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    • 96. 发明申请
    • METHODS AND SYSTEMS FOR LOW INTERFACIAL OXIDE CONTACT BETWEEN BARRIER AND COPPER METALLIZATION
    • 阻挡层和铜金属之间的低界面氧化物接触的方法和系统
    • US20100267229A1
    • 2010-10-21
    • US12828082
    • 2010-06-30
    • Fritz RedekerJohn BoydYezdi DordiHyungsuk Alexander YoonShijian Li
    • Fritz RedekerJohn BoydYezdi DordiHyungsuk Alexander YoonShijian Li
    • H01L21/768
    • C25D7/123C23C18/1653C23C28/023C23C28/322C23C28/34C23C28/341H01L21/28562H01L21/76843H01L21/76849H01L21/76856H01L21/76862H01L21/76873H01L21/76874H01L23/53238H01L2221/1089H01L2924/0002H01L2924/00
    • The present invention relates to methods and systems for the metallization of semiconductor devices. One aspect of the present invention is a method of depositing a copper layer onto a barrier layer so as to produce a substantially oxygen free interface therebetween. In one embodiment, the method includes providing a substantially oxide free surface of the barrier layer. The method also includes depositing an amount of atomic layer deposition (ALD) copper on the oxide free surface of the barrier layer effective to prevent oxidation of the barrier layer. The method further includes depositing a gapfill copper layer over the ALD copper. Another aspect of the present invention is a system for depositing a copper layer onto barrier layer so as to produce a substantially oxygen-free interface therebetween. In one embodiment, the integrated system includes at least one barrier deposition module. The system also includes an ALD copper deposition module configured to deposit copper by atomic layer deposition. The system further includes a copper gapfill module and at least one transfer module coupled to the at least one barrier deposition module and to the ALD copper deposition module. The transfer module is configured so that the substrate can be transferred between the modules substantially without exposure to an oxide-forming environment.
    • 本发明涉及用于半导体器件金属化的方法和系统。 本发明的一个方面是将铜层沉积在阻挡层上以在其间产生基本上无氧的界面的方法。 在一个实施例中,该方法包括提供阻挡层的基本上无氧化物的表面。 该方法还包括在阻挡层的无氧化物表面上沉积一定量的原子层沉积(ALD)铜,以有效地防止阻挡层的氧化。 该方法还包括在ALD铜上沉积间隙填充铜层。 本发明的另一方面是一种用于在阻挡层上沉积铜层以在其间产生基本上无氧的界面的系统。 在一个实施例中,集成系统包括至少一个阻挡层沉积模块。 该系统还包括配置为通过原子层沉积沉积铜的ALD铜沉积模块。 该系统还包括铜间隙填充模块和耦合到至少一个阻挡层沉积模块和ALD铜沉积模块的至少一个传输模块。 转移模块被配置为使得基板可以在基本上不暴露于氧化物形成环境的基础之间传递。
    • 98. 发明授权
    • Methods of post-contact back end of the line through-hole via integration
    • 线后通孔的通孔整合方法
    • US07615480B2
    • 2009-11-10
    • US11820811
    • 2007-06-20
    • John BoydFritz RedekerYezdi DordiHyungsuk Alexander YoonShijian Li
    • John BoydFritz RedekerYezdi DordiHyungsuk Alexander YoonShijian Li
    • H01L21/20
    • H01L23/48H01L21/4763H01L21/76898H01L2924/14
    • Presented are methods of fabricating three-dimensional integrated circuits that include post-contact back end of line through-hole via integration for the three-dimensional integrated circuits. In one embodiment, the method comprises forming metal plug contacts through a hard mask and a premetal dielectric to transistors in the semiconductor. The method also includes etching a hole for a through-hole via through the hard mask to the semiconductor using a patterned photoresist process, removing the patterned photoresist and using a hard mask process to etch the hole to an amount into the semiconductor. The method further includes depositing a dielectric liner to isolate the hole from the semiconductor, depositing a gapfill metal to fill the hole, and planarizing the surface of the substrate to the hard mask. Another aspect of the present invention includes three-dimensional integrated circuits fabricated according to methods of the present invention.
    • 提出了制造三维集成电路的方法,其包括用于三维集成电路的集成的线路通孔的后接触后端。 在一个实施例中,该方法包括通过硬掩模和前金属电介质形成金属插头触点到半导体中的晶体管。 该方法还包括使用图案化的光致抗蚀剂工艺将用于通孔的通孔穿过硬掩模蚀刻到半导体,去除图案化的光致抗蚀剂并使用硬掩模工艺将孔蚀刻到半导体中的量。 所述方法还包括沉积介电衬垫以将所述孔与所述半导体隔离,沉积间隙填充金属以填充所述孔,以及将所述衬底的表面平面化至所述硬掩模。 本发明的另一方面包括根据本发明的方法制造的三维集成电路。
    • 99. 发明申请
    • METHOD FOR MEASURING DOPANT CONCENTRATION DURING PLASMA ION IMPLANTATION
    • 在等离子体植入过程中测量痰浓度的方法
    • US20090233384A1
    • 2009-09-17
    • US12049047
    • 2008-03-14
    • Majeed A. FoadShijian Li
    • Majeed A. FoadShijian Li
    • H01L21/66
    • G01N21/68G01N21/59H01L21/26513H01L22/12H01L22/26
    • Embodiments of the invention generally provide methods for end point detection at predetermined dopant concentrations during plasma doping processes. In one embodiment, a method includes positioning a substrate within a process chamber, generating a plasma above the substrate and transmitting a light generated by the plasma through the substrate, wherein the light enters the topside and exits the backside of the substrate, and receiving the light by a sensor positioned below the substrate. The method further provides generating a signal proportional to the light received by the sensor, implanting the substrate with a dopant during a doping process, generating multiple light signals proportional to a decreasing amount of the light received by the sensor during the doping process, generating an end point signal proportional to the light received by the sensor once the substrate has a final dopant concentration, and ceasing the doping process.
    • 本发明的实施方案通常提供了在等离子体掺杂过程期间以预定掺杂剂浓度进行终点检测的方法。 在一个实施例中,一种方法包括将衬底定位在处理室内,在衬底上方产生等离子体,并将由等离子体产生的光透射穿过衬底,其中光进入顶侧并离开衬底的背面,并接收 通过位于基板下方的传感器进行光照射。 该方法进一步提供产生与传感器接收的光成比例的信号,在掺杂过程期间用掺杂剂注入衬底,在掺杂过程期间产生与传感器接收的减少量的光成比例的多个光信号,产生 一旦衬底具有最终的掺杂剂浓度,终点信号与传感器接收的光成比例,并停止掺杂过程。