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11. 发明授权

US5817878A Process for the acylation of aromatic ethers 失效
标题翻译：芳香醚酰化的方法
公开(公告)号：US5817878A
公开(公告)日：1998-10-06
申请号：US765537
申请日：1997-01-09
申请人： Michel Spagnol , Laurent Gilbert , Eric Benazzi , Christian Marcilly
发明人： Michel Spagnol , Laurent Gilbert , Eric Benazzi , Christian Marcilly
IPC分类号： B01J29/70 , B01J29/04 , C07C45/46 , C07C49/84 , C07C205/04 , C07C211/09 , C07C231/12 , C07C235/32 , C07C253/30 , C07C255/40 , C07C45/45
CPC分类号： B01J29/04 , C07C45/46
摘要： The present invention concerns a process for the acylation of an aromatic ether. Preferably, the invention relates to a process for the acylation of an unsubstituted aromatic ether, in particular anisole. The acylation process of the invention consists of reacting the ether with an acylation agent in the presence of a zeolitic catalyst, and is characterized in that the acylation reaction is carried out in the presence of an effective quantity of a catalyst comprising a beta zeolite with an atomic ratio denoted "global Si/Me.sup.1 " between the number of atoms of the element silicon and the number of atoms of every trivalent element Me.sup.1 contained in the zeolite of no less than 15, preferably in the range 15 to 55, and more preferably in the range 18 to 35.
摘要翻译： PCT No.PCT / FR96 / 00717 Sec。 371日期1997年1月9日 102（e）日期1997年1月9日PCT提交1996年5月10日PCT公布。 WO96 / 35656PC PCT出版物日期：1996年11月14日本发明涉及一种酰化芳族醚的方法。优选地，本发明涉及酰化未取代芳族醚，特别是苯甲醚的方法。本发明的酰化方法包括在沸石催化剂存在下使醚与酰化剂反应，其特征在于酰化反应在有效量的包含β沸石的催化剂存在下进行，原子比在元素硅的原子数与沸石中所含的每个三价元素Me1的原子数之间的“全局Si / Me1”表示为不小于15，优选在15至55的范围内，更优选在范围18到35。

12. 发明授权

US5489730A Catalyst for alkylation of C.sub.4 -C.sub.5 isoparaffin by at least one C.sub.3 -C.sub.6 olefin 失效
标题翻译：用于通过至少一种C 3 -C 6烯烃烷基化C 4 -C 5异链烷烃的催化剂
公开(公告)号：US5489730A
公开(公告)日：1996-02-06
申请号：US304186
申请日：1994-09-12
申请人： Jean Francois Joly , Christian Marcilly , Eric Benazzi , Frederic Chaigne , Jean Yves Bernhard
发明人： Jean Francois Joly , Christian Marcilly , Eric Benazzi , Frederic Chaigne , Jean Yves Bernhard
IPC分类号： B01J27/053 , B01J27/12 , B01J27/182 , C07B61/00 , C07C2/62 , C07C9/16 , C10G35/04 , C10G35/06
CPC分类号： C07C2/62 , B01J27/053 , C07C2521/08 , C07C2527/053 , C07C2527/054
摘要： The present invention relates to a catalyst comprising silica and sulphuric acid which impregnates said silica, and the use of said catalyst in catalytic alkylation of isobutane and/or isopentane in the presence of at least one olefin containing 3 to 6 carbon atoms per molecule, said catalyst being characterized in that the silica, prior to its impregnation with sulphuric acid, has a total porous volume greater than 1.5 cm.sup.3 per gram and in that said catalyst consists essentially of particles of an average diameter of between 0.1 and 150 .mu.m.
摘要翻译：本发明涉及包含二氧化硅和硫酸的催化剂，其浸渍所述二氧化硅，以及所述催化剂在每分子含有3至6个碳原子的至少一种烯烃的存在下催化烷基化异丁烷和/或异戊烷中的用途，所述催化剂的特征在于，二氧化硅在其用硫酸浸渍之前具有大于1.5cm 3 / g的总多孔体积，并且所述催化剂基本上由平均直径为0.1至150μm的颗粒组成。

13. 发明授权

US5444175A Process for the alkylation of paraffins 失效
标题翻译：烷烃烷基化方法
公开(公告)号：US5444175A
公开(公告)日：1995-08-22
申请号：US109566
申请日：1993-08-20
申请人： Jean-Francois Joly , Eric Benazzi , Christian Marcilly , Renaud Pontier , Jean-Francois Le Page
发明人： Jean-Francois Joly , Eric Benazzi , Christian Marcilly , Renaud Pontier , Jean-Francois Le Page
IPC分类号： B01J29/06 , C07B61/00 , C07C2/60 , C07C2/62 , C07C9/16 , C10G35/06 , C10L1/04 , C07C2/58
CPC分类号： C07C2/62 , C07C2/60 , C07C2521/08 , C07C2527/054 , C07C2531/025
摘要： The invention relates to an alkylation process, in which a charge incorporating at least one isoparaffin and at least one olefin containing 2 to 6 carbon atoms per molecule, is treated in the presence of a solid alkylation catalyst. In the process, catalyst present in a reaction R is contacted with the charge, recycled liquid effluent discharged from reaction zone R and liquid effluent discharged from an isobutane/n-butane/alkylate separation zone S. The process uses a specific catalyst, e.g., sulfuric acid impregnated on a porous support.
摘要翻译：本发明涉及一种烷基化方法，其中在固体烷基化催化剂存在下处理含有至少一种异链烷烃和至少一种每分子含有2-6个碳原子的烯烃的电荷。在该过程中，反应R中存在的催化剂与从反应区R排放的电荷，再循环液体流出物和从异丁烷/正丁烷/烷基化物分离区S排出的液体流出物接触。该方法使用特定的催化剂，浸渍在多孔载体上的硫酸。

14. 发明授权

US5336833A Catalyst based on silica and sulphuric acid and its use for the alkylation of paraffins 失效
标题翻译：基于二氧化硅和硫酸的催化剂及其用于烷烃烷基化的用途
公开(公告)号：US5336833A
公开(公告)日：1994-08-09
申请号：US966648
申请日：1992-10-26
申请人： Jean-Francois Joly , Christian Marcilly , Eric Benazzi
发明人： Jean-Francois Joly , Christian Marcilly , Eric Benazzi
IPC分类号： B01J21/08 , B01J27/02 , B01J27/053 , B01J27/06 , B01J31/02 , B01J37/02 , C07B61/00 , C07C2/58 , C07C2/62 , C07C9/16
CPC分类号： B01J21/08 , B01J27/02 , B01J27/053 , B01J27/06 , B01J31/0227 , C07C2/62 , B01J2231/323 , B01J37/0201 , C07C2521/02 , C07C2521/08 , C07C2527/02 , C07C2527/054 , C07C2527/133 , C07C2531/025
摘要： Impregnated catalyst based on silica and a solid state sulfuric acid and its use in the catalytic alkylation of isobutene and/or isopentane in the presence of at least one olefin having 3-6 carbon atoms per molecule. The catalyst may contain an additive, e.g., B(OH).sub.3, HBF.sub.4, H.sub.3 PO.sub.4, FSO.sub.3 H, CF.sub.3 SO.sub.3 H, SbF.sub.5, CF.sub.3 COOH, and SO.sub.3.
摘要翻译：基于二氧化硅和固态硫酸的浸渍催化剂及其在每分子具有3-6个碳原子的至少一种烯烃的存在下在异丁烯和/或异戊烷的催化烷基化中的用途。催化剂可以含有添加剂，例如B（OH）3，HBF 4，H 3 PO 4，FSO 3 H，CF 3 SO 3 H，SbF 5，CF 3 COOH和SO 3。

15. 发明授权

US5132479A Mordenite-based catalyst containing at least one metal from group VIII and its use for isomerizing a C.sub.8 aromatic fraction 失效
$Mordenite-based catalyst containing at least one metal from group VIII and its use for isomerizing a C.sub.8 aromatic fraction$
标题翻译：含有至少一种金属的基于MORDENITE的催化剂，由VIII族及其用于同位素化C8芳族化合物
公开(公告)号：US5132479A
公开(公告)日：1992-07-21
申请号：US786865
申请日：1991-11-01
申请人： Christine Travers , Francis Raatz , Christian Marcilly
发明人： Christine Travers , Francis Raatz , Christian Marcilly
IPC分类号： B01J29/20 , B01J29/22 , B01J35/00 , C07B61/00 , C07C5/27 , C07C15/08 , C10G45/64
CPC分类号： C10G45/64 , B01J29/20 , B01J29/22 , C07C5/2724 , B01J2229/16 , B01J2229/37 , B01J2229/40 , B01J2229/42 , B01J35/002
摘要： The invention relates to a catalyst for isomerizing a C.sub.8 aromatic fraction containing a mordenite and at least one metal from group VIII of the periodic classification of elements (such as Pt or Pd), characterized in that the mordenite is such that its skeleton Si/Al atomic ratio is between 6 and 10.5, its sodium weight content is below 2000 ppm, its unit cell volume is between 2.73 and 2.78 nm.sup.3, its benzene adsorption capacity is between 4 and 10% based on the dry mordenite weight and its 1,3,5-trimethylbenzene adsorption capacity is between 0.5 and 2.5% by weight based on the dry mordenite weight. The invention also relates to the preparation of said mordenite.

16. 发明授权

US4766099A Catalyst for oil hydrorefining or mild hydrocracking of heavy oil charges to produce middle distillates 失效
标题翻译：用于油加氢精制或轻度加氢裂化重油装料以生产中间馏分的催化剂
公开(公告)号：US4766099A
公开(公告)日：1988-08-23
申请号：US860927
申请日：1986-05-08
申请人： Pierre Dufresne , Christian Marcilly
发明人： Pierre Dufresne , Christian Marcilly
IPC分类号： C10G47/12 , B01J21/16 , B01J27/128 , B01J27/132 , B01J29/04 , C10G49/02
CPC分类号： B01J29/049 , B01J21/16 , C10G49/02 , B01J2229/42
摘要： The invention concerns a catalyst comprising:(a) a carrier containing at least 20% by weight of a fluorinated bridged clay of the smectite group,(b) an amorphous matrix containing at least 10% by weight of alumina, and(c) at least one group VIII metal or metal compound or an association of at least one group VI B metal or metal compound with at least one metal or compound of a metal selected from group VIII non-noble metal. The metals amount, calculated as oxide(s), in proportion to the final catalyst weight, is from 0.01 to 5% for the group VIII noble metals, from 0.01 to 20% for group VIII non-noble metals and from 5 to 40% for the association of group VI B metals with group VII non-noble metals.The carrier amount is such that the florinated bridged clay content of the final catalyst is at least 12% by weight; the matrix amount forms the complement to 100% by weight of the catalyst.The catalysts according to the invention can be used for mild hydrocracking operations having as an object improving the viscosity of the lubricating oils and hydrocracking of heavy oil cuts so as to obtain middle distillates: kerosene and gas oils
摘要翻译：本发明涉及一种催化剂，其包含：（a）载体，其含有至少20重量％的蒙皂石基团的氟化桥接粘土，（b）含有至少10重量％氧化铝的无定形基质，和（c）至少一种VIII族金属或金属化合物或至少一种VIB族金属或金属化合物与至少一种选自第VIII族非贵金属的金属或化合物的缔合。与最终催化剂重量成比例的氧化物计算的金属量，对于VIII族贵金属为0.01〜5％，对于VIII族非贵金属为0.01〜20％，为5〜40％第VIB族金属与第VII族非贵金属的结合。载体量使得最终催化剂的桥连粘土含量至少为12重量％基质量与催化剂的100重量％形成补体。根据本发明的催化剂可用于温和的加氢裂化操作，其作为改善润滑油的粘度和重油馏分的加氢裂化的目的，以获得中间馏分：煤油和瓦斯油

17. 发明授权

US4738941A Hydrocracking catalyst for the production of middle distillates 失效
标题翻译：用于生产中间馏分的加氢裂化催化剂
公开(公告)号：US4738941A
公开(公告)日：1988-04-19
申请号：US041946
申请日：1987-04-24
申请人： Pierre Dufresne , Christian Marcilly
发明人： Pierre Dufresne , Christian Marcilly
IPC分类号： C10G47/18 , B01J29/06 , B01J29/10 , C10G47/16
CPC分类号： B01J29/106 , C10G47/16
摘要： The invention relates to a new hydrocarbon hydroconversion catalyst, which is a mixture of an amorphous matrix, a zeolite and at least one metal of Group VIII and optionally of Group VI, the zeolite having a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of about between 8 and 70, a sodium content of less than 0.15% by weight, a unit mesh parameter a.sub..degree. of between 24.55 and 24.24.times.10.sup.-10 m, a sodium ion recovery capacity C.sub.Na, expressed in grams of sodium per 100 grams of modified zeolite, greater than 0.85, a specific surface area greater than 400 m.sup.2 g.sup.-1, a water vapor adsorption capacity at 25.degree. C. (with a P/Po ratio of 0.10) greater than 6% by weight, a pore distribution between 1 and 20% of the pore volume contained essentially in pores of diameters between 20 and 80.times.10.sup.-10m, the remaining pore volume being contained essentially in pores of diameters less than 20.times.10.sup.-10 m, the matrix being characterized by the following textural properties:S.gtoreq.100 m.sup.2.g.sup.-1Vpt.gtoreq.0.4 cm.sup.3.g.sup.-1V.sub.75 .gtoreq.0.25 cm.sup.3.g.sup.-1V.sub.75 /Vpt.gtoreq.0.5.
摘要翻译：本发明涉及一种新的烃加氢转化催化剂，其是无定形基体，沸石和至少一种第VIII族金属和任选的第VI族的混合物，SiO 2 / Al 2 O 3摩尔比约为8至70的沸石，钠含量小于0.15重量％，单位网格参数a DEG在24.55和24.24x10-10微米之间，钠离子回收能力CNa以每克克改变的沸石表示的钠，大于0.85 ，比表面积大于400m2g-1，25℃下的水蒸汽吸附容量（P / Po比为0.10）大于6重量％，孔隙分布在孔的1〜20％体积基本上包含在20至80×10 -10 m之间的直径的孔中，剩余的孔体积基本上包含在小于20×10 -10 m的直径的孔中，该基质的特征在于以下织构性质：S> = 100m 2·g -1 Vpt> / = 0.4 cm3.g-1 V75> / = 0.25 cm3.g-1 V75 / Vpt> / = 0.5。

18. 发明授权

US4191632A Process for the production of benzene from hydrocarbon fractions rich in alkyl-aromatic hydrocarbons and containing paraffinic and naphthenic hydrocarbons 失效
$Process for the production of benzene from hydrocarbon fractions rich in alkyl-aromatic hydrocarbons and containing paraffinic and naphthenic hydrocarbons$
标题翻译：从富含烷基 - 芳烃并含有链烷烃和环烷烃的烃馏分生产苯的方法
公开(公告)号：US4191632A
公开(公告)日：1980-03-04
申请号：US893912
申请日：1978-04-06
申请人： Jean Cosyns , Christian Marcilly , Jean Miquel , Jean-Francois Le Page
发明人： Jean Cosyns , Christian Marcilly , Jean Miquel , Jean-Francois Le Page
IPC分类号： C10G65/12 , B01J29/00 , C07B61/00 , C07C1/00 , C07C4/06 , C07C4/16 , C07C4/18 , C07C5/373 , C07C15/04 , C07C67/00 , C10G65/04 , C07C3/58 , C10G37/10
CPC分类号： C10G65/043 , C07C4/16 , C07C4/18 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/14 , C07C2529/18 , Y02P20/52
摘要： A process for producing benzene is provided which comprises the steps of subjecting a charge rich in alkylaromatic hydrocarbons and containing 2-20% by weight paraffinic and/or naphthenic hydrocarbons, in a first catalytic zone, to a hydrotreatment in the presence of a catalyst mixture containing a selective mordenite catalyst and a reforming catalyst, then subjecting at least a portion of the resultant effluent to thermal or catalytic hydrodealkylation in a second zone, and separating and recovering benzene from the effluent from the second zone.
摘要翻译：提供一种生产苯的方法，该方法包括以下步骤：在催化剂混合物存在下，使含有富含烷基芳族烃并含有2-20％（重量）链烷烃和/或环烷烃的电荷在第一催化区中进行加氢处理含有选择性丝光沸石催化剂和重整催化剂，然后将至少一部分所得流出物在第二区域中进行热或催化加氢脱烷基化，并从第二区域的流出物中分离和回收苯。

19. 发明授权

US5456822A Catalyst of the galloaluminosilicate type containing gallium, a nobel metal of the platinum family and at least on additional metal, and its use in the aromatization of hydrocarbons 失效
标题翻译：包含镓的镓铝硅酸盐型催化剂，铂族的诺贝尔金属，至少在额外的金属上，以及其在烃类芳构化中的应用
公开(公告)号：US5456822A
公开(公告)日：1995-10-10
申请号：US141000
申请日：1993-10-26
申请人： Christian Marcilly , Fabio Alario , Jean-Francois Joly , Fabienne Le Peltier
发明人： Christian Marcilly , Fabio Alario , Jean-Francois Joly , Fabienne Le Peltier
IPC分类号： B01J29/44 , B01J29/87 , C07C2/00 , C07C15/00 , C10G35/095 , C10G35/085
CPC分类号： B01J29/87 , B01J29/44 , C07C2/00 , B01J2229/26 , B01J2229/42 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/40 , C07C2523/46 , C07C2523/50 , C07C2523/72 , C07C2523/74 , C07C2523/745 , C07C2523/755 , C07C2529/44
摘要： Disclosed are reactions for the aromatization of hydrocarbons containing 2 to 9 carbon atoms per molecule, with a composite catalyst containing:an MFI zeolite in hydrogen form, the framework containing at least one of the elements silicon, aluminum and/or gallium; a matrix; gallium; at least one noble metal of the platinum family, at least one additional metal selected from the group made up of tin, germanium, indium, copper, iron, molybdenum, gallium, thallium, gold, silver, ruthenium, chromium, tungsten and lead, and possibly a compound selected from the group made up of alkali and alkaline earth metals.
摘要翻译：公开了每分子含有2至9个碳原子的烃的芳构化反应，其中复合催化剂包含：氢形式的MFI沸石，所述骨架含有至少一种元素硅，铝和/或镓; 矩阵镓; 至少一种铂族贵金属，选自由锡，锗，铟，铜，铁，钼，镓，铊，金，银，钌，铬，钨和铅组成的组中的至少一种另外的金属，并且可能是选自碱金属和碱土金属组成的组中的化合物。

20. 发明授权

US4784750A Catalytic cracking process 失效
标题翻译：催化裂化过程
公开(公告)号：US4784750A
公开(公告)日：1988-11-15
申请号：US870595
申请日：1986-06-04
申请人： Pierre Dufresne , Christian Marcilly
发明人： Pierre Dufresne , Christian Marcilly
IPC分类号： C10G11/04 , B01J29/08 , C10G11/00 , C10G11/05
CPC分类号： C10G11/05 , B01J29/084
摘要： The invention concerns a hydrocarbon cracking catalyst containing a mixture of amorphous matrix with a zeolite, the zeolite having a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio ranging from about 8 to 70, a sodium content lower than 0.15% by weight, a parameter a.sub..degree. of elementary mesh from 24.55 to 24.24.times.10.sup.-10 m, a capacity C.sub.Na to retake sodium ions, expressed in grams of sodium per 100 grams of modified zeolite, higher than 0.85, a specific surface higher than 400 m.sup.2.g.sup.-1, a sodium ion uptake steam adsorption capacity at 25.degree. C. (with a P/Po ratio of 0.10) higher than 6% by weight, a pore distribution such that from 1 to 20% of the pore volume is pores of a diameter ranging from 20 to 80.10.sup.-10 m, the remaining pore volume being essentially pores of a diameter lower than 20.10.sup.-10 m, the matrix being characterized by the following textural properties:S .gtoreq.100 m.sup.2.g.sup.-1TPV .gtoreq.0.4 cm.sup.3.g.sup.-1PV.sub.75 .gtoreq.0.25 cm.sup.3.g.sup.-1PV.sub.75 /TPV .gtoreq.0.5
摘要翻译：本发明涉及一种含有无定形基质与沸石混合物的烃裂解催化剂，该沸石的SiO 2 / Al 2 O 3摩尔比约为8-70，钠含量低于0.15％（重量），参数a DEG基本网格从24.55至24.24×10-10 m，CNa重新获得钠离子，以每克100克改性沸石钠表示，高于0.85，比表面积高于400 m2.g-1，钠离子吸收蒸汽吸附容量在25℃（P / Po比为0.10）高于6重量％，孔分布使得孔体积的1至20％是直径为20至80.10-10的孔 m，剩余的孔体积基本上是直径小于20.10-10μm的孔，该基体的特征在于以下结构性质：S> = 100m 2·g-1 TPV> / = 0.4cm 3·g-1 PV 75 > = 0.25cm 3·g -1 PV75 / TPV> / = 0。

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