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1. 发明授权

US5756422A Substituted quinoline compounds and their use as safeners 失效
标题翻译：取代的喹啉化合物及其作为安全剂的用途
公开(公告)号：US5756422A
公开(公告)日：1998-05-26
申请号：US535028
申请日：1995-10-18
申请人： Xenia Holdgrun , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Xenia Holdgrun , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N43/42 , A01N47/36 , C07D215/28
CPC分类号： C07D215/28 , A01N25/32 , A01N43/42 , A01N47/36
摘要： Substituted quinoline compounds, processes for their preparation, composition containing them, and their use as safeners Compounds of the formula I and salts thereof ##STR1## in which R.sup.1 �lacuna! CN, C(.dbd.Z)--Q(A.sub.i X.sub.i).sub.q --R, --C(.dbd.Z)--QR*, 1,2,3,4-tetrazol-5-yl, 1,3,4-triazol-2-yl, 1,3-oxazol-2-yl, and the remaining radicals are as defined in claim 1, are suitable for use as safeners for protecting crop plants such as, for example, cereals, rice and maize, against herbicide damage. Some of the compounds are known and some are novel and they can be prepared from quinolin-8-oxy derivatives by the processes of claim 7.
摘要翻译： PCT No.PCT / EP94 / 01396 Sec。 371 1995年10月18日第 102（e）日期1995年10月18日PCT 1994年5月2日PCT PCT。第WO94 / 26716号公报日期：1994年11月24日取代喹啉化合物，其制备方法，含有它们的组合物及其作为安全剂的用途式I化合物及其盐其中R1 [lacuna] CN，C（= Z） -Q（AiXi）qR，-C（= Z）-QR *，1,2,3,4-四唑-5-基，1,3,4-三唑-2-基，1,3-恶唑-2 并且剩余的基团如权利要求1中所定义，适合用作安全剂，用于保护作物植物，例如谷物，水稻和玉米，以防止除草剂损害。一些化合物是已知的，一些是新的，它们可以通过权利要求7的方法由喹啉-8-氧基衍生物制备。

2. 发明授权

US5739079A Substituted (hetero) aryl compounds, process for their preparation, agents containing them and their use as safeners 失效
标题翻译：取代的（杂）芳基化合物，其制备方法，含有它们的试剂及其作为安全剂的用途
公开(公告)号：US5739079A
公开(公告)日：1998-04-14
申请号：US440886
申请日：1995-05-15
申请人： Xenia Holdgrun , Lothar Willms , Klaus Bauer , Klaus Trinks , Hermann Bieringer
发明人： Xenia Holdgrun , Lothar Willms , Klaus Bauer , Klaus Trinks , Hermann Bieringer
IPC分类号： A01N39/00 , A01N25/32 , C07C59/66 , C07C59/68 , C07C69/712 , C07C69/716 , C07C205/56 , C07C243/22 , C07C251/38 , C07C255/13 , C07C255/19 , C07C323/52 , C07D213/64 , C07D215/26 , C07D215/28 , C07D239/34 , C07D239/42 , C07D251/12 , C07D263/58
CPC分类号： C07D213/64 , A01N25/32 , C07C323/52 , C07C59/68 , C07C69/712 , C07C69/716 , C07D215/26 , C07D215/28 , C07D239/34 , C07D263/58
摘要： Substituted (hetero)aryl compounds, process for their preparation, agents containing them, and their use as safeners Compounds of the formula I and their salts, as defined in claim 1, are suitable as safeners for protecting crop plants against the phytotoxic side-effects of herbicides.
摘要翻译：取代的（杂）芳基化合物，其制备方法，含有它们的试剂及其作为安全剂的用途如权利要求1所定义的式I化合物及其盐适合作为保护作物对植物毒性副作用的安全剂的除草剂。

3. 发明授权

US06410482B1 (Het) arylsulfonylureas having an amino function, their presentation and their use as herbicides and plant growth regulators 失效
标题翻译：（Het）芳基磺酰脲具有氨基功能，它们的表现及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06410482B1
公开(公告)日：2002-06-25
申请号：US08855251
申请日：1997-05-13
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D40112
CPC分类号： C07D521/00 , A01N47/36 , C07C311/46
摘要： (Het)Arylsulfonylureas having an imino function, their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof in which A is a (hetero)aromatic or heterocyclic bridge linked to the group SO2 by a direct bond, or via O, S, NH, CH2 or via alkylated NH or alkylated methylene, B is a group having an imino-containing fragment N═C—N, N═C—S, N═C—O or N═C—C which is linked to A by one of the nitrogen atoms of the fragment, R═H or an aliphatic radical, W═O or S and X, Y and Z are as defined in claim 1 are suitable as herbicides and plant growth regulators. The preparation is carried out for example similarly to known processes via novel intermediates of the formula (XII) (cf. claims 6 and 10),
摘要翻译：（Het）具有亚氨基功能的芳基磺酰脲，它们的制备及其作为除草剂和植物生长调节剂的用途式（I）化合物及其盐，其中A是通过直接连接到基团SO 2上的（杂）芳族或杂环桥或通过O，S，NH，CH 2或通过烷基化NH或烷基化亚甲基，B是具有亚氨基的片段N = CN，N = CS，N = CO或N = CC的基团，其通过所述片段的氮原子之一R = H或脂族基，W = O或S和X，Y和Z如权利要求1中所定义，适合作为除草剂和植物生长调节剂。通过式（XII）的新型中间体（参见权利要求6和10）类似于已知方法进行制备，

4. 发明授权

US06331506B1 Disubstituted methylidene hydrazinophenyl sulfonylureas, process for their production and their use as herbicides and plant growth regulators 失效
标题翻译：二取代亚甲基肼基苯基磺酰脲，其生产方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06331506B1
公开(公告)日：2001-12-18
申请号：US09142961
申请日：1998-09-16
申请人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Heinz Kehne , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D23948
CPC分类号： C07D521/00 , A01N47/36
摘要： Disubstituted methylidenehydrazinophenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof in which R1 to R6, W, X, Y, Z are as defined in claim 1 and the group R2R3C is a carbon atom which is subsituted by at least one electron-withdrawing radical R2 or R3 are suitable as herbicides and plant growth regulators. They can be prepared in accordance with known processes via intermediates, some of which are novel.
摘要翻译：二取代亚甲基肼基苯基磺酰脲，其制备方法及其作为除草剂和植物生长调节剂的用途式（I）化合物及其盐，其中R 1至R 6，W，X，Y，Z如权利要求1所定义，R 2 R 3 C为碳由至少一个吸电子基团R2或R3取代的原子适合作为除草剂和植物生长调节剂。它们可以根据已知方法通过中间体制备，其中一些是新颖的。

5. 发明授权

US06239071B1 2,4-diamino-1,3,5-triazines, processes for their preparation and their use as herbicides and plant growth regulators 失效
标题翻译： 2,4-二氨基-1,3,5-三嗪，其制备方法及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06239071B1
公开(公告)日：2001-05-29
申请号：US08701360
申请日：1996-08-22
申请人： Wolfgang Giencke , Klemens Minn , Lothar Willms , Hermann Bieringer , Klaus Bauer , Christopher Rosinger
发明人： Wolfgang Giencke , Klemens Minn , Lothar Willms , Hermann Bieringer , Klaus Bauer , Christopher Rosinger
IPC分类号： A01N4368
CPC分类号： C07D251/18
摘要： Compounds of the formula (I) and their salts in which R1 is optionally substituted (C1-C6)alkyl or optionally substituted phenyl, A is an optionally substituted hydrocarbon diradical and R2, R3, R4, R5, X and n are as defined in claim 1, are suitable as herbicides and plant growth regulators. The compounds (I) can be prepared according to processes as claimed in claim 6 by means of intermediates which are novel in some cases, e.g. of the formula (IV) as claimed in claim 10.
摘要翻译：式（I）化合物及其盐，其中R 1为任选取代的（C 1 -C 6）烷基或任意取代的苯基，A为任选取代的烃基，R 2，R 3，R 4，R 5，X和n如权利要求1所定义，适合作为除草剂和植物生长调节剂。化合物（I）可以根据权利要求6所述的方法，通过中间体制备，所述中间体在一些情况下是新的，例如。权利要求10所述的式（IV）化合物。

6. 发明授权

US5861357A 5-acylamino-2-alkoxycarbonylphenylsulfonylureas as selective herbicides 失效
标题翻译：作为选择性除草剂的5-酰基氨基-2-烷氧基羰基苯基磺酰脲
公开(公告)号：US5861357A
公开(公告)日：1999-01-19
申请号：US757372
申请日：1996-11-27
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： A01N47/36 , C07D521/00 , A01N43/20 , A01N43/54 , A01N43/66
CPC分类号： C07D521/00 , A01N47/36
摘要： Compounds of the formula (I) ##STR1## in which R.sup.1 to R.sup.5, X, W, n and Z are defined as in claim 1 are particularly suitable for use as selective herbicides in crops of useful plants.
摘要翻译：其中R1至R5，X，W，n和Z如权利要求1中所定义的式（I）化合物（I）特别适合用作有用植物作物中的选择性除草剂。

7. 发明授权

US5698539A Mixtures of herbicides and antidotes, (hetero)-aryloxy compounds, their preparation, compositions containing them, and their use 失效
标题翻译：除草剂和解毒剂，（杂） - 芳氧基化合物的混合物，它们的制备，含有它们的组合物及其用途
公开(公告)号：US5698539A
公开(公告)日：1997-12-16
申请号：US461443
申请日：1995-06-05
申请人： Frank Ziemer , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Frank Ziemer , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N39/02 , A01N39/04 , A01N43/40 , A01N43/58 , A01N47/06 , A01N47/36 , C07C59/70 , C07C69/712 , C07C205/37 , C07D213/64 , C07D237/14 , A01N43/54
CPC分类号： C07D213/64 , A01N25/32 , A01N39/02 , A01N39/04 , A01N43/40 , A01N43/58 , A01N47/06 , A01N47/36 , C07C205/37 , C07C59/70 , C07C69/712 , C07D237/14
摘要： The invention relates to crop protection agents which comprise an active substance combination of herbicide and safener. The herbicides are selected from the group comprising the ALS inhibitors (ALS=acetolactate synthase) such as sulfonylureas, imidazolines, triazolopyrimidinesulfonamides, pyrimidyloxypyridinecarboxylic acid derivatives and pyrimidyloxybenzoic acid derivatives. The safeners are compounds of the formula I ##STR1## which are as defined in claim 1, where Z and Y are N or CH, it being possible for H to be replaced by X, X is H, Hal, haloalkyl or -alkoxy, alkyl, alkoxy, alkylthio, NO.sub.2, NH.sub.2, CN, alkylsulfonyl, A is alkylene or alkenylene, B is carboxyl or a derivative of the carboxyl group. The mixtures are mainly suitable for controlling harmful plants in the crops maize and cereals.
摘要翻译：本发明涉及包含除草剂和安全剂的活性物质组合的作物保护剂。除草剂选自包括ALS抑制剂（ALS =乙酰乳酸合成酶）如磺酰脲，咪唑啉，三唑并嘧啶磺酰胺，嘧啶氧基吡啶羧酸衍生物和嘧啶氧基苯甲酸衍生物。安全剂是如权利要求1所定义的式I（I）化合物，其中Z和Y是N或CH，H可被X代替，X是H，Hal，卤代烷基或 - 烷氧基，烷基，烷氧基，烷硫基，NO2，NH2，CN，烷基磺酰基，A是亚烷基或亚烯基，B是羧基或羧基的衍生物。混合物主要适用于控制作物玉米和谷物中的有害植物。

8. 发明授权

US5658854A Acylated aminophenylsulfonylureas; preparation and use as herbicides and plant growth regulators 失效
标题翻译：酰化氨基苯基磺酰脲作为除草剂和植物生长调节剂的制备和使用
公开(公告)号：US5658854A
公开(公告)日：1997-08-19
申请号：US268274
申请日：1994-06-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D239/42 , A01N47/36 , A01N47/46 , A01P13/02 , C07C309/89 , C07C311/39 , C07C311/65 , C07D239/47 , C07D239/48 , C07D251/44 , C07D251/46 , C07D251/48 , C07D251/52 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36 , C07C309/89 , C07C311/39 , C07C311/65
摘要： Acylated aminophenylureas, preparation and use as herbicides and plant growth regulatorsThe compounds of the formula I or their salts ##STR1## in which G is a radical G1, G2 or G3 ##STR2## R.sup.1 is H or alkyl, R.sup.2 is COOH, CSOH or a derivative of the carboxyl or thiocarboxyl group, of 1 to 20 carbon atoms, or acyl of the type CO-R.degree. of 1-12 carbon atoms, or an imino, hydrazone or oxime derivative of the group CO-R.degree., and R.degree. , R.sup.3a, R.sup.4a, R.sup.3b, R.sup.4b, W, X, Y and Z are as defined in claim 1, are suitable as selective herbicides and plant growth regulators in crops.The preparation is carried out in analogy to known processes (see claim 5) by way of intermediates, some of which are new, from the group consisting of benzene-sulfonamides (II), benzenesulfonyl isocyanates (IV) and benzesulfonyl chlorides (VI) and heterocyclically substituted carbamates (III), amines (V) and/or (thio)-isocyanates (XIX).
摘要翻译：酰化氨基苯基脲，作为除草剂和植物生长调节剂的制备和用途式I化合物或其盐，其中G是基团G1，G2或G3（G1）（图像）（G2）（G3）R1为H或烷基，R2为COOH，CSOH或含1-20个碳原子的羧基或硫代羧基的衍生物，或碳原子数为1〜12的CO-R DEG型酰基，或CO-R DEG基团的亚氨基，腙或肟衍生物，R DEG，R3a，R4a，R3b，R4b，W，X，Y和Z如权利要求1所定义，适合作为选择性除草剂和植物生长农作物的监管者。类似于已知方法（参见权利要求5），通过中间体（其中一些是新的），由苯磺酰胺（II），苯磺酰基异氰酸酯（IV）和苯磺酰氯（VI）和苯磺酰基异氰酸酯杂环取代的氨基甲酸酯（III），胺（V）和/或（硫代） - 异氰酸酯（XIX）。

9. 发明授权

US5529976A Pyridyl sulphonyl ureas as herbicides and plant growth regulators 失效
标题翻译：吡啶磺酰脲作为除草剂和植物生长调节剂
公开(公告)号：US5529976A
公开(公告)日：1996-06-25
申请号：US336571
申请日：1994-11-09
申请人： Heinz Kehne , Lothar Willms , Oswald Ort , Klaus Bauer , Hermann Bieringer
发明人： Heinz Kehne , Lothar Willms , Oswald Ort , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N47/36 , A47B91/06 , C07D213/76 , C07D401/12 , C07D521/00 , A01N43/66 , A01N43/68
CPC分类号： C07D213/76 , A01N47/36 , C07D401/12 , C07D521/00
摘要： Compounds of formula (I), where R.sup.1, R.sup.2, n, W, R.sup.3 and A are as defined in claim 1, are suitable for use as herbicides and plant growth regulators. They can be produced by a process similar to known processes. To produce them, new compounds of formula (II) are reacted with a carbamate of formula R.sup.* --O--CO--NR.sup.3 A, where R.sup.3 stands for phenyl or alkyl. The compounds of formula (II) can be obtained from the corresponding sulphochlorides.
摘要翻译：式（I）的化合物，其中R 1，R 2，n，W，R 3和A如权利要求1中所定义，适用于除草剂和植物生长调节剂。它们可以通过与已知方法类似的方法生产。为了制备它们，式（II）的新化合物与式R * -O-CO-NR 3 A的氨基甲酸酯反应，其中R3代表苯基或烷基。式（II）化合物可以从相应的氯化亚砜获得。

10. 发明授权

US5516750A Substituted isoxazolines, process for their preparation, composition containing them, and their use of safeners 失效
标题翻译：取代的异恶唑啉，其制备方法，含有它们的组合物及其使用安全剂
公开(公告)号：US5516750A
公开(公告)日：1996-05-14
申请号：US306110
申请日：1994-09-14
申请人： Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D261/04 , A01N25/32 , A01N35/06 , A01N39/02 , A01N43/80 , A01N47/36 , A01P13/00 , C07D413/04 , C07D413/06 , A01N43/72 , C07D261/02
CPC分类号： A01N25/32 , A01N43/80
摘要： Substituted isoxazolines, process for their preparation, compositions containing them, and their use as safeners.Compounds of the formula (I) and salts thereof, ##STR1## in which R.sup.1 is carboxyl, formyl or another acyl radical or a derivative of the last-mentioned 3 groups,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.18 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.2 -C.sub.8 -alkynyl, C.sub.1 -C.sub.18 -alkoxy, C.sub.2 -C.sub.8 -alkenyloxy, C.sub.2 -C.sub.8 -alkynyloxy, C.sub.1 -C.sub.18 -alkylthio, C.sub.2 -C.sub.8 -alkenylthio, each of the last-mentioned 9 radicals in each case being unsubstituted or substituted, or (C.sub.1 -C.sub.8 -alkoxy)carbonyl, andR.sup.3 and R.sup.4 independently of one another are an aliphatic, araliphatic or heteroaraliphatic radical having 1 to 30 carbon atoms which is unsubstituted or substituted by one or more functional groups, oran aromatic or heteroaromatic radical which is unsubstituted or substituted,are suitable as safenets for pesticides, preferably herbicides, in crop plants. The compounds can be prepared from alkenes (II) and nitrile oxides (III) by the process of claim 6.
摘要翻译：取代的异恶唑啉，其制备方法，含有它们的组合物及其作为安全剂的用途。式（I）化合物及其盐，其中R1是羧基，甲酰基或另一个酰基或最后提到的3个基团的衍生物，其中R 2是氢，卤素，C 1 -C 18 - 烷基，C 3 -C 8 - 环烷基，C 2 -C 8 - 烯基，C 2 -C 8 - 炔基，C 1 -C 18 - 烷氧基，C 2 -C 8 - 烯氧基，C 2 -C 8 - 炔氧基，C 1 -C 18烷硫基，在每种情况下最后提及的9个基团是未取代的或取代的，或（C 1 -C 8 - 烷氧基）羰基，且R 3和R 4彼此独立地是具有1至30个碳原子的脂族，芳脂族或杂脂族基团，其是未取代的或被一个或多个官能团取代，或未取代或取代的芳族或杂芳族基团适合作为农作物的保藏剂，优选除草剂在作物植物中。化合物可以通过权利要求6的方法由烯烃（II）和氧化腈（III）制备。

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