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11. 发明授权

US06818205B2 Use of fluorescent whitening agents 失效
标题翻译：使用荧光增白剂
公开(公告)号：US06818205B2
公开(公告)日：2004-11-16
申请号：US10149396
申请日：2002-06-11
申请人： Dieter Reinehr , Helmut Luther , Georges Metzger
发明人： Dieter Reinehr , Helmut Luther , Georges Metzger
IPC分类号： A61K742
CPC分类号： A61Q19/02 , A61K8/466 , A61K8/49 , A61K8/494 , A61K8/4966 , A61K8/498 , A61K8/731 , A61K8/732 , A61K8/8147 , A61K8/8158 , A61K2800/434 , A61Q17/04
摘要： The use of a polymeric carrier material treated with a fluorescent whitening agent, for lightening human skin and for protecting human skin against UV radiation, is described.
摘要翻译：描述了使用用荧光增白剂处理的聚合物载体材料，用于减轻人体皮肤和保护人体皮肤免受紫外线辐射。

12. 发明授权

US06528469B2 Fabric bleaching composition 失效
标题翻译：织物漂白组合物
公开(公告)号：US06528469B2
公开(公告)日：2003-03-04
申请号：US09077047
申请日：1998-10-13
申请人： Dieter Reinehr , Georges Metzger
发明人： Dieter Reinehr , Georges Metzger
IPC分类号： C11D300
CPC分类号： C11D3/3932 , D06L4/12
摘要： A fabric bleaching composition comprising a peroxy compound and a specified manganese compound is disclosed, as well as a process for bleaching and/or cleaning a fabric by contacting it with said fabric bleaching composition.
摘要翻译：公开了包含过氧化合物和特定锰化合物的织物漂白组合物，以及通过使其与所述织物漂白组合物接触来漂白和/或清洁织物的方法。

13. 发明授权

US06458169B2 Fluorescent whitening agents 失效
标题翻译：荧光增白剂
公开(公告)号：US06458169B2
公开(公告)日：2002-10-01
申请号：US09767112
申请日：2001-01-22
申请人： Peter Rohringer , Georges Metzger , Dieter Reinehr
发明人： Peter Rohringer , Georges Metzger , Dieter Reinehr
IPC分类号： C07D25100
CPC分类号： C09B23/148 , C07D251/68 , C11D3/42 , D06L4/621 , D06L4/657 , D06L4/75 , D06M13/07 , D06M13/358 , D06P1/6426 , D21H21/30 , Y10S8/919
摘要： The present invention provides new compounds having the formula: in which X is O or, preferably, NH; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; n is 1 or 2; and each R2, independently, is hydrogen, C1-C3alkyl, halogen, cyano, COOR in which R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, SO3M in which M has its previous significance or, when n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl; provided that those compounds are excluded in which a) X is NH, n is 1 and R2 is SO3M in which M has its previous significance; or b) X is NH, n is 2 and one R2 is SO3M in which M has its previous significance, and the other R2 is hydrogen, methyl or halogen; or c) X is NH, n is 1, R1 is glycine and R2 is H or CO2H; or d) X is NH, n is 2, each R2 is SO3M in which M has its previous significance and the SO3M groups are in 2,5-positions in the phenyl ring and R1 is D,L-alanine, L-valine, L-leucine, L-isoleucine, L-threonine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-proline, D,L-methionine or glycine. Most of the new class of 4,4′-diaminostilbene-2,2′-disulfonic acid compounds are useful as fluorescent whitening agents, especially for paper.
摘要翻译：本发明提供了新的具有下式的化合物：其中X为O或优选为NH; M是氢，碱金属原子，铵或由胺形成的阳离子; 每个R 1独立地是氨基酸被除去的氨基酸残基; n为1或2; 并且每个R 2独立地是氢，C 1 -C 3烷基，卤素，氰基，其中R是氢或C 1 -C 3烷基的COOR，其中R具有其先前含义的CONH-R，其中R具有其先前含义的SO 2 NH- 其中R具有其先前意义的NH-COR，其中M具有其先前含义的SO 3 M，或当n为1时，R 2也可以是其中R 3为C 1 -C 3烷基或苯基的CO-R 3;条件是将这些化合物排除在哪一个）X是NH，n是1，R2是SO3M，其中M具有其先前的意义; 环）X是NH，n是2，一个R2是SO3M，其中M具有其先前的意义，另一个R 2是氢，甲基或卤素; orc）X是NH，n是1，R1是甘氨酸，R2是H或CO2H; ord）X是NH，n是2，每个R2是SO3M，其中M具有其先前的意义，SO3M基团在苯环中是2,5位，R1是D，L-丙氨酸，L-缬氨酸，L L-亮氨酸，L-异亮氨酸，L-苏氨酸，L-天冬氨酸，L-谷氨酸，L-苯丙氨酸，L-脯氨酸，D，L-甲硫氨酸或甘氨酸。新的4,4'-二氨基芪 - 2,2'-二磺酸化合物可用作荧光增白剂，特别是用于纸。

14. 发明授权

US6040443A Process for the production of benzoxazinones 失效
标题翻译：生产苯并恶嗪酮的方法
公开(公告)号：US6040443A
公开(公告)日：2000-03-21
申请号：US119300
申请日：1998-07-20
申请人： Georges Metzger , Dieter Reinehr , Serge Hauger
发明人： Georges Metzger , Dieter Reinehr , Serge Hauger
IPC分类号： C07D265/22 , C07D265/02
CPC分类号： C07D265/22
摘要： There is described a process for the production of a 1,3-benzoxazin-4-one having the formula: ##STR1## in which R.sub.1 and R.sub.2, independently, are hydrogen, cyano, halogen, nitro, C.sub.1 -C.sub.20 alkyl, O--C.sub.1 -C.sub.20 alkyl, phenyl, NH--CO--C.sub.1 -C.sub.20 alkyl, N(R.sub.3).sub.2, SO.sub.2 N(R.sub.3).sub.2, COOR.sub.3 or CON(R.sub.3).sub.2 in which R.sub.3 is hydrogen, cyano, halogen, nitro, C.sub.1 -C.sub.20 alkyl, O--C.sub.1 -C.sub.20 alkyl, phenyl or NH--CO--C.sub.1 -C.sub.20 alkyl, comprising reacting, at elevated temperature, 1 molar equivalent of an o-hydroxybenzamide of formula: ##STR2## in which R.sub.1 has its previous significance, with 2 to 6 molar equivalents of a benzoyl chloride of formula: ##STR3## in which R.sub.2 has its previous significance. The 1,3-benzoxazin-4-ones having the formula (1) so obtained are important intermediates for the production of triazine compounds having excellent absorption spectrum characteristics and good resistance to exposure to UV light.
摘要翻译：描述了制备具有下式的1,3-苯并恶嗪-4-酮的方法：其中R 1和R 2独立地是氢，氰基，卤素，硝基，C 1 -C 20烷基，O-C 1 -C 20烷基，苯基，NH-CO-C 1 -C 20烷基，N（R 3）2，SO 2 N（R 3）2，COOR 3或CON（R 3）2，其中R 3是氢，氰基，卤素，硝基，C 1 -C 20烷基，O-C 1 -C 20烷基苯基或NH-CO-C 1 -C 20烷基，其包括在升高的温度下，将1摩尔当量的具有其先前意义的式的邻羟基苯甲酰胺与2至6摩尔当量的下式的苯甲酰氯反应：其中R2具有以前的意义。具有式（1）的1,3-苯并恶嗪-4-酮是制备具有优异的吸收光谱特性和良好的耐紫外线性的三嗪化合物的重要中间体。

15. 发明申请

US20050038245A1 Naphthyltriazines as stabilizers for organic material 审中-公开
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US20050038245A1
公开(公告)日：2005-02-17
申请号：US10492721
申请日：2002-10-10
申请人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/00 , A61Q19/00 , C07D251/24 , C09K15/30 , A61K7/42 , C07D251/48
CPC分类号： C07D251/24
摘要： Novel compounds of formula (I) are described, wherein E corresponds to the formula (a) or to the formula (b) and the radicals R1, R2, R11, R22, R′22, R33, and R′33 are as defined in claim 1. Compounds of formula (I) are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式（I）化合物，其中E对应于式（a）或式（b），基团R 1，R 2，R 11，R 22，R 22，R 33和R 33如上定义式（I）化合物适于稳定有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，以防止光，氧和/或热的损害。

16. 发明授权

US06468958B2 Biphenyl-substituted triazines 有权
标题翻译：联苯取代三嗪
公开(公告)号：US06468958B2
公开(公告)日：2002-10-22
申请号：US09848013
申请日：2001-05-03
申请人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
发明人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
IPC分类号： C07D25124
CPC分类号： C07D405/04 , A61K8/4966 , A61Q17/04 , C07D251/10 , C07D251/24 , C08K5/3435 , C08K5/3475 , C08K5/3492
摘要： Biphenyl-substituted triazines of the formulae which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
摘要翻译：用于高热稳定性的配方的联苯取代三嗪作为有机聚合物的稳定剂用作抗光，氧和热引起的损伤，作为纺织纤维材料的光稳定剂和用作人体皮肤的防晒剂。

17. 发明授权

US06255483B1 Biphenyl-substituted triazines 有权
标题翻译：联苯取代三嗪
公开(公告)号：US06255483B1
公开(公告)日：2001-07-03
申请号：US09383163
申请日：1999-08-25
申请人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
发明人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
IPC分类号： C07D25124
CPC分类号： C07D405/04 , A61K8/4966 , A61Q17/04 , C07D251/10 , C07D251/24 , C08K5/3435 , C08K5/3475 , C08K5/3492
摘要： Biphenyl-substituted triazines of the formulae which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
摘要翻译：用于高热稳定性的配方的联苯取代三嗪作为有机聚合物的稳定剂用作抗光，氧和热引起的损伤，作为纺织纤维材料的光稳定剂和用作人体皮肤的防晒剂。

18. 发明授权

US06193960B1 Triazine derivatives 失效
标题翻译：三嗪衍生物
公开(公告)号：US06193960B1
公开(公告)日：2001-02-27
申请号：US09544852
申请日：2000-04-06
申请人： Georges Metzger , Dieter Reinehr , Helmut Luther
发明人： Georges Metzger , Dieter Reinehr , Helmut Luther
IPC分类号： A61K742
CPC分类号： C07D251/52 , A61K8/4966 , A61K8/4993 , A61Q17/04 , C07D251/48 , C07D251/50 , C07D251/70
摘要： The present invention relates to novel s-triazine compounds, processes for their preparation and the use of these novel compounds as UV filters in sunscreen compositions. The novel compounds are those of the formula The triazine compounds of the formula (1) according to the invention are distinguished by a high UV absorption and are particularly suitable as UV filters, i.e. for protecting ultra-violet-sensitive organic materials, in particular the skin and the hair of man and animals, from the harmful action of UV radiation.
摘要翻译：本发明涉及新型的三嗪化合物，它们的制备方法以及这些新化合物作为防晒组合物中的紫外线过滤剂的用途。新化合物是下式的那些：根据本发明的式（1）的三嗪化合物是其特征在于高的紫外线吸收，并且特别适用于紫外线过滤器，即用于保护紫外线有害的紫外线辐射有害作用的紫外线敏感有机材料，特别是人和动物的皮肤和头发。

19. 发明申请

US20050169859A1 Naphthyltriazines as stabilizers for organic material 有权
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US20050169859A1
公开(公告)日：2005-08-04
申请号：US11098640
申请日：2005-04-04
申请人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/00 , A61Q19/00 , C07D251/24 , C09K15/30 , A61K7/42 , C07D251/48 , G03C1/005 , G03C1/494
CPC分类号： C07D251/24
摘要： Novel compounds of formula I are described wherein E corresponds to the formula or to the formula and the radicals R1, R2, R11, R22, R′22, R′33 and R′33 are as defined in claim 1. Compounds of formula I are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式I化合物，其中E对应于式或式，基团R 1，R 2，R 11， R 22，R 22，R 33a和R 33如权利要求1中所定义。式I化合物适用于稳定化有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，防止光，氧和/或热的损害。

20. 发明授权

US06143888A Use of triazine-based UVAs for use as quenchers in paper-making processes 失效
标题翻译：在制纸过程中使用三嗪基UVA作为猝灭剂
公开(公告)号：US06143888A
公开(公告)日：2000-11-07
申请号：US194767
申请日：1998-12-02
申请人： Peter Rohringer , Dieter Reinehr , Robert Hochberg , Georges Metzger
发明人： Peter Rohringer , Dieter Reinehr , Robert Hochberg , Georges Metzger
IPC分类号： C07D251/18 , C07D251/14 , C07D251/22 , C07D251/42 , C07D251/48 , C07D251/54 , C07D251/68 , C08K5/3492 , C09B67/00 , C09K3/00 , D06L3/12 , D06M13/358 , D21H21/28 , D21H21/30 , C09K11/06
CPC分类号： D06L3/1214 , C07D251/42 , C07D251/48 , C07D251/54 , D06L3/1207 , D06L3/1257 , D06M13/358 , D21H21/30
摘要： The present invention provides a process for the inhibition (quenching) of the effect of an anionic fluorescent whitening agents on a substrate, comprising treating the substrate with a triazine UVA compound, some of which are new compounds.
摘要翻译： PCT No.PCT / EP97 / 02606 Sec。 371日期1998年12月2日第 102（e）日期1998年12月2日PCT提交1997年5月22日PCT公布。第WO97 / 46541号公报日期1997年12月11日本发明提供了抑制（淬灭）阴离子荧光增白剂对底物的作用的方法，其包括用三嗪UVA化合物处理底物，其中一些是新化合物。

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