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11. 发明授权

US06784278B2 Polycarbonates, polyester carbonates and polyesters having branched terminal groups 失效
标题翻译：聚碳酸酯，聚酯碳酸酯和具有支链端基的聚酯
公开(公告)号：US06784278B2
公开(公告)日：2004-08-31
申请号：US10167203
申请日：2002-06-11
申请人： Helmut-Werner Heuer , Rolf Wehrmann , Alexander Meyer , Harald Pielartzik , Friedrich-Karl Bruder , Jos M. J. Paulusse
发明人： Helmut-Werner Heuer , Rolf Wehrmann , Alexander Meyer , Harald Pielartzik , Friedrich-Karl Bruder , Jos M. J. Paulusse
IPC分类号： C08G6400
CPC分类号： C08G63/64 , C07C43/295 , C07C49/83 , C07C69/88 , C07C69/90 , C07C2601/18 , C07C2601/20 , C08G63/20 , C08G64/14
摘要： The use of phenols having a branched structure as terminal groups in polycarbonates, polyester carbonates and polyesters is disclosed. Also disclosed are polycarbonates, polyester carbonates and polyesters having such branched terminal groups, the process for their production and molded parts made therefrom.
摘要翻译：公开了在聚碳酸酯，聚酯碳酸酯和聚酯中使用具有支化结构作为端基的酚。还公开了聚碳酸酯，聚酯碳酸酯和具有这种支化端基的聚酯，其制备方法和由其制成的模塑部件。

12. 发明授权

US5693722A Method for modifying the backbone of polymeric resins 失效
标题翻译：改性聚合物树脂骨架的方法
公开(公告)号：US5693722A
公开(公告)日：1997-12-02
申请号：US764377
申请日：1996-12-13
申请人： Duane B. Priddy, Jr. , Burkhard Kohler , Robert J. Kumpf , Harald Pielartzik
发明人： Duane B. Priddy, Jr. , Burkhard Kohler , Robert J. Kumpf , Harald Pielartzik
IPC分类号： C08G63/64 , C08G64/14 , C08G64/30 , C08F20/00
CPC分类号： C08G64/30 , C08G63/64 , C08G64/14
摘要： A process is disclosed whereby a polymeric resin (containing ester and/or carbonate bonds) is readily converted into a resin having a modified molecular structure. Accordingly, a polycyclic carbonate (a monomer or oligomer) is transesterified with the polymer resin in the melt, preferably upon extrusion, optionally in the presence of a catalyst. Significantly, the cyclic carbonates are, by the inventive process, inserted into the structure of the polymer, effecting branching of the molecular structure, a branching which manifests itself in the modified properties of the resin.
摘要翻译：公开了一种方法，其中聚合物树脂（含有酯和/或碳酸酯键）容易转化为具有改性分子结构的树脂。因此，多烯碳酸酯（单体或低聚物）优选在挤出时，任选地在催化剂存在下，与聚合物树脂在熔体中酯交换。重要的是，通过本发明的方法，环状碳酸酯被插入到聚合物的结构中，实现分子结构的支化，其表现为树脂的改性特性。

13. 发明授权

US5529739A Process for the production of molded products using internal mold release agents 失效
标题翻译：使用内部脱模剂生产成型产品的方法
公开(公告)号：US5529739A
公开(公告)日：1996-06-25
申请号：US339854
申请日：1994-11-15
申请人： Erik H. Jonsson , Harald Pielartzik , Kristen L. Parks , Randall C. Rains
发明人： Erik H. Jonsson , Harald Pielartzik , Kristen L. Parks , Randall C. Rains
IPC分类号： B29C45/00 , B29C33/60 , B29C67/24 , B29K75/00 , B29C45/83
CPC分类号： B29C67/246 , B29C33/60 , B29K2075/00
摘要： The present invention is directed to an improved internal mold release system for the production of high density molded SRIM parts, i.e. molded parts having a density of from 1.3 to 2.0 g/cc. In particular, the process involves reacting a reaction mixture comprising an organic polyisocyanate and at least one organic compound containing isocyanate-reactive hydrogens in the presence of a catalyst and an internal mold release agent in a closed mold. The internal mold release agent is a compound corresponding to the formula: ##STR1## wherein R.sup.2 represents hydrogen, the group R.sup.5 --NH--CO--, or a C.sub.1 to C.sub.24 alkyl or substituted alkyl group, a C.sub.3 to C.sub.24 cycloalkyl or substituted cycloalkyl group, a C.sub.2 to C.sub.24 alkenyl or substituted alkenyl group, or a C.sub.6 to C.sub.24 aryl or substituted aryl group, andwherein R.sup.1, R.sup.3, R.sup.4 and R.sup.5 may be the same or different and represent a C.sub.1 to C.sub.24 alkyl or substituted alkyl group, a C.sub.3 to C.sub.24 cycloalkyl or substituted cycloalkyl group, a C.sub.2 to C.sub.24 alkenyl or substituted alkenyl group, or a C.sub.6 to C.sub.24 aryl or substituted aryl group,with the proviso that at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is a C.sub.12 to C.sub.24 alkyl or substituted alkyl group, or a C.sub.12 to C.sub.24 alkenyl or substituted alkenyl group, and with the further proviso that substituent groups are inert toward isocyanate groups at temperatures of 100.degree. C. or less.
摘要翻译：本发明涉及用于生产高密度模制SRIM部件的改进的内部脱模系统，即密度为1.3-2.0g / cc的模塑部件。特别地，该方法包括使反应混合物包含有机多异氰酸酯和至少一种含有异氰酸酯反应性氢的有机化合物在催化剂和内部脱模剂存在下在封闭模具中反应。内部脱模剂是对应于下式的化合物：其中R 2表示氢，R5-NH-CO-或C 1至C 24烷基或取代的烷基，C 3至C 24环烷基或取代的环烷基 C2-C24烯基或取代烯基，或C6-C24芳基或取代芳基，其中R1，R3，R4和R5可以相同或不同，表示C1至C24烷基或取代的烷基， C 3至C 24环烷基或取代的环烷基，C 2至C 24烯基或取代的烯基或C 6至C 24芳基或取代的芳基，条件是R 1，R 2，R 3，R 4和R 5中的至少一个为C 12 C 24烷基或取代的烷基，或C 12〜C 24链烯基或取代的链烯基，进一步的条件是取代基在100℃或更低的温度下对异氰酸酯基团是惰性的。

14. 发明授权

US5342905A Process for making an ester containing polyether sulfone 失效
标题翻译：制备含聚醚砜的酯的方法
公开(公告)号：US5342905A
公开(公告)日：1994-08-30
申请号：US10736
申请日：1993-01-29
申请人： Robert J. Kumpf , Aaron D. Meltzer , Harald Pielartzik
发明人： Robert J. Kumpf , Aaron D. Meltzer , Harald Pielartzik
IPC分类号： C08G75/23 , C08G63/688 , C08G65/48 , C08G75/00 , C08G75/20 , C08G8/02 , C08G69/32
CPC分类号： C08G75/20 , C08G63/6886 , C08G65/48
摘要： A two step process for the preparation of an ester group-containing polyether sulfone is disclosed. In the first step a dihalogenodiphenyl sulfone is reacted with excess amount of an aromatic dihydroxy compound and in a second step the reaction product is reacted with a dicarboxylic acid derivative. The excess amount of the aromatic dihydroxy compound is that amount which is sufficient to react with said derivative to form the corresponding ester. The process of the invention is characterized by its economics and good yield and by the high purity of the product. The thus produced polyether sulfone is useful as a thermoplastic resin and as a reactant in the melt blending process for the preparation of block copolymers.
摘要翻译：公开了制备含酯基的聚醚砜的两步法。在第一步中，二卤代二苯砜与过量的芳族二羟基化合物反应，第二步反应产物与二羧酸衍生物反应。过量的芳族二羟基化合物是足以与所述衍生物反应形成相应酯的量。本发明的方法的特征在于其经济性和良好的产率以及高纯度的产品。由此制备的聚醚砜可用作热塑性树脂和用作制备嵌段共聚物的熔融共混方法中的反应物。

15. 发明授权

US5328977A Polymerization catalyst for the preparation of poly(isocyanates) 失效
标题翻译：用于制备聚（异氰酸酯）的聚合催化剂
公开(公告)号：US5328977A
公开(公告)日：1994-07-12
申请号：US151227
申请日：1993-11-12
申请人： Aaron D. Meltzer , Gary W. Munko , Harald Pielartzik
发明人： Aaron D. Meltzer , Gary W. Munko , Harald Pielartzik
IPC分类号： C08G18/02 , C08G69/00 , C08G18/22
CPC分类号： C08G18/02 , C08G69/00
摘要： An improvement in the process of preparing nylon-1 by the polymerization of isocyanates is disclosed. Accordingly, the improvement comprising using in the process a catalyst conforming to(X).sub.n Me(OR).sub.mwhere Me is titanium or zirconium, X is chlorine or bromine atom, R is an aliphatic radical having 1 to 20 carbon atoms and where the sum of m=n is 4 with the proviso that where Me is titanium n is 1 or 2, and where Me is zirconium n is 1-4.
摘要翻译：公开了通过异氰酸酯聚合制备尼龙-1的方法的改进。因此，改进包括在该方法中使用符合（X）nMe（OR）m的催化剂，其中Me是钛或锆，X是氯或溴原子，R是具有1至20个碳原子的脂族基团，其中总和 m = n为4，条件是Me为钛，n为1或2，Me为锆，n为1-4。

16. 发明授权

US06670406B2 Process for producing polyether polyols 有权
标题翻译：制备聚醚多元醇的方法
公开(公告)号：US06670406B2
公开(公告)日：2003-12-30
申请号：US10077855
申请日：2002-02-19
申请人： Jörg Hofmann , Stephan Ehlers , Bernd Klinksiek , Bert Klesczewski , Christian Steinlein , Lars Obendorf , Harald Pielartzik , Jose F. Pazos
发明人： Jörg Hofmann , Stephan Ehlers , Bernd Klinksiek , Bert Klesczewski , Christian Steinlein , Lars Obendorf , Harald Pielartzik , Jose F. Pazos
IPC分类号： C07C4311
CPC分类号： B01J19/2465 , C08G65/2663 , C08G65/2696
摘要： The present invention relates to a process for the production of a polyether polyol by polyaddition of an alkylene oxide onto a starter compound containing active hydrogen atoms conducted in the presence of a double metal cyanide catalyst comprising conducting a reaction mixture at least once through a zone which has an energy density of at least 5×106 J/m3, wherein the dwell time of the reaction mixture in this zone is at least 10−6 seconds per pass.
摘要翻译：本发明涉及一种生产聚醚多元醇的方法，该方法是通过在双金属氰化物催化剂的存在下将烯化氧加成到含有活性氢原子的起始化合物上，包括将反应混合物至少一次通过一个具有至少5×10 6 J / m 3的能量密度，其中该区域中反应混合物的停留时间为每次通过至少10 -6秒。

17. 发明授权

US06458918B1 Method for producing partially crystalline polyether polyols 失效
标题翻译：部分结晶聚醚多元醇的制备方法
公开(公告)号：US06458918B1
公开(公告)日：2002-10-01
申请号：US09530304
申请日：2000-04-27
申请人： Walter Schäfer , Jörg Hofmann , Pramod Gupta , Hanns-Peter Müller , Harald Pielartzik
发明人： Walter Schäfer , Jörg Hofmann , Pramod Gupta , Hanns-Peter Müller , Harald Pielartzik
IPC分类号： C08G6512
CPC分类号： C08G65/269 , B01J31/068 , B01J31/165 , B01J31/2226 , B01J2231/48 , B01J2531/0216 , B01J2531/0219 , B01J2531/26 , B01J2531/31 , B01J2531/46 , B01J2531/62 , B01J2531/64 , B01J2531/70 , B01J2531/842 , B01J2531/845 , C08G65/12 , C08G65/2642 , C08G2250/00
摘要： The present invention relates to a process for the preparation of novel, partially crystalline polyether polyols with a functionality of ≧2, an average molecular weight Mn of 500 to 100,000 and a molar proportion of isotactic triads determining the crystallinity of >28%. The new polyether polyols are prepared by polymerizing alkylene oxides in the presence of a bimetallic :-oxoalkoxide modified with hydroxyl compounds.
摘要翻译：本发明涉及一种制备具有官能度> = 2，平均分子量Mn为500至100,000的新型部分结晶的聚醚多元醇和确定结晶度> 28％的全同立构三单元组的摩尔比例的方法。新的聚醚多元醇通过在用羟基化合物改性的双金属氧化物存在下聚合烯化氧来制备。

18. 发明授权

US06297346B1 Mixtures of cyclic oligocarbonates, their production and use 失效
标题翻译：环状寡聚碳酸酯的混合物，其生产和使用
公开(公告)号：US06297346B1
公开(公告)日：2001-10-02
申请号：US09572465
申请日：2000-05-17
申请人： Burkhard Köhler , Duane Priddy, Jr. , Yun Chen , Harald Pielartzik , Robert Kumpf
发明人： Burkhard Köhler , Duane Priddy, Jr. , Yun Chen , Harald Pielartzik , Robert Kumpf
IPC分类号： C08G6400
CPC分类号： C08G64/22
摘要： The present invention relates to mixtures of cyclic oligocarbonates, to their production by way of mixtures of bischloroformates, and to their use for the production of linear polycarbonates and for the modification of other linear polycarbonates.
摘要翻译：本发明涉及环状寡聚碳酸酯的混合物，其通过双氯甲酸酯的混合物的生产，以及它们用于生产线性聚碳酸酯和改性其它线性聚碳酸酯的用途。

19. 发明授权

US6156871A Mixtures of cyclic oligocarbonates, their production and use 失效
标题翻译：环状寡聚碳酸酯的混合物，其生产和使用
公开(公告)号：US6156871A
公开(公告)日：2000-12-05
申请号：US923848
申请日：1997-09-04
申请人： Burkhard Kohler , Duane Priddy, Jr. , Yun Chen , Harald Pielartzik , Robert Kumpf
发明人： Burkhard Kohler , Duane Priddy, Jr. , Yun Chen , Harald Pielartzik , Robert Kumpf
IPC分类号： C07C68/02 , C07C69/96 , C08G64/04 , C08G64/06 , C08G64/26 , C08G64/30 , C08G64/00
CPC分类号： C07C69/96 , C08G64/06 , C08G64/26 , C08G64/30
摘要： The present invention relates to mixtures of cyclic oligocarbonates, to their production by way of mixtures of bischloroformates, and to their use for the production of linear polycarbonates and for the modification of other linear polycarbonates.
摘要翻译：本发明涉及环状寡聚碳酸酯的混合物，其通过双氯甲酸酯的混合物的生产，以及它们用于生产线性聚碳酸酯和改性其它线性聚碳酸酯的用途。

20. 发明授权

US5633389A Thermoreversible coating and a process for its manufacture 失效
标题翻译：热可逆涂层及其制造工艺
公开(公告)号：US5633389A
公开(公告)日：1997-05-27
申请号：US448847
申请日：1995-05-24
申请人： Erik H. Jonsson , Philip E. Yeske , Douglas A. Wicks , Harald Pielartzik
发明人： Erik H. Jonsson , Philip E. Yeske , Douglas A. Wicks , Harald Pielartzik
IPC分类号： C07D233/72 , C07D233/78 , C08G18/46 , C09D175/00 , C09D175/02
CPC分类号： C07D233/78 , C08G18/4615 , C09D175/00
摘要： The invention relates to a thermoreversible process for the preparation of a hydantoin comprisng(a) reacting an unsaturated polyester with a monofunctional amine to yield a poly(ester aspartate), and(b) reacting said poly(ester aspartate) with an isocyanate to produce a poly(ester urea), and(c) heating said poly(ester urea) to form a hydantoin compound.The process is useful for the preparation of coatings.
摘要翻译：本发明涉及一种用于制备乙内酰脲的热可逆方法，其包括（a）使不饱和聚酯与单官能胺反应以产生聚（酯天冬氨酸酯），和（b）使所述聚（酯天冬氨酸酯）与异氰酸酯反应以产生聚（酯尿素），和（c）加热所述聚（酯脲）以形成乙内酰脲化合物。该方法可用于制备涂料。

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