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    • 12. 发明授权
    • Liquid silicone rubber composition for application to high-voltage
electrical insulators and articles
    • 液体硅橡胶组合物适用于高压绝缘子和制品
    • US5994461A
    • 1999-11-30
    • US104920
    • 1998-06-25
    • Akito NakamuraYasumichi ShigehisaYuichi Tsuji
    • Akito NakamuraYasumichi ShigehisaYuichi Tsuji
    • C08K3/36C08L83/04C08L83/05C08L83/07H01B3/46
    • C08L83/04C08G77/12C08G77/20C08G77/24C08G77/70
    • A high voltage electrical insulator formed from a curable liquid silicone rubber composition, and subsequently cured, a composition consisting essentially of(A) 100 weight parts of a fluid mixture of polyorganosiloxane comprising(a) at least 5 weight percent of a polyorganosiloxane resin comprising repeating units selected from the group consisting of SiO.sub.4/2 and RSiO.sub.3/2, where R is a monovalent hydrocarbon group, and(b) polydiorganosiloxane having a viscosity in the range from about 100 mPa.multidot.s to 100,000 mPa.multidot.s, that contains at least 2 silicon-bonded alkenyl groups in each molecule,(B) 1 to 100 weight parts microparticulate silica,(C) polyorganohydrogensiloxane that contains at least 2 silicon-bonded hydrogen atoms in each molecule, in a quantity that provides a value from 0.5:1 to 20:1 for the ratio of the number of moles of silicon-bonded hydrogen in the instant composition to the number of moles of silicon-bonded alkenyl in component (A), and(D) a catalytic quantity of a platinum catalyst.The liquid silicone rubber composition, prior to its cure, evidences a desirable fluidity and excellent moldability. Upon its cure the composition produces very mechanically strong silicone rubber moldings that have excellent high-voltage insulating properties tracking resistance, erosion resistance, arcing resistance without the use of fillers such as aluminum oxide, aluminum hydroxide or quartz.
    • 一种由可固化液体硅橡胶组合物形成并随后固化的高压电绝缘体,组合物基本上由(A)100重量份聚有机硅氧烷的流体混合物组成,其包含(a)至少5重量%的聚有机硅氧烷树脂,其包含重复 选自SiO4 / 2和RSiO3 / 2的单元,其中R是一价烃基,和(b)粘度在约100mPax至100,000mPaxs的聚二有机硅氧烷,其含有至少2个硅键合 (B)1〜100重量份微粒二氧化硅,(C)在各分子中含有至少2个与硅键合的氢原子的聚有机氢硅氧烷,其数量为0.5:1〜20:1 对于本发明组合物中与硅键合的氢的摩尔数与组分(A)中与硅键合的烯基的摩尔数的比率,和(D)催化量的铂 um催化剂。 液体硅橡胶组合物在其固化之前证明了所需的流动性和优异的成型性。 在其固化时,组合物产生非常机械强度的硅橡胶模制品,其具有优异的耐高压绝缘性能,耐侵蚀性,耐电弧性,而不使用填料如氧化铝,氢氧化铝或石英。