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11. 发明专利

JP2005116311A Fuel cell system equipped with deterioration evaluation means of catalyst for carbon monoxide removal, and its operation method 审中-公开
标题翻译：燃料电池系统配备有用于一氧化碳去除的催化剂的检测评估方法及其操作方法
公开(公告)号：JP2005116311A
公开(公告)日：2005-04-28
申请号：JP2003348283
申请日：2003-10-07
申请人： Babcock Hitachi Kk , Hitachi Ltd , バブコック日立株式会社 , 株式会社日立製作所
发明人： YOSHII YASUO , YOSHIDA NORIKO , NAGAYAMA KOSEI , HIGASHIYAMA KAZUHISA , YATABE HIROSHI , MIYATA TERUFUMI
IPC分类号： C01B3/38 , H01M8/06
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To prevent harmful CO from entering into a fuel cell stack by a prescribed quantity or more by evaluating the deterioration state of the CO removal catalyst which selectively oxidizes CO in a gas fuel.
SOLUTION: This is a fuel cell system that is equipped with a reforming device which reforms a hydrocarbon system fuel into a reformed gas containing carbon monoxide and hydrogen, a carbon monoxide removal device which, by supplying an oxidation gas into the reformed gas, reacts carbon monoxide and oxygen selectively under existence of a CO selective oxidation catalyst, a fuel reforming device which has an oxidant gas supply means at the upstream of the carbon monoxide removal device and an oxygen concentration sensor at the downstream of the carbon monoxide removal device, and a fuel cell at the downstream of the fuel reforming device, and that diagnoses the deterioration state of a catalyst filled in the carbon monoxide removal device by oxygen concentration detected by the above oxygen concentration sensor.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：通过评价在气体燃料中选择性氧化CO的CO除去催化剂的劣化状态，以防止有害CO进入燃料电池堆中规定量以上。解决方案：这是一种燃料电池系统，其配备有将烃系统燃料重整成含有一氧化碳和氢气的重整气体的重整装置，一氧化碳去除装置，其通过向重整气体中供给氧化气体在CO选择氧化催化剂存在下选择性地反应一氧化碳和氧气，在一氧化碳去除装置的上游具有氧化剂气体供给装置的燃料重整装置和一氧化碳去除装置的下游的氧浓度传感器以及在燃料重整装置的下游的燃料电池，并且通过由上述氧浓度传感器检测的氧浓度来诊断填充在一氧化碳去除装置中的催化剂的劣化状态。版权所有（C）2005，JPO＆NCIPI

12. 发明专利

JP2004322021A Method and apparatus for purifying exhaust gas from internal combustion engine, catalyst for the method, and catalyst production method 审中-公开
公开(公告)号：JP2004322021A
公开(公告)日：2004-11-18
申请号：JP2003123627
申请日：2003-04-28
申请人： Babcock Hitachi Kk , Hitachi Ltd , バブコック日立株式会社 , 株式会社日立製作所
发明人： KIJIMA YOSHITAKA , NAGAYAMA TOSHIAKI , KANAE MASAHITO , IIZUKA HIDEHIRO , HIGASHIYAMA KAZUHISA
IPC分类号： F02D45/00 , B01D53/94 , B01J23/66 , B01J29/74 , F01N3/08 , F01N3/10 , F01N3/20
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas purification method which is excellent in performance for purifying HC (hydrocarbons) and NOx by the addition of water and can demonstrate the performance at low temperatures, an apparatus for the method, to produce a catalyst for the method, and to provide a method for producing the catalyst. SOLUTION: In the method for purifying exhaust gas from an internal combustion engine, water is added into the exhaust gas, and the gas containing the water is contacted with the exhaust gas purifying catalyst carrying at least one selected from Pd, Pt, and Rh, Ce, and Ag on a porous carrier. COPYRIGHT: (C)2005,JPO&NCIPI

13. 发明专利

JP2010036137A Catalyst for removing nitrogen oxide, apparatus and method for removing nitrogen oxide using the same 审中-公开
标题翻译：用于除去氮氧化物的催化剂，使用其除去氮氧化物的装置和方法
公开(公告)号：JP2010036137A
公开(公告)日：2010-02-18
申请号：JP2008203695
申请日：2008-08-07
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： ARATO TOSHIAKI , YOSHIDA NORIKO , IIZUKA HIDEHIRO , HIGASHIYAMA KAZUHISA , MUKAI TOSHIFUMI
IPC分类号： B01J23/22 , B01D53/94 , F01N3/08
CPC分类号： F01N3/2066 , B01D53/9413 , B01D2251/204 , B01D2251/2062 , B01D2251/2067 , B01D2251/208 , B01D2255/20707 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776 , B01D2255/9205 , B01J21/063 , B01J23/22 , B01J35/1061 , B01J35/1066 , B01J37/0201 , B01J37/08 , F01N2370/02 , F01N2610/02 , F23J15/02 , F23J2217/102 , F23J2219/10 , Y02T10/24
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for removing nitrogen oxides that is prevented from degrading due to a phosphorus compound or an arsenic compound, and to provide an apparatus and method for removing nitrogen oxides using the catalyst. SOLUTION: The catalyst for removing nitrogen oxides in an exhaust gas, wherein a component for removing the nitrogen oxides is supported by a carrier, has pores whose average pore size is 20 to 100 Å measured by a gas adsorption method for measuring a pore size of 20 to 3,000 Å, and whose volume is 50% or more of the total volume of the pores measured by the gas adsorption method. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于除去由磷化合物或砷化合物引起的降解的氮氧化物的催化剂，并提供使用该催化剂除去氮氧化物的装置和方法。解决方案：用于去除排气中的氮氧化物的催化剂，其中用于除去氮氧化物的组分由载体负载，具有通过气体吸附法测量的平均孔径为20至100的孔孔径为20〜3000，体积为通过气体吸附法测定的孔的总体积的50％以上。版权所有（C）2010，JPO＆INPIT

14. 发明专利

JP2008272617A Exhaust gas cleaning device 审中-公开
标题翻译：排气清洁装置
公开(公告)号：JP2008272617A
公开(公告)日：2008-11-13
申请号：JP2007116301
申请日：2007-04-26
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： IIZUKA HIDEHIRO , NAGAYAMA TOSHIAKI , ARATO TOSHIAKI , HIGASHIYAMA KAZUHISA , MUKAI TOSHIFUMI
IPC分类号： B01D53/94 , B01D53/86 , B01J20/02 , F01N3/02 , F01N3/08 , F01N3/20 , F01N3/24 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To solve the problem that unburned fuel is generated and may be accumulated in a lean NOx cleaning catalyst in any light oil injection heat deterioration and sulfur poisoning of the lean NOx cleaning catalyst are caused by combustion of the unburned fuel accumulated on the lean NOx cleaning catalyst although light oil is needed to be injected into an engine cylinder or into a lean exhaust gas in the case of enriching an exhaust gas flowing in the lean NOx cleaning catalyst in an internal combustion engine. SOLUTION: The problem can be solved by locating an oxidizing agent for the unburned fuel at the upstream of a sulfur catching material. The oxidizing agent for the unburned fuel possesses the function of burning the unburned fuel contained in an exhaust gas. The sulfur catching material containing an alkali metal compound and/or an alkali earth metal compound as the main components catches the sulfur content contained in the exhaust gas and does not leave the once-caught sulfur content substantially by using a material which catches and does not discharge sulfur substantially as a part or the whole of the carrier. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题为了解决在任何轻油注入热劣化和贫NOx清洗催化剂的硫中毒时，在稀燃NOx清洗催化剂中产生未燃烧燃料并可积累的问题，由于未燃烧的燃烧在富含在内燃机中的稀NOx清洗催化剂中流动的废气的情况下，虽然需要将轻油注入发动机气缸或稀薄排气中，但是在稀NOx清洗催化剂上积聚的燃料。解决方案：通过在硫捕获材料的上游定位用于未燃烧燃料的氧化剂可以解决问题。用于未燃燃料的氧化剂具有燃烧废气中所含的未燃烧燃料的功能。含有碱金属化合物和/或碱土金属化合物作为主要成分的硫捕获材料捕获废气中所含的硫含量，并且不会通过使用捕获和不捕获的材料基本上留下一次捕获的硫含量将硫基本作为载体的一部分或全部排出。版权所有（C）2009，JPO＆INPIT

15. 发明专利

JP2005144253A Catalyst for cleaning exhaust gas 审中-公开
标题翻译：催化剂用于清洁排气
公开(公告)号：JP2005144253A
公开(公告)日：2005-06-09
申请号：JP2003382251
申请日：2003-11-12
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： MURAKAMI KAZUMI , TOMINAGA SHIGERU , ITO TAKESHI , HAMADA IKUHISA , HIGASHIYAMA KAZUHISA
IPC分类号： F01N3/08 , B01D53/94 , B01J29/22 , F01N3/10 , F01N3/24
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for cleaning exhaust gas, at a zeolite adsorption site of which HC (hydrocarbon) is trapped and made to stay until the catalyst reaches a combustible high-temperature state and by which exhaust gas can be cleaned by burning the trapped HC by supplying the sufficient amount of oxygen. SOLUTION: This catalyst is used mainly for cleaning the exhaust gas to be discharged from an internal-combustion engine and is constituted so that an HC adsorbing material layer based on Ag-deposited zeolite is formed in the innermost layer of this catalyst, a combustion catalyst layer containing a catalytic component of at least one noble metal of palladium, platinum, and rhodium, and an oxygen storing/discharging material is formed in the outermost layer of this catalyst, and an oxygen storing/discharging material-single layer is formed between the HC adsorbing material layer and the combustion catalyst layer. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种用于清洁废气的催化剂，在被捕获并保持HC（烃）的沸石吸附部位停留直至催化剂达到可燃高温状态并且排气可以通过提供足够量的氧来燃烧被捕获的HC来清洁。解决方案：该催化剂主要用于清理从内燃机排出的废气，并且构成为在该催化剂的最内层形成基于Ag沉积沸石的HC吸附材料层，在该催化剂的最外层形成含有钯，铂，铑的至少一种贵金属的催化剂成分和氧气储存/排出材料的燃烧催化剂层，并且存储/排出材料单层为形成在HC吸附材料层和燃烧催化剂层之间。版权所有（C）2005，JPO＆NCIPI

16. 发明专利

JP2005007260A Exhaust gas cleaner 审中-公开
标题翻译：排气清洁剂
公开(公告)号：JP2005007260A
公开(公告)日：2005-01-13
申请号：JP2003173018
申请日：2003-06-18
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： TOMINAGA SHIGERU , MURAKAMI KAZUMI , ITO TAKESHI , HAMADA IKUHISA , HIGASHIYAMA KAZUHISA
IPC分类号： F01N3/08 , B01D53/86 , B01J29/74 , B01J35/04 , F01N3/10 , F01N3/24 , F01N3/28
CPC分类号： Y02A50/2324
摘要： PROBLEM TO BE SOLVED: To provide an exhaust gas cleaning catalyst and an exhaust gas cleaner, which show superior cleaning capability even if they are mounted on different types of vehicles. SOLUTION: (1) The exhaust gas cleaner has an adsorbing combustion catalyst A, which is a low cell density honeycomb of 400 cpsi or lower and carries a hydrocarbon adsorbing material and a combustion catalyst, and an adsorption/combustion catalyst B, which is a low cell density honeycomb of 600 cpsi or higher and carries a hydrocarbon adsorbing material and a combustion catalyst. The adsorbing combustion catalyst A is arranged upstream in an direction of exhaust gas flow. (2) The exhaust gas cleaner comprises a three way catalyst for cleaning an exhaust gas exhausted from an internal-combustion engine, and a hydrocarbon adsorbing combustion catalyst arranged downstream relative to the three way catalyst. The hydrocarbon adsorbing combustion catalyst has the adsorbing combustion catalysts A, B, and the adsorbing combustion catalyst A is arranged upstream in the direction of exhaust gas flow. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供即使安装在不同类型的车辆上也显示出优异的清洁能力的废气净化催化剂和废气净化器。（1）废气净化器具有吸附燃烧用催化剂A，该吸附燃烧用催化剂A是400cpsi以下的低泡孔密度的蜂窝体，具有烃吸附材料和燃烧催化剂，吸附燃烧用催化剂B，其为600cpsi以上的低细胞密度蜂窝体，并携带烃吸附材料和燃烧催化剂。吸附燃烧催化剂A在排气流动方向上游配置。（2）废气净化器包括用于清洗从内燃机排出的废气的三向催化剂和相对于三元催化剂配置在下游的烃吸附燃烧催化剂。烃吸附燃烧催化剂具有吸附燃烧催化剂A，B，吸附燃烧催化剂A沿废气流动方向配置在上游。版权所有（C）2005，JPO＆NCIPI

17. 发明专利

JP2009133247A Exhaust emission control device 审中-公开
标题翻译：排气排放控制装置
公开(公告)号：JP2009133247A
公开(公告)日：2009-06-18
申请号：JP2007309633
申请日：2007-11-30
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： NAGAYAMA TOSHIAKI , IIZUKA HIDEHIRO , ARATO TOSHIAKI , MUKAI TOSHIFUMI , HIGASHIYAMA KAZUHISA
IPC分类号： F01N3/08 , B01D53/50 , B01D53/81 , B01D53/86 , B01D53/94 , B01J20/06 , F01N3/02 , F01N3/10 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide an exhaust emission control system dispensing with a process for removing sulfur component adhering on a lean NOx catalyst and capable of efficiently purifying exhaust gas with a small volume.
SOLUTION: SOx trap material for removing the sulfur component is employed in this exhaust emission control system, and a SOx oxidation function is given to the SOx trap material. The exhaust emission control system is provided with a three-way catalyst or an oxidation catalyst, the SOx trap material with SOx oxidation function, and the lean NOx catalyst.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：解决问题的方案：提供一种废气排放控制系统，其排出附着在稀NOx催化剂上的硫成分的除去方法，能够有效地净化排气量小的废气。解决方案：在该废气排放控制系统中采用用于除去硫成分的SOx捕集材料，并且向SO x捕集材料施加SOx氧化功能。废气排放控制系统设有三元催化剂或氧化催化剂，具有SOx氧化功能的SOx捕集材料和贫NOx催化剂。版权所有（C）2009，JPO＆INPIT

18. 发明专利

JP2009072740A Exhaust emission control method and device for internal combustion engine 审中-公开
标题翻译：排气排放控制方法和内燃机发动机装置
公开(公告)号：JP2009072740A
公开(公告)日：2009-04-09
申请号：JP2007246443
申请日：2007-09-25
申请人： Babcock Hitachi Kk , バブコック日立株式会社
发明人： ARATO TOSHIAKI , IIZUKA HIDEHIRO , NAGAYAMA TOSHIAKI , MUKAI TOSHIFUMI , HIGASHIYAMA KAZUHISA
IPC分类号： B01D53/94 , B01J20/06 , F01N3/08 , F01N3/10 , F01N3/28
摘要： PROBLEM TO BE SOLVED: To provide an exhaust emission control device and method for an internal combustion engine with enhanced exhaust emission control performance and reduced fuel consumption of the internal combustion engine. SOLUTION: The exhaust emission control device cleans exhaust gas of the internal combustion engine by a nitrogen oxides collection type exhaust gas cleaning catalyst, wherein a sulfur collecting material having a composite oxide with an alkali metal element or an alkaline earth metal element and Ti as the main components is set in an exhaust gas flow passage upstream of the nitrogen oxides collection type exhaust gas cleaning catalyst. An oxidation catalyst oxidizing sulfur to sulfur oxides may be provided in an exhaust gas passage upstream of the sulfur collecting material. By the present invention, sulfur contained in exhaust gas can be efficiently collected and removed, contributing to enhancement of the exhaust gas cleaning performance of the exhaust emission control device and enhancement of durability. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：解决的问题：提供一种具有增强的废气排放控制性能和降低内燃机的燃料消耗的内燃机的废气排放控制装置和方法。解决方案：废气排放控制装置通过氮氧化物收集型废气净化催化剂清洗内燃机的废气，其中具有与碱金属元素或碱土金属元素的复合氧化物的硫收集材料和作为主要成分的Ti被设置在氮氧化物收集型排气净化催化剂上游的排气流路中。在硫收集材料上游的废气通道中可以设置氧化硫至硫氧化物的氧化催化剂。通过本发明，可以有效地收集和去除废气中所含的硫，有助于提高废气排放控制装置的排气净化性能，提高耐久性。版权所有（C）2009，JPO＆INPIT

19. 发明专利

JP2004060587A Exhaust emission control method and exhaust emission control device 审中-公开
公开(公告)号：JP2004060587A
公开(公告)日：2004-02-26
申请号：JP2002222800
申请日：2002-07-31
申请人： Babcock Hitachi Kk , Hitachi Ltd , バブコック日立株式会社 , 株式会社日立製作所
发明人： NAGAYAMA TOSHIAKI , IIZUKA HIDEHIRO , OKUDE KOJIRO , KANAE MASAHITO , HIGASHIYAMA KAZUHISA , YAMASHITA HISAO , KAMIKAWA MASAYUKI
IPC分类号： F02D45/00 , B01D53/94 , F01N3/08 , F01N3/20 , F01N3/24 , F01N3/28 , F02D41/04
摘要： PROBLEM TO BE SOLVED: To efficiently purify hydrocarbon by feeding necessary oxygen when the hydrocarbon is purified near a hydrocarbon combustion temperature. SOLUTION: This exhaust emission control device is disposed in an exhaust emission flow passage for exhaust emission exhausted from an internal combustion engine and having a catalyst part with oxygen adsorbing material, hydrocarbon adsorbing material, and hydrocarbon combustible material. The exhaust emission from the internal combustion engine having an air/fuel ratio controlled higher than a theoretical air/fuel ratio is brought into contact with the catalyst part in a period between a time when the internal combustion engine is started and a time when the temperature of the exhaust emission reaches a hydrocarbon combustion temperature. COPYRIGHT: (C)2004,JPO

20. 发明专利

JP2003081603A Hydrogen producing apparatus and power generating system using the same 审中-公开
标题翻译：氢生产装置和使用该装置的发电系统
公开(公告)号：JP2003081603A
公开(公告)日：2003-03-19
申请号：JP2001274920
申请日：2001-09-11
申请人： Babcock Hitachi Kk , Hitachi Ltd , バブコック日立株式会社 , 株式会社日立製作所
发明人： HIGASHIYAMA KAZUHISA , KOMACHIYA MASAHIRO , HIYAMA KIYOSHI , KAMO YUICHI , IMADA NORIYUKI , OKANO TETSURO , KAKO HIROYUKI
IPC分类号： C01B3/02 , B01J19/00 , C01B3/32 , C01B3/34 , C01B3/38 , G05B5/01 , H01M8/04 , H01M8/06 , H01M8/10
CPC分类号： B01J19/0013 , B01J2219/00063 , B01J2219/00164 , B01J2219/00198 , B01J2219/00202 , B01J2219/00213 , B01J2219/00231 , C01B3/32 , C01B3/323 , C01B3/34 , C01B3/382 , C01B3/386 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0833 , C01B2203/0844 , C01B2203/085 , C01B2203/1052 , C01B2203/1064 , C01B2203/1223 , C01B2203/1241 , C01B2203/1258 , C01B2203/127 , C01B2203/1276 , C01B2203/1288 , C01B2203/141 , C01B2203/142 , C01B2203/16 , C01B2203/1604 , C01B2203/1619 , C01B2203/1628 , C01B2203/1685 , C01B2203/169 , C01B2203/1695 , C01B2203/82 , G05B5/01 , H01M8/0612 , H01M8/0662
摘要： PROBLEM TO BE SOLVED: To reconcile the reduction of equipment cost and the maintenance and stabilization of precision related to hydrogen production in a power generating system using a hydrogen producing apparatus. SOLUTION: For the stabilization of the reaction, especially for the maintenance of the reaction temperature, the feedback control by a feedback unit 8 is performed for the supply of air (oxygen or oxidizing agent) 1c. Other materials 1a, 1b are supplied by the open-loop control according to the instruction of a flow selection unit 6 which indicates a preset value depending on the required hydrogen production volume. In addition, a continuous flow setting unit 3 capable of setting the flow continuously is employed for the supply of air and the flow control of the other materials 1a, 1b is performed by use of a discrete flow setting units 2a, 2b each of which provides the flow by a discrete valuation by use of an on-off combination of on-off valves.
摘要翻译：要解决的问题：使用氢气制造装置调节在发电系统中降低设备成本和维持和稳定与氢气生产有关的精度。解决方案：为了稳定反应，特别是为了维持反应温度，通过反馈单元8对空气（氧气或氧化剂）1c的供给进行反馈控制。其他材料1a，1b根据流量选择单元6的指令由开环控制提供，该流量选择单元6根据所需的氢气产生量指示预设值。另外，能够连续地设定流量的连续流量设定单元3用于供给空气，其他材料1a，1b的流量控制是通过使用离散流量设定单元2a，2b进行的，通过使用开关阀的开 - 关组合通过离散估值的流量。

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