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121. 发明授权

US4243815A Preparation of methylene-bis(4-phenylcarbamic acid esters) 失效
标题翻译：亚甲基 - 双（4-苯基氨基甲酸酯）的制备
公开(公告)号：US4243815A
公开(公告)日：1981-01-06
申请号：US114362
申请日：1980-01-22
申请人： Franz Merger , Gerhard Nestler
发明人： Franz Merger , Gerhard Nestler
IPC分类号： C07B61/00 , B01J31/00 , C07C67/00 , C07C239/00 , C07C269/00 , C07C271/06 , C07C125/07
CPC分类号： C07C271/06
摘要： A process for the preparation of methylene-bis-(4-phenylcarbamic acid esters), wherein an N-phenylcarbamic acid ester is reacted with a formaldehyde-acetal in the presence of an acid at up to 200.degree. C.
摘要翻译：一种制备亚甲基双（4-苯基氨基甲酸酯）的方法，其中在高达200℃的酸存在下，使N-苯基氨基甲酸酯与甲醛缩醛反应。

122. 发明授权

US4239552A Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents 失效
标题翻译：机洗餐具洗涤，使用多元醇，羧酸和它们的酯作为漂洗剂
公开(公告)号：US4239552A
公开(公告)日：1980-12-16
申请号：US59776
申请日：1979-07-23
申请人： Johannes Perner , Dieter Stoeckigt , Paul Diessel , Franz Merger , Juergen Paetsch
发明人： Johannes Perner , Dieter Stoeckigt , Paul Diessel , Franz Merger , Juergen Paetsch
IPC分类号： C11D3/20 , C11D1/72 , C11D7/08 , C11D7/26
CPC分类号： C11D3/2086 , C11D3/2065 , C11D3/2093
摘要： A process for machine dishwashing, employing a rinsing liquor which contains carboxylic acids or hydroxycarboxylic acids or mixtures of these and dihydric, trihydric or tetrahydric alcohols, the alcohols and carboxylic acids being of 5 to 9 carbon atoms, of which one carbon atom is quaternary, the alcoholic hydroxyl groups being exclusively primary and the carboxyl group being bonded to the quaternary carbon atom.
摘要翻译：一种机洗碗碟洗涤方法，使用含有羧酸或羟基羧酸的这种漂洗液或这些和二羟基，三元或四元醇的混合物，其中一个碳原子为四价的碳原子数为5〜9的醇和羧酸，醇羟基仅为伯，羧基与季碳原子键合。

123. 发明授权

US06201160B1 Preparation of alcohols 失效
标题翻译：醇的制备
公开(公告)号：US06201160B1
公开(公告)日：2001-03-13
申请号：US08737736
申请日：1996-11-19
申请人： Martin Brudermüller , Matthias Irgang , Martin Schmidt-Radde , Franz Merger , Tom Witzel , Detlef Kratz , Eckehard Danz , Arnold Wittwer , Michael Hesse , Manfred Sauerwald , Cristina Freire Erdbrügger
发明人： Martin Brudermüller , Matthias Irgang , Martin Schmidt-Radde , Franz Merger , Tom Witzel , Detlef Kratz , Eckehard Danz , Arnold Wittwer , Michael Hesse , Manfred Sauerwald , Cristina Freire Erdbrügger
IPC分类号： C07C2704
CPC分类号： C07C29/145 , B01J21/08 , B01J23/72 , B01J23/868 , C07C29/141 , C07C29/175 , C07C2601/08 , C07C2603/68 , C07C31/205 , C07C31/20 , C07C31/12 , C07C31/125 , C07C31/278 , C07C31/274
摘要： Alcohols are prepared by the catalytic hydrogenation of the corresponding carbonyl compounds at elevated temperatures and at superatmospheric pressure in the liquid phase by a process in which the catalyst used contains copper on an SiO2-containing carrier in the presence or absence of one or more of the elements magnesium, barium, zinc and chromium.
摘要翻译：醇通过在液相中在升高的温度和超大气压下的催化氢化制备，其中使用的催化剂在含有SiO 2的载体上含有铜，在存在或不存在一种或多种元素镁，钡，锌和铬。

124. 发明授权

US5616784A Thermal cleavage of carbamic esters 失效
标题翻译：氨基甲酸酯的热裂解
公开(公告)号：US5616784A
公开(公告)日：1997-04-01
申请号：US570250
申请日：1995-12-11
申请人： Hans V. Schwarz , Andreas Otterbach , Otto Mattner , Franz Merger , Wolfgang Schwarz , Eckhardt Brandt , Peter Magnussen , Roland Minges
发明人： Hans V. Schwarz , Andreas Otterbach , Otto Mattner , Franz Merger , Wolfgang Schwarz , Eckhardt Brandt , Peter Magnussen , Roland Minges
IPC分类号： B01J6/00 , C07C263/04 , C07C265/00 , C07C271/06 , C07C45/00
CPC分类号： C07C263/04
摘要： In a reactor for the thermal cleavage of mono- and polyfunctional carbamic esters into the corresponding isocyanates and the hydroxyl component in the liquid phase, the geometry of the reactor, defined by the degassing area in relation to the volume and the arrangement of the heating surfaces, permits cleavage in a two-phase mixture which has a volumetric gas content of more than 50%.
摘要翻译：在用于将单官能和多官能的氨基甲酸酯热裂解成相应的异氰酸酯和液相中的羟基组分的反应器中，由相对于体积的排气面积和加热表面的排列限定的反应器的几何形状允许在体积气体含量大于50％的两相混合物中断裂。

125. 发明授权

US5536854A Preparation of 2-methyl-1,4-butanediol and 3-methyltetrahydrofuran 失效
标题翻译：制备2-甲基-1,4-丁二醇和3-甲基四氢呋喃
公开(公告)号：US5536854A
公开(公告)日：1996-07-16
申请号：US380134
申请日：1995-01-26
申请人： Hans-Juergen Weyer , Rolf Fischer , Franz Merger , Juergen Frank , Jochem Henkelmann , Hardo Siegel , Thomas Ruehl
发明人： Hans-Juergen Weyer , Rolf Fischer , Franz Merger , Juergen Frank , Jochem Henkelmann , Hardo Siegel , Thomas Ruehl
IPC分类号： C07C29/141 , C07C29/149 , C07C29/17 , C07D307/06 , C07D307/08
CPC分类号： C07D307/06 , C07C29/141 , C07C29/149 , C07C29/177
摘要： 2-Methyl-1,4-butanediol and 3-methyltetrahydrofuran are prepared by reacting a compound of the general formula I or II ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.8 -alkyl and the formyl group of II may also be present as acetal with a C.sub.1 -C.sub.8 -alkanol, is reacted with hydrogen in the presence of copper or of a metal of groups 7 to 10 of the Periodical Table of elements or of a compound of these metals.
摘要翻译： 2-甲基-1,4-丁二醇和3-甲基四氢呋喃通过使通式I或II的化合物（其中R 1和R 2各自为氢或C 1 -C 8 - 烷基）和甲酰基 II族基团也可以与C 1 -C 8 - 链烷醇一起作为缩醛存在，在铜或金属元素周期表第7至10族的金属或这些金属的化合物的存在下与氢反应。

126. 发明授权

US5434291A Preparation of aminopropionitriles 失效
标题翻译：氨基丙腈的制备
公开(公告)号：US5434291A
公开(公告)日：1995-07-18
申请号：US251334
申请日：1994-06-01
申请人： Tom Witzel , Rudolf Kummer , Franz Merger , Guido Voit , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder
发明人： Tom Witzel , Rudolf Kummer , Franz Merger , Guido Voit , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder
IPC分类号： C07C253/18 , C07C253/30 , C07C255/24
CPC分类号： C07C253/30 , C07C255/24
摘要： A process for the preparation of aminopropionitriles of the general formula I ##STR1## in which R denotes hydrogen or methyl, wherein ammonia is caused to react with an acrylonitrile of the general formula II ##STR2## In which the substituent has the aforementioned meanings, in a molar ratio of from 1:1 to 500:1 over a heterogenic catalyst at temperatures ranging from 40.degree. to 180.degree. C. and pressures ranging from 10 to 350 bar.
摘要翻译：（I）的氨基丙腈的制备方法，其中R表示氢或甲基，其中使氨与通式II的丙烯腈反应（II）其中取代基具有上述含义，摩尔比为1：1至500：1，相对于异质催化剂，温度范围为40至180℃，压力范围为10至350巴。

127. 发明授权

US5304685A Preparation of 3-(hydroxyphenyl)propionaldehydes and their hydrogenation to 3-(hydroxyphenyl)propanols 失效
标题翻译： 3-（羟基苯基）丙醛的制备及其氢化为3-（羟基苯基）丙醇
公开(公告)号：US5304685A
公开(公告)日：1994-04-19
申请号：US037881
申请日：1993-03-26
申请人： Franz Merger , Martin Schmidt-Radde
发明人： Franz Merger , Martin Schmidt-Radde
IPC分类号： C07B61/00 , C07C37/00 , C07C39/11 , C07C45/68 , C07C45/71 , C07C47/27 , C07C45/00 , C07C29/14
CPC分类号： C07C39/11 , C07C45/71 , C07C47/27
摘要： A process for preparing 3-(hydroxyphenyl)propionaldehydes of the formula I ##STR1## and, where appropriate, for preparing 3-(hydroxyphenyl)propanols of the formula II ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl or C.sub.5 -C.sub.20 -alkylcycloalkylalkyl,R.sup.3 and R.sup.4 are each aryl, C.sub.7 -C.sub.20 -aralkyl, heterocycloalkyl or C.sub.3 -C.sub.20 -heterocycloalkylalkyl, entailsa) reacting phenols of the formula III ##STR3## where R.sup.1 and R.sup.2 have the abovementioned meanings, with 3-hydroxypropionaldehydes of the formula IV ##STR4## where R.sup.3 and R.sup.4 have the abovementioned meanings, in the presence of a basic catalyst at from 90.degree. to 230.degree. C. and under from 0.01 to 50 bar and, where appropriate,b) treating the resulting 3-(hydroxyphenyl)propionaldehydes of the formula I ##STR5## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the abovementioned meanings, with hydrogen in the presence of a hydrogenation catalyst at from 0.degree. to 250.degree. C. and under from 0.1 to 300 bar.
摘要翻译：制备式I（I）的3-（羟基苯基）丙醛的方法，以及适当时制备式II的3-（羟基苯基）丙醇的方法，其中R 1，R 2，R 3和 R 4各自为氢，C 1 -C 20 - 烷基，C 3 -C 20 - 环烷基，C 4 -C 20 - 烷基环烷基，C 4 -C 20 - 环烷基烷基或C 5 -C 20 - 烷基环烷基烷基，R 3和R 4各自为芳基，C 7 -C 20 - 芳烷基，杂环烷基或 C 3 -C 20杂环烷基烷基需要a）使具有上述含义的式III化合物III（III）的酚与式IV的3-羟基丙醛反应，其中R 3和R 4具有在碱性催化剂存在下，在90〜230℃，0.01〜50巴下，适当时，b）处理得到的式（I）的3-（羟基苯基）丙醛 I）其中R 1，R 2，R 3和R 4具有上述含义，在氢化催化剂存在下，在0〜250℃下， 0.1至300巴。

128. 发明授权

US5149861A Recovery of trialkylamines and methyl formate from mixtures obtained in the preparation of trimethylolalkanes 失效
标题翻译：三氯甲烷制备中获得的混合物中的丙烯酰胺和甲基丙烯酸的回收
公开(公告)号：US5149861A
公开(公告)日：1992-09-22
申请号：US664463
申请日：1991-03-01
申请人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch , Heribert Deck , Heinz Auer , Erwin Brunner
发明人： Franz Merger , Peter Hettinger , Leopold Hupfer , Juergen Paetsch , Heribert Deck , Heinz Auer , Erwin Brunner
IPC分类号： C07C69/06 , C07C27/00 , C07C27/02 , C07C29/38 , C07C29/74 , C07C29/88 , C07C31/22 , C07C67/00 , C07C67/03 , C07C67/08 , C07C209/00 , C07C209/86 , C07C211/03 , C07C211/05
CPC分类号： C07C29/88 , C07C67/03
摘要： Trialkylamines and methyl formate are recovered from reaction mixtures obtained in the preparation of trimethylolalkanes by reaction of n-alkanals with from 2.2 to 4.5 moles of formaldehyde in aqueous solution in the presence of from 0.6 to 3 mole of trialkylamine, each quantity based on 1 mole of alkanal, and subsequent hydrogenation in a process wherein the crude reaction mixturea) is heated to from 100.degree. to 200.degree. C., the water present in the reaction mixture is substantially separated off by distillation, together with any excess free trialkylamine, the trialkylamine present in the form of a trialkylammonium formate is freed to form a trimethylolalkane formate, the trialkylamine is distilled off and the trimethylolalkane formate is transesterified with methanol to trimethylolalkane and methyl formate in the presence or absence of a catalytic amount of an alkali metal alkoxide or alkaline earth metal alkoxide, orb) is substantially dewatered, any excess free trialkylamine being removed at the same time, the trialkylamine present in the form of a trialkylammonium formate is separated off by admixing the remaining mixture with methanol and heating the admixture to from 100.degree. to 200.degree. C. to form methyl formate and trialkylamine.
摘要翻译：三烷基胺和甲酸甲酯从制备三羟甲基烷烃得到的反应混合物中回收，通过在0.6至3摩尔三烷基胺存在的情况下，正链烷与2.2至4.5摩尔甲醛在水溶液中的反应，每个量基于1摩尔然后在将粗反应混合物a）加热至100至200℃的过程中随后进行氢化，反应混合物中存在的水通过蒸馏与任何过量的游离三烷基胺基本上分离出来，以三烷基铵甲酸盐形式存在的三烷基胺可以形成甲酸三羟甲基烷烃，在存在或不存在催化量的碱金属醇盐的条件下，将三烷基胺蒸馏除去，甲醇三甲氧基链烷烃甲酯与甲醇酯交换为三羟甲基烷烃和甲酸甲酯，或碱土金属醇盐或b）基本脱水，任何过量游离的三烷基胺为同时除去以三烷基甲酸铵形式存在的三烷基胺，通过将剩余的混合物与甲醇混合并将混合物加热至100至200℃以分离，形成甲酸甲酯和三烷基胺。

129. 发明授权

US5118864A Preparation of cyclopentenones 失效
标题翻译：环戊二烯的制备
公开(公告)号：US5118864A
公开(公告)日：1992-06-02
申请号：US664382
申请日：1991-03-04
申请人： Franz Merger , Tom Witzel , Hans Horler , Helmut Lermer
发明人： Franz Merger , Tom Witzel , Hans Horler , Helmut Lermer
IPC分类号： B01J21/12 , B01J29/06 , C07B61/00 , C07C45/45 , C07C45/54 , C07C49/597
CPC分类号： C07C45/455 , Y02P20/582
摘要： Cyclopentenones of the formula I ##STR1## where each of R.sup.1 to R.sup.4 is independently of the others hydrogen or an organic radical, are prepared by converting a carboxylic ester of the formula IIa, IIb or IIcR.sup.1 CH.dbd.CR.sup.2 --CHR.sup.3 --CHR.sup.4 --CO.sub.2 R.sup.5 (IIa) and/orR.sup.1 CH.sub.2 --CR.sup.2 .dbd.CR.sup.3 --CHR.sup.4 --CO.sub.2 R.sup.5(IIb) and/orR.sup.1 CH.sub.2 --CHR.sup.2 --CR.sup.3 .dbd.CR.sup.4 --CO.sub.2 R.sup.5(IIc),where each of R.sup.1 to R.sup.4 is as defined above and R.sup.5 is C.sub.1 -C.sub.8 -alkyl, over an acidic heterogeneous catalyst at 50.degree.-800.degree. C. and 0.001-50 bar.
摘要翻译：通过将式IIa，IIb或IIc的羧酸酯R1CH = CR2-CHR3-CHR4转化成其中R 1至R 4各自独立地为氢或有机基团的式I（I）的环戊烯酮 -CO 2 R 5（IIa）和/或R 1 CH 2 -CR 2 = CR 3 -CHR 4 -CO 2 R 5（IIb）和/或R 1 CH 2 -CHR 2 -CR 3 = CR 4 -CO 2 R 5（IIc），其中R 1至R 4各自如上所定义， -C 1-8 - 烷基，在50-800℃和0.001-50巴的酸性非均相催化剂上。

130. 发明授权

US5012005A Conversion of 1,3-dioxanes to 4-oxaaldehydes 失效
标题翻译： 1,3-二恶烷转化为4-氧杂醛
公开(公告)号：US5012005A
公开(公告)日：1991-04-30
申请号：US385925
申请日：1989-07-27
申请人： Wolfgang Hoelderich , Franz Merger
发明人： Wolfgang Hoelderich , Franz Merger
IPC分类号： C07C45/60 , C07C47/198 , C07C47/277 , C07D335/02
CPC分类号： C07C47/277 , C07C45/60 , C07C47/198 , C07D335/02
摘要： 4-oxaaldehydes of the formula ##STR1## are prepared by catalytic isomerization of 1,3-dioxanes by a process in which a 1,3-dioxane of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.4 and R.sup.5 are identical or different and are each hydrogen, a straight-chain or branched alkyl, alkenyl or alkynyl radical of not more than 18 carbon atoms, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl, aralkyl, aralkenyl or alkenylaryl radical of 5 to 16 carbon atoms or a heterocyclic radical and furthermore R.sup.1 and R.sup.2 and/or R.sup.4 and R.sup.5 together with the carbon atoms to which they are bonded may form a cycloalkane, a cycloalkene or a heterocyclic structure, and the stated radicals may furthermore carry substituents which are inert under the reaction conditions, and R.sup.3 is hydrogen or straight-chain or branched alkyl, is isomerized using a metal oxide catalyst, which has been treated with an acid, and/or a silica phase having a zeolite structure.
摘要翻译：通过其中R1，R2，R4和R5是相同或不同的式“IMAGE”的1,3-二恶烷的方法，通过1,3-二恶烷的催化异构化制备式“IMAGE”的4-氧代醛，各自为氢，不超过18个碳原子的直链或支链烷基，烯基或炔基，5至8个碳原子的环烷基或环烯基，芳基，烷基芳基，芳烷基，芳烯基或链烯基芳基，其5至 16个碳原子或杂环基团，此外，R 1和R 2和/或R 4和R 5与它们所键合的碳原子一起可以形成环烷烃，环烯烃或杂环结构，并且所述基团还可以具有取代基，使用已用酸处理的金属氧化物催化剂和/或具有沸石结构的二氧化硅相异构化在反应条件下惰性的R 3为氢或直链或支链烷基。

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