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91. 发明授权

US5625016A High temperature solution polymerization process 失效
标题翻译：高温溶液聚合工艺
公开(公告)号：US5625016A
公开(公告)日：1997-04-29
申请号：US545973
申请日：1995-10-20
申请人： Rinaldo S. Schiffino , Donna J. Crowther
发明人： Rinaldo S. Schiffino , Donna J. Crowther
IPC分类号： C08F2/04 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F210/18
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/18 , C08F4/65927 , C08F2/06 , C08F210/06 , C08F2500/25 , C08F2500/03
摘要： This invention is a solution process for the preparation of high molecular weight ethylene-.alpha.-olefin-diolefin copolymers comprising contacting ethylene, one or more .alpha.-olefin monomer, and optionally one or more diene monomer, with a catalyst system at a polymerization temperature at or above about 80.degree. C., ethylene, one or more .alpha.-olefin monomer, and optionally one or more diene monomer, with a catalyst system comprising an unbridged Group 4 metal compound having a bulky monocyclopentadienyl ligand, a uninegative bulky Group 15 ligand and two uninegative, activation reactive ligands and a catalyst activator compound. The process can be advantageously practiced a reaction temperature of at least 80.degree. C., most preferably above 100.degree. C., to achieve high number average molecular weight polymer having high .alpha.-olefin monomer and diene monomer contents with high diene conversion rates. The process is particularly suitable for the preparation of elastomeric ethylene-propylene or ethylene-propylene-diene monomer elastomers.
摘要翻译：本发明是用于制备高分子量乙烯-α-烯烃 - 二烯烃共聚物的溶液方法，包括在聚合温度下将乙烯，一种或多种α-烯烃单体和任选的一种或多种二烯单体与催化剂体系接触或高于约80℃，乙烯，一种或多种α-烯烃单体和任选的一种或多种二烯单体，其催化剂体系包含具有大体积单环戊二烯基配体的未桥连的第4族金属化合物，非负性大体积的第15族配体和两个无结构的活化反应性配体和催化剂活化剂化合物。该方法可以有利地实施至少80℃，最优选高于100℃的反应温度，以实现具有高二烯转化率的高α-烯烃单体和二烯单体含量的高数均分子量聚合物。该方法特别适用于制备弹性体乙烯 - 丙烯或乙烯 - 丙烯 - 二烯单体弹性体。

92. 发明申请

US20130245213A1 Catalysts For Producing Polyaplha-Olefins 有权
标题翻译：用于生产Polyaplha-Olefins的催化剂
公开(公告)号：US20130245213A1
公开(公告)日：2013-09-19
申请号：US13423686
申请日：2012-03-19
申请人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
发明人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
IPC分类号： C08F4/76 , C08F110/14
CPC分类号： C08F110/14 , C08F210/16 , C08F10/00 , C08F4/6592 , C08F2500/02 , C08F2500/03 , C08F2500/17
摘要： This invention is directed to new mono-cyclopentadienyl (“mono-Cp”) metallocene catalyst compounds useful for producing high viscosity PAOs with narrow molecular weight distribution and good shear stability. Specifically, this invention relates to a group of bridged mono-Cp catalysts wherein, in an embodiment of the invention, the aromatic ring structure is substituted with: 1) at least one phenyl group, 2) at least one alkyl group, and 3) at least one other group, such as a hydrocarbyl group, a heteroatom, or a heteroatom-containing group.
摘要翻译：本发明涉及用于生产具有窄分子量分布和良好剪切稳定性的高粘度PAO的新单环戊二烯（“一Cp”）茂金属催化剂化合物。具体地，本发明涉及一组桥连的单Cp催化剂，其中在本发明的一个实施方案中，芳环结构被以下物质取代：1）至少一个苯基，2）至少一个烷基，和3）至少一个其它基团，例如烃基，杂原子或含杂原子的基团。

93. 发明申请

US20130137830A1 Functionalized High Vinyl Terminated Propylene Based Oligomers 有权
标题翻译：官能化高乙烯基终止丙烯基低聚物
公开(公告)号：US20130137830A1
公开(公告)日：2013-05-30
申请号：US13752998
申请日：2013-01-29
申请人： Patrick S. Brant , Donna J. Crowther
发明人： Patrick S. Brant , Donna J. Crowther
IPC分类号： C08F210/06
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
摘要翻译：本发明涉及Mn为300〜30,000g / mol，含有10〜90mol％丙烯和10〜90mol％乙烯的官能化共聚物，其中低聚物具有至少X％的烯丙基链端，其中：1 ）X =（ - 0.94（加入摩尔％乙烯）+100），当共聚低聚物中存在10至60摩尔％的乙烯时，和2）X = 45，当大于60且小于70摩尔％的乙烯为存在于共聚低聚物中，和3）X =（1.83 *（摩尔％乙烯掺入）-83），当共聚低聚物中存在70至90摩尔％的乙烯时。本发明还涉及包含丙烯的官能化均聚物，其中所述低聚物具有：至少93％的烯丙基链端，约500至约20,000g / mol的Mn，异丁基链至烯丙基乙烯基的比例为0.8 ：1〜1.2：1.0，小于100ppm的铝。本发明还涉及制备包含丙烯的官能化均聚物或共聚物的方法，其中生产率大于4500g / mmol Hf（或Zr）/小时。

94. 发明授权

US08436114B2 Polyethylene and process for production thereof 失效
标题翻译：聚乙烯及其生产方法
公开(公告)号：US08436114B2
公开(公告)日：2013-05-07
申请号：US13275680
申请日：2011-10-18
申请人： Donna J. Crowther , David M. Fiscus
发明人： Donna J. Crowther , David M. Fiscus
IPC分类号： C08F4/642 , C08F4/6592 , C08F210/02
CPC分类号： C08F210/14 , B32B27/32 , C08F4/52 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F210/16 , C08F297/08 , C08F299/00 , Y10S526/943 , Y10T428/1345 , Y10T428/31938 , C08F2/34 , C08F4/6428 , C08F2500/03 , C08F2500/08 , C08F2500/20 , C08F2500/21
摘要： This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
摘要翻译：本发明涉及一种聚合烯烃的方法，其中在用作活化剂之前，将甲基铝氧烷溶液中的三甲基铝的量调节至1至25mol％，其中通过溶液的1 H NMR测定摩尔％的三甲基铝在与任何支持组合之前。本发明还涉及一种聚合烯烃的方法，其中存在于甲基铝氧烷溶液中的未知物质的量在使用前调节为0.10至0.65个整合单元作为活化剂，其中未知物质的量由在与任何载体组合之前进行的溶液的1 H NMR光谱。优选地，甲基铝氧烷溶液存在于还包含茂金属过渡金属化合物的催化剂体系中。

95. 发明授权

US08022154B2 Ethylene polymers, their production and use 有权
标题翻译：乙烯聚合物，其生产和使用
公开(公告)号：US08022154B2
公开(公告)日：2011-09-20
申请号：US12266360
申请日：2008-11-06
申请人： Donna J. Crowther , Kuangyao Brian Peng
发明人： Donna J. Crowther , Kuangyao Brian Peng
IPC分类号： C08F4/72 , C08F210/00 , C08F4/44 , C08L23/00
CPC分类号： C08F210/16 , C08F2/00 , C08F210/14 , C08F2500/03 , C08F2500/17 , C08F2500/12 , C08F2500/18 , C08F2500/26
摘要： This invention relates to an ethylene polymer comprising ethylene and up to 5 mole % of at least one comonomer, wherein the ethylene polymer has an Mw, of 10,000 to 50,000, an Mw/Mn of between 1.5 to 4.5, a density of at least 0.925 g/cc, an unsaturation level of less than 1 per 1000 carbons, a melting point of at least 120° C., a Tc of greater than Z° C., where Z=0.501×(density in kg/m3)−367, and a Brookfield viscosity o at 140° C. of 100,000 mPas or more.
摘要翻译：本发明涉及包含乙烯和至多5摩尔％的至少一种共聚单体的乙烯聚合物，其中乙烯聚合物具有10,000至50,000的Mw，1.5至4.5的Mw / Mn，至少0.925的密度 g / cc，不小于1/1000个碳的不饱和度，熔点至少为120℃，Tc大于Z℃，其中Z = 0.501×（密度以kg / m3计）-367 ，在140℃下的Brookfield粘度o为100,000mPa·s以上。

96. 发明申请

US20090088542A1 OLEFIN POLYMERIZATION CATALYSTS, THEIR SYNTHESIS AND USE 有权
标题翻译： OLEFIN聚合催化剂，其合成和使用
公开(公告)号：US20090088542A1
公开(公告)日：2009-04-02
申请号：US11866113
申请日：2007-10-02
申请人： Donna J. Crowther , Celestino M. Perez
发明人： Donna J. Crowther , Celestino M. Perez
IPC分类号： C08F4/44 , B01J31/12
CPC分类号： B01J31/1815 , B01J2231/12 , B01J2531/0238 , B01J2531/842 , C08F10/00 , C08F110/02 , C08F4/7042 , C08F2500/04
摘要： A catalyst system for the polymerization or copolymerization of α-olefins comprises a bis(imino)pyridyl complex of a transition metal on a support having an aluminum halide and/or an alkylaluminum halide chemically or physically bonded thereto.
摘要翻译：用于α-烯烃的聚合或共聚的催化剂体系包括在具有卤化铝和/或与其化学或物理结合的烷基铝卤化物的载体上的过渡金属的双（亚氨基）吡啶基复合物。

97. 发明授权

US06388115B1 Polymerization process for producing easier processing polymers 有权
公开(公告)号：US06388115B1
公开(公告)日：2002-05-14
申请号：US09932549
申请日：2001-08-17
申请人： Donna J. Crowther , Ching-Tai Lue
发明人： Donna J. Crowther , Ching-Tai Lue
IPC分类号： C07F1700
CPC分类号： C07F17/00 , B01J31/1608 , B01J31/2295 , B01J2531/0288 , B01J2531/48 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/10
摘要： The present invention relates to a process for polymerizing olefin(s) utilizing a cyclic bridged metallocene-type catalyst system to produce enhanced processability polymers.

98. 发明授权

US06262202B1 Noncoordinating anions for olefin polymerization 失效
标题翻译：用于烯烃聚合的非配位阴离子
公开(公告)号：US06262202B1
公开(公告)日：2001-07-17
申请号：US09261627
申请日：1999-03-03
申请人： John F. Walzer, Jr. , Donna J. Crowther , Bernard J. Folie
发明人： John F. Walzer, Jr. , Donna J. Crowther , Bernard J. Folie
IPC分类号： C08F452
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F210/06 , C08F210/16 , C08F210/18 , C08L23/142 , C08L23/16 , C08L2205/025 , C08L2308/00 , C08L2312/00 , C08L2314/06 , Y10S526/916 , Y10S526/943 , C08F2/06 , C08F4/6592 , C08F2/001 , C08L2666/04 , C08F2500/17 , C08F2500/03 , C08F2500/08 , C08F2500/15 , C08F2500/21 , C08F2500/04 , C08F2500/20 , C08F210/14 , C08F2500/12 , C08F2500/25 , C08F236/20
摘要： Bulky noncoordinating anions that are surprisingly stable under olefin polymerization conditions such that olefin polymers can be prepared with unexpectedly high molecular weights at high catalyst efficiencies. Thus the invention is directed to an olefin polymerization process comprising contacting under polymerization conditions one or more ethylenically unsaturated monomers with a catalyst composition comprising at least one organometallic transition metal compound activated to a cationic state and a stabilizing, compatible non-coordinating Group 13 anionic complex having halogenated aromatic ligands in an essentially tetrahedral structure wherein the aromatic groups are polycyclic fused or pendant aromatic rings.
摘要翻译：在烯烃聚合条件下出人意料地稳定的大体积非配位阴离子，使得烯烃聚合物可以以高催化剂效率以出人意料的高分子量制备。因此，本发明涉及烯烃聚合方法，其包括在聚合条件下使一种或多种烯键式不饱和单体与包含活化至阳离子状态的至少一种有机金属过渡金属化合物和稳定的相容性非配位性13族阴离子络合物的催化剂组合物接触具有基本四面体结构的卤代芳族配体，其中芳族基团是多环稠合或侧环芳环。

99. 发明授权

US06207606B1 Mixed catalysts and their use in a polymerization process 失效
标题翻译：混合催化剂及其在聚合过程中的应用
公开(公告)号：US06207606B1
公开(公告)日：2001-03-27
申请号：US09079743
申请日：1998-05-15
申请人： Ching-Tai Lue , Donna J. Crowther
发明人： Ching-Tai Lue , Donna J. Crowther
IPC分类号： B01J3100
CPC分类号： C08F210/02 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/16 , Y10S526/943 , C08F4/65904 , C08F210/14 , C08F2500/11 , C08F2500/12 , C08F2500/18 , C08F2500/14 , C08F2500/04
摘要： The present invention relates to a mixed catalyst system of at least one bridged, bulky ligand metallocene-type compound, and at least one bridged, asymmetrically substituted, bulky ligand metallocene-type compound, a method of making the mixed catalyst system and to its use in a polymerization process to produce olefin polymers having an unexpected improvement in processability.
摘要翻译：本发明涉及至少一种桥联，体积大的配体金属茂型化合物和至少一种桥联的，不对称取代的庞大配体金属茂型化合物的混合催化剂体系，制备混合催化剂体系的方法及其用途在聚合过程中生产具有出人意料的加工性改进的烯烃聚合物。

100. 发明授权

US5502124A Transition metal olefin polymerization processes 失效
标题翻译：过渡金属烯烃聚合方法
公开(公告)号：US5502124A
公开(公告)日：1996-03-26
申请号：US445062
申请日：1995-05-19
申请人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
发明人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
IPC分类号： C08F4/642 , B01J31/12 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/639 , C08F4/6592 , C08F4/69 , C08F4/72 , C08F4/74 , C08F10/00 , C08F10/02 , C08F4/68
CPC分类号： C08F10/00 , B01J31/122 , B01J31/146 , B01J31/1805 , B01J31/2295 , C07F11/00 , C07F11/005 , C07F17/00 , C07F9/005 , C08F10/02 , B01J2531/0227 , B01J2531/57 , B01J2531/58 , B01J2531/66 , C08F2420/04 , C08F4/639 , C08F4/63908 , C08F4/63912 , Y10S526/904
摘要： This invention relates to processes using non-Group 4 transition metal compositions useful as olefin polymerization catalysts, wherein the transition metal is in a high oxidation state. The invention further relates to design of new ligand systems and methods of preparing and using the same. Compositions useful as catalyst precursors are neutral transition metal complexes comprising the unique ligand systems of the invention. The inventive compositions may be activated to a catalytic state by ion-exchange reagents or by Lewis acids.
摘要翻译：本发明涉及使用可用作烯烃聚合催化剂的非4族过渡金属组合物的方法，其中过渡金属处于高氧化态。本发明还涉及新的配体体系的设计及其制备和使用方法。可用作催化剂前体的组合物是包含本发明独特配体体系的中性过渡金属配合物。本发明的组合物可以通过离子交换试剂或路易斯酸活化至催化状态。

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