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    • 96. 发明申请
    • PREPARATION OF 4,4'-DIHYDROXY-ALPHA-ALKYLSTILBENES AND 4,4'-DIHYDROXY-ALPHA, ALPHA'-DIALKYLSTILBENES
    • 4,4'-二羟基-AlPHA-ALKYLSTILBENES的制备和4,4'-二羟基-AlPHA,ALPHA-二烷基
    • WO1995015301A1
    • 1995-06-08
    • PCT/US1994013480
    • 1994-11-21
    • THE DOW CHEMICAL COMPANY
    • THE DOW CHEMICAL COMPANYHEFNER, Robert, E., Jr.VILLARREAL, Maria, I.CARR, David, A.
    • C07C37/20
    • C07C39/215C07C37/20
    • 4,4'-Dihydroxy-alpha-alkylstilbenes of high purity were prepared by reacting at a temperature of from -20 DEG C to 20 DEG C a mixture of: (1) at least one alpha-haloketone; (2) at least one phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound; and (3) at least one strong protonic acid or Lewis acid, such that the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound: alpha-haloketone(s) is from 0.1:1 to 1.9:1, and the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound: alpha-haloketone(s):strong protonic acid or Lewis acid is from 0.1:1:0.0026 to 1.9:1:0.95. The high purity 4,4'-dihydroxy-alpha-alkylstilbenes are useful for the advancement of epoxy resins, for the preparation of phenoxy resins and for the preparation of epoxy resins.
    • 通过在-20℃至20℃的温度下使下列混合物反应制备高纯度的4,4'-二羟基-α-烷基二苯乙烯:(1)至少一种α-卤代酮; (2)至少一种含酚羟基的化合物或含烷氧基的芳族化合物; 和(3)至少一种强质子酸或路易斯酸,使得含酚羟基的化合物或含烷氧基的芳族化合物:α-卤代酮的摩尔比为0.1:1至1.9:1,并且 含酚羟基化合物或含烷氧基的芳族化合物:α-卤代酮:强质子酸或路易斯酸的摩尔比为0.1:1:0.0026至1.9:1:0.95。 高纯度4,4'-二羟基-α-烷基芪可用于环氧树脂的前进,苯氧基树脂的制备和环氧树脂的制备。
    • 99. 发明申请
    • METHOD TO INCREASE THE LEVEL OF 'alpha'-GLYCOL IN LIQUID EPOXY RESIN
    • 增加液体环氧树脂中α-甘露醇含量的方法
    • WO1995011266A1
    • 1995-04-27
    • PCT/US1994001502
    • 1994-02-14
    • THE DOW CHEMICAL COMPANY
    • THE DOW CHEMICAL COMPANYHAIRSTON, Thomas, J.
    • C08G59/14
    • C08G59/1427
    • The performance of expoxy resins in several end-uses is enhanced by the presence of small quantities of hydrolyzed resin terminated by alpha -glycol groups. The invention is a process in which a mixture that contains liquid epoxy resin and water is reacted at elevated temperatures in order to hydrolyze epoxy groups into alpha -glycol groups, characterized in that: (1) the reaction temperature is between 130 DEG C and 200 DEG C; (2) the reaction mixture contains between 0.5 and 10 parts water per 100 parts resin by weight; and (3) the mixture contains 0 to 1 weight percent organic solvents and 0 to 100 ppm each of: organic acids, organic diacids, phosphonium compounds, and alkali or alkaline earth metals and their salts. The process raises the level of alpha -glycol groups in the resin, but uses no solvents or catalysts, so that it is easy to clean up the resulting resin.
    • 通过存在少量由α-二醇基团封端的水解树脂,可以增强多种最终用途中的环氧树脂的性能。 本发明是一种将含有液体环氧树脂和水的混合物在升高的温度下反应以将环氧基水解成α-二醇基团的方法,其特征在于:(1)反应温度为130℃至200℃ ℃; (2)反应混合物每100份树脂重量含有0.5至10份水; 和(3)混合物含有0至1重量%的有机溶剂和0至100ppm的有机酸,有机二酸,鏻化合物和碱金属或碱土金属及其盐。 该方法提高了树脂中的α-二醇基团的水平,但不使用溶剂或催化剂,因此容易清除所得树脂。