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1. 发明授权

US5994461A Liquid silicone rubber composition for application to high-voltage electrical insulators and articles 失效
标题翻译：液体硅橡胶组合物适用于高压绝缘子和制品
公开(公告)号：US5994461A
公开(公告)日：1999-11-30
申请号：US104920
申请日：1998-06-25
申请人： Akito Nakamura , Yasumichi Shigehisa , Yuichi Tsuji
发明人： Akito Nakamura , Yasumichi Shigehisa , Yuichi Tsuji
IPC分类号： C08K3/36 , C08L83/04 , C08L83/05 , C08L83/07 , H01B3/46
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/70
摘要： A high voltage electrical insulator formed from a curable liquid silicone rubber composition, and subsequently cured, a composition consisting essentially of(A) 100 weight parts of a fluid mixture of polyorganosiloxane comprising(a) at least 5 weight percent of a polyorganosiloxane resin comprising repeating units selected from the group consisting of SiO.sub.4/2 and RSiO.sub.3/2, where R is a monovalent hydrocarbon group, and(b) polydiorganosiloxane having a viscosity in the range from about 100 mPa.multidot.s to 100,000 mPa.multidot.s, that contains at least 2 silicon-bonded alkenyl groups in each molecule,(B) 1 to 100 weight parts microparticulate silica,(C) polyorganohydrogensiloxane that contains at least 2 silicon-bonded hydrogen atoms in each molecule, in a quantity that provides a value from 0.5:1 to 20:1 for the ratio of the number of moles of silicon-bonded hydrogen in the instant composition to the number of moles of silicon-bonded alkenyl in component (A), and(D) a catalytic quantity of a platinum catalyst.The liquid silicone rubber composition, prior to its cure, evidences a desirable fluidity and excellent moldability. Upon its cure the composition produces very mechanically strong silicone rubber moldings that have excellent high-voltage insulating properties tracking resistance, erosion resistance, arcing resistance without the use of fillers such as aluminum oxide, aluminum hydroxide or quartz.
摘要翻译：一种由可固化液体硅橡胶组合物形成并随后固化的高压电绝缘体，组合物基本上由（A）100重量份聚有机硅氧烷的流体混合物组成，其包含（a）至少5重量％的聚有机硅氧烷树脂，其包含重复选自SiO4 / 2和RSiO3 / 2的单元，其中R是一价烃基，和（b）粘度在约100mPax至100,000mPaxs的聚二有机硅氧烷，其含有至少2个硅键合（B）1〜100重量份微粒二氧化硅，（C）在各分子中含有至少2个与硅键合的氢原子的聚有机氢硅氧烷，其数量为0.5:1〜20:1 对于本发明组合物中与硅键合的氢的摩尔数与组分（A）中与硅键合的烯基的摩尔数的比率，和（D）催化量的铂 um催化剂。液体硅橡胶组合物在其固化之前证明了所需的流动性和优异的成型性。在其固化时，组合物产生非常机械强度的硅橡胶模制品，其具有优异的耐高压绝缘性能，耐侵蚀性，耐电弧性，而不使用填料如氧化铝，氢氧化铝或石英。

2. 发明授权

US5399602A Oil-resistant silicone rubber composition 失效
标题翻译：耐油硅橡胶组合物
公开(公告)号：US5399602A
公开(公告)日：1995-03-21
申请号：US283340
申请日：1994-08-01
申请人： Takao Matsushita , Yasumichi Shigehisa
发明人： Takao Matsushita , Yasumichi Shigehisa
IPC分类号： C08L83/07 , C08L83/04 , C08L83/08 , F02F7/00 , C08K5/54
CPC分类号： C08L83/08 , F02F7/006
摘要： The composition of the present invention comprises an oil-resistant silicone rubber composition that undergoes little swelling even when used in regular or continuous contact with mineral oil-based lubricating oil such as engine oil and so forth. The oil-resistant silicone rubber composition comprises:(A) a dimethylsiloxane-3,3,3-trifluoropropylmethylsiloxane-methylvinylsiloxane copolymer gum that contains 0.001 to 5 mole percent methylvinylsiloxane unit,(B) a hydrocarbon oil or diorganopolysiloxane oil wherein the total in each diorganopolysiloxane oil molecule of the number of silicon-bonded hydrogen atoms and the number of functional groups reactive with component (A) or (C) is less than two,(C) a reinforcing filler, and(D) a curing agent in a quantity sufficient to cure the composition.
摘要翻译：本发明的组合物包括耐油性硅橡胶组合物，即使在与诸如发动机油等的矿物油基润滑油定期或连续接触的情况下也几乎没有膨胀。耐油硅橡胶组合物包含：（A）二甲基硅氧烷-3,3,3-三氟丙基甲基硅氧烷 - 甲基乙烯基硅氧烷共聚物胶，其含有0.001至5摩尔％的甲基乙烯基硅氧烷单元，（B）烃油或二有机聚硅氧烷油，其中每个硅键合氢原子数的二有机聚硅氧烷油分子和与组分（A）或（C）反应的官能团的数目小于2，（C）增强填料，和（D）一定量的固化剂足以固化组合物。

3. 发明授权

US5973030A Liquid silicone rubber compositions and methods for the preparation thereof 失效
标题翻译：液体硅橡胶组合物及其制备方法
公开(公告)号：US5973030A
公开(公告)日：1999-10-26
申请号：US862113
申请日：1997-05-22
申请人： Takao Matsushita , Yasumichi Shigehisa , Yuichi Tsuji
发明人： Takao Matsushita , Yasumichi Shigehisa , Yuichi Tsuji
IPC分类号： C08K3/22 , C08K3/26 , C08K3/36 , C08K5/3475 , C08K5/56 , C08K9/06 , C08L83/04 , C08L83/05 , C08L83/07 , C08G77/04
CPC分类号： C08L83/04 , C08G77/045 , C08G77/12 , C08G77/16 , C08G77/20
摘要： Liquid silicone rubber compositions that prior to cure have good fluidity and excellent moldability and that cure into a highly flame retardant silicone rubber with excellent high-voltage electrical insulating properties. The liquid silicone rubber compositions comprise: (A) polyorganosiloxane; (B) fumed silica; (C) surface-treated zinc carbonate powder as afforded by treating the surface of (a) zinc carbonate powder or basic zinc carbonate powder with (b) an organosilicon compound selected from organosilanes, organosilazanes, and organosiloxane oligomers; (D) polyorganohydrogensiloxane; and (E) platinum catalyst. The liquid silicone rubber compositions may further comprise (F) surface treated aluminum hydroxide powder, (G) triazole compound, and (H) a reaction mixture of (d) platinum compound and (e) 3,5-dimethyl-1-hexyn-3-ol.
摘要翻译：在固化之前的液体硅橡胶组合物具有良好的流动性和优异的成型性，并且固化成具有优异的高电压电绝缘性能的高阻燃硅橡胶。液体硅橡胶组合物包含：（A）聚有机硅氧烷; （B）气相二氧化硅; （C）通过（a）碳酸锌粉末或碱式碳酸锌粉末的表面处理（b）选自有机硅烷，有机硅氮烷和有机硅氧烷低聚物的有机硅化合物的表面提供的表面处理的碳酸锌粉末; （D）聚有机氢硅氧烷; 和（E）铂催化剂。液体硅橡胶组合物还可以包含（F）表面处理的氢氧化铝粉末，（G）三唑化合物，和（H）（d）铂化合物和（e）3,5-二甲基-1-己炔基 - 3-醇。

4. 发明授权

US5880199A Liquid silicone rubber composition and method for the preparation thereof 失效
标题翻译：液体硅橡胶组合物及其制备方法
公开(公告)号：US5880199A
公开(公告)日：1999-03-09
申请号：US861542
申请日：1997-05-22
申请人： Takao Matsushita , Yasumichi Shigehisa , Yuichi Tsuji
发明人： Takao Matsushita , Yasumichi Shigehisa , Yuichi Tsuji
IPC分类号： C08K3/22 , C08K3/26 , C08K3/36 , C08K5/3475 , C08K5/56 , C08L83/04 , C08L83/05 , C08L83/07 , C08K3/34
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20
摘要： A liquid silicone rubber composition that prior to its cure has a suitable fluidity and excellent moldability and that cures into a highly flame retardant silicone rubber molding with excellent electrical properties. The liquid silicone rubber composition comprises(A) polyorganosiloxane,(B) microparticulate silica,(C) aluminum hydroxide powder,(D) zinc carbonate powder,(E) polyorganohydrogensiloxane,(F) benzotriazole,(G) the reaction mixture of(a) a platinum compound and(b) 3,5-dimethyl-1-hexyn-3-ol, and(H) hydrosilylation reaction catalyst.
摘要翻译：在其固化之前的液体硅橡胶组合物具有合适的流动性和优异的成型性，并且固化成具有优异电性能的高阻燃硅橡胶模制品。液体硅橡胶组合物包含（A）聚有机硅氧烷，（B）微粒二氧化硅，（C）氢氧化铝粉末，（D）碳酸锌粉末，（E）聚有机氢硅氧烷，（F）苯并三唑，（G））铂化合物和（b）3,5-二甲基-1-己炔-3-醇和（H）氢化硅烷化反应催化剂。

5. 发明授权

US5942571A Silicone rubber composition for use in high-voltage electrical insulating parts and method for manufacturing the same 失效
标题翻译：用于高压电绝缘部件的硅橡胶组合物及其制造方法
公开(公告)号：US5942571A
公开(公告)日：1999-08-24
申请号：US14812
申请日：1998-01-28
申请人： Akito Nakamura , Yasumichi Shigehisa , Yuichi Tsuji
发明人： Akito Nakamura , Yasumichi Shigehisa , Yuichi Tsuji
IPC分类号： C08K3/08 , C08K3/22 , C08K3/36 , C08K3/38 , C08L83/04 , C08L83/05 , C08L83/07 , C08K5/34
CPC分类号： C08K3/38 , C08K3/22 , C08K3/36 , C08L83/04 , C08G77/045 , C08G77/12 , C08G77/20
摘要： A liquid silicone rubber composition for use in high-voltage eletrical insulating parts comprising (A) a polyorganosiloxane containing alkenyl groups, (B) fumed silica, (C) a polyorganohydridosiloxane, (D) a platinum type catalyst, (E) finely powdered aluminum hydroxide, and (F) a powdered metal compound selected from the group consisting of powdered zinc oxidc, powdered zinc borate, and powdered magnesium hydroxide and a method for manufacturing such a composition.
摘要翻译：一种用于高压电绝缘部件的液体硅橡胶组合物，其包含（A）含有烯基的聚有机硅氧烷，（B）热解法二氧化硅，（C）聚有机氢硅氧烷，（D）铂型催化剂，（E）细粉末铝氢氧化物和（F）选自粉末状氧化锌粉末，硼酸锌粉末和粉末状氢氧化镁的粉末状金属化合物及其制造方法。

6. 发明授权

US5378742A Oil-resistant silicone rubber composition 失效
标题翻译：耐油硅橡胶组合物
公开(公告)号：US5378742A
公开(公告)日：1995-01-03
申请号：US127913
申请日：1993-09-28
申请人： Takao Matsushita , Yasumichi Shigehisa
发明人： Takao Matsushita , Yasumichi Shigehisa
IPC分类号： C08L83/07 , C08L83/04 , C08L83/08 , F02F7/00 , C08K9/06
CPC分类号： C08L83/08 , F02F7/006
摘要： The composition of the present invention comprises a oil-resistant silicone rubber composition that undergoes little swelling even when used in regular or continuous contact with mineral oil-based lubricating oil such as engine oil and so forth. The oil-resistant silicone rubber composition comprises:(A) a dimethylsiloxane-3,3,3-trifluoropropylmethylsiloxane-methylvinylsiloxane copolymer gum that contains 0.001 to 5 mole percent methylvinylsiloxane unit,(B) a hydrocarbon oil or diorganopolysiloxane oil wherein the total in each diorganopolysiloxane oil molecule of the number of silicon-bonded hydrogen atoms and the number of functional groups reactive with component (A) or (C) is less than two,(C) a reinforcing filler, and(D) a curing agent in a quantity sufficient to cure the composition.
摘要翻译：本发明的组合物包括耐油性硅橡胶组合物，即使在与诸如发动机油等的矿物油基润滑油定期或连续接触的情况下也几乎没有溶胀。耐油硅橡胶组合物包含：（A）二甲基硅氧烷-3,3,3-三氟丙基甲基硅氧烷 - 甲基乙烯基硅氧烷共聚物胶，其含有0.001至5摩尔％的甲基乙烯基硅氧烷单元，（B）烃油或二有机聚硅氧烷油，其中每个硅键合氢原子数的二有机聚硅氧烷油分子和与组分（A）或（C）反应的官能团的数目小于2，（C）增强填料，和（D）一定量的固化剂足以固化组合物。

7. 发明授权

US6043309A Silicone rubber composition for use in high-voltage electrical insulating parts and method for manufacturing 失效
标题翻译：用于高压电气绝缘零件的硅橡胶组合物及其制造方法
公开(公告)号：US6043309A
公开(公告)日：2000-03-28
申请号：US14719
申请日：1998-01-28
申请人： Akito Nakamura , Yasumichi Shigehisa , Yuichi Tsuji
发明人： Akito Nakamura , Yasumichi Shigehisa , Yuichi Tsuji
IPC分类号： C08K3/22 , C08K3/26 , C08K3/36 , C08K5/3475 , C08K5/5419 , C08L83/04 , C08L83/05 , C08L83/07 , H01B3/46 , H01B7/295 , C08J3/24 , C08K3/12 , C08K3/20 , C08K5/23
CPC分类号： C08K5/5419 , C08L83/04 , C08G77/12 , C08G77/20
摘要： A curable liquid silicone rubber composition for use in high-voltage electrical insulating parts, which consists of (A) a polyorganosiloxane containing alkenyl groups, (B) fumed silica, (C) a polyorganohydriodosiloxane, (D) a platinum catalyst, (E) finely powdered aluminum hydroxide, and (F) 1 to 150 parts by weight of a finely powdered metal compound selected from the group consisting of finely powdered carbonate or finely powdered hydrogen salt of a metal selected from the 1st, 2nd, 3rd, 7th, or 9th group of the periodic table.
摘要翻译：一种用于高电压电绝缘部件的可固化液体硅橡胶组合物，其由（A）含烯基的聚有机硅氧烷，（B）热解法二氧化硅，（C）聚有机三氧化硅氧烷，（D）铂催化剂，（E）细粉状氢氧化铝，和（F）1至150重量份选自以下的精细粉末状金属化合物：选自第1，第2，第3，第7或第7或第7的金属的细粉状碳酸盐或细粉末氢盐第9组周期表。

8. 发明授权

US5904887A Molding method of composite 失效
标题翻译：复合成型方法
公开(公告)号：US5904887A
公开(公告)日：1999-05-18
申请号：US531263
申请日：1995-09-20
申请人： Akito Nakamura , Yasumichi Shigehisa
发明人： Akito Nakamura , Yasumichi Shigehisa
IPC分类号： B29C35/02 , B01J23/42 , B29C45/14 , B29C45/16 , B29K101/10 , C08K9/10 , C08L83/04 , C08L83/07 , B29C33/40
CPC分类号： B29C45/1676 , C08K9/10 , B29K2083/005 , B29K2283/00
摘要： A manufacturing method for making a composite comprising silicone rubber and a thermoplastic resin in high precision and in high productivity. In the method, a thermoplastic resin is injected into the cavity of a mold. Then, a liquid silicone rubber composition which comprises (A) organopolysiloxane, (B) spherical fine particle catalyst consisting of platinum base catalyst-containing thermoplastic resin, (C) organohydrogenpolysiloxane, and (D) hydrosilylation reaction inhibiting compound, is injected into the same mold and cured.
摘要翻译：一种以高精度和高生产率制造包含硅橡胶和热塑性树脂的复合材料的制造方法。在该方法中，将热塑性树脂注入到模具的空腔中。然后，将含有（A）有机聚硅氧烷，（B）由含铂基催化剂的热塑性树脂，（C）有机氢聚硅氧烷和（D）氢化硅烷化反应抑制化合物）组成的球形微粒催化剂的液态硅橡胶组合物注入相同的模具和固化。

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