionally with the addition of at least one of catholyte and anolyte overflow from the subsequent electrolysis,(b) removing undissolved constituents by filtration,(c) removing dissolved iron by the addition of at least one of ammonia and ammonium sulphate to the filtrate obtained, crystallizing iron ammonium sulphate and filtering,(d) crystallizing and filtering ammonium chrome alum from the remaining solution and returning the filtrate for dissolving ferrochrome in step (a),(e) dissolving the ammonium chrome alum in water,(f) precipitating and separating chromium-(III) hydroxide from the resulting solution by adding a base, optionally under reducing conditions,(g) dissolving the separated chromium hydroxide in chromic acid and optionally sulphuric acid so that either a single solution in chromic acid is obtained or two solutions are obtained, one in chromic acid and another in sulphuric acid,(h) separating the solution(s) from undissolved constituents, and(i) utilizing the solution of chromium hydroxide in chromic acid as anolyte in the electrolytic production of chromic acid in an electrolytic cell divided by a membrane, and either utilizing the same solution as catholyte in the above mentioned electrolytic cell divided by a membrane or utilizing the solution of chromium hydroxide in sulphuric acid as catholyte in the above mentioned electrolytic cell divided by a membrane, hydrogen and metallic chromium being deposited electrolytically at the cathode and/or chromium (II) ions being produced electrolytically at the cathode.
摘要翻译：一种生产铬酸的方法，包括（a）将铬铁铬酸盐和母液从随后的铵铬明矾结晶中溶解，任选地从随后的电解中加入至少一种阴极电解液和阳极电解液溢出物（b ）通过过滤除去未溶解的组分，（c）通过向所得滤液中加入至少一种氨和硫酸铵除去溶解的铁，结晶硫酸铁铵并过滤，（d）从剩余溶液中结晶并过滤铵铬明矾并在步骤（a）中返回用于溶解铬铁的滤液，（e）将铵铬明矾溶解在水中，（f）通过加入碱（任选在还原条件下）将所得溶液中的铬 - （III）（g）将分离的氢氧化铬溶解在铬酸和任选的硫酸中，使得单一的铬酸溶液得到两种溶液，一种在铬酸中，另一种在硫酸中，（h）将溶液与未溶解的组分分离，和（i）在电解生产中利用铬酸中的铬酸溶液作为阳极电解液在由电解槽中分离的膜中的铬酸，或者利用与上述电解槽中的阴极电解液相同的溶液，或者利用氢氧化铬溶液作为阴极电解液，除去上述电解槽在阴极处电解沉积的阴极和/或铬（II）离子沉积的膜，氢和金属铬。

17. 发明授权

US5091562A Process for eliminating 1-carboxy-1-phosphonocyclopentan-3-one from, or reducing its content in, technical 2-phosphonobutane-1,2,4-tricarboxylic acid using bleaching liquor 失效
标题翻译：用漂白液除去1-羧基-1-磷杂环戊烯-3-酮的方法或减少其中含有的技术性2-膦酰基-1,2,4-三羧酸的方法
公开(公告)号：US5091562A
公开(公告)日：1992-02-25
申请号：US676051
申请日：1991-03-27
申请人： Michael Immenkeppel , Roland Kleinstuck , Hans-Dieter Block , Hermann Sicius , Peter Schmidt
发明人： Michael Immenkeppel , Roland Kleinstuck , Hans-Dieter Block , Hermann Sicius , Peter Schmidt
IPC分类号： C07F9/38
CPC分类号： C07F9/3808
摘要： The present invention relates to a process for eliminating 1-phosphono-1-carboxycyclopentan-3-one (ketone) from, or reducing its content in, an aqueous solution of 2-phosphonobutane-1,2,4-tricarboxylic acid, characterized in that the solution is adjusted to a pH value of > 6 using an aqueous inorganic base, particularly sodium hydroxide, and aqueous bleaching liquor is subsequently added in a molar ratio of NaOCl to ketone of >5:1.
摘要翻译：本发明涉及从2-膦酰基丁烷-1,2,4-三羧酸的水溶液中除去1-膦酰基-1-羧基环戊烷-3-酮（酮）或降低其含量的方法，其特征在于使用无机碱水溶液，特别是氢氧化钠将溶液调节至pH值> 6，随后以Na 2 Cl与酮的摩尔比> 5:1加入水性漂白液。

18. 发明授权

US4988748A Flame-resistant thermoplastic polycarbonate molding compounds 失效
标题翻译：耐火热塑性聚碳酸酯模塑料
公开(公告)号：US4988748A
公开(公告)日：1991-01-29
申请号：US377078
申请日：1989-07-10
申请人： Karl Fuhr , Friedemann Muller , Karl-Heinz Ott , Hans-Dieter Block , Bernd Urbanneck , Werner Ballas
发明人： Karl Fuhr , Friedemann Muller , Karl-Heinz Ott , Hans-Dieter Block , Bernd Urbanneck , Werner Ballas
IPC分类号： C08K5/52 , C08K3/00 , C08K5/523 , C08L69/00
CPC分类号： C08K5/523 , C08L69/00
摘要： The invention relates to thermoplastic polycarbonate molding compounds containing polycarbonates, copolymers, phosphorus compounds, tetrafluoroethylene polymers and, optionally, graft polymers and also further additives and other thermoplastics and also stabilizers, pigments, flow aids, mold release agents, antistatic agents and/or other flameproffing agents, characterized in that they contain as phosphorus compounds those corresponding to formula (I) ##STR1## and to a process for the production of the polycarbonate molding compounds.
摘要翻译：本发明涉及含有聚碳酸酯，共聚物，磷化合物，四氟乙烯聚合物和任选的接枝聚合物以及其它添加剂和其它热塑性塑料以及稳定剂，颜料，助流剂，脱模剂，抗静电剂和/或其它的热塑性聚碳酸酯模塑料其特征在于它们含有对应于式（I）的化合物（I）和制备聚碳酸酯模塑料的方法。

19. 发明授权

US4981573A Process for the production of alkali dichromates and chromic acid employing an anode of valve metal activated by electrodepositing noble metals from melts 失效
标题翻译：使用通过从熔体中电沉积贵金属而活化的阀门金属的阳极来生产碱性重铬酸盐和铬酸的方法
公开(公告)号：US4981573A
公开(公告)日：1991-01-01
申请号：US392873
申请日：1989-08-11
申请人： Helmut Klotz , Rainer Weber , Hans-Dieter Block , Norbert Lonhoff
发明人： Helmut Klotz , Rainer Weber , Hans-Dieter Block , Norbert Lonhoff
IPC分类号： C01G37/14 , C25B1/14 , C25B1/22 , C25B11/08
CPC分类号： C25B1/22
摘要： A process for the production of alkali dichromates and chromic acid by electrolysis of alkali monochromate or alkali dichromate solutions wherein the anodes used in the electrolysis are dimensionally stable anodes of valve metals activated by electrodeposition of noble metals and/or noble compounds from melts containing noble metal salts.
摘要翻译：通过电解碱性单色酸盐或碱性重铬酸盐溶液来生产碱性重铬酸盐和铬酸的方法，其中用于电解的阳极是通过从含有贵金属的熔体电沉积贵金属和/或贵金属而活化的阀金属的尺寸稳定的阳极盐。

20. 发明授权

US4377537A Preparation of alkane phosphonic and phosphinic acid aryl esters 失效
标题翻译：烷烃膦酸和次膦酸芳酯的制备
公开(公告)号：US4377537A
公开(公告)日：1983-03-22
申请号：US222221
申请日：1981-01-02
申请人： Hans-Dieter Block , Hans-Gunther Frohlen
发明人： Hans-Dieter Block , Hans-Gunther Frohlen
IPC分类号： B01J21/00 , C07F9/32 , C07F9/38 , C07F9/40
CPC分类号： C07F9/4084 , C07F9/3282
摘要： A process for the preparation of an alkane phosphonic acid diaryl ester or an alkane phosphinic acid aryl ester of the formula ##STR1## wherein R.sup.1 is C.sub.1 -C.sub.20 alkyl or alkenyl group,R.sup.2 is a C.sub.1 -C.sub.20 alkyl or alkenyl group or a C.sub.6 -C.sub.10 aryl or aryloxy group,R.sup.3 is C.sub.6 -C.sub.10 aryl group,k is 0 or 1,p is 1 or 2,k+p=2,plus an alkane phosphonic acid diaryl ester, alkane phosphinic acid aryl ester or phosphine oxide of the formula ##STR2## R.sup.4 and R.sup.5 each independently is C.sub.1 -C.sub.20 alkyl group, a C.sub.6 -C.sub.10 aryl group or a C.sub.6 -C.sub.10 aryloxy group,R.sup.6 is C.sub.1 -C.sub.20 alkyl or alkenyl group,n and m each is 0, 1 or 2, andn+m=2,comprising reacting an aryloxy compound of trivalent phosphorus of the formula ##STR3## (a) with an alkyl phosphite or alkyl phosphonite of the formula ##STR4## in the presence of an Arbusow catalyst, or (b) a rearrangement product formed in the presence of an Arbusow catalyst and of the formula ##STR5##
摘要翻译：制备下式的烷烃膦酸二芳基酯或烷烃次膦酸芳基酯的方法，其中R 1是C 1 -C 20烷基或烯基，R 2是C 1 -C 20烷基或链烯基或C 6 -C 20烷基， C10芳基或芳氧基，R3为C6-C10芳基，k为0或1，p为1或2，k + p = 2，加上烷烃膦酸二芳基酯，烷烃次膦酸芳酯或氧化膦其中R4和R5各自独立地为C1-C20烷基，C6-C10芳基或C6-C10芳氧基，R6是C1-C20烷基或烯基，n和m各自为0 ，1或2和n + m = 2，包括在Arbusow催化剂的存在下使式（a）的三价磷的芳氧基化合物与式IMAMA的烷基亚磷酸酯或烷基亚膦酸酯反应，或（b）在Arbusow催化剂存在下形成并具有式（IMAGE）的重排产物

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式