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91. 发明授权

US5861357A 5-acylamino-2-alkoxycarbonylphenylsulfonylureas as selective herbicides 失效
标题翻译：作为选择性除草剂的5-酰基氨基-2-烷氧基羰基苯基磺酰脲
公开(公告)号：US5861357A
公开(公告)日：1999-01-19
申请号：US757372
申请日：1996-11-27
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： A01N47/36 , C07D521/00 , A01N43/20 , A01N43/54 , A01N43/66
CPC分类号： C07D521/00 , A01N47/36
摘要： Compounds of the formula (I) ##STR1## in which R.sup.1 to R.sup.5, X, W, n and Z are defined as in claim 1 are particularly suitable for use as selective herbicides in crops of useful plants.
摘要翻译：其中R1至R5，X，W，n和Z如权利要求1中所定义的式（I）化合物（I）特别适合用作有用植物作物中的选择性除草剂。

92. 发明授权

US5756422A Substituted quinoline compounds and their use as safeners 失效
标题翻译：取代的喹啉化合物及其作为安全剂的用途
公开(公告)号：US5756422A
公开(公告)日：1998-05-26
申请号：US535028
申请日：1995-10-18
申请人： Xenia Holdgrun , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Xenia Holdgrun , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N43/42 , A01N47/36 , C07D215/28
CPC分类号： C07D215/28 , A01N25/32 , A01N43/42 , A01N47/36
摘要： Substituted quinoline compounds, processes for their preparation, composition containing them, and their use as safeners Compounds of the formula I and salts thereof ##STR1## in which R.sup.1 �lacuna! CN, C(.dbd.Z)--Q(A.sub.i X.sub.i).sub.q --R, --C(.dbd.Z)--QR*, 1,2,3,4-tetrazol-5-yl, 1,3,4-triazol-2-yl, 1,3-oxazol-2-yl, and the remaining radicals are as defined in claim 1, are suitable for use as safeners for protecting crop plants such as, for example, cereals, rice and maize, against herbicide damage. Some of the compounds are known and some are novel and they can be prepared from quinolin-8-oxy derivatives by the processes of claim 7.
摘要翻译： PCT No.PCT / EP94 / 01396 Sec。 371 1995年10月18日第 102（e）日期1995年10月18日PCT 1994年5月2日PCT PCT。第WO94 / 26716号公报日期：1994年11月24日取代喹啉化合物，其制备方法，含有它们的组合物及其作为安全剂的用途式I化合物及其盐其中R1 [lacuna] CN，C（= Z） -Q（AiXi）qR，-C（= Z）-QR *，1,2,3,4-四唑-5-基，1,3,4-三唑-2-基，1,3-恶唑-2 并且剩余的基团如权利要求1中所定义，适合用作安全剂，用于保护作物植物，例如谷物，水稻和玉米，以防止除草剂损害。一些化合物是已知的，一些是新的，它们可以通过权利要求7的方法由喹啉-8-氧基衍生物制备。

93. 发明授权

US5698539A Mixtures of herbicides and antidotes, (hetero)-aryloxy compounds, their preparation, compositions containing them, and their use 失效
标题翻译：除草剂和解毒剂，（杂） - 芳氧基化合物的混合物，它们的制备，含有它们的组合物及其用途
公开(公告)号：US5698539A
公开(公告)日：1997-12-16
申请号：US461443
申请日：1995-06-05
申请人： Frank Ziemer , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Frank Ziemer , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N39/02 , A01N39/04 , A01N43/40 , A01N43/58 , A01N47/06 , A01N47/36 , C07C59/70 , C07C69/712 , C07C205/37 , C07D213/64 , C07D237/14 , A01N43/54
CPC分类号： C07D213/64 , A01N25/32 , A01N39/02 , A01N39/04 , A01N43/40 , A01N43/58 , A01N47/06 , A01N47/36 , C07C205/37 , C07C59/70 , C07C69/712 , C07D237/14
摘要： The invention relates to crop protection agents which comprise an active substance combination of herbicide and safener. The herbicides are selected from the group comprising the ALS inhibitors (ALS=acetolactate synthase) such as sulfonylureas, imidazolines, triazolopyrimidinesulfonamides, pyrimidyloxypyridinecarboxylic acid derivatives and pyrimidyloxybenzoic acid derivatives. The safeners are compounds of the formula I ##STR1## which are as defined in claim 1, where Z and Y are N or CH, it being possible for H to be replaced by X, X is H, Hal, haloalkyl or -alkoxy, alkyl, alkoxy, alkylthio, NO.sub.2, NH.sub.2, CN, alkylsulfonyl, A is alkylene or alkenylene, B is carboxyl or a derivative of the carboxyl group. The mixtures are mainly suitable for controlling harmful plants in the crops maize and cereals.
摘要翻译：本发明涉及包含除草剂和安全剂的活性物质组合的作物保护剂。除草剂选自包括ALS抑制剂（ALS =乙酰乳酸合成酶）如磺酰脲，咪唑啉，三唑并嘧啶磺酰胺，嘧啶氧基吡啶羧酸衍生物和嘧啶氧基苯甲酸衍生物。安全剂是如权利要求1所定义的式I（I）化合物，其中Z和Y是N或CH，H可被X代替，X是H，Hal，卤代烷基或 - 烷氧基，烷基，烷氧基，烷硫基，NO2，NH2，CN，烷基磺酰基，A是亚烷基或亚烯基，B是羧基或羧基的衍生物。混合物主要适用于控制作物玉米和谷物中的有害植物。

94. 发明授权

US5658854A Acylated aminophenylsulfonylureas; preparation and use as herbicides and plant growth regulators 失效
标题翻译：酰化氨基苯基磺酰脲作为除草剂和植物生长调节剂的制备和使用
公开(公告)号：US5658854A
公开(公告)日：1997-08-19
申请号：US268274
申请日：1994-06-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D239/42 , A01N47/36 , A01N47/46 , A01P13/02 , C07C309/89 , C07C311/39 , C07C311/65 , C07D239/47 , C07D239/48 , C07D251/44 , C07D251/46 , C07D251/48 , C07D251/52 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36 , C07C309/89 , C07C311/39 , C07C311/65
摘要： Acylated aminophenylureas, preparation and use as herbicides and plant growth regulatorsThe compounds of the formula I or their salts ##STR1## in which G is a radical G1, G2 or G3 ##STR2## R.sup.1 is H or alkyl, R.sup.2 is COOH, CSOH or a derivative of the carboxyl or thiocarboxyl group, of 1 to 20 carbon atoms, or acyl of the type CO-R.degree. of 1-12 carbon atoms, or an imino, hydrazone or oxime derivative of the group CO-R.degree., and R.degree. , R.sup.3a, R.sup.4a, R.sup.3b, R.sup.4b, W, X, Y and Z are as defined in claim 1, are suitable as selective herbicides and plant growth regulators in crops.The preparation is carried out in analogy to known processes (see claim 5) by way of intermediates, some of which are new, from the group consisting of benzene-sulfonamides (II), benzenesulfonyl isocyanates (IV) and benzesulfonyl chlorides (VI) and heterocyclically substituted carbamates (III), amines (V) and/or (thio)-isocyanates (XIX).
摘要翻译：酰化氨基苯基脲，作为除草剂和植物生长调节剂的制备和用途式I化合物或其盐，其中G是基团G1，G2或G3（G1）（图像）（G2）（G3）R1为H或烷基，R2为COOH，CSOH或含1-20个碳原子的羧基或硫代羧基的衍生物，或碳原子数为1〜12的CO-R DEG型酰基，或CO-R DEG基团的亚氨基，腙或肟衍生物，R DEG，R3a，R4a，R3b，R4b，W，X，Y和Z如权利要求1所定义，适合作为选择性除草剂和植物生长农作物的监管者。类似于已知方法（参见权利要求5），通过中间体（其中一些是新的），由苯磺酰胺（II），苯磺酰基异氰酸酯（IV）和苯磺酰氯（VI）和苯磺酰基异氰酸酯杂环取代的氨基甲酸酯（III），胺（V）和/或（硫代） - 异氰酸酯（XIX）。

95. 发明授权

US5516750A Substituted isoxazolines, process for their preparation, composition containing them, and their use of safeners 失效
标题翻译：取代的异恶唑啉，其制备方法，含有它们的组合物及其使用安全剂
公开(公告)号：US5516750A
公开(公告)日：1996-05-14
申请号：US306110
申请日：1994-09-14
申请人： Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D261/04 , A01N25/32 , A01N35/06 , A01N39/02 , A01N43/80 , A01N47/36 , A01P13/00 , C07D413/04 , C07D413/06 , A01N43/72 , C07D261/02
CPC分类号： A01N25/32 , A01N43/80
摘要： Substituted isoxazolines, process for their preparation, compositions containing them, and their use as safeners.Compounds of the formula (I) and salts thereof, ##STR1## in which R.sup.1 is carboxyl, formyl or another acyl radical or a derivative of the last-mentioned 3 groups,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.18 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.2 -C.sub.8 -alkynyl, C.sub.1 -C.sub.18 -alkoxy, C.sub.2 -C.sub.8 -alkenyloxy, C.sub.2 -C.sub.8 -alkynyloxy, C.sub.1 -C.sub.18 -alkylthio, C.sub.2 -C.sub.8 -alkenylthio, each of the last-mentioned 9 radicals in each case being unsubstituted or substituted, or (C.sub.1 -C.sub.8 -alkoxy)carbonyl, andR.sup.3 and R.sup.4 independently of one another are an aliphatic, araliphatic or heteroaraliphatic radical having 1 to 30 carbon atoms which is unsubstituted or substituted by one or more functional groups, oran aromatic or heteroaromatic radical which is unsubstituted or substituted,are suitable as safenets for pesticides, preferably herbicides, in crop plants. The compounds can be prepared from alkenes (II) and nitrile oxides (III) by the process of claim 6.
摘要翻译：取代的异恶唑啉，其制备方法，含有它们的组合物及其作为安全剂的用途。式（I）化合物及其盐，其中R1是羧基，甲酰基或另一个酰基或最后提到的3个基团的衍生物，其中R 2是氢，卤素，C 1 -C 18 - 烷基，C 3 -C 8 - 环烷基，C 2 -C 8 - 烯基，C 2 -C 8 - 炔基，C 1 -C 18 - 烷氧基，C 2 -C 8 - 烯氧基，C 2 -C 8 - 炔氧基，C 1 -C 18烷硫基，在每种情况下最后提及的9个基团是未取代的或取代的，或（C 1 -C 8 - 烷氧基）羰基，且R 3和R 4彼此独立地是具有1至30个碳原子的脂族，芳脂族或杂脂族基团，其是未取代的或被一个或多个官能团取代，或未取代或取代的芳族或杂芳族基团适合作为农作物的保藏剂，优选除草剂在作物植物中。化合物可以通过权利要求6的方法由烯烃（II）和氧化腈（III）制备。

96. 发明授权

US5155222A Process for the preparation of N-alkylsulfonylaminosulfonylureas 失效
标题翻译：制备N-烷基磺酰氨基脲的方法
公开(公告)号：US5155222A
公开(公告)日：1992-10-13
申请号：US731518
申请日：1991-07-17
申请人： Stephen Lachhein , Lothar Willms
发明人： Stephen Lachhein , Lothar Willms
IPC分类号： A01N47/36 , A01N43/54 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D521/00
CPC分类号： C07D521/00
摘要： Known herbicides of the formula (I) ##STR1## in which R.sup.1 is alkyl, alkenyl or alkynyl, which are optionally substituted by halogen, alkoxy or alkoxycarbonyl,R.sup.2 is H, alkyl, alkenyl, alkynyl or cycloalkyl,R.sup.3 and R.sup.4 are H or alkyl,R.sup.5 and R.sup.6 are H, alkyl or alkoxy, each of which can be substituted by halogen, alkoxy or alkylthio, or are halogen, alkylthio, alkylamino or dialkylamino,or, if R.sup.2 or R.sup.3 is H, their salts with bases, can be obtained when compounds of the formula IIR.sup.1 -SO.sub.2 -NR.sup.2 -SO.sub.2 -NHR.sup.3 (II)in whichR.sup.1, R.sup.2 and R.sup.3 are as defined above,are reacted with compounds of the formula III ##STR2## in which R.sup.4, R.sup.5 and R.sup.6 are as defined above andR.sup.7 is alkyl, haloalkyl or optionally substituted phenyl,in an inert organic solvent, to give the compounds of the formula I.
摘要翻译：式（I）的已知除草剂其中R 1为任选被卤素，烷氧基或烷氧基羰基取代的烷基，烯基或炔基，R 2为H，烷基，烯基，炔基或环烷基，R 3和R 4 卤素，烷硫基，烷基氨基或二烷基氨基，或者如果R2或R3是H，则它们的盐与当其中R 1，R 2和R 3如上所定义的式IIR 1 -SO 2 -NR 2 -SO 2 -NHR 3（II）的化合物与式III的化合物（III）反应时，可以获得碱，其中R4，R5和R6如上定义，R7是烷基，卤代烷基或任选取代的苯基，在惰性有机溶剂中，得到式I化合物。

97. 发明授权

US5129941A Heterocyclically substituted sulfonylureas, and their use as herbicides or plant growth regulators 失效
标题翻译：杂环取代的磺酰脲，它们作为除草剂或植物生长调节剂
公开(公告)号：US5129941A
公开(公告)日：1992-07-14
申请号：US553702
申请日：1990-07-17
申请人： Heinz-Josef Loher , Lothar Willms , Michael Frey , Klaus Bauer , Hermann Bierigner
发明人： Heinz-Josef Loher , Lothar Willms , Michael Frey , Klaus Bauer , Hermann Bierigner
IPC分类号： C07D249/14 , A01N43/54 , A01N43/66 , A01N43/90 , A01N47/36 , C07C307/06 , C07C311/32 , C07C311/34 , C07C311/47 , C07C311/48 , C07C311/65 , C07C313/06 , C07C313/36 , C07C317/28 , C07C323/49 , C07C335/42 , C07D239/26 , C07D239/30 , C07D239/32 , C07D239/34 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/70 , C07D251/12 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/44 , C07D251/46 , C07D251/52 , C07D251/70 , C07D401/12 , C07D403/12 , C07D471/04 , C07D473/16 , C07D473/18 , C07D473/24 , C07D473/32 , C07D473/40 , C07D475/04 , C07D475/08 , C07D487/04 , C07D491/04 , C07D491/048 , C07D491/052 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Sulfonylureas of the formula ##STR1## where A is a bond or a C.sub.1 -C.sub.10 -hydrocarbon radical,R.sup.1 is an optionally unsaturated hydrocarbon radical which is optionally substituted by halogen, optionally unsaturated alkoxy, alkylthio, alkylsulfonyl or alkylsulfinyl, cycloalkyl, optionally substituted phenyl or a heterocycle, or is optionally substituted phenyl, NRR' with R and R' being alkyl, alkoxy or alkylene (cyclic with N),Y is S, SO or SO.sub.2,R.sup.1 is optionally unsaturated alkoxy which is optionally substituted, or is cycloalkoxy, cycloalkenyloxy, cyclopropylmethyloxy, epoxypropyloxy, furfuryloxy, tetrahydrofurfuryloxy or optionally substituted phenoxyalkoxy or phenoxy,R.sup.3 is alkyl which is optionally unsaturated, or is alkoxy,R.sup.4 is optionally substituted pyrimidinyl, pyrimidinylmethyl, pyrimidinyl with a fused-on cyclopentane, oxolane, oxolene, oxane, pyridine or pyrazine ring or purinyl or triazolyl, andZ is O or S,have herbicidal and/or plant-growth-regulatory properties.
摘要翻译：式（I）的磺酰脲，其中A是键或C1-C10-烃基，R1是任选不饱和的烃基，其任选被卤素，任选不饱和的烷氧基，烷硫基，烷基磺酰基或烷基亚磺酰基，环烷基，或任选取代的苯基或杂环，或任选取代的苯基，NR R'与R和R'为烷基，烷氧基或亚烷基（与N一起环状），Y为S，SO或SO 2，R 1为任选取代的任意不饱和烷氧基，或者是环烷氧基，环烯氧基，环丙基甲氧基，环氧丙氧基，呋喃氧基，四氢呋喃氧基或任选取代的苯氧基烷氧基或苯氧基，R3是任选不饱和的烷基，或是烷氧基，R 4是任选被取代的嘧啶基，嘧啶基甲基，嘧啶基与稠合的环戊烷，吡咯或吡嗪环或嘌呤基或三唑基，Z为O或S具有除草和/或植物生长调节性质。

98. 发明授权

US5103004A N-sultamsulfonamides 失效
标题翻译： N-SULTAMSULFONAMIDES
公开(公告)号：US5103004A
公开(公告)日：1992-04-07
申请号：US749158
申请日：1991-08-23
申请人： Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
发明人： Lothar Willms , Klaus Bauer , Hermann Bieringer , Helmut Burstell
IPC分类号： A01N47/36 , C07D417/12 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Heterocyclically substituted N-sultamsulfonamides, processes for their preparation and their use as herbicides and plant growth regulators.Compounds of the formula I or their salts ##STR1## wherein R.sup.1 and R.sup.2 denote H, halogen, alkyl, alkenyl, alkynyl or alkoxy, which can be substituted, or denote --(CH.sub.2).sub.n --COOR.sup.11 ;R.sup.3 denotes H, alkyl, alkenyl or alkynyl;R.sup.4 denotes a heterocyclic radical of the formulae ##STR2## where E is CH or N; X is O or S and a, b, c, d, e in each case denote 0, 1 or 2, with the proviso that c+d+e.gtoreq.2, possess excellent herbicidal and plant growth-regulating properties.

99. 发明授权

US4718937A N-alkoxyaminosulfonylureas and N-alkylsulfonylaminosulfonylureas 失效
标题翻译： N-烷氧基氨基磺酰脲和N-烷基磺酰基氨基磺酰脲
公开(公告)号：US4718937A
公开(公告)日：1988-01-12
申请号：US849737
申请日：1986-04-09
申请人： Lothar Willms , Hilmar Mildenberger , Klaus Bauer , Helmut Burstell
发明人： Lothar Willms , Hilmar Mildenberger , Klaus Bauer , Helmut Burstell
IPC分类号： C07D251/16 , A01N47/36 , A01N57/36 , A01P13/00 , C07D239/42 , C07D239/47 , C07D239/52 , C07D251/46 , C07D513/04 , C07D521/00 , C07D251/52 , A01N43/66 , A01N43/70
CPC分类号： C07D521/00 , A01N47/36 , C07D513/04
摘要： The compounds of the general formula (I) ##STR1## in which X denotes O or --SO.sub.2 --, Y denotes CH or N, R.sub.1 denotes alkyl, alkenyl or (C.sub.2 -C.sub.6)-alkinyl which are optionally substituted, R.sub.2 denotes alkyl, alkenyl, alkinyl or cyclohexyl, R.sub.3 and R.sub.4 denote H or alkyl, and R.sub.5 and R.sub.6 denote H, (substituted) alkyl, (substituted) alkoxy, halogen, alkylthio, monoalkylamino or dialkylamino, and also salts thereof, possess advantageous herbicidal properties against monocotyledonous and dicotyledonous weeds and are suitable for selective use in large-scale crops. In addition, they possess a good plant growth-regulating action.
摘要翻译：通式（I）的化合物其中X表示O或-SO 2 - ，Y表示CH或N，R 1表示任选被取代的烷基，烯基或（C 2 -C 6） - alk基，R 2表示烷基，链烯基，炔基或环己基，R 3和R 4表示H或烷基，R 5和R 6表示H，（取代的）烷基，（取代的）烷氧基，卤素，烷硫基，单烷基氨基或二烷基氨基及其盐具有有利的除草性单子叶和双子叶杂草，适用于大规模作物的选择性使用。此外，它们具有良好的植物生长调节作用。

100. 发明授权

US4448731A 1,2-Dihalogenoalkylsulfonyl isocyanates and 1,2-di-halogenocycloalkylsulfonyl isocyanates and process for their manufacture 失效
标题翻译： 1,2-二卤代烷基磺酰基异氰酸酯和1,2-二卤代环烷基磺酰基异氰酸酯及其制备方法
公开(公告)号：US4448731A
公开(公告)日：1984-05-15
申请号：US412848
申请日：1982-08-30
申请人： Lothar Willms , Dieter Gunther , Thomas Huttelmaier
发明人： Lothar Willms , Dieter Gunther , Thomas Huttelmaier
IPC分类号： A01N47/40 , A01N41/02 , C07C67/00 , C07C301/00 , C07C303/40 , C07C311/50 , C07C143/828
CPC分类号： C07C311/65
摘要： Compounds of the formula ##STR1## wherein X is halogen, R.sub.1 and R.sub.2 are hydrogen, halogen, (halo)alk(en)yl, (halo)alkoxyalkyl or together form an (optionally substituted) alkylene bridge, and R.sub.3 is hydrogen, alkyl or halogen are valuable intermediates in particular for the manufacture of pesticides.
摘要翻译：式（I）的化合物其中X为卤素，R 1和R 2为氢，卤素，（卤素）烷基（环）基，（卤素）烷氧基烷基或一起形成（任选取代的）亚烷基桥，R3为氢，烷基或卤素是有价值的中间体，特别是制造农药的中间体。

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