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1. 发明授权

US5129941A Heterocyclically substituted sulfonylureas, and their use as herbicides or plant growth regulators 失效
标题翻译：杂环取代的磺酰脲，它们作为除草剂或植物生长调节剂
公开(公告)号：US5129941A
公开(公告)日：1992-07-14
申请号：US553702
申请日：1990-07-17
申请人： Heinz-Josef Loher , Lothar Willms , Michael Frey , Klaus Bauer , Hermann Bierigner
发明人： Heinz-Josef Loher , Lothar Willms , Michael Frey , Klaus Bauer , Hermann Bierigner
IPC分类号： C07D249/14 , A01N43/54 , A01N43/66 , A01N43/90 , A01N47/36 , C07C307/06 , C07C311/32 , C07C311/34 , C07C311/47 , C07C311/48 , C07C311/65 , C07C313/06 , C07C313/36 , C07C317/28 , C07C323/49 , C07C335/42 , C07D239/26 , C07D239/30 , C07D239/32 , C07D239/34 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/70 , C07D251/12 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/44 , C07D251/46 , C07D251/52 , C07D251/70 , C07D401/12 , C07D403/12 , C07D471/04 , C07D473/16 , C07D473/18 , C07D473/24 , C07D473/32 , C07D473/40 , C07D475/04 , C07D475/08 , C07D487/04 , C07D491/04 , C07D491/048 , C07D491/052 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Sulfonylureas of the formula ##STR1## where A is a bond or a C.sub.1 -C.sub.10 -hydrocarbon radical,R.sup.1 is an optionally unsaturated hydrocarbon radical which is optionally substituted by halogen, optionally unsaturated alkoxy, alkylthio, alkylsulfonyl or alkylsulfinyl, cycloalkyl, optionally substituted phenyl or a heterocycle, or is optionally substituted phenyl, NRR' with R and R' being alkyl, alkoxy or alkylene (cyclic with N),Y is S, SO or SO.sub.2,R.sup.1 is optionally unsaturated alkoxy which is optionally substituted, or is cycloalkoxy, cycloalkenyloxy, cyclopropylmethyloxy, epoxypropyloxy, furfuryloxy, tetrahydrofurfuryloxy or optionally substituted phenoxyalkoxy or phenoxy,R.sup.3 is alkyl which is optionally unsaturated, or is alkoxy,R.sup.4 is optionally substituted pyrimidinyl, pyrimidinylmethyl, pyrimidinyl with a fused-on cyclopentane, oxolane, oxolene, oxane, pyridine or pyrazine ring or purinyl or triazolyl, andZ is O or S,have herbicidal and/or plant-growth-regulatory properties.
摘要翻译：式（I）的磺酰脲，其中A是键或C1-C10-烃基，R1是任选不饱和的烃基，其任选被卤素，任选不饱和的烷氧基，烷硫基，烷基磺酰基或烷基亚磺酰基，环烷基，或任选取代的苯基或杂环，或任选取代的苯基，NR R'与R和R'为烷基，烷氧基或亚烷基（与N一起环状），Y为S，SO或SO 2，R 1为任选取代的任意不饱和烷氧基，或者是环烷氧基，环烯氧基，环丙基甲氧基，环氧丙氧基，呋喃氧基，四氢呋喃氧基或任选取代的苯氧基烷氧基或苯氧基，R3是任选不饱和的烷基，或是烷氧基，R 4是任选被取代的嘧啶基，嘧啶基甲基，嘧啶基与稠合的环戊烷，吡咯或吡嗪环或嘌呤基或三唑基，Z为O或S具有除草和/或植物生长调节性质。

2. 发明授权

US5030270A Sulfonylureas with heterocyclic substituents, and the use thereof as herbicides or plant-growth regulators 失效
标题翻译：具有杂环取代基的磺酰脲，以及其作为除草剂或植物生长调节剂的用途
公开(公告)号：US5030270A
公开(公告)日：1991-07-09
申请号：US389070
申请日：1989-08-03
申请人： Heinz-Josef Loher , Lothar Willms , Michael Frey , Klaus Bauer , Hermann Bieringer
发明人： Heinz-Josef Loher , Lothar Willms , Michael Frey , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D251/22 , A01N47/36 , A01P13/00 , C07D239/26 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/70 , C07D249/14 , C07D251/16 , C07D251/18 , C07D251/44 , C07D251/46 , C07D251/50 , C07D251/52 , C07D251/70 , C07D405/00 , C07D471/04 , C07D473/34 , C07D475/04 , C07D491/048 , C07D491/052 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： Sulfonylureas with heterocyclic substituents, a process for the preparation thereof, and the use thereof as herbicides or plant-growth regulators.Sulfonylureas with heterocyclic substituents, of the formula ##STR1## in which the variables are defined in the specification, as well as the salts thereof have herbicidal and plant-growth regulatory properties on mon- and dicotyledonous plants.
摘要翻译：具有杂环取代基的磺酰脲，其制备方法及其作为除草剂或植物生长调节剂的用途。具有杂环取代基的磺酰脲，其中变体在说明书中定义的式“IMAGE”以及其盐在单子叶和双子叶植物上具有除草和植物生长调节性质。

3. 发明授权

US5332715A Plant-protecting substituted isoxazolines, isoxazoles, isothiazolines and isothiazoles, and also processes for their preparation and their use 失效
标题翻译：植物保护取代的异恶唑啉，异恶唑，异噻唑啉和异噻唑，以及它们的制备和使用方法
公开(公告)号：US5332715A
公开(公告)日：1994-07-26
申请号：US952895
申请日：1992-11-18
申请人： Heinz-Josef Loher , Klaus Bauer , Hermann Bieringer
发明人： Heinz-Josef Loher , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N55/00 , A01N55/10 , C07F7/08 , C07F7/10 , C07D231/06 , C07D231/12 , C07F7/02
CPC分类号： A01N55/00 , A01N25/32 , C07F7/0812 , C07F7/0814
摘要： Plant-protecting substituted isoxazolines, isoxazoles, isothiazolines and isothiazoles, and also processes for their preparation and their useCompounds of the formula I(R.sup.1)(R.sup.2)(R.sup.3)Si--A--Het--B--CO--Z (I)whereHet is an isoxazole-, isoxazoline-, isothiazole- or isothiazoline-3,5-diyl radical,A and B are a bond or alkylene,R.sup.1, R.sup.2 and R.sup.3 are substituted or unsubstituted, saturated or unsaturated alkyl or, if desired, phenylalkyl or phenyl,Z is OH, OR where R is saturated or unsaturated, substituted or unsubstituted alkyl or substituted or unsubstituted phenyl or benzyl or trialkylsilylmethoxy, substituted or unsubstituted phenylamino or oxazolinyl or amino, mono- or dialkylamino or -hydrazino, cycloalkylamino, NH.sub.2 NH.sub.2, pyridino, morpholino, dimethylmorpholino, a radical --ON.dbd.CR.sup.4 R.sup.5 or O--CHR.sup.7 --CO--OR.sup.6 where R.sup.4, R.sup.5 =alkyl and/or R.sup.4 CR.sup.5 is cycloalkyl and R.sup.6, R.sup.7 are H or a saturated or unsaturated acyclic hydrocarbon radical,are suitable for protecting crop plants against phytotoxic side effects of herbicides.
摘要翻译：植物保护取代的异恶唑啉，异恶唑，异噻唑啉和异噻唑，以及其制备方法及用途式Ⅰ（R1）（R2）（R3）Si-A-Het-B-CO-Z（Ⅰ） Het是异恶唑，异恶唑啉，异噻唑或异噻唑啉-3,5-二基，A和B是键或亚烷基，R 1，R 2和R 3是取代或未取代的饱和或不饱和烷基，或者如果需要，苯基烷基或苯基，Z是OH，OR，其中R是饱和或不饱和的，取代或未取代的烷基或取代或未取代的苯基或苄基或三烷基甲硅烷基甲氧基，取代或未取代的苯基氨基或恶唑啉基或氨基，单或二烷基氨基或肼基，环烷基氨基，NH 2 NH 2，吡啶基，吗啉代，二甲基吗啉代，基团-ON = CR4R5或O-CHR7-CO-OR6，其中R4，R5 =烷基和/或R4CR5为环烷基，R6，R7为H或饱和或不饱和的无环烃基，保护作物免受植物毒副作用的除草剂。

4. 发明授权

US5536698A Crop-protecting compositions containing isoxazolines or isothiazdines, novel isoxazolines, and their preparation 失效
标题翻译：含有异恶唑啉或异噻嗪类的抗坏血酸组合物，新异恶唑及其制备方法
公开(公告)号：US5536698A
公开(公告)日：1996-07-16
申请号：US467934
申请日：1995-06-06
申请人： Heinz-Josef Loher , Klaus Bauer , Hermann Bieringer
发明人： Heinz-Josef Loher , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , C07D261/04 , C07D275/02 , C07D275/03 , C07F7/08
CPC分类号： C07D275/03 , A01N25/32 , C07D261/04 , C07F7/0812
摘要： Crop-protecting compositions containing isoxazolines or isothiazolines, novel isoxazolines and isothiazolines, and their preparationCrop-protecting compositions which contain isoxazolines or isothiazolines of the formula ##STR1## in which X is oxygen or sulfur, R is hydroxyl or has the meanings given in the description, Z is halogen, nitro, cyano, in each case optionally substituted alkyl, alkoxy, alkylmercapto, cycloalkyl, amino, hydroxymethyl, alkylamino, dialkylamino, alkoxymethyl, aryl or aryloxy and n is an integer from 0 to 5. Novel isoxazolines and isothiazolines of this formula, a process for their preparation, and their use as a protection against phytotoxic secondary effects of herbicides.
摘要翻译：含有异恶唑啉或异噻唑啉的抗割草组合物，新的异恶唑啉和异噻唑啉及其制备含有式为“IMAGE”的异恶唑啉或异噻唑的作物保护组合物，其中X为氧或硫，R为羟基或具有描述，Z是卤素，硝基，氰基，在各种情况下是任选取代的烷基，烷氧基，烷基巯基，环烷基，氨基，羟甲基，烷基氨基，二烷基氨基，烷氧基甲基，芳基或芳氧基，n是0-5的整数。新的异恶唑烷和异噻唑啉的这种配方，其制备方法及其作为防止除草剂植物毒性次要作用的用途。

5. 发明授权

US5380852A 5-chloroquinolin-8-oxyalkanecarboxylic acid derivatives, useful as antidotes for herbicides 失效
标题翻译： 5-氯喹啉-8-氧碳基羧酸衍生物，可用作除草剂的解毒剂
公开(公告)号：US5380852A
公开(公告)日：1995-01-10
申请号：US810487
申请日：1991-12-19
申请人： Rainer Schutze , Heinz-Josef Loher , Frank Ziemer , Klaus Bauer , Hermann Bieringer
发明人： Rainer Schutze , Heinz-Josef Loher , Frank Ziemer , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N43/42 , A01N25/32 , C07D215/28 , C07F7/10
CPC分类号： C07D215/28 , A01N25/32
摘要： Disclosed are compounds of the formula (I): ##STR1## The substituents are disclosed in the specification. The compounds are herbicidal safenets. Accordingly, processes for the preparation and use of the compounds of formula (I) are also disclosed.
摘要翻译：公开了式（I）的化合物：（I）取代基在说明书中公开。这些化合物是除草剂。因此，还公开了式（I）化合物的制备和使用的方法。

6. 发明授权

US5521143A Plant-protecting agents containing isoxazolines or isothiazolines, and novel isoxazolines and isothiazolines 失效
标题翻译：含有异恶唑啉或异噻唑啉的植物保护剂，以及新的异恶唑啉和异噻唑啉
公开(公告)号：US5521143A
公开(公告)日：1996-05-28
申请号：US972448
申请日：1993-01-29
申请人： Heinz-Josef Loher , Klaus Bauer , Hermann Bieringer
发明人： Heinz-Josef Loher , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N43/80 , A01N55/10 , C07D261/04 , C07D261/20 , C07D275/02 , C07D275/03 , A01N43/72 , C07D261/02
CPC分类号： C07D275/03 , A01N25/32 , A01N43/80 , C07D261/04
摘要： Isoxazolines or isothiazolines having the formula (I), or their salts, in which (Z).sub.n, X and R have the definition given in the first claim, are useful as safeners against the phytotoxic side effects of herbicides, preferably in cereal crops.
摘要翻译： PCT No.PCT / EP91 / 01503 371日期：1993年1月29日 102（e）日期1993年1月29日PCT 1991年8月8日PCT PCT。出版物WO92 / 03053 日本3月5日，1992.具有式（I）的异唑啉酮或异噻唑盐或其盐，其中（Z）n，X和R具有第一权利要求中给出的定义，可用作防止植物毒性副作用的安全剂除草剂，优选在谷类作物中。

7. 发明授权

US06239306B1 Phenylsulfonylureas, processes for their preparation, and their use as herbicides and plant growth regulations 有权
标题翻译：苯磺酰脲，其制备方法，以及它们作为除草剂和植物生长条件的用途
公开(公告)号：US06239306B1
公开(公告)日：2001-05-29
申请号：US09241213
申请日：1999-02-01
申请人： Klaus Lorenz , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Klaus Lorenz , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07C32716
CPC分类号： C07D521/00 , A01N47/36 , C07C311/46
摘要： Compounds of the formula (I) and their salts as defined in claim 1, in which R1 is CO—Q—R8, where R8=H or R R2 and R3 are H or (C1-C4)alkyl, R4 is H, R, RO, OH, RCO, RSO2, PhSO2 R5 is RSO2, PhSO2, PhCO, RNHSO2, R2NSO2, RCO, CHO, COCOR′, CW—T—R9, CW—NR10R11, CW—N(R12)2 or R4 and R5 together are the chain (CH2)mB or —B1—(CH2)m1B— where B=SO2, m=3, 4; m1=2, 3; T and W=O, S; Q=O, S, NR13 where R13=H, R; R6=H, R, RO, RCO, ROCO, Hal, NO2, CN; R7=H, CH3; R9=R; R10, R11=H, R; N(R12)2=heterocycle A=pyrimidinyl and triazinyl radical or an analog thereof, where R=(substituted) aliphatic hydrocarbon radical, are suitable as selective herbicides. They are prepared by analogous processes via sulfonamides, some of which are new, of the formula (II) (see claim 4).
摘要翻译：式（I）的化合物及其盐如权利要求1所定义，其中R 1为CO-Q-R 8，其中R 8 = H或R 2，R 3为H或（C 1 -C 4）烷基，R 4为H，R ，OH，RCO，RSO2，PhSO2R5是RSO2，PhSO2，PhCO，RNHSO2，R2NSO2，RCO，CHO，COCOR'，CW-T-R9，CW-NR10R11，CW-N（R12）2或R4和R5一起是链（CH2）mB或-B1-（CH2）m1B-，其中B = SO2，m = 3,4; m1 = 2,3; T和W = O，S; Q = O，S，NR 13其中R 13 = H，R; R 6 = H，R，RO，RCO，ROCO，Hal，NO 2，CN; R 7 = H，CH 3; R9 = R; R10，R11 = H，R; N（R 12）2 =杂环A =嘧啶基和三嗪基或其类似物，其中R =（取代的）脂族烃基适合作为选择性除草剂。它们通过磺酰胺类似的方法制备，其中一些是新的式（II）（参见权利要求4）。

8. 发明授权

US06235680B1 N-acylsulfonamides, novel mixtures of herbicides and antidotes, and their use 失效
标题翻译： N-酰基磺酰胺，除草剂和解毒剂的新型混合物及其用途
公开(公告)号：US06235680B1
公开(公告)日：2001-05-22
申请号：US08863476
申请日：1997-05-27
申请人： Frank Ziemer , Klaus Haaf , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Frank Ziemer , Klaus Haaf , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： A01N2532
CPC分类号： C07D333/38 , A01N25/32 , C07C311/51 , C07C311/53 , C07C323/62 , C07C333/08 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D307/68 , C07F9/4006
摘要： Novel N-acylsulfonamides, novel mixtures of herbicides and antidotes, and their use Safeners against phytotoxic side effects of pesticides in crop plants are compounds of the formula (I) and salts thereof where R1 is hydrogen, a hydrocarbon radical, a hydrocarbonoxy radical, a hydrocarbonthio radical or a heterocyclyl radical, each of the last-mentioned 4 radicals being unsubstituted or substituted by one or more identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, carboxyl, formyl, carboxamide, sulfonamide and radicals of the formula —Za—Ra R2 is hydrogen or (C1-C4)-alkyl or R1 and R2 together with the group of the formula —CO—N— are the radical of a 3- to 8-membered saturated or unsaturated ring and R3 to R5, n and m are as defined in claim 1. The compounds can be prepared by the process of claim 8.
摘要翻译：新型N-酰基磺酰胺，除草剂和解毒剂的新型混合物及其用途农药对作物植物的植物毒副作用的安全剂是式（I）化合物及其盐，其中R 1是氢，烃基，烃氧基，烃硫基或杂环基，每个最后提到的4个基团是未取代的或被一个或多个选自卤素，氰基，硝基，氨基，羟基，羧基，甲酰基，甲酰胺，磺酰胺和基团的相同或不同的基团取代式-Za-RaR2是氢或（C1-C4） - 烷基或R1和R2与式-CO-N-的基团是3-至8-元饱和或不饱和环的基团和R3至R5 ，n和m如权利要求1所定义。化合物可以通过权利要求8的方法制备。

9. 发明授权

US5576440A 2-pyridylsulfonamides 失效
标题翻译： 2-吡啶基磺酰胺
公开(公告)号：US5576440A
公开(公告)日：1996-11-19
申请号：US368742
申请日：1995-01-04
申请人： Heinz Kehne , Lothar Willms , Oswald Ort , Klaus Bauer , Hermann Bieringer
发明人： Heinz Kehne , Lothar Willms , Oswald Ort , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N47/36 , A47B91/06 , C07D213/76 , C07D401/12 , C07D521/00 , C07D213/71 , C07D409/12 , C07D417/04
CPC分类号： C07D213/76 , A01N47/36 , C07D401/12 , C07D521/00
摘要： Compounds of formula (I), where R.sup.1, R.sup.2, n, W, R.sup.3 and A are as defined in claim 1, are suitable for use as herbicides and plant growth regulators. They can be produced by a process similar to known processes. To produce them, new compounds of formula (II) are reacted with a carbamate of formula R*--O--CO--NR.sup.3 A, where R.sup.3 stands for phenyl or alkyl. The compounds of formula (II) can be obtained from the corresponding sulphochlorides.
摘要翻译：式（I）的化合物，其中R 1，R 2，n，W，R 3和A如权利要求1中所定义，适用于除草剂和植物生长调节剂。它们可以通过与已知方法类似的方法生产。为了制备它们，式（II）的新化合物与式R * -O-CO-NR 3 A的氨基甲酸酯反应，其中R3代表苯基或烷基。式（II）化合物可以从相应的氯化亚砜获得。

10. 发明授权

US5441922A Combinations of benzoyl cyclohexanedione herbicides and crop-protecting substances 失效
标题翻译：苯并环己二酮除草剂与作物保护物质的组合
公开(公告)号：US5441922A
公开(公告)日：1995-08-15
申请号：US998009
申请日：1992-12-29
申请人： Oswald Ort , Lothar Willms , Hans-Joachim Zeiss , Stephan Mller , Herbert Stark , Rainer Schutze , Klaus Bauer , Hermann Bieringer
发明人： Oswald Ort , Lothar Willms , Hans-Joachim Zeiss , Stephan Mller , Herbert Stark , Rainer Schutze , Klaus Bauer , Hermann Bieringer
IPC分类号： A01N25/32 , A01N35/06 , A01N43/42 , A01N43/56 , A01N43/653 , A01N43/80
CPC分类号： A01N43/56 , A01N25/32 , A01N35/06 , A01N43/42 , A01N43/653 , A01N43/80
摘要： Herbicide/safener combinations ofA) herbicides selected from the group of the 2-acylated 1,3-dicarbonyl compounds or salts thereof, andB) safeners B1 and/or B2 ##STR1## as they are defined in claim 1, are suitable for controlling harmful plants in crops such as cereals, maize and rice.
摘要翻译： A）除草剂的除草剂/安全剂组合，其选自2-酰化的1,3-二羰基化合物或其盐，以及B）安全剂B1和/或B2（B1），图像（B2），因为它们在权利要求1中定义，适用于控制作物如谷物，玉米和大米中的有害植物。

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