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1. 发明授权

US5091562A Process for eliminating 1-carboxy-1-phosphonocyclopentan-3-one from, or reducing its content in, technical 2-phosphonobutane-1,2,4-tricarboxylic acid using bleaching liquor 失效
标题翻译：用漂白液除去1-羧基-1-磷杂环戊烯-3-酮的方法或减少其中含有的技术性2-膦酰基-1,2,4-三羧酸的方法
公开(公告)号：US5091562A
公开(公告)日：1992-02-25
申请号：US676051
申请日：1991-03-27
申请人： Michael Immenkeppel , Roland Kleinstuck , Hans-Dieter Block , Hermann Sicius , Peter Schmidt
发明人： Michael Immenkeppel , Roland Kleinstuck , Hans-Dieter Block , Hermann Sicius , Peter Schmidt
IPC分类号： C07F9/38
CPC分类号： C07F9/3808
摘要： The present invention relates to a process for eliminating 1-phosphono-1-carboxycyclopentan-3-one (ketone) from, or reducing its content in, an aqueous solution of 2-phosphonobutane-1,2,4-tricarboxylic acid, characterized in that the solution is adjusted to a pH value of > 6 using an aqueous inorganic base, particularly sodium hydroxide, and aqueous bleaching liquor is subsequently added in a molar ratio of NaOCl to ketone of >5:1.
摘要翻译：本发明涉及从2-膦酰基丁烷-1,2,4-三羧酸的水溶液中除去1-膦酰基-1-羧基环戊烷-3-酮（酮）或降低其含量的方法，其特征在于使用无机碱水溶液，特别是氢氧化钠将溶液调节至pH值> 6，随后以Na 2 Cl与酮的摩尔比> 5:1加入水性漂白液。

2. 发明授权

US4931586A Process for the continuous production of 2-phosphone-butane-1,2,4-tricarboxylic acid and alkali metal salts thereof 失效
标题翻译：用于连续生产2-膦酸丁烷-1,2,4-三羧酸及其碱金属盐的方法
公开(公告)号：US4931586A
公开(公告)日：1990-06-05
申请号：US394592
申请日：1989-08-16
申请人： Roland Kleinstuck , Cornelia Lensch , Michael Immenkeppel , Hans-Dieter Block , Herbert Odenbach
发明人： Roland Kleinstuck , Cornelia Lensch , Michael Immenkeppel , Hans-Dieter Block , Herbert Odenbach
IPC分类号： B01J31/02 , C07B61/00 , C07F9/38
CPC分类号： C07F9/3808
摘要： This invention relates to an improved process for the continuous production of 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC) and alkali metal salts thereof, in which dialkylphosphite, and ethene-1,2-dicarboxylic acid dialkyl ester, are reacted in the presence of a basic catalyst to form phosphonosuccinic acid tetraalkyl ester, the ester thus obtained is directly reacted with alkyl-acrylate, in the presence of an alkaline catalyst and the reaction product thus obtained is directly hydrolyzed to PBTC or alkali metal salts thereof.
摘要翻译：本发明涉及连续生产2-膦酰基丁烷-1,2,4-三羧酸（PBTC）及其碱金属盐的改进方法，其中亚磷酸二烷基酯和乙烯-1,2-二羧酸二烷基酯是在碱性催化剂的存在下反应形成膦酰基琥珀酸四烷基酯，所得到的酯在碱性催化剂的存在下与烷基 - 丙烯酸酯直接反应，由此获得的反应产物直接水解成PBTC或其碱金属盐。

3. 发明授权

US5639909A Production of 2-phosphonobutane-1,2,4-tricarboxylic acid and the alkali metal salts thereof 失效
标题翻译： 2-膦酰基丁烷-1,2,4-三羧酸及其碱金属盐的制备
公开(公告)号：US5639909A
公开(公告)日：1997-06-17
申请号：US650681
申请日：1996-05-20
申请人： Christoph Holzner , Wolfgang Ohlendorf , Hans-Dieter Block , Horst Bertram , Roland Kleinstuck , Hans-Heinrich Moretto
发明人： Christoph Holzner , Wolfgang Ohlendorf , Hans-Dieter Block , Horst Bertram , Roland Kleinstuck , Hans-Heinrich Moretto
IPC分类号： C07F9/38 , C07F9/40
CPC分类号： C07F9/3808 , C07F9/4006
摘要： This invention relates to an improved process for the production of 2-phosphono-butane-1,2,4-tricarboxylic acid (PBTC) and the alkali metal salts thereof, in which process dialkyl phosphite, preferably dimethyl or diethyl phosphite, and ethene-1,2-dicarboxylic acid dialkyl ester, in particular the dimethyl or diethyl ester of maleic acid and/or fumaric acid, are initially reacted in the presence of a basic catalyst to yield a phosphonosuccinic acid tetraalkyl ester, the resultant ester is thereupon reacted without further working up with acrylic acid alkyl ester, preferably methyl or ethyl acrylate, in the presence of an alkaline catalyst and the reaction product obtained in this manner is saponified without further working up to yield PBTC or the alkali metal salts thereof. The product when mixed with bleaching lye exhibits reduced chlorine depletion.
摘要翻译：本发明涉及一种制备2-膦酰基 - 丁烷-1,2,4-三羧酸（PBTC）及其碱金属盐的改进方法，其中亚磷酸二烷基酯，优选亚磷酸二甲酯或二乙酯和乙烯 - 1,2-二羧酸二烷基酯，特别是马来酸和/或富马酸的二甲基酯或二乙酯，最初在碱性催化剂存在下反应，得到磷酸二琥珀酸四烷基酯，得到的酯随后反应而没有进一步用丙烯酸烷基酯，优选丙烯酸甲酯或丙烯酸乙酯在碱性催化剂的存在下进行处理，将以这种方式获得的反应产物进行皂化而不进一步加工得到PBTC或其碱金属盐。当与漂白碱液混合时，产品会减少氯的消耗。

4. 发明授权

US5233088A Process for the preparation of alkali metal salts of 2-phosphonobutane-1,2,4-tricarboxylic acid 失效
标题翻译：制备2-膦酰基-1,2,4-三羧酸的碱金属盐的方法
公开(公告)号：US5233088A
公开(公告)日：1993-08-03
申请号：US746841
申请日：1991-08-19
申请人： Uwe Arndt , Hans-Dieter Block , Roland Kleinstuck
发明人： Uwe Arndt , Hans-Dieter Block , Roland Kleinstuck
IPC分类号： C07F9/38
CPC分类号： C07F9/3808
摘要： The present invention relates to a process for the preparation of alkali metal salts of 2-phosphonobutane-1,2,4-tricarboxylic acid, characterized in that 2-phosphonobutane-1,2,4-tricarboxylic acid penta-alkyl esters or partial esters are reacted with an aqueous alkali metal hydroxide solution in a ratio of from 0.5 to 0.76 mol, preferably from 0.6 to 0.7 mol of alkali metal hydroxide per mol of ester function at temperatures from 20.degree. to 200.degree. C. in a one-shot process.
摘要翻译：本发明涉及2-膦酰基丁烷-1,2,4-三羧酸的碱金属盐的制备方法，其特征在于2-膦酰基丁烷-1,2,4-三羧酸五烷基酯或偏酯在一步法中在20℃至200℃的温度下，每摩尔酯官能团与碱金属氢氧化物水溶液的比例为0.5至0.76摩尔，优选0.6至0.7摩尔碱金属氢氧化物。。

5. 发明授权

US4246103A Propane-1,3-diphosphonic acids for conditioning water 失效
标题翻译：丙烷-1,3-二膦酸调理水
公开(公告)号：US4246103A
公开(公告)日：1981-01-20
申请号：US15999
申请日：1979-02-28
申请人： Hans-Dieter Block , Herbert Kallfass , Roland Kleinstuck
发明人： Hans-Dieter Block , Herbert Kallfass , Roland Kleinstuck
IPC分类号： C02F5/00 , C02F5/08 , C02F5/10 , C02F5/12 , C02F5/14 , C09K3/00 , C23F11/167 , C23F14/02
CPC分类号： C23F11/167 , C02F5/14 , C23F11/1676
摘要： Water is conditioned by adding thereto a corrosion-inhibiting, concretion inhibiting, precipitation retarding, deflocculating, dispersing or fluidifying amount of an acid of the formula ##STR1## in which R.sup.1 and R.sup.2, independently of one another, represent hydrogen where a or b=1, or where a or b=0 represent an optionally substituted alkyl radical with 1-8 carbon atoms or an optionally substituted phenyl radical,R.sup.3 represents hydrogen, an optionally substituted alkyl radical with 1 to 4 carbon atoms, an optionally substituted phenyl radical, a halogen atom from the group comprising fluorine, chlorine and bromine, a hydroxyl group, an alkoxy group containing 1 to 8 carbon atoms, a carboxyl group or a group --P(O)--(O).sub.a --R.sup.1 OH,R.sup.4 represents hydrogen, an alkyl radical with 1 to 4 carbon atoms, an alkenyl radical with up to 3 carbon atoms, an optionally substituted phenyl radical, a carboxyl group, a fluorine or chlorine atom or a group --P(O)--(O).sub.a --R.sup.1 OH, orR.sup.3 and R.sup.4 together form a ring bridge with 3 to 5 methylene groups,R.sup.5 represents hydrogen, an optionally substituted alkyl radical with 1 to 4 carbon atoms, a carboxymethyl or carboxyethyl group optionally substituted by a methyl group, a succinyl group or a group having the structure--CHR.sup.4 --CHR.sup.3 --P(O)--(O).sub.a --R.sup.1 OH or the structure--CH.sub.2 --P(O)--(O).sub.a --R.sup.1 OH,R.sup.6 represents an optionally substituted phenyl radical, a carboxyl group or a group having the structure --P(O)--(O).sub.b --R.sup.2 OH, anda and b independently of one another represent the numbers 0 or 1,or a salt thereof.
摘要翻译：通过向其中加入腐蚀抑制，抑制凝结抑制，沉淀阻滞，抗絮凝，分散或流化量的式“IMAGE”酸，其中R 1和R 2彼此独立地表示氢，其中a或b = 1或其中a或b = 0表示任选取代的具有1-8个碳原子的烷基或任选取代的苯基，R 3表示氢，任选取代的具有1至4个碳原子的烷基，任选取代的苯基，来自包含氟，氯和溴的卤素原子，羟基，含有1至8个碳原子的烷氧基，羧基或基团-P（O） - （O）a -R 10 OH，R 4表示氢，具有1至4个碳原子的烷基，具有至多3个碳原子的烯基，任选取代的苯基，羧基，氟或氯原子或基团-P（O） - （O）a - R1 OH或R3和R4一起形成环桥 e具有3至5个亚甲基，R 5表示氢，任选取代的具有1至4个碳原子的烷基，任选被甲基取代的羧甲基或羧乙基，琥珀酰基或具有结构-CHR4-CHR3- P（O） - （O）a-R 1 OH或结构-CH 2 -P（O） - （O）a -R 1 OH，R 6表示任选取代的苯基，羧基或具有结构-P （O） - （O）b -R 2 OH，a和b彼此独立地表示数字0或1，或其盐。

6. 发明授权

US4118435A Catalyzed production of phosphorous and phosphonous acid ester chlorides 失效
标题翻译：催化磷酸亚膦酸酯的生产
公开(公告)号：US4118435A
公开(公告)日：1978-10-03
申请号：US819535
申请日：1977-07-27
申请人： Roland Kleinstuck , Hans-Dieter Block
发明人： Roland Kleinstuck , Hans-Dieter Block
IPC分类号： B01J27/00 , C07B61/00 , C07F9/146 , C07F9/42 , C07F9/48
CPC分类号： C07F9/146 , C07F9/425
摘要： In the production of phosphorous or phosphonous acid ester chlorides of the formulaR.sub.m (R'O).sub.n PCl.sub.3-m-nwhereinR and R' are various organic radicals,m = 0 or 1,n = 1 or 2, andm+n = 1 or 2,By reacting a trialkylphosphite, a triarylphosphite, a dialkylchlorophosphite or a diarylchlorophosphite with phosphorustrichloride, phosphorous acid alkyl ester dichloride, phosphorous acid aryl ester dichloride, or by reacting a dialkyl-phosphonite with dichlorophosphonite, at a temperature between about -10.degree. C and 120.degree. C, the improvement which comprises effecting the reaction in the presence of a catalytic quantity of a compound of at least one of 3- and 5-valent phosphorus, e.g. a phosphine, phosphine oxide, phosphine sulfide, halogen-phosphorane or phosphoric acid-tris-amide. A small amount of an alcohol or dialkalphosphite increases the yield.
摘要翻译：在制备磷或膦酸酯的情况下，式Rm（R'O）nPCl3-mn，其中R和R'为各种有机基团，M = 0 OR 1，N = 1或2，M + N = 1 OR 2，通过用磷酸三氯化磷，磷酸二烷基酯，磷酸三氟乙酸盐，磷酸二苯酯或二氯磷酸盐反应二氢氯磷酸盐，在-10℃下反应，形成三磷酸盐，二氢氯磷酸盐，二氢氯磷酸盐或二氢氯磷酸盐和120℃，其改进包括在催化量的3-和5-价磷中的至少一种的化合物存在下进行反应，例如膦，氧化膦，硫化膦，卤素 - 正膦或磷酸 - 三 - 酰胺。少量的酒精或二亚磷酸酯提高产量。

7. 发明授权

US5525257A Composition for water treatment containing polyaspartic acidora derivative thereof and a polcarboxylic acid and methods of using the composition 失效
标题翻译：含有聚天冬氨酸或其衍生物和多元羧酸的水处理组合物和使用该组合物的方法
公开(公告)号：US5525257A
公开(公告)日：1996-06-11
申请号：US320004
申请日：1994-10-07
申请人： Roland Kleinstuck , Hermann Sicius , Torsten Groth , Winfreid Joentgen
发明人： Roland Kleinstuck , Hermann Sicius , Torsten Groth , Winfreid Joentgen
IPC分类号： C02F5/10 , C02F5/12 , C08L33/00 , C08L77/00 , C08L77/04 , C09K8/04 , C09K8/528 , C09K8/54 , C09K15/22 , C23F11/173 , C23F14/02 , C02F5/00
CPC分类号： C23F11/173 , C02F5/10 , C02F5/12 , C09K8/528 , C09K8/54
摘要： An improved composition for water treatment and for alkaline cleaning contains polyaspartic acid or a derivative thereof and a polycarboxylic acid.
摘要翻译：用于水处理和碱性清洁的改进的组合物包含聚天冬氨酸或其衍生物和多元羧酸。

8. 发明授权

US5523023A Water treatment/cleaning composition comprising polyaspartic acid or derivatives thereof and phosphonic acid 失效
标题翻译：包含聚天冬氨酸或其衍生物和膦酸的水处理/清洁组合物
公开(公告)号：US5523023A
公开(公告)日：1996-06-04
申请号：US319994
申请日：1994-10-07
申请人： Roland Kleinstuck , Hermann Sicius , Torsten Groth , Winfried Joentgen
发明人： Roland Kleinstuck , Hermann Sicius , Torsten Groth , Winfried Joentgen
IPC分类号： C02F5/12 , C02F5/14 , C09K8/528 , C09K8/54 , C10G21/20 , C10G21/24 , C11D3/36 , C11D3/37 , C23F11/10 , C23F11/167 , C23F11/173 , C11D3/28 , C11D3/33
CPC分类号： C23F11/10 , C02F5/12 , C02F5/14 , C09K8/528
摘要： An improved composition for water treatment and for alkaline cleaning contains polyaspartic acid or a derivative thereof and a phosphonic acid.
摘要翻译：用于水处理和碱性清洁的改进的组合物包含聚天冬氨酸或其衍生物和膦酸。

9. 发明授权

US4623672A Isocyanate addition products and a process for their production 失效
标题翻译：异氰酸酯加成产物及其生产工艺
公开(公告)号：US4623672A
公开(公告)日：1986-11-18
申请号：US762166
申请日：1985-08-05
申请人： Roland Kleinstuck , Rolf Wiedermann
发明人： Roland Kleinstuck , Rolf Wiedermann
IPC分类号： C08G18/00 , C08G18/02 , C08K5/49 , C08K5/5333 , C08L75/00 , C08L75/04 , C08G18/38 , C08G18/14
CPC分类号： C08K5/5333 , Y10S521/906
摘要： Flame retardant isocyanate addition products are made by reacting an isocyanate with a compound selected from the group consisting of 1-phosphonoethane-2-carboxylic acid-tri-C.sub.1 -C.sub.4 -alkyl esters, 1-phosphonopropane-2-carboxylic acid-tri-C.sub.1 -C.sub.4 -alkyl esters and mixtures thereof. Known isocyanate-reactive compounds, blowing agents, catalysts, additives and auxiliary agents may optionally be included in the reaction mixture. These flame retardant products are useful in construction applications such as insulation panels for roof insulation.
摘要翻译：阻燃异氰酸酯加成产物通过异氰酸酯与选自1-膦酰基乙烷-2-羧酸 - 三-C1- C4-烷基酯，1-膦酰基丙烷-2-羧酸 - 三-C1 -C 1-4 - 烷基酯及其混合物。已知的异氰酸酯反应性化合物，发泡剂，催化剂，添加剂和辅助剂可以任选地包括在反应混合物中。这些阻燃产品可用于建筑应用，如屋顶保温隔热板。

10. 发明授权

US5726280A Sulfonic acid group-containing polyaspartic acid derivatives, use thereof and prepartion thereof 失效
标题翻译：含磺酸基的聚天冬氨酸衍生物，其用途及其制备
公开(公告)号：US5726280A
公开(公告)日：1998-03-10
申请号：US628929
申请日：1996-04-08
申请人： Hermann Uhr , Lutz Heuer , Torsten Groth , Winfried Joentgen , Roland Kleinstuck
发明人： Hermann Uhr , Lutz Heuer , Torsten Groth , Winfried Joentgen , Roland Kleinstuck
IPC分类号： C02F5/12 , C08G73/10 , C11D3/37 , C08G69/00 , C11D3/08
CPC分类号： C02F5/12 , C08G73/1092 , C11D3/3719
摘要： Sulfonic acid group-containing polyaspartic acid derivatives, some of which are novel, having repeating units of the structures I and II ##STR1## in which ##STR2## are suitable for water treatment and as a detergent additive.
摘要翻译：含有磺酸基的聚天冬氨酸衍生物，其中一些是新型的，具有结构I和II（I）的重复单元，如果合适的话，其中含有洗涤剂添加剂。

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