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101. 发明授权

US4195031A Process for the continuous production of monoisocyanates 失效
标题翻译：连续生产单异氰酸酯的方法
公开(公告)号：US4195031A
公开(公告)日：1980-03-25
申请号：US965648
申请日：1978-12-20
申请人： Wolfgang Reichmann , Klaus Konig , Johannes Koster
发明人： Wolfgang Reichmann , Klaus Konig , Johannes Koster
IPC分类号： C07C265/02 , C07C20060101 , C07C67/00 , C07C241/00 , C07C263/04 , C07C265/04 , C07C118/00
CPC分类号： C07C263/04
摘要： The instant invention relates to an improved process for the continuous production of an aliphatic monoisocyanate from the corresponding N-alkyl carbamic acid aryl ester. More particularly, the invention is directed to a process for the continuous production of monoisocyanates corresponding to the formulaR--NCOin whichR represents an aliphatic hydrocarbon radical containing 1 to 3 carbon atoms comprising thermally decomposing the corresponding N-alkylcarbamic acid aryl esters corresponding to the formulaR--NH--CO--O--R'in whichR has the meaning above andR' represents a radical of the type obtained by removing the hydroxyl group from a monophenol having a boiling point below 250.degree. C. at normal pressure, and separating the decomposition products by decomposition, further characterized in that(a) a solution of the N-alkylcarbamic acid aryl ester in an organic solvent, which solvent is inert under the reaction conditions and has a boiling point lying at least 20.degree. C. above the boiling point of the monoisocyanate to be formed, is heated to a temperature of from 160.degree. C. to 250.degree. C. at normal pressure or at slightly reduced pressure within the range of 200 to 1013 mbar, thereby resulting in the decomposition of the ester into the corresponding monoisocyanate and the corresponding phenol, as well as the evaporation of the solvent and the decomposition products, and(b) the vapors formed are fed into a distillation column with the monoisocyanate obtained at the head of the column and with the phenol and at least a major portion of the solvent obtained from a side stream or from several side streams.
摘要翻译：本发明涉及从相应的N-烷基氨基甲酸芳基酯连续制备脂族单异氰酸酯的改进方法。更具体地说，本发明涉及连续制备相应于式R-NCO的单异氰酸酯的方法，其中R代表含有1至3个碳原子的脂族烃基，包括热分解相应的N-烷基氨基甲酸芳基酯式R-NH-CO-OR'其中R具有上述含义，R'表示通过在常压下从沸点低于250℃的单酚除去羟基得到的类型的基团，并且分离分解产物，其特征还在于（a）N-烷基氨基甲酸芳基酯在有机溶剂中的溶液，该溶剂在反应条件下是惰性的，并且沸点至少在20℃以上要形成的单异氰酸酯的沸点在常压或稍微减压的范围内加热到160℃至250℃的温度 e为200至1013毫巴，从而导致酯分解成相应的单异氰酸酯和相应的苯酚，以及溶剂和分解产物的蒸发，和（b）所形成的蒸气进料到蒸馏塔与在柱的头部和苯酚获得的单异氰酸酯以及从侧流或从多个侧流获得的至少大部分溶剂。

102. 发明授权

US4191705A Process for the preparation of carbonic acid esters of polyester-polyols 失效
标题翻译：聚酯多元醇碳酸酯的制备方法
公开(公告)号：US4191705A
公开(公告)日：1980-03-04
申请号：US845174
申请日：1977-10-25
申请人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
发明人： Christian Lindner , Carlhans Suling , Herbert Bartl , Manfred Schreckenberg , Dieter Freitag , Klaus Konig
IPC分类号： C08G63/00 , C08G63/64 , C08G63/91 , C07C68/00 , C07C69/96
CPC分类号： C08G63/64 , C08G63/916
摘要： The present invention relates to a process for the preparation of carbonic acid esters of polyester-polyols by transesterifying the polyols with carbonic acid aryl esters at elevated temperatures under vacuum in the presence of a catalyst. The reaction conditions are controlled to avoid the formation of by-products and the chain extension of the polyester-polyols. The present invention is also concerned with the polyester carbonic acid esters so formed, their use in producing polycarbonate block copolymers and the copolymers so produced. The copolymers may be produced by transesterifying the polyester carbonic acid esters with bisphenols and subjecting the bis-hydroxyaryl carbonates so formed to normal polycarbonate synthesis such as interfacial or melt polycondensation.
摘要翻译：本发明涉及一种通过在催化剂存在下在真空下在升高的温度下将多元醇与碳酸芳酯酯交换而制备聚酯多元醇的碳酸酯的方法。控制反应条件以避免副产物的形成和聚酯多元醇的链延长。本发明还涉及如此形成的聚酯碳酸酯，它们在生产聚碳酸酯嵌段共聚物中的用途以及如此制备的共聚物。共聚物可以通过将聚酯碳酸酯与双酚酯交换并使如此形成的双羟基芳基碳酸酯进行正常的聚碳酸酯合成如界面或熔融缩聚来制备。

103. 发明授权

US4089835A Stable polyurethane dispersions and process for production thereof 失效
标题翻译：稳定的聚氨酯分散体及其制备方法
公开(公告)号：US4089835A
公开(公告)日：1978-05-16
申请号：US691174
申请日：1976-05-28
申请人： Klaus Konig , Manfred Dietrich
发明人： Klaus Konig , Manfred Dietrich
IPC分类号： C08G18/08 , C08G18/10 , C08G18/28 , C08G18/32 , C08G18/40 , C08G18/65 , C08K5/11 , C08G18/12
CPC分类号： C08G18/65 , C08G18/0876 , C08G18/10 , C08G18/2805 , C08G18/3225 , C08G18/409 , Y10S516/928
摘要： The instant invention is directed to stable dispersions and the process of their manufacture. The stable dispersions of the instant invention comprise polyureas and/or polyhydrazo-dicarbonamides as the disperse phase in an hydroxyl group containing material selected from the group consisting of polyethers, polyesters, polyester amides, polycarbonates, and mixtures thereof, and are produced by reacting (1) organic polyisocyanates with (2) polyamines containing primary and/or secondary amino groups and/or hydrazines and/or hydrazides in (3) the hydroxyl group containing material. Component (3) may also contain relatively low molecular weight polyols and/or inert organic solvents. Components (1), (2) and (3) are continuously introduced into a flow mixer in such a quantity that the average residence time in the mixer is less than ten minutes.
摘要翻译：本发明涉及稳定的分散体及其制造方法。本发明的稳定分散体包含聚脲和/或聚二氢二碳酰胺作为选自聚醚，聚酯，聚酯酰胺，聚碳酸酯及其混合物的含羟基材料中的分散相，并且通过使（ 1）具有（2）含（3）含羟基材料的伯和/或仲氨基和/或肼和/或酰肼的多胺的有机多异氰酸酯。组分（3）还可以含有相对低分子量的多元醇和/或惰性有机溶剂。将组分（1），（2）和（3）连续引入流动混合器中，使得在混合器中的平均停留时间小于10分钟。

104. 发明授权

US6153761A Sulphonylaminocarbonyltriazolinones having halogenoalkylthio substituents 失效
标题翻译：具有卤代烷硫基取代基的磺酰基氨基羰基三唑啉酮
公开(公告)号：US6153761A
公开(公告)日：2000-11-28
申请号：US368379
申请日：1999-08-04
申请人： Klaus-Helmut Muller , Rolf Kirsten , Ernst Rudolf F. Gesing , Joachim Kluth , Kurt Findeisen , Johannes R. Jansen , Klaus Konig , Hans-Jochem Riebel , Dietmar Bielefeldt , Markus Dollinger , Hans-Joachim Santel , Klaus Stenzel
发明人： Klaus-Helmut Muller , Rolf Kirsten , Ernst Rudolf F. Gesing , Joachim Kluth , Kurt Findeisen , Johannes R. Jansen , Klaus Konig , Hans-Jochem Riebel , Dietmar Bielefeldt , Markus Dollinger , Hans-Joachim Santel , Klaus Stenzel
IPC分类号： A01N47/38 , C07D249/12 , C07D249/14 , C07D405/12 , C07D409/12 , C07D417/12
CPC分类号： A01N47/38 , C07D249/12
摘要： The invention relates to novel sulphonylaminocarbonyltriazolinones of the formula (I), ##STR1## in which R.sup.1 represents hydrogen, hydroxyl, amino, alkylideneamino or a respectively optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkylamino, dialkylamino, alkanoylamino, cycloalkyl, cycloalkylalkyl, cycloalkylamino, aryl, arylalkyl,R.sup.2 represents respectively halogen-substituted alkyl or alkenyl andR.sup.3 represents a respectively optionally substituted radical from the group consisting of alkyl, aralkyl, aryl, heteroaryl,and to salts of compounds of the formula (I), to processes and novel intermediates for preparing the compounds (I) and to their use as herbicides and/or fungicides.
摘要翻译：本发明涉及式（I）的新型磺酰基氨基羰基三唑啉酮，其中R 1表示氢，羟基，氨基，亚烷基氨基或分别任选取代的基团，其由烷基，烯基，炔基，烷基氨基，二烷基氨基，烷酰基氨基，环烷基，环烷基烷基，环烷基氨基，芳基，芳基烷基，R 2分别表示卤素取代的烷基或烯基，R 3表示分别由烷基，芳烷基，芳基，杂芳基和式（I）化合物的盐，方法和用于制备化合物（I）的新中间体及其作为除草剂和/或杀真菌剂的用途。

105. 发明授权

US6001776A Herbicidal sulphonylamino(thio)carbonyl triazolin(thi)ones with heterocyclyl(alk)oxy substituents 失效
标题翻译：具有杂环基（alk）氧取代基的除草磺酰氨基（硫代）羰基三唑啉（thi）
公开(公告)号：US6001776A
公开(公告)日：1999-12-14
申请号：US981972
申请日：1998-01-09
申请人： Klaus-Helmut Muller , Joachim Kluth , Rolf Kirsten , Ernst Rudolf Gesing , Kurt Findeisen , Johannes Rudolf Jansen , Klaus Konig , Mark Wilhelm Drewes , Markus Dollinger , Hans-Joachim Santel
发明人： Klaus-Helmut Muller , Joachim Kluth , Rolf Kirsten , Ernst Rudolf Gesing , Kurt Findeisen , Johannes Rudolf Jansen , Klaus Konig , Mark Wilhelm Drewes , Markus Dollinger , Hans-Joachim Santel
IPC分类号： C07D401/12 , A01N47/38 , C07D249/12 , C07D403/12 , C07D405/12 , C07D409/12
CPC分类号： C07D403/12 , A01N47/38 , C07D405/12
摘要： The novel title compounds of the formula (I) ##STR1## in which Q.sup.1 represents oxygen or sulphur,Q.sup.2 represents oxygen or sulphur,R.sup.1 represents hydrogen, hydroxyl, amino or alkylideneamino or represents an in each case optionally substituted radical from the series consisting of alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkylamino, dialkylamino, alkanoylamino, cycloalkyl, cycloalkylalkyl, cycloalkylamino, aryl and arylalkyl,R.sup.2 represents in each case optionally substituted heterocyclyl or heterocyclylalkyl, andR.sup.3 represents an in each case optionally substituted radical from the series consisting of alkyl, aralkyl, aryl and heteroaryl,and salts of compounds of the formula (I), processes and novel intermediates for their preparation, and their use as herbicides.
摘要翻译： PCT No.PCT / EP96 / 02933 Sec。 371日期1998年1月9日 102（e）1998年1月9日PCT PCT 1996年7月4日PCT公布。公开号WO97 / 03981 日期：1997年2月6日其中Q1表示氧或硫的式（I）的新标题化合物，Q2表示氧或硫，R1表示氢，羟基，氨基或亚烷基氨基，或表示在每种情况下任选取代的基团由烷基，烯基，炔基，烷氧基，烯氧基，烷基氨基，二烷基氨基，烷酰基氨基，环烷基，环烷基烷基，环烷基氨基，芳基和芳基烷基组成，R2代表在任何情况下都是任选取代的杂环基或杂环基烷基，R3代表任意取代的基团由烷基，芳烷基，芳基和杂芳基组成的系列，以及式（I）化合物的盐，其制备方法和新的中间体及其作为除草剂的用途。

106. 发明授权

US5994273A Herbicidal or fungicidal sulphonylaminocarbonyltriazolinones with halogenated alk(en)ylthio substituents 失效
标题翻译：具有卤代烷（烯）基硫取代基的除草或杀真菌磺酰氨基羰基三唑啉酮
公开(公告)号：US5994273A
公开(公告)日：1999-11-30
申请号：US894932
申请日：1997-11-17
申请人： Klaus-Helmut Muller , Rolf Kirsten , Ernst Rudolf F. Gesing , Joachim Kluth , Kurt Findeisen , Johannes R. Jansen , Klaus Konig , Hans-Jochem Riebel , Dietmar Bielefeldt , Markus Dollinger , Hans-Joachim Santel , Klaus Stenzel
发明人： Klaus-Helmut Muller , Rolf Kirsten , Ernst Rudolf F. Gesing , Joachim Kluth , Kurt Findeisen , Johannes R. Jansen , Klaus Konig , Hans-Jochem Riebel , Dietmar Bielefeldt , Markus Dollinger , Hans-Joachim Santel , Klaus Stenzel
IPC分类号： A01N47/38 , C07D249/12 , C07D249/14 , C07D405/12 , C07D409/12 , C07D417/12 , A01N43/653
CPC分类号： A01N47/38 , C07D249/12
摘要： The invention relates to novel sulphonylaminocarbonyltriazolinones of the formula (I), ##STR1## in which R.sup.1 represents hydrogen, hydroxyl, amino, alkylideneamino or a respectively optionally substituted radical from the group consisting of alkyl, alkenyl, alkinyl, alkylamino, dialkylamino, alkanoylamino, cycloalkyl, cycloalkylalkyl, cycloalkylamino, aryl, arylalkyl,R.sup.2 represents respectively halogen-substituted alkyl or alkenyl andR.sup.3 represents a respectively optionally substituted radical from the group consisting of alkyl, aralkyl, aryl, heteroaryl,and to salts of compounds of the formula (I), to processes and novel intermediates for preparing the compounds (I) and to their use as herbicides and/or fungicides.
摘要翻译： PCT No.PCT / EP96 / 00834 Sec。 371日期：1997年11月17日 102（e）1997年11月17日PCT PCT 1996年3月1日PCT公布。公开号WO96 / 27591 日期1996年9月12日本发明涉及式（I）的新型磺酰基氨基羰基三唑啉酮，其中R 1表示氢，羟基，氨基，亚烷基氨基或分别任选取代的基团，其由烷基，烯基，炔基，烷基氨基，二烷基氨基，烷酰基氨基，环烷基，环烷基烷基，环烷基氨基，芳基，芳基烷基，R 2分别表示卤素取代的烷基或烯基，R 3表示任选取代的，由烷基，芳烷基，芳基，杂芳基和式（I），用于制备化合物（I）的方法和新型中间体及其作为除草剂和/或杀真菌剂的用途。

107. 发明授权

US5846383A Process for producing structurally resistant paper 失效
标题翻译：生产结构抗性纸的方法
公开(公告)号：US5846383A
公开(公告)日：1998-12-08
申请号：US945525
申请日：1997-10-27
申请人： Harro Traubel , Klaus Konig
发明人： Harro Traubel , Klaus Konig
IPC分类号： D21H19/24 , C08G18/80 , D21H17/08 , D21H17/46 , D21H21/20
CPC分类号： D21H21/20 , C08G18/8009 , D21H17/08
摘要： Process for the production of structurally strong papers (or paper-like materials) which have a terminable strength by treatment of paper in the pulp or of finished paper in the surface with 0.0001 to 50% by weight, preferably 0.01-25% by weight (based on the pulp), of a mixture of isocyanates which contain on average at least two isocyanate groups and of which at least 20% by weight (preferably at least 50%) are those in which the NCO groups are bonded via an organic radical which contains at least one ester and/or amide group in the main chain.
摘要翻译： PCT No.PCT / EP96 / 01670 Sec。 371日期1997年10月27日第 102（e）1997年10月27日PCT PCT 1996年4月22日PCT公布。第WO96 / 35019号公报日期1996年11月7日生产结构坚固的纸（或纸状材料）的方法，其具有通过在纸浆或表面处理纸中处理纸而具有可终止强度，其具有0.0001至50重量％，优选为0.01- 25重量％（基于纸浆），含有平均至少两个异氰酸酯基的异氰酸酯混合物，其中至少20重量％（优选至少50重量％）为NCO基团键合的异氰酸酯混合物通过在主链中含有至少一个酯和/或酰胺基团的有机基团。

108. 发明授权

US5750629A Uretdione diisocyanates and a process for their production 失效
标题翻译：脲二异氰酸酯及其制备方法
公开(公告)号：US5750629A
公开(公告)日：1998-05-12
申请号：US788726
申请日：1997-01-23
申请人： Hans-Josef Laas , Reinhard Halpaap , Josef Pedain , Klaus Konig
发明人： Hans-Josef Laas , Reinhard Halpaap , Josef Pedain , Klaus Konig
IPC分类号： B01D3/28 , B01J31/24 , C07B61/00 , C07D229/00 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04
CPC分类号： C08G18/8016 , C07D229/00 , C08G18/798
摘要： The present invention relates to a process for preparing pure bis(isocyanatoalkyl)monouretdiones corresponding to formula (I) ##STR1## wherein R represents identical or different, linear or branched alkyl groups having 4 to 9 carbon atoms, by oligomerizing at least a portion of the isocyanate groups of aliphatic diisocyanates in the presence of catalysts which accelerate the dimerization of isocyanate groups, terminating the reaction at the desired degree of oligomerization, removing unreacted excess diisocyanate by extraction or thin film distillation to obtain a distillation residue, subjecting the distillation residue to thin film distillation at a temperature of 160.degree. to 220.degree. C. and a pressure of 0.01 to 1.0 mbar and obtaining bis(isocyanato-alkyl)monouretdiones corresponding to formula (I) as the distillate. The present invention also relates to the resulting bis(isocyanato-alkyl)monouretdiones corresponding to formula I and to their use for the production of polyisocyanate addition products, in particular as the isocyanate components in polyurethane coatings compositions, in which the isocyanate groups may optionally be present in blocked form.
摘要翻译：本发明涉及一种制备对应于式（I）的纯双（异氰酸根合烷基）单脲基的方法，其中R表示相同或不同的具有4至9个碳原子的直链或支链烷基，至少通过低聚一部分脂族二异氰酸酯的异氰酸酯基团在催化剂存在下加速异氰酸酯基团的二聚反应，以期望的低聚程度终止反应，通过萃取或薄膜蒸馏除去未反应的过量二异氰酸酯，得到蒸馏残渣，蒸馏残渣，在160〜220℃的温度和0.01〜1.0mbar的压力下进行薄膜蒸馏，得到与式（I）相应的作为馏出物的双（异氰酸基 - 烷基）单脲。本发明还涉及所得到的对应于式I的双（异氰酸根合 - 烷基）单脲基团，以及其用于制备多异氰酸酯加成产物的用途，特别是作为聚氨酯涂料组合物中的异氰酸酯组分，其中异氰酸酯基团可任选地为以阻塞形式存在。

109. 发明授权

US5710303A Process for the preparation of alkoxytriazolinones 失效
标题翻译：制备烷氧基三唑啉酮的方法
公开(公告)号：US5710303A
公开(公告)日：1998-01-20
申请号：US723706
申请日：1996-09-30
申请人： Heinz-Jurgen Wroblowsky , Klaus Konig
发明人： Heinz-Jurgen Wroblowsky , Klaus Konig
IPC分类号： C07C281/04 , C07C281/16 , C07D249/12 , C07C275/70
CPC分类号： C07D249/12 , C07C281/04
摘要： Alkoxytriazolinones of the formula (I), ##STR1## are obtained in good yields and in high purity by reacting iminocarbonic diesters (II) with carbazinic esters (III) ##STR2## at -20.degree. C. to +120.degree. C. (1st step) and subjecting the semicarbazide derivatives (IV) formed in this process with elimination of R.sup.2 --OH ##STR3## to a cyclizing condensation reaction in the presence of a base at 20.degree. C. to 150.degree. C. with elimination of R.sup.3 --OH, if appropriate (2nd step) and, finally, by reacting the resulting 5-alkoxytriazolinones of the formula (V) �=formula (I) where R.sup.1 =H! with an alkylating agent of the formula R.sup.1 --X (VI) at 0.degree. C. to 150.degree. C., if appropriate in the presence of a base.
摘要翻译：通过使亚氨基碳酸二酯（II）与咔嗪酸酯（III）在-20℃至+ 120℃下反应，以良好的产率和高纯度获得式（I），（IMAGE）（I）的烷氧基三唑啉酮（第1步），在20℃〜150℃下，在碱的存在下，将在该工序中形成的氨基脲衍生物（Ⅳ）与R2-OH的反应进行环化缩合反应，（Ⅴ）[=式（I）其中R1 = H）与式R1-X（Ⅵ）的烷基化剂反应得到的5-烷氧基三唑啉酮）在0℃至150℃，如果合适，在碱的存在下。

110. 发明授权

US5594147A Process for the preparation of alkoxytriazolinones 失效
标题翻译：制备烷氧基三唑啉酮的方法
公开(公告)号：US5594147A
公开(公告)日：1997-01-14
申请号：US528584
申请日：1995-09-15
申请人： Heinz-Jurgen Wroblowsky , Klaus Konig
发明人： Heinz-Jurgen Wroblowsky , Klaus Konig
IPC分类号： C07C281/06 , C07D249/12
CPC分类号： C07D249/12 , C07C281/06
摘要： Alkoxytriazolinones of the general formula (I), ##STR1## in which R.sup.1 represents hydrogen, or represents in each case optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl, andR.sup.2 represents in each case optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl,(which can be used as intermediates for the preparation of herbicidal active compounds) are obtained in very good yields and in high purity by reacting imino(thio)carbonic esters (II) with alkoxyethyl carbazinates (III) ##STR2## in which Q represents O or S, R.sup.3 represents (for example) alkyl, aryl or aralkyl and R.sup.4 represents (for example) alkyl,at -20.degree. C. to +150.degree. C. (1st step) and subjecting the new semicarbazide derivatives (IV) ##STR3## which are formed with elimination of R.sup.3 --QH, if appropriate after intermediate isolation, to a cyclizing condensation reaction at 0.degree. C. to 200.degree. C., without the addition of a base, advantageously under reduced pressure, with the elimination of alkoxyethanols (2nd step).
摘要翻译：通式（I）的烷氧基三唑啉酮，其中R 1表示氢，或在每种情况下表示任选取代的烷基，烯基，炔基，环烷基，环烷基烷基，芳基或芳基烷基，和R 2表示在各种情况下任选取代的烷基，烯基，炔基，环烷基，环烷基烷基，芳基或芳基烷基（可用作制备除草活性化合物的中间体）以非常好的产率和高纯度通过使亚氨基（硫代）碳酸酯（II）其中Q代表O或S，R3代表（例如）烷基，芳基或芳烷基，R4代表（例如）烷基，在-20℃至+ 150℃（第1步），在0℃〜200℃进行环化缩合反应，在中间分离后，如果合适，将R3-QH所形成的新的氨基脲衍生物（IV）没有添加基础，优势我们在减压下，消除烷氧基乙醇（第二步）。

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