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11. 发明授权

US06399229B1 Light-transmitting color film, method for producing the same, and coating solution for forming the color film 失效
标题翻译：透光彩色胶片，其制造方法以及形成彩色胶片的涂布液
公开(公告)号：US06399229B1
公开(公告)日：2002-06-04
申请号：US09333326
申请日：1999-06-15
申请人： Hiromitsu Takeda , Kennichi Fujita , Taro Miyauchi , Toshifumi Tsujino , Tatsuya Noguchi , Hideki Okamoto , Takashi Muromachi
发明人： Hiromitsu Takeda , Kennichi Fujita , Taro Miyauchi , Toshifumi Tsujino , Tatsuya Noguchi , Hideki Okamoto , Takashi Muromachi
IPC分类号： B32B900
CPC分类号： C03C17/02 , C03C17/25 , C03C17/34 , C03C2217/23
摘要： The present invention is directed to a light-transmitting color film comprising oxides which have high chemical resistance and excellent light-absorption effect, making them available in a wide color range; a method for producing the same; and a coating solution used for forming the color film. In the light-transmitting color film comprising an oxide of an element which serves as a network former and oxides of transition metal elements serving as coloring components, the element serving as a network former is at least one selected from Si, Al, and B, and the transition metal elements comprise Cu, Mn, and Ni; and the two types of oxides form a complex oxide. Moreover, a method for producing the light-transmitting color film comprises: coating on the substrate a coating solution for forming the color film which contains at least one alkoxide of elements selected from Si, Al, and B which serve as network formers, and as coloring components, transition metal salts comprising at least Cu, Mn, and Ni, and at least one organic compound having a functional group which can coordinate the transition metals; and thereafter firing the substrate.
摘要翻译：本发明涉及包含具有高耐化学性和优异的光吸收效果的氧化物的透光彩色胶片，使其在宽的色彩范围内可用; 其制造方法; 以及用于形成彩色膜的涂布溶液。在作为网络形成体的元素的氧化物和作为着色成分的过渡金属元素的氧化物的透光性彩色膜中，作为网络形成体的元素为选自Si，Al，B中的至少一种，过渡金属元素包括Cu，Mn和Ni; 并且这两种氧化物形成复合氧化物。此外，透光性彩色膜的制造方法包括：在基板上涂布形成所述彩色膜的涂布液，所述涂布液含有选自Si，Al和B中的至少一种选自Si，Al和B的元素作为网络形成剂的醇盐，以及作为着色组分，至少包含Cu，Mn和Ni的过渡金属盐和至少一种具有可以配位过渡金属的官能团的有机化合物; 然后烧制基板。

12. 发明授权

US06340646B1 Colored film-coated ultraviolet/infrared absorbent glass plate and window glass of vehicle 失效
标题翻译：彩色涂膜紫外线/红外线吸收玻璃板和车窗玻璃
公开(公告)号：US06340646B1
公开(公告)日：2002-01-22
申请号：US09437229
申请日：1999-11-10
申请人： Yukihito Nagashima , Mitsuhiro Kawazu , Toshifumi Tsujino
发明人： Yukihito Nagashima , Mitsuhiro Kawazu , Toshifumi Tsujino
IPC分类号： C03C3095
CPC分类号： C03C4/085 , C03C3/095 , C03C4/082 , C03C17/007 , C03C17/008 , C03C2217/45 , C03C2217/479 , Y10T428/252 , Y10T428/256
摘要： A colored film-coated ultraviolet/infrared absorbent glass plate is formed of base glass, colorants, and a colored film. The base glass includes 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O; 5 to 15 wt. % total amount of MgO and CaO; 10 to 20 wt. % total amount of Na2O and K2O; 0.05 to 0.3 wt. % of SO3; and 0 to 5 wt. % B2O3. The colorants includes 0.35 to 0.55 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.08 to 0.15 wt. % FeO; 0.8 to 1.5 wt. % CeO2; and 0 to 0.5 wt. % TiO2. FeO expressed as Fe2O3 is equal to or more than 20 wt. % and less than 27 wt. % of T-Fe2O3. The colored film has a red color shade with a thickness between 30 nm and 300 nm and includes fine particles of gold and silicon oxide of more than 50 wt. % and equal to or less than 95 wt. %. The colored film is applied onto a surface of the ultraviolet/infrared absorbent glass plate.
摘要翻译：彩色薄膜紫外/红外线吸收玻璃板由基底玻璃，着色剂和着色膜形成。基础玻璃包括65至80wt。％SiO2; 0至5wt。％Al2O3; 0〜10重量％％MgO; 5至15wt。％CaO; 10至18wt。％Na2O; 0至5wt。％K2O; 5至15wt。 MgO和CaO的总量％ 10〜20重量％ Na2O和K2O的总量％ 0.05〜0.3重量％ SO3％和0-5重量％％B2O3。着色剂包括0.35至0.55wt。以Fe2O3表示的总氧化铁（T-Fe2O3）％; 0.08〜0.15wt ％FeO; 0.8〜1.5wt。％CeO2; 和0〜0.5wt。％TiO2。以Fe2O3表示的FeO等于或大于20wt。％且小于27wt。％的T-Fe2O3。着色膜具有厚度在30nm和300nm之间的红色色调，并且包括大于50重量％的金和氧化硅的细颗粒。％且等于或小于95wt。％。将着色膜施加到紫外/红外线吸收玻璃板的表面上。

13. 发明授权

US5164223A Process for producing light control plate 失效
标题翻译：生产光控板的工艺
公开(公告)号：US5164223A
公开(公告)日：1992-11-17
申请号：US766792
申请日：1991-09-27
申请人： Toshifumi Tsujino , Hiroaki Yamamoto , Naoto Hirayama , Satoshi Ishizuka , Koichi Maeda
发明人： Toshifumi Tsujino , Hiroaki Yamamoto , Naoto Hirayama , Satoshi Ishizuka , Koichi Maeda
IPC分类号： G02B5/02 , B29C35/08 , B29C37/00 , B29D7/01 , B29D11/00 , B32B17/10 , C08J7/04 , G02B1/04 , G02B1/12 , G02B5/00
CPC分类号： B29D7/01 , B29C35/08 , B29C37/0078 , B29D11/00 , B32B17/10036 , B32B17/10706 , C08J7/047 , G02B1/04 , B29C2035/0827 , B29K2105/0002 , B29L2011/00 , C08J2433/00
摘要： A process for producing a light control plate which selectively scatters incident light of a specific angle, which comprises:(1) bringing at least one photopolymerizable compound of a photopolymerizable monomer and a photopolymerizable oligomer into contact with a transparent plastic film or sheet, each of the monomer and the oligomer having a polymerizable carbon-carbon double bond and being capable of forming a polymer having a refractive index different from a refractive index of said transparent plastic film or sheet, to allow said photopolymerizable compound to infiltrate into said transparent film or sheet through a surface of said transparent film or sheet, thereby forming a swollen surface layer, and(2) irradiating the swollen surface layer with light from a linear light source at a predetermined angle to cure said swollen surface surface layer.

14. 发明申请

US20050003209A1 Glass substrate with colored film fine-particle-containing solution for forming colored film and method for producing glass substrate with colored film 审中-公开
标题翻译：具有用于形成着色膜的带有彩色膜微粒的溶液的玻璃基板和用彩色膜制造玻璃基板的方法
公开(公告)号：US20050003209A1
公开(公告)日：2005-01-06
申请号：US10496701
申请日：2002-11-29
申请人： Kazuyuki Inoguchi , Kazutaka Kamitani , Toshifumi Tsujino
发明人： Kazuyuki Inoguchi , Kazutaka Kamitani , Toshifumi Tsujino
IPC分类号： B32B17/10 , C03B18/12 , C03C1/02 , C03C1/10 , C03C17/00 , B32B17/06
CPC分类号： C03B18/12 , B32B17/10036 , B32B17/10339 , B32B17/10761 , C03C1/02 , C03C1/024 , C03C1/10 , C03C17/002 , C03C17/007 , C03C2217/452 , C03C2217/475 , Y10T428/25 , Y10T428/265 , Y10T428/31616
摘要： The present invention provides a glass sheet with a colored film that can be recycled as a cutlet raw material. The glass sheet includes a glass substrate and a colored film that coats at least part of the surface thereof. This colored film includes an alkali metal oxide, a silicon oxide, and fine particles containing carbon as their main component. The colored film functions as light-shielding films that reduce the visible light transmittance and ultraviolet transmittance.
摘要翻译：本发明提供一种具有可作为切片原料再循环的着色膜的玻璃板。玻璃板包括玻璃基板和涂覆其表面的至少一部分的着色膜。该着色膜包括碱金属氧化物，氧化硅和以碳为主要成分的微粒。着色膜用作减少可见光透射率和紫外线透射率的遮光膜。

15. 发明授权

US06686049B1 Anti-reflection colored film-coated glass products and plasma display panel optical filters 失效
标题翻译：防反射彩色镀膜玻璃制品和等离子显示屏光学滤光片
公开(公告)号：US06686049B1
公开(公告)日：2004-02-03
申请号：US09545742
申请日：2000-04-03
申请人： Koichiro Nakamura , Toshifumi Tsujino
发明人： Koichiro Nakamura , Toshifumi Tsujino
IPC分类号： B32B900
CPC分类号： C03C17/008 , G02B1/115 , H01J2211/442
摘要： Anti-reflection colored film-coated glass products prepared by forming on a transparent glass substrate with a refractive index of 1.47-1.53, a high refractive index film with a refractive index of 1.59-2.30 and a film thickness of 80-140 nm and containing 0-85% silicon oxides, 10-95% titanium oxides and 5-30% fine gold particles in terms of weight percentage, and by forming on the high refractive index film, a low refractive index film with a refractive index which is a value in the range of 1.35-1.58 and at least 0.20 smaller than the refractive index of the high refractive index film, having a film thickness of 70-99 nm and containing 90-100% silicon oxides in terms of weight percentage. These anti-reflection colored film-coated glass products of the invention have excellent anti-reflection performance for visible light and allow freedom in control of the color tones of transmitted light, and thus provide anti-reflection colored film-coated glass products with high visible light transmittance as well as the PDP optical filters that employ them.
摘要翻译：通过在折射率为1.47-1.53的透明玻璃基板上形成抗折射着色的薄膜涂覆的玻璃产品，折射率为1.59-2.30的高折射率膜和80-140nm的膜厚，并含有 0-85％的氧化硅，10-95％的氧化钛和5-30％的细金颗粒，按重量百分比计，通过在高折射率膜上形成折射率为低的折射率膜在高折射率膜的折射率为1.35-1.58和至少0.20的范围内，膜厚度为70-99nm，含有90-100％的氧化硅，按重量百分比计。本发明的防反射彩色膜包覆玻璃制品对可见光具有优异的抗反射性能，并且可以自由地控制透射光的色调，并且因此提供具有高可见光的抗反射彩色膜涂层玻璃制品透光率以及采用它们的PDP光学滤波器。

16. 发明授权

US5137801A Process for producing light control plate having light-scattering pervious region 失效
标题翻译：具有光散射透过区域的光控制板的制造方法
公开(公告)号：US5137801A
公开(公告)日：1992-08-11
申请号：US531683
申请日：1990-06-01
申请人： Toshifumi Tsujino , Satoshi Ishizuka , Koichi Maeda , Shinichiro Kitayama , Shigeo Hozumi
发明人： Toshifumi Tsujino , Satoshi Ishizuka , Koichi Maeda , Shinichiro Kitayama , Shigeo Hozumi
IPC分类号： G02B1/04 , G02B1/10 , G03F7/00
CPC分类号： G03F7/001 , G02B1/04 , G02B1/10
摘要： A process for producing a light control plate, which comprises(1) preparing an assembly composed of a film of a photopolymerizing composition and a light pervious body having a light scattering pervious pattern arranged along the surface of the film and (2) irradiating light to the assembly from that side of the assembly on which the light pervious body exists, thereby to polymerize the photopolymerizable composition of the film and to form a light control plate having a light pervious region through which light advances straightforwardly defined by the light scattering pervious pattern.
摘要翻译：一种光控制板的制造方法，其特征在于，包括：（1）制备由光聚合性组合物的膜构成的组装体和具有沿着所述膜表面排列的具有光散射透过图案的透光体，以及（2）照射光该组件从该组件的该透光体的一侧存在，从而使该膜的可光聚合组合物聚合，并形成具有透光区域的光控制板，该光通过该光控制板直接由光散射透过图案限定。

17. 发明授权

US5112722A Method of producing light control plate which induces scattering of light at different angles 失效
标题翻译：产生诱导不同角度的光散射的光控制板的方法
公开(公告)号：US5112722A
公开(公告)日：1992-05-12
申请号：US507114
申请日：1990-04-10
申请人： Toshifumi Tsujino , Koichi Maeda , Satoshi Ishizuka , Hiroaki Yamamoto , Shinichiro Kitayama , Shigeo Hozumi
发明人： Toshifumi Tsujino , Koichi Maeda , Satoshi Ishizuka , Hiroaki Yamamoto , Shinichiro Kitayama , Shigeo Hozumi
IPC分类号： G02B1/04 , G02B5/02 , G03F7/00
CPC分类号： G02B5/0236 , G02B1/04 , G02B5/0257 , G02B5/0268 , G02B5/0278 , G03F7/0005
摘要： A method of producing a light control plate which induces scattering of light at different angles of incidence for different places. The method comprises (1) preparing an assembly comprising a film of a photo-polymerizable composition and a light-pervious body having a light-impervious pattern arranged along the surface of the film, (2) irradiating light limitedly to the assembly from that side where the light-pervious body at a limited angle while moving the assembly continuously in the planar direction of the film thereby to polymerize at least part of the photopolymerizable film, the light being emitted from a first linear light source whose long axis is positioned in a direction crossing the moving direction of the assembly; and thereafter (3) polymerizing the photopolymerizable composition of that portion of the film-like molded article which is covered with the light-impervious pattern of the light-pervious body by light irradiation or heating.

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