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    • 13. 发明授权
      US4997855A Vinyl fluorides and pesticidal uses 失效
    • Vinyl fluorides and pesticidal uses
    • 乙烯基氟化物和杀虫剂用途
    • US4997855A
    • 1991-03-05
    • US246009
    • 1988-09-15
    • Clinton J. Peake
    • Clinton J. Peake
    • A01N29/02 , A01N49/00 , C07C17/26
    • A01N49/00 , A01N29/02 , C07C17/2637
    • Nematodes and insects are controlled by application of vinyl fluorides of the formula ##STR1## where R is CH.sub.2 X--, CHX.sub.2 --, CX.sub.3 --, XCH.dbd.CH--, CH.sub.2 .dbd.CX-- or straight chain alkyl(C.sub.2 -C.sub.8);R.sup.1 is hydrogen, fluoro, chloro, bromo, CH.sub.2 Z--, CHZ.sub.2 -- or CZ.sub.3 --;R.sup.2, X and Z independently are hydrogen, fluoro, chloro or bromo; Y.sup.1, Y.sup.2, Y.sup.3, and Y.sup.4 independently are CH.sub.3 or any value of R.sup.2, X and Z; a is 0-12; n is 7-13; and n is greater than a.Particular species controlled are the root-knot, stunt, lesion, cyst and free-living nematodes, and the southern corn rootworm. The vinyl fluorides also have anthelmintic utility.
    • 线虫和昆虫通过使用式为“IMAGE”的乙烯基氟化物，其中R是CH 2 - ，CHX 2 - ，CX 3 - ，XCH = CH-，CH 2 = CX-或直链烷基（C 2 -C 8） R1是氢，氟，氯，溴，CH2Z-，CHZ2-或CZ3-; R2，X和Z独立地是氢，氟，氯或溴; Y1，Y2，Y3和Y4独立地为CH3或R2，X和Z的任何值; a是0-12; n为7-13; 而n大于a。 特定的物种是根结，特技，病变，囊肿和自由生活线虫以及南部的玉米根虫。 乙烯基氟化物也具有驱虫效用。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 16. 依法登记的发明
      USH1996H1 Insecticidal photostable acid salt derivatives of N-benzyl-4-benzhydrolpiperidines 有权
    • Insecticidal photostable acid salt derivatives of N-benzyl-4-benzhydrolpiperidines
    • USH1996H1
    • 2001-10-02
    • US09196880
    • 1998-11-20
    • Clinton J. Peake , Thomas G. Cullen , Robert N. Henrie, II , Jane A. Dybas
    • Clinton J. Peake , Thomas G. Cullen , Robert N. Henrie, II , Jane A. Dybas
    • C07D42100
    • It has now been found that certain novel photostable agriculturally acceptable organic or inorganic salts of formula I are useful as insecticides: where R is alkoxycarbonyl, alkoxycarbonylamino, cycloalkylalkoxy, 2-alkyl-2H-tetrazol-5-yl, or 2-haloalkyl-2H-tetrazol-5-yl; R1 is trihaloalkyl, or trihaloalkoxy; n is 0, or 1; and, wherein said salts are derived from hydrochloric acid; hydrobromic acid; boric acid; phosphoric acid; maleic acid; fumaric acid; phthalic acid; salicylic acid optionally substituted with alkyl or halogen; D-glucuronic acid; the sulfonic acid R2SO3H where R2 is alkyl, haloalkyl, hydroxyalkyl, D-10-camphoryl, or phenyl optionally substituted with alkyl or halogen; the carboxylic acid R3CO2H where R3 is hydrogen, alkyl, trihaloalkyl, carboxyl, phenyl optionally substituted with alkyl or halogen, or pyridyl; the boronic acid R4B(OH)2 where R4 is alkyl or phenyl optionally substituted with alkyl or halogen; the phosphonic acid R5PO3H2 where R5 is alkyl, haloalkenyl, or phenyl optionally substituted with alkyl or halogen; the sulfuric acid R6OSO3H where R6 is hydrogen or alkyl; or the alkanoic acid X-(CH2)qCO2H where q is 0 to 11, X is halogen, trihaloalkyl, haloalkenyl, cyano, aminocarbonyl, or CO2R7 where R7 is hydrogen or alkyl. Preferred compounds include those where R is 2-ethyl-2H-tetrazol-5-yl; R1 is trifluoromethyl; n is 1; and said salts are derived from hydrochloric acid, or the sulfonic acid R2SO3H where R2 is alkyl, or hydroxyalkyl.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 17. 发明授权
      US06184234B2 Insecticidal N-(substituted arylmethyl)-4-[bis(substituted phenyl or pyridyl)methyl]piperidines 失效
    • Insecticidal N-(substituted arylmethyl)-4-[bis(substituted phenyl or pyridyl)methyl]piperidines
    • 杀虫剂N-（取代的芳基甲基）-4- [双（取代的苯基或吡啶基）甲基]哌啶
    • US06184234B2
    • 2001-02-06
    • US09414375
    • 1999-10-07
    • Ian R. Silverman , Daniel H. Cohen , John W. Lyga , Steven W. Szczepanski , Syed F. Ali , Thomas G. Cullen , Robert N. Henrie, II , Clinton J. Peake
    • Ian R. Silverman , Daniel H. Cohen , John W. Lyga , Steven W. Szczepanski , Syed F. Ali , Thomas G. Cullen , Robert N. Henrie, II , Clinton J. Peake
    • A01N4340
    • C07D231/12 , A01N43/40 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/60 , A01N43/653 , A01N43/713 , A01N43/76 , A01N43/82 , A01N47/20 , A01N55/00 , C07D211/14 , C07D211/22 , C07D211/24 , C07D211/26 , C07D211/94 , C07D233/56 , C07D249/08 , C07D401/06 , C07D401/10 , C07D401/12 , C07D401/14 , C07D405/06 , C07D405/10 , C07D409/06 , C07D413/06 , C07D413/10 , C07D417/10 , C07D417/12 , C07F7/1804
    • Compounds of the following structure, the corresponding N-oxides and agriculturally acceptable salts thereof, are disclosed as effective insecticides: wherein U is —(CH2)n—; Q is hydroxy; and R is: and wherein V, W, Y, and Z are each hydrogen; X is a five- or six-membered heterocycle; optionally substituted with bromine, chlorine, fluorine, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkoxyalkyl, haloalkoxyalkyl, or aminocarbonyl; and the heterocycle is optionally connected to the phenyl ring through a —O—, —S—, —(CH2)p, —C(O)—, or —O—(CR3R4)q linkage; R1 and R2 are independently selected from phenyl or pyridyl substituted with pentahalothio, haloalkylthio, haloalkylsulfinyl, or haloalkylsulfonyl; phenyl substituted with —OC(M)2O—, where M is bromine, chorine or fluorine, to provide a dihalobenzodioxolyl fused ring; or pyridyl substituted with —OC(M)2O— to provide a dihalodioxolenopyridyl fused ring; R3 and R4 are independently selected from hydrogen and methyl; n and p are independently 1, 2, or 3; and q is 1 or 2; with the proviso that at least one of R1 and R2 is substituted in the para position of the phenyl ring or the 5-position of the 2-pyridyl ring; each alkyl portion of said optional substituent on X wherein the optional substituent is alkyl, haloalkyl, alkoxyl, haloalkoxyl, alkoxyalkyl, or haloalkoxyalkyl contains from 1 to 4 carbon atoms; each heterocycle contains from 1 to 4 nitrogen atoms, 1 or 2 oxygen or sulfur atoms, or 1 or 2 nitrogen atoms and an oxygen or sulfur atom; and the corresponding N-oxides and agriculturally acceptable salts.
    • 以下结构的化合物，其相应的N-氧化物和农业上可接受的盐被公开为有效的杀虫剂：其中U是 - （CH 2）n - ; Q是羟基; 且R为：且其中V，W，Y和Z各自为氢; X为五元或六元杂环; 任选被溴，氯，氟，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷氧基烷基，卤代烷氧基烷基或氨基羰基取代; 并且杂环任选地通过-O - ， - S - ， - （CH 2）p，-C（O） - 或-O-（CR 3 R 4）q键连接到苯环; R 1和R 2独立地选自 苯基或被五卤代硫代，卤代烷硫基，卤代烷基亚磺酰基或卤代烷基磺酰基取代的吡啶基; 用-OC（M）2 O-取代的苯基，其中M是溴，氯或氟，得到二卤代二苯甲基稠合环; 或被-OC（M）2 O-取代的吡啶基，以提供二卤代苯并吡啶基稠环; R 3和R 4独立地选自氢和甲基; n和p独立地为1,2或3; 平均值为1或2; 条件是R 1和R 2中的至少一个在苯环的对位或2-吡啶基环的5-位上被取代; X上任选取代基的每个烷基部分，其中任选的取代基是烷基，卤代烷基，烷氧基，卤代烷氧基，烷氧基烷基或卤代烷氧基烷基含有1至4个碳原子; 每个杂环含有1至4个氮原子，1或2个氧或硫原子，或1或2个氮原子和氧或硫原子; 和相应的N-氧化物和农业上可接受的盐。
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