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11. 发明申请

WO2005058793A1 A PROCESS FOR THE PREPARATION OF AN ALKYL ALKENOATE 审中-公开
标题翻译：一种制备阿尔卡尼酸酯的方法
公开(公告)号：WO2005058793A1
公开(公告)日：2005-06-30
申请号：PCT/EP2004/053536
申请日：2004-12-16
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , HAAN, Rene Johan , LANGE, Jean-Paul
发明人： HAAN, Rene Johan , LANGE, Jean-Paul
IPC分类号： C07C67/327
CPC分类号： C07C67/03 , C07C69/533
摘要： A process for the preparation of an alkyl alkenoate, wherein a lactone of the general molecular formula (I) wherein n is 1, 2 or 3, R 1 is a C 1 -C 4 alkyl group, and R 2 , R 3 and R 4 are, independently, a H atom or a C 1 -C 4 alkyl group, is reacted with a C 1 -C 4 alkyl alcohol in a liquid phase in the presence of a strong acid catalyst at transesterification conditions to form the alkyl alkenoate, wherein alkyl alkenoate and alcohol are continuously removed from the liquid phase by distillation.
摘要翻译：一种制备烷基链烯酸酯的方法，其中通式（I）的内酯，其中n为1,2或3，R 1为C 1 -C 4烷基，R 2，R 3和R 4独立地为在强酸催化剂的存在下，在酯交换反应条件下，将H原子或C1-C4烷基与C1-C4烷基醇反应，形成烷基链烯酸酯，其中烷基链烯酸酯和醇从液相通过蒸馏。

12. 发明申请

WO2004024658A1 CATALYTIC CONVERSION OF AN ORGANIC CARBONATE 审中-公开
标题翻译：有机碳的催化转化
公开(公告)号：WO2004024658A1
公开(公告)日：2004-03-25
申请号：PCT/EP2003/050401
申请日：2003-09-11
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE JONGE, Johannes Petrus , LANGE, Jean-Paul
发明人： DE JONGE, Johannes Petrus , LANGE, Jean-Paul
IPC分类号： C07C29/09
CPC分类号： C07C68/065 , B01J23/06 , B01J23/26 , B01J23/80 , C07C29/12 , C07C29/128 , C07C31/205 , C07C69/96
摘要： Method for the catalytic conversion of organic carbonate to the corresponding alcohol, wherein the organic carbonate is contacted with alcohol and/or water in the presence of zinc supported catalyst.
摘要翻译：将有机碳酸酯催化转化成相应的醇的方法，其中有机碳酸酯在负载有锌的催化剂存在下与醇和/或水接触。

13. 发明申请

WO2012041990A1 PROCESS FOR PRODUCING FURFURAL 审中-公开
标题翻译：生产过程的方法
公开(公告)号：WO2012041990A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/067049
申请日：2011-09-29
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN BUIJTENEN, Jeroen , LANGE, Jean-Paul , SPIERING, Wouter
发明人： VAN BUIJTENEN, Jeroen , LANGE, Jean-Paul , SPIERING, Wouter
IPC分类号： C07D307/50
CPC分类号： C07D307/50
摘要： A process is provided for producing furfural from solid biomass by gaseous acid catalysed hydrolysis and dehydration in the presence of superheated steam and one or more acid catalysts comprising the steps of (a) heating the solid biomass to a temperature which is sufficiently high to ensure that the superheated steam and the acid catalyst or catalysts to be used remain in gaseous form during the reaction; (b) contacting the heated solid biomass of step (a) with a gaseous stream comprising superheated steam and one or more acid catalysts to produce a gaseous stream comprising superheated steam, one or more acid catalysts and furfural; (c) recirculating the gaseous stream comprising superheated steam, one or more acid catalysts and furfural to bring it into further contact with the heated solid biomass; (d) maintaining the recirculation cycle of step (c) to enrich the concentration of furfural in the recirculating gaseous stream; and(e) withdrawing part of the recirculating gaseous stream as a purge stream from which the furfural is separated.
摘要翻译：提供了一种用于在过热蒸汽和一种或多种酸催化剂的存在下通过气态酸催化水解和脱水从固体生物质产生糠醛的方法，所述酸催化剂包括以下步骤：（a）将固体生物质加热到足够高的温度以确保过氧化蒸汽和酸催化剂或催化剂在反应期间保持气态; （b）使步骤（a）的加热的固体生物质与包含过热蒸汽和一种或多种酸催化剂的气流接触以产生包含过热蒸汽，一种或多种酸催化剂和糠醛的气流; （c）使包含过热蒸汽，一种或多种酸催化剂和糠醛的气流再循环以使其与加热的固体生物质进一步接触; （d）保持步骤（c）的再循环循环以富集再循环气流中糠醛的浓度; 和（e）将部分循环气流作为从其分离出糠醛的吹扫流排出。

14. 发明申请

WO2011141545A1 PROCESS FOR LIQUEFYING A CELLULOSIC MATERIAL 审中-公开
标题翻译：用于液化材料的方法
公开(公告)号：WO2011141545A1
公开(公告)日：2011-11-17
申请号：PCT/EP2011/057692
申请日：2011-05-12
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VON HEBEL, Klaas Lambertus , LANGE, Jean-Paul
发明人： VON HEBEL, Klaas Lambertus , LANGE, Jean-Paul
IPC分类号： C10G1/00 , C08H8/00 , C12P7/00
CPC分类号： C10G1/00 , C08H8/00 , C10G2300/1014 , C10G2300/4081 , C10G2300/44 , Y02P30/20
摘要： A process for liquefying a cellulosic material comprising hydrolysing the cellulosic material in the presence of an acid catalyst in a solvent mixture to produce a liquefied product, wherein the solvent mixture contains water and in the range of 5 to 95 wt% of a co-solvent and wherein the co-solvent is present in an amount of less than or equal to 90% by weight based on the weight of water and co-solvent, which co-solvent comprises one or more polar solvents, and wherein the solvent mixture is at least partly recycled.
摘要翻译：一种用于液化纤维素材料的方法，包括在酸性催化剂存在下在溶剂混合物中水解纤维素材料以产生液化产物，其中所述溶剂混合物含有水，并且在共溶剂的范围为5至95重量％并且其中所述助溶剂以基于水和助溶剂的重量计小于或等于90重量％的量存在，所述共溶剂包含一种或多种极性溶剂，并且其中所述溶剂混合物在最少部分回收利用。

15. 发明申请

WO2011076736A1 PROCESS FOR PREPARING HYDROCARBONS 审中-公开
标题翻译：制备油料的方法
公开(公告)号：WO2011076736A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/070239
申请日：2010-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN BUIJTENEN, Jeroen , LANGE, Jean-Paul , PRICE, Richard, John
发明人： VAN BUIJTENEN, Jeroen , LANGE, Jean-Paul , PRICE, Richard, John
IPC分类号： C07D307/12 , C07D307/44 , C10L1/18
CPC分类号： C07D307/12 , C07D307/44
摘要： A process for preparing a hydrocarbon or mixture of hydrocarbons comprising the steps of (i) hydrogenating furfural, 5-hydroxymethylfurfural or a mixture of furfural and 5-hydroxymethylfurfural to provide furfuryl alcohol, 2, 5-furandimethanol or a mixture of furfuryl alcohol and 2, 5-furandimethanol; (ii) oligomerizing the alcohol or mixture of alcohols of step (i) in the presence of an acidic catalyst to provide a carbon-carbon coupled oligomer; and (iii) hydrogenating the oligomer of step (ii) is provided. The hydrocarbons are useful as fuel blending components. Processes for controlling the oligomerization of alcohol or mixture of alcohols to optimise the production of oligomers suitable for conversion to hydrocarbons useful as kerosene and diesel components are also provided.
摘要翻译：一种制备碳氢化合物或烃混合物的方法，包括以下步骤：（ⅰ）氢化糠醛，5-羟甲基糠醛或糠醛与5-羟甲基糠醛的混合物，得到糠醇，2,5-呋喃二甲醇或糠醇与2 ，5-呋喃二甲醇; （ii）在酸性催化剂存在下使步骤（ⅰ）的醇或醇的混合物低聚以提供碳 - 碳偶合的低聚物; 和（iii）氢化步骤（ⅱ）的低聚物。烃可用作燃料混合组分。还提供了用于控制醇或醇混合物的低聚的方法以优化适用于转化为用作煤油和柴油组分的烃的低聚物的生产。

16. 发明申请

WO2010136437A1 GASOLINE COMPOSITIONS 审中-公开
标题翻译：汽油组合物
公开(公告)号：WO2010136437A1
公开(公告)日：2010-12-02
申请号：PCT/EP2010/057133
申请日：2010-05-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , FELIX-MOORE, Allison , LANGE, Jean-Paul , SMITH, Johanne , PRICE, Richard, John
发明人： FELIX-MOORE, Allison , LANGE, Jean-Paul , SMITH, Johanne , PRICE, Richard, John
IPC分类号： C10L1/02 , C10L1/14 , C10L1/18 , C10L10/10
CPC分类号： C10L1/023 , C10L1/18 , C10L1/1824 , C10L1/1852 , C10L1/1855 , C10L1/19 , C10L10/08 , C10L10/10 , C10L2200/0469
摘要： The present invention provides a composition comprising component A and at least one component selected from components B, C, D and E, wherein: component A is an alkyl alkenoate compound, or a mixture of alkyl alkenoate compounds, selected from compounds of formula (I) : wherein R 1 is a linear alkenyl group containing 3 to 5 carbon atoms, optionally substituted by a methyl group, and R 2 is a linear or branched alkyl group containing 1 to 6 carbon atoms, with the proviso that component A has a boiling point or boiling point range within the temperature range of from 90 to 200 °C; component B is ethanol; component C is a compound of formula (II) or formula (III): wherein the R 3 , R 4 , R 5 and R 6 groups are independently selected from hydrogen and C 1-6 hydrocarbyl groups, with the proviso that component C has a boiling point or boiling point range of at most 110 C; component D is butanol; and component E is an ether of the general formula (IV): R 7 -O-C(Me) 3 wherein R 7 is selected from methyl, ethyl or mixtures thereof. The present invention further provides a gasoline composition comprising said composition.
摘要翻译：本发明提供包含组分A和至少一种选自组分B，C，D和E的组分的组合物，其中：组分A是烷基烯酸酯化合物或选自式（I）的化合物的烷基烯酸酯化合物的混合物）：其中R 1是含有3至5个碳原子的直链烯基，任选被甲基取代，R 2是含有1至6个碳原子的直链或支链烷基，条件是组分A具有沸点或沸点范围在90〜200℃的温度范围内; 组分B是乙醇; 组分C是式（II）或式（III）的化合物：其中R 3，R 4，R 5和R 6基团独立地选自氢和C 1-6烃基，条件是组分C具有沸点或沸点点范围最多110℃; 组分D为丁醇; 并且组分E是通式（IV）的醚：R 7 -O-C（Me）3，其中R 7选自甲基，乙基或其混合物。本发明还提供了包含所述组合物的汽油组合物。

17. 发明申请

WO2007099111A1 A HYDROGENATION PROCESS FOR THE CONVERSION OF A CARBOXYLIC ACID OR AN ESTER HAVING A CARBONYL GROUP 审中-公开
标题翻译：用于转化羧酸或具有羰基的酯的氢化方法
公开(公告)号：WO2007099111A1
公开(公告)日：2007-09-07
申请号：PCT/EP2007/051879
申请日：2007-02-28
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , LANGE, Jean-Paul , PETRUS, Leonardus , HAAN, Rene Johan
发明人： LANGE, Jean-Paul , PETRUS, Leonardus , HAAN, Rene Johan
IPC分类号： C07C51/367 , C07C67/31 , C07D307/32 , C07D309/30
CPC分类号： C07D307/33 , C07C51/367 , C07D309/30 , C07C59/01
摘要： A hydrogenation process for the conversion of a reactant selected from the group consisting of a carboxylic acid having a carbonyl group and an ester of a carboxylic acid having a carbonyl group to form a carboxylic acid or an ester with a hydroxyl group or a lactone, wherein the reactant is contacted with a heterogeneous catalyst comprising a hydrogenating compound, in the presence of formic acid, at a temperature in the range of from 150 to 400 °C and a pressure in the range of from 1.0 to 150 bar (absolute).
摘要翻译：用于将选自具有羰基的羧酸和具有羰基的羧酸的酯的反应物转化以形成羧酸或具有羟基或内酯的酯的氢化方法，其中在甲酸存在下，反应物与包含氢化化合物的非均相催化剂在150-400℃的温度和1.0-150巴（绝对）范围内的压力下接触。

18. 发明申请

WO2005003113A1 PROCESS FOR THE PREPARATION OF PROPYLENE CARBONATE 审中-公开
标题翻译：制备丙烯碳酸酯的方法
公开(公告)号：WO2005003113A1
公开(公告)日：2005-01-13
申请号：PCT/EP2004/051270
申请日：2004-06-28
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , LANGE, Jean-Paul
发明人： LANGE, Jean-Paul
IPC分类号： C07D317/36
CPC分类号： C07C29/12 , Y02P20/584 , C07C31/205
摘要： Process for the preparation of propylene carbonate, which process comprises contacting propylene oxide with carbon dioxide at a temperature of from 150 to 250°C in the presence of a recycled tetraalkylphosphonium bromide catalyst.
摘要翻译：制备碳酸丙烯酯的方法，该方法包括在循环的四烷基溴化鏻催化剂存在下，在150-250℃的温度下使环氧丙烷与二氧化碳接触。

19. 发明申请

WO2004056793A1 PROCESS FOR THE PREPARATION OF PROPANEDIOL 审中-公开
标题翻译：制备丙二醇的方法
公开(公告)号：WO2004056793A1
公开(公告)日：2004-07-08
申请号：PCT/EP2003/051076
申请日：2003-12-19
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VON HEBEL, Klaas, Lambertus , LANGE, Jean-Paul
发明人： VON HEBEL, Klaas, Lambertus , LANGE, Jean-Paul
IPC分类号： C07D317/36
CPC分类号： C07C68/065 , C07C29/12 , C07C69/96 , C07C31/205
摘要： Process for the preparation of 1,2-propanediol from propylene oxide, which process comprises: (a) contacting propylene oxide with carbon dioxide in the presence of a homogeneous phosphorus containing catalyst to obtain propylene carbonate, (b) optionally removing at least part of the carbon dioxide, (c) adding water and/or an alcohol to the reaction product containing propylene carbonate and phosphorus containing catalyst and contacting the mixture with a heterogeneous catalyst to obtain 1,2-propanediol in combination with dialkylcarbonate and/or carbon dioxide, and (d) separating 1,2-propanediol from the reaction product obtained.
摘要翻译：用于由环氧丙烷制备1,2-丙二醇的方法，该方法包括：（a）在均相含磷催化剂存在下使环氧丙烷与二氧化碳接触以获得碳酸亚丙酯，（b）任选地除去至少部分二氧化碳，（c）向含有碳酸亚丙酯和含磷催化剂的反应产物中加入水和/或醇，并使该混合物与多相催化剂接触，得到与二烷基碳酸酯和/或二氧化碳组合的1,2-丙二醇，和（d）从所得反应产物中分离1,2-丙二醇。

20. 发明申请

WO2011141546A2 PROCESS FOR LIQUEFYING A CELLULOSIC MATERIAL 审中-公开
标题翻译：用于液化材料的方法
公开(公告)号：WO2011141546A2
公开(公告)日：2011-11-17
申请号：PCT/EP2011/057695
申请日：2011-05-12
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VON HEBEL, Klaas Lambertus , LANGE, Jean-Paul
发明人： VON HEBEL, Klaas Lambertus , LANGE, Jean-Paul
IPC分类号： C08H8/00 , C10G1/06
CPC分类号： C10G1/002 , C08H8/00 , C10G1/065 , C10G3/50 , C10G2300/1014 , C10G2300/208 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , C10L1/04 , C10L2200/0469 , C10L2290/544 , Y02E50/13 , Y02P30/20
摘要： A process for liquefying a cellulosic material to produce a liquefied product, which process comprises contacting the cellulosic material simultaneously with - an acid catalyst; - a solvent mixture containing water and a co-solvent, which co-solvent comprises one or more polar solvents and which co-solvent is present in an amount of more than or equal to 10% by weight and less than or equal to 95% by weight, based on the total weight of water and co-solvent; - a hydrogenation catalyst; and - a source of hydrogen. Products obtained from the above process and use of such products to prepare biofuels.
摘要翻译：一种用于液化纤维素材料以产生液化产品的方法，该方法包括将纤维素材料与酸催化剂同时接触; - 含有水和共溶剂的溶剂混合物，所述共溶剂包含一种或多种极性溶剂，并且所述助溶剂的存在量为大于或等于10重量％且小于或等于95重量％，基于水和共溶剂的总重量; - 氢化催化剂; 和 - 氢源。从上述方法获得的产品和使用这些产品制备生物燃料。

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