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    • 11. 发明授权
    • Electrochromic device with an electrolyte comprising a lithium salt and
a sodium salt
    • 具有包含盐酸盐和钠盐的电解质的电致发光器件
    • US5099356A
    • 1992-03-24
    • US501922
    • 1990-03-28
    • Yasuhiko OhsawaKatsunori AokiTakeshi MiyamotoMasazumi IshikawaHiroshi InabaKiyoshi Nakase
    • Yasuhiko OhsawaKatsunori AokiTakeshi MiyamotoMasazumi IshikawaHiroshi InabaKiyoshi Nakase
    • G02F1/15
    • G02F1/1525G02F2001/1517
    • The invention relates to an electrochromic (EC) device having oppositely arranged two EC electrode layers. The first EC electrode layer uses Prussian blue, osmium purple or ruthenium purple and accordingly takes on a characteristic color by electrochemical oxidation, and the second EC electrode layer uses a transition metal oxide which takes on a characteristic color by electrochemical reduction, such as WO.sub.3. The space between the two EC electrode layers is filled with an electrolyte solution. When an EC device of this type is left in the bleached state for some period of time and then driven for coloration, the density of coloration is insufficient because of a decrease in the quantity of electricity in the oxidizing and coloring reaction of the first EC electrode layer. The invention solves this problem by using, as the electrolyte solution, a solution of a lithium salt and a sodium salt in an organic solvent prepared such that Na.sup.+ ion amounts to 3-30 mol % of the total of Li.sup.+ ion and Na.sup.+ ion.
    • 本发明涉及具有相对布置的两个EC电极层的电致变色(EC)装置。 第一EC电极层使用普鲁士蓝,锇紫或钌紫,因此通过电化学氧化而呈现特征色,第二EC电极层使用通过电化学还原形成特征色的过渡金属氧化物,如WO3。 两个EC电极层之间的空间填充有电解质溶液。 当这种类型的EC装置处于漂白状态一段时间,然后驱动着色时,由于第一EC电极的氧化和着色反应中的电量减少,着色密度不足 层。 本发明通过将锂盐和钠盐的溶液用于制备成使Na +离子占Li +离子和Na +离子总数的3-30mol%而制备的有机溶剂中来解决这个问题。
    • 14. 发明授权
    • Secondary battery electrode, and secondary battery using the same
    • 二次电池电极和二次电池使用相同
    • US08778539B2
    • 2014-07-15
    • US12084691
    • 2006-11-09
    • Yasuhiko OhsawaMieko Kawai
    • Yasuhiko OhsawaMikio Kawai
    • H01M4/13H01M4/58
    • H01M4/131H01M4/364H01M4/505H01M4/525H01M10/0525H01M2004/021Y02T10/7011
    • A secondary battery electrode, which is formed by stacking an electrode active material layer (I) containing spinel-structured lithium manganate as an electrode active material and an electrode active material layer (II) containing, as an electrode active material, a composite oxide represented by the following Chemical formula (1) in a thickness direction of the electrode, in which the electrode active material layer (I) is disposed in contact with a current collector, and an average particle diameter of the composite oxide is smaller than an average particle diameter of the spinel-structured lithium manganate. In such a way, it is possible to provide a secondary battery electrode capable of realizing a secondary battery excellent in both of a volumetric energy density and a volumetric output density. LiCovNiXMnYMZO2  (1)
    • 通过堆叠含有尖晶石结构的锰酸锂作为电极活性物质的电极活性物质层(I)和含有作为电极活性物质的电极活性物质层(II)形成的二次电池电极,所述复合氧化物为 通过以下化学式(1)在电极的厚度方向上电极活性物质层(I)与集电体接触,并且复合氧化物的平均粒径小于平均粒子 尖晶石结构的锰酸锂的直径。 以这种方式,可以提供能够实现体积能量密度和体积输出密度都优异的二次电池的二次电池电极。 LiCovNiXMnYMZO2(1)
    • 17. 发明授权
    • Battery and gas effluent system therefor
    • 电池和排气系统
    • US06284404B1
    • 2001-09-04
    • US09366957
    • 1999-08-04
    • Hideaki HorieMikio KawaiYasuhiko OhsawaTakaaki AbeToyoaki NakagawaOsamu ShimamuraYuuji TanjoKen Iwai
    • Hideaki HorieMikio KawaiYasuhiko OhsawaTakaaki AbeToyoaki NakagawaOsamu ShimamuraYuuji TanjoKen Iwai
    • H01M212
    • H01M2/12H01M6/10H01M6/42H01M10/0525Y02E60/122
    • A vehicle (V) includes a battery enclosure (152) enclosing a battery system (B). Each battery (Bn) includes a cell (1) that comprises a rolled lamination (LM) of a positive sheet electrode (11) having layers (13) of positive-pole-oriented active substance coated on both side of a charge collecting sheet (12), a negative sheet electrode (21) having layers (23) of negative-pole-oriented active substance coated on both sides of another charge collecting sheet (22), and electrolyte-containing separator (31) between the layers of active substances. The batter further includes a cell enclosure (2) totally enclosing the cell. A gas effluent system (100) for the battery system comprises a gas release system (RSn) for generated gas in the cell of each battery to be released outside the cell enclosure, and a gas discharge system (DS) for released gas to be discharged outside the battery enclosure. The gas release system comprises gas release circuitry including a network (NT) of blanks (Cp: P=1,2, . . . , q, . . . ) formed in the lamination, e.g. pointed or zoned blanks (14, 14A, 15, 16, 17, 18) formed in the layer(s) of active substance(s) and/or the charge collecting electrode(s), a blank space (Sp) between the cell and the cell enclosure, and release valve (4a, 6a). The gas discharge system comprises a gas discharge circuit (DC) communicable with the gas release circuitry, and provided as a draft controllable ducting (150, 170) defined between a floor panel (153) of vehicle body (VB) and a wall of the battery enclosure.
    • 车辆(V)包括封闭电池系统(B)的电池外壳(152)。 每个电池(Bn)包括电池(1),其包括具有涂覆在电荷收集片材的两面上的正极取向活性物质层(13)的正片状电极(11)的卷绕层压体(LM) 12),具有涂覆在另一个电荷收集片(22)两侧的负极取向活性物质层(23)的负片状电极(21)和活性物质层之间的含电解质的隔离物(31) 。 面糊还包括完全包围单元的单元壳体(2)。 用于电池系统的气体流出物系统(100)包括用于在每个电池的单元中产生的气体的气体释放系统(RSn),以释放到电池外壳外部;以及气体放电系统(DS),用于放电的放电气体 在电池盒外面。 气体释放系统包括气体释放电路,其包括在层压中形成的坯料(Cp:P = 1,2,...,q,...)的网络(NT) 形成在一个或多个活性物质层和/或电荷收集电极层中的尖锐或分区的空白(14,14A,15,16,17,18),电池之间的空白空间(Sp) 和电池外壳以及释放阀(4a,6a)。 气体放电系统包括可与气体释放电路连通的气体放电回路(DC),并且被设置为限定在车体(VB)的地板面板(153)与车身(VB)的壁之间的可牵引的导管(150,170) 电池外壳。