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    • 12. 发明授权
    • Microbicidal compositions
    • US5384321A
    • 1995-01-24
    • US105096
    • 1993-08-10
    • Walter KunzRolf Schurter
    • Walter KunzRolf Schurter
    • A01N43/82C07D285/14A01N43/72
    • C07D285/14A01N43/82
    • Compositions comprising, as active ingredients, compounds of the formula I ##STR1## in which: X.sub.1, X.sub.2 and X.sub.3 independently of one another are hydrogen, methyl, methoxy, methylthio, halogen or nitro;A is C.sub.1 -C.sub.2 alkyl which is substituted by a maximum of 3 X--C.sub.1 -C.sub.4 alkyl groups, methyl which is substituted by 2 or 3 halogen atoms, ethyl which is substituted by hydroxyl and/or not more than 4 halogen atoms; vinyl which is unsubstituted or substituted by not more than 3 halogen atoms; furthermore ethynyl, propargyl, formyl, acetyl, acetyl which is substituted by not more than 3 halogen atoms, or one of the groups C(R).dbd.N--N(R.sub.2)R.sub.3, C(N.dbd.N--U.sub.1).dbd.N--NH--U.sub.1, CH(R)--[N(R.sub.1)].sub.n --N(R.sub.2)R.sub.3, C(R)(CN)OR.sub.4, C(R).dbd.N(O).sub.n R.sub.3, CH(R)--O--N.dbd.C(R.sub.1)R.sub.2, CH(R)--O--N.dbd.C(CN)--CONH--R.sub.5, C(R.sub.6).dbd.N--(O).sub.n R, CH(R)--Y--E--R.sub.3, CO--[C(OR).sub.2 ].sub.n Q, C(Q).dbd.CH--OR or T--Q;in which furthermore:n is zero or 1;X and Y independently of one another are oxygen or sulfur,R and R.sub.1 independently of one another are hydrogen or C.sub.1 -C.sub.2 alkyl;R.sub.2 is hydrogen, C.sub.1-C.sub.8 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, benzyl or cyano;R.sub.3 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.7 cycloalkyl, benzyl or is an aryl radical U;R.sub.4 is hydrogen, C.sub.1 -C.sub.6 alkyl, Si(C.sub.1 -C.sub.6 alkyl).sub.3 or OCOC.sub.1 -C.sub.3 alkyl;R.sub.5 is hydrogen or CONHR.sub.1 ;R.sub.6 is N(R.sub.1)R.sub.2, hydrazino or Q;E is CO or SO.sub.2 ;U and U.sub.1 independently of one another are a phenyl radical which is unsubstituted or monosubstituted or polysubstituted by identical or different substituents from the series comprising methyl, methoxy, halogen, trifluoromethyl, nitro or cyano;T is C.sub.1 -C.sub.2 alkylene, methylene which is substituted by amino, hydroxyl or halogen, the substituents being independent of one another, or is ethenylene which is unsubstituted or substituted by halogen or cyano;Q is COXR or cyano.The novel compositions have crop-protecting properties and are particularly suitable for protecting plants against infestation by phytopathogenic microorganisms such as fungi, bacteria and viruses.
    • 14. 发明授权
    • Certain-3-amino-2-pyridine-sulfonamide intermediates
    • 某些3-氨基-2-吡啶 - 磺酰胺中间体
    • US5336773A
    • 1994-08-09
    • US43231
    • 1993-04-06
    • Werner ForyRolf Schurter
    • Werner ForyRolf Schurter
    • A01N47/36C07D213/71C07D213/73C07D213/74C07D401/12C07D521/00C07D213/69C07D213/70
    • C07D213/73A01N47/36C07D213/74C07D521/00
    • N-Pyridinesulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl; C.sub.2 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl, each of which is monosubstituted or polysubstituted by halogen; C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl, each of which is substituted by --NR.sub.5 R.sub.6, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkyl--S(O).sub.n --; C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl, each of which is substituted by C.sub.2 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkenyl, C.sub.2 -C.sub.6 alkynyl or C.sub.4 -C.sub.8 alkadienyl; it being possible for the C.sub.2 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkenyl and C.sub.4 -C.sub.8 alkadienyl radicals to be monosubstituted or polysubstituted by halogen; or R.sub.1 and R.sub.2 together are a 4-5-membered C.sub.4 -C.sub.10 alkylene chain which can be interrupted by oxygen, sulfur or N--R.sub. 7 ; R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio; C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio, each of which is monosubstituted or polysubstituted by halogen; R.sub.4, R.sub.5, R.sub.6 and R.sub.7 independently of one another are hydrogen or C.sub.1 -C.sub.4 alkyl; n is 0, 1 or 2; X is C.sub.1 -C.sub.3 alkyl, or C.sub.1 -C.sub.3 alkyl which is monosubstituted to trisubstituted by halogen; C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy which is monosubstituted to trisubstituted by halogen; Y is halogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkyl which is monosubstituted to trisubstituted by halogen; C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy which is monosubstituted to trisubstituted by halogen; cyclopropyl, methylamino or dimethylamino; and E is nitrogen or the methine group, and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good selective herbicidal and growth-regulating properties when used pre- and post-emergence.
    • 其中R 1和R 2彼此独立地是氢,C 1 -C 8烷基或C 3 -C 8环烷基的式I(I)的N-吡啶磺酰基-N'-嘧啶基 - 和 - 三嗪基脲; C 2 -C 8烷基或C 3 -C 8环烷基,其各自被卤素单取代或多取代; C 1 -C 8烷基或C 3 -C 8环烷基,其各自被-NR 5 R 6,C 1 -C 4烷氧基或C 1 -C 4烷基-S(O)n - 取代; C 1 -C 4烷基或C 3 -C 6环烷基,其各自被C 2 -C 4烯基,C 5 -C 6环烯基,C 2 -C 6炔基或C 4 -C 8链烯基取代; C2-C4链烯基,C5-C6环烯基和C4-C8链二烯基可能被卤素单取代或多取代; 或R 1和R 2一起是可被氧,硫或N-R 7中断的4-5元C4-C10亚烷基链; R3是氢,卤素,C1-C4烷基,C1-C4烷氧基或C1-C4烷硫基; C 1 -C 4烷基,C 1 -C 4烷氧基或C 1 -C 4烷硫基,其各自被卤素单取代或多取代; R 4,R 5,R 6和R 7彼此独立地是氢或C 1 -C 4烷基; n为0,1或2; X是C 1 -C 3烷基或被卤素单取代至三取代的C 1 -C 3烷基; C 1 -C 3烷氧基或被卤素单取代至三取代的C 1 -C 3烷氧基; Y是卤素,被C 1 -C 3烷基或被卤素单取代至三取代的C 1 -C 3烷基; C 1 -C 3烷氧基或被卤素单取代至三取代的C 1 -C 3烷氧基; 环丙基,甲基氨基或二甲基氨基; E是氮或次甲基,这些化合物与胺,碱金属碱或碱土金属碱或季铵碱的盐在出苗前和出苗后使用时具有很好的选择性除草和生长调节特性。
    • 15. 发明授权
    • Compositions for protecting plants against disease
    • 用于保护植物免受疾病的组合物
    • US5302607A
    • 1994-04-12
    • US58838
    • 1993-05-06
    • Walter KunzRolf Schurter
    • Walter KunzRolf Schurter
    • A01N43/82C07D285/14C07D417/12C07F7/08C07F7/18
    • C07D285/14A01N43/82C07D417/12C07F7/0812C07F7/0836C07F7/0898C07F7/184C07F7/1844
    • Novel benzo-1,2,3-thiadiazole-7-carboxylic acid esters of formula ##STR1## in which Y is oxygen or sulfur;Q.sub.1 and Q.sub.2 independently of one another are each hydrogen or halogen;R.sub.1 and R.sub.2 independently of one another are each hydrogen or C.sub.1 -C.sub.4 alkyl; X.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, trifluoromethyl, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.2 alkoxy halo-substituted in the alkyl moiety, nitro, cyano, dimethylamino, phenyl, phenoxy, or phenyl or phenoxy each substituted by halogen and/or by C.sub.1 -C.sub.2 alkyl and/or by C.sub.1 -C.sub.2 alkoxy;X.sub.2 is hydrogen, halogen or methyl;X.sub.3 is hydrogen or halogen; andA comprises the bridge member ##STR2## R.sub.5 is C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.6 alkoxy, phenyl, or phenyl substituted by halogen or methoxy; R.sub.6 is C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy; ##STR3## that together represents a saturated or unsaturated 3- to 7-membered heterocycle W.sub.3 having a maximum of 2 oxygen or sulfur atoms as additional hetero atoms.The novel active ingredients have plant-protecting properties and are suitable especially for the preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.
    • 新的式(Ⅰ)的苯并1,2,3-噻二唑-7-羧酸酯,其中Y是氧或硫; Q1和Q2各自独立地为氢或卤素; R 1和R 2彼此独立地为氢或C 1 -C 4烷基; X 1是氢,卤素,C 1 -C 4烷基,三氟甲基,C 1 -C 3烷基,在烷基部分被卤素取代的C 1 -C 2烷氧基,硝基,氰基,二甲基氨基,苯基,苯氧基,或各自被卤素和/或被C1 C 2烷基和/或被C 1 -C 2烷氧基取代; X2是氢,卤素或甲基; X3是氢或卤素; 并且A包含桥连构件,R 5是C 1 -C 6烷基,C 3 -C 6环烷基,C 1 -C 6烷氧基,苯基或被卤素或甲氧基取代的苯基; R6是C1-C6烷基或C1-C6烷氧基; 它们一起表示饱和或不饱和的具有最多2个氧原子或硫原子作为附加杂原子的3-至7-元杂环W3。 新型活性成分具有植物保护性质,特别适用于植物防止植物病原微生物如真菌,细菌和病毒侵袭的预防性保护。
    • 17. 发明授权
    • Compositions for protecting plants from diseases
    • 用于保护植物免受疾病的组合物
    • US5229384A
    • 1993-07-20
    • US845518
    • 1992-02-27
    • Walter KunzRolf Schurter
    • Walter KunzRolf Schurter
    • A01N43/82C07D285/14
    • C07D285/14A01N43/82
    • Novel benzo-1,2,3-thiadiazole derivatives of the formula ##STR1## in which; A is --OR.sub.4, --SR.sub.4, --N(R.sub.5)R.sub.6, --N(R.sub.7)--N(R.sub.5)R.sub.6, --O--N.dbd.C(R.sub.8)R.sub.9, --N(R.sub.7)--OR.sub.10, or ##STR2## R.sub.4 is C.sub.1 -C.sub.18 alkyl, C.sub.3 -C.sub.35 alkyl which is interrupted by an oxygen or sulfur atom, C.sub.1 -C.sub.8 alkyl which is substituted by halogen or --COOR.sub.7, C.sub.3 -C.sub.6 alkenyl which is unsubstituted or substituted by halogen, C.sub.3 -C.sub.6 alkinyl which is unsubstituted or substituted by halogen, C.sub.4 -C.sub.7 cycloalkyl which is unsubstituted or substituted by halogen or methyl, an aryl or heterocyclic radical U having not more than 3 heteroatoms O, N and/or S, or a radical U which is linked via an alkylene bridge containing not more than 6 carbon atoms and up to 2 oxygen atoms.The novel active substances have plant protection properties and are particularly suitable for preventive protection of plants against attack by phytopathogenic microorganisms such as fungi, bacteria and viruses.
    • 新颖的式(I)的苯并-1,2,3-噻二唑衍生物,其中: A是-OR4,-SR4,-N(R5)R6,-N(R7)-N(R5)R6,-ON = C(R8)R9,-N(R7)-OR10或R4是R4 C1-C18烷基,被氧或硫原子间隔的C3-C35烷基,被卤素或-COOR7取代的C1-C8烷基,未被取代或被卤素取代的C3-C6链烯基,未被取代或被卤素取代的C3-C6烷基 未被取代或被卤素或甲基取代的C 4 -C 7环烷基,具有不超过3个O,N和/或S杂原子的芳基或杂环基团U或通过不超过6个亚烷基桥连接的基团U 碳原子和至多2个氧原子。 新型活性物质具有植物保护性,特别适用于植物防止植物病原微生物如真菌,细菌和病毒侵袭的预防性保护。