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1. 发明申请

US20130137830A1 Functionalized High Vinyl Terminated Propylene Based Oligomers 有权
标题翻译：官能化高乙烯基终止丙烯基低聚物
公开(公告)号：US20130137830A1
公开(公告)日：2013-05-30
申请号：US13752998
申请日：2013-01-29
申请人： Patrick S. Brant , Donna J. Crowther
发明人： Patrick S. Brant , Donna J. Crowther
IPC分类号： C08F210/06
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
摘要翻译：本发明涉及Mn为300〜30,000g / mol，含有10〜90mol％丙烯和10〜90mol％乙烯的官能化共聚物，其中低聚物具有至少X％的烯丙基链端，其中：1 ）X =（ - 0.94（加入摩尔％乙烯）+100），当共聚低聚物中存在10至60摩尔％的乙烯时，和2）X = 45，当大于60且小于70摩尔％的乙烯为存在于共聚低聚物中，和3）X =（1.83 *（摩尔％乙烯掺入）-83），当共聚低聚物中存在70至90摩尔％的乙烯时。本发明还涉及包含丙烯的官能化均聚物，其中所述低聚物具有：至少93％的烯丙基链端，约500至约20,000g / mol的Mn，异丁基链至烯丙基乙烯基的比例为0.8 ：1〜1.2：1.0，小于100ppm的铝。本发明还涉及制备包含丙烯的官能化均聚物或共聚物的方法，其中生产率大于4500g / mmol Hf（或Zr）/小时。

2. 发明授权

US09744500B2 Microporous polymeric membranes, battery separators, and production methods therefor 有权
公开(公告)号：US09744500B2
公开(公告)日：2017-08-29
申请号：US13259226
申请日：2010-03-05
申请人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Donna J. Crowther , Patrick Brant , Kazuhiro Yamada
发明人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Donna J. Crowther , Patrick Brant , Kazuhiro Yamada
IPC分类号： H01M2/14 , B01D71/26 , B01D71/76 , H01M2/16 , B32B27/32 , B29C47/00
CPC分类号： B01D71/26 , B01D71/76 , B29C47/00 , B32B27/32 , H01M2/14 , H01M2/16 , H01M2/164 , H01M2/1653
摘要： A multilayer microporous membrane including polymer and having a shutdown temperature of ≦130.5° C. and a storage stability of 0.3V or less.

3. 发明授权

US09295950B2 Microporous membranes, methods for making such membranes, and the use of such membranes as battery separator film 有权
标题翻译：微孔膜，制造这种膜的方法以及使用这种膜作为电池隔膜
公开(公告)号：US09295950B2
公开(公告)日：2016-03-29
申请号：US13260658
申请日：2010-03-05
申请人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Donna J. Crowther , Patrick Brant
发明人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Donna J. Crowther , Patrick Brant
IPC分类号： H01M2/14 , B01D71/26 , B01D71/76 , H01M2/16 , B32B27/32 , B29C47/00
CPC分类号： B01D71/26 , B01D71/76 , B29C47/00 , B32B27/32 , H01M2/14 , H01M2/16 , H01M2/164 , H01M2/1653
摘要： The invention relates to microporous membranes comprising polymer and having well-balanced permeability, shutdown temperature, and pin puncture strength. The invention also relates to methods for making such membranes, and the use of such membranes as battery separator film in, e.g., lithium ion secondary batteries.
摘要翻译：本发明涉及包含聚合物并具有良好平衡渗透性，关闭温度和针穿刺强度的微孔膜。本发明还涉及制造这种膜的方法，以及在例如锂离子二次电池中使用这种膜作为电池隔膜。

4. 发明授权

US08993681B2 Dendritic ethylene polymers and processes for making 有权
标题翻译：树枝状乙烯聚合物和制备方法
公开(公告)号：US08993681B2
公开(公告)日：2015-03-31
申请号：US13182868
申请日：2011-07-14
申请人： Andy H. Tsou , Shuji Luo , Donna J. Crowther , Gabor Kiss , Johannes M. Soulages , Pradeep P. Shirodkar
发明人： Andy H. Tsou , Shuji Luo , Donna J. Crowther , Gabor Kiss , Johannes M. Soulages , Pradeep P. Shirodkar
IPC分类号： C08F279/02 , C08F36/20 , C08L45/00 , C08J3/24 , C08F255/06 , C08F8/02
CPC分类号： C08F36/20 , C08F8/02 , C08F255/06 , C08G83/002 , C08J3/24 , C08F210/18
摘要： Provided is a dendritic ethylene polymer. The polymer is a dendritic polymer of an ethylene/alpha-olefin-diene copolymer and a vinyl-terminated polyethylene. There is also provided a process for making a dendritic ethylene polymer. The process includes the steps of preparing a dendritic ethylene polymer by reacting ethylene/alpha-olefin-diene copolymer with vinyl-terminated polyethylene in the presence of a radical source. There is also provided a blend and a blown film that include the dendritic ethylene polymer.
摘要翻译：提供树枝状乙烯聚合物。聚合物是乙烯/α-烯烃 - 二烯共聚物和乙烯基封端的聚乙烯的树枝状聚合物。还提供了制备树枝状乙烯聚合物的方法。该方法包括在自由基源存在下使乙烯/α-烯烃 - 二烯共聚物与乙烯基封端的聚乙烯反应制备树枝状乙烯聚合物的步骤。还提供了包含树枝状乙烯聚合物的共混物和吹塑薄膜。

5. 发明授权

US08835563B2 Block copolymers from silylated vinyl terminated macromers 有权
标题翻译：来自甲硅烷基化乙烯基封端的大分子单体的嵌段共聚物
公开(公告)号：US08835563B2
公开(公告)日：2014-09-16
申请号：US13072330
申请日：2011-03-25
申请人： Donna J. Crowther , Jacqueline A. Lovell , Patrick Brant
发明人： Donna J. Crowther , Jacqueline A. Lovell , Patrick Brant
IPC分类号： C08F299/00 , C08F8/42
CPC分类号： C08F8/42 , C08F299/00
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a metallocene catalyst with a difunctional diblock hydrosilane, and one or more vinyl terminated polyolefins. This invention further relates to the diblock hydrosilane-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及使聚烯烃官能化的方法，包括使茂金属催化剂与双官能二嵌段氢化硅烷和一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制备的二嵌段氢硅烷官能化的聚烯烃。

6. 发明授权

US08796376B2 Functionalized polymers and oligomers 有权
标题翻译：官能化聚合物和低聚物
公开(公告)号：US08796376B2
公开(公告)日：2014-08-05
申请号：US13430247
申请日：2012-03-26
申请人： Rahul R. Kulkarni , Pradeep P. Shirodkar , Alistair D. Westwood , Donna J. Crowther , Wei Tang
发明人： Rahul R. Kulkarni , Pradeep P. Shirodkar , Alistair D. Westwood , Donna J. Crowther , Wei Tang
IPC分类号： C09D5/16 , C09D123/36 , C08K3/34 , C07D237/08 , C08F8/30 , C08L23/36
CPC分类号： C07D237/08 , B82Y30/00 , C08C19/22 , C08F8/30 , C08K3/34 , C08K3/346 , C09D5/1662 , C09D123/36 , C08L23/36
摘要： A functionalized polyolefin having one or more pyridazine moieties is disclosed herein. A method to produce the functionalized polyolefin is also disclosed. A composition including the functionalized polyolefin is also disclosed.
摘要翻译：本文公开了具有一个或多个哒嗪部分的官能化聚烯烃。还公开了制备官能化聚烯烃的方法。还公开了包含官能化聚烯烃的组合物。

7. 发明授权

US08664461B2 Catalysts for producing polyalpha-olefins and processes related thereto 有权
标题翻译：用于生产聚α-烯烃的催化剂及其相关工艺
公开(公告)号：US08664461B2
公开(公告)日：2014-03-04
申请号：US13423686
申请日：2012-03-19
申请人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
发明人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
IPC分类号： C07C2/08 , C07C2/34 , C08F4/6592
CPC分类号： C08F110/14 , C08F210/16 , C08F10/00 , C08F4/6592 , C08F2500/02 , C08F2500/03 , C08F2500/17
摘要： This invention is directed to new mono-cyclopentadienyl (“mono-Cp”) metallocene catalyst compounds useful for producing high viscosity PAOs with narrow molecular weight distribution and good shear stability. Specifically, this invention relates to a group of bridged mono-Cp catalysts wherein, in an embodiment of the invention, the aromatic ring structure is substituted with: 1) at least one phenyl group, 2) at least one alkyl group, and 3) at least one other group, such as a hydrocarbyl group, a heteroatom, or a heteroatom-containing group.
摘要翻译：本发明涉及用于生产具有窄分子量分布和良好剪切稳定性的高粘度PAO的新单环戊二烯（“一Cp”）茂金属催化剂化合物。具体地，本发明涉及一组桥连的单Cp催化剂，其中在本发明的一个实施方案中，芳环结构被以下物质取代：1）至少一个苯基，2）至少一个烷基，和3）至少一个其它基团，例如烃基，杂原子或含杂原子的基团。

8. 发明授权

US08618033B2 Ethylene copolymers, methods for their production, and use 有权
标题翻译：乙烯共聚物，其制备方法和用途
公开(公告)号：US08618033B2
公开(公告)日：2013-12-31
申请号：US13005356
申请日：2011-01-12
申请人： Rainer Kolb , Donna J. Crowther , Peijun Jiang
发明人： Rainer Kolb , Donna J. Crowther , Peijun Jiang
IPC分类号： C10M143/02 , C08F10/00 , C08F2/00
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F210/02 , C08F210/06 , C08L23/0807 , C10M143/04 , C10M143/06 , C10M143/08 , C10M171/02 , C10M171/04 , C10M2205/022 , C10N2230/02 , C10N2230/04 , C10N2230/45 , C10N2240/04 , C10N2240/042 , C10N2240/08 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C08L2666/02 , C10M2205/026 , C10M2205/024 , C10M2205/028 , C08F210/14 , C08F2500/03 , C08F2500/12 , C08F210/00
摘要： Provided is an ethylene copolymer having 40 wt. % to 70 wt. % of units derived from ethylene and at least 30 wt. % of units derived from at least one α-olefin having 3 to 20 carbon atoms and has the following properties: (a) a weight-average molecular weight (Mw), as measured by GPC, in the range of about 50,000 to about 200,000 g/mol; (b) a melting point (Tm) in ° C., as measured by DSC, that satisfies the relation: Tm>3.4×E−180 where E is the weight % of units derived from ethylene in the copolymer; (c) a ratio of Mw/Mn of about 1.8 to about 2.5; (d) a content of Group 4 metals of no more than 5 ppm; and (e) a ratio of wt ppm Group 4 metals/wt ppm Group 5 metals of at least 3. Also provided are methods for making an ethylene copolymer and compositions comprising an ethylene copolymer.
摘要翻译：提供了一种乙烯共聚物，其具有40wt。％至70wt。衍生自乙烯的单元的％和至少30重量％衍生自至少一种具有3至20个碳原子的α-烯烃的单元的％具有以下特性：（a）通过GPC测量的重均分子量（Mw）在约50,000至约200,000的范围内 g / mol; （b）通过DSC测量的熔点（Tm）（℃），满足关系：Tm> 3.4×E-180其中E是共聚物中衍生自乙烯的单元的重量％; （c）约1.8至约2.5的Mw / Mn比; （d）不超过5ppm的第4族金属的含量; 和（e）第4族金属wt / wtppm第5族金属的比例至少为3.还提供了制备乙烯共聚物和包含乙烯共聚物的组合物的方法。

9. 发明申请

US20130253120A1 Functionalized Polymers and Oligomers 有权
标题翻译：官能化聚合物和低聚物
公开(公告)号：US20130253120A1
公开(公告)日：2013-09-26
申请号：US13430247
申请日：2012-03-26
申请人： Rahul R. KULKARNI , Pradeep P. Shirodkar , Alistair D. Westwood , Donna J. Crowther , Wei Tang
发明人： Rahul R. KULKARNI , Pradeep P. Shirodkar , Alistair D. Westwood , Donna J. Crowther , Wei Tang
IPC分类号： C09D5/16 , C08K3/34 , C09D123/36 , C07D237/08 , C08F8/30 , C08L23/36 , B82Y30/00
CPC分类号： C07D237/08 , B82Y30/00 , C08C19/22 , C08F8/30 , C08K3/34 , C08K3/346 , C09D5/1662 , C09D123/36 , C08L23/36
摘要： A functionalized polyolefin having one or more pyridazine moieties is disclosed herein. A method to produce the functionalized polyolefin is also disclosed. A composition including the functionalized polyolefin is also disclosed.
摘要翻译：本文公开了具有一个或多个哒嗪部分的官能化聚烯烃。还公开了制备官能化聚烯烃的方法。还公开了包含官能化聚烯烃的组合物。

10. 发明授权

US08501894B2 Hydrosilyation of vinyl macromers with metallocenes 有权
标题翻译：乙烯基大分子单体与金属茂的水合作用
公开(公告)号：US08501894B2
公开(公告)日：2013-08-06
申请号：US13072305
申请日：2011-03-25
申请人： Donna J. Crowther , Jacqueline A. Lovell , Patrick Brant
发明人： Donna J. Crowther , Jacqueline A. Lovell , Patrick Brant
IPC分类号： C08G77/12
CPC分类号： C08F8/42 , C07B2200/11 , C07F7/0805
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a metallocene catalyst with a hydrosilane, and one or more vinyl terminated polyolefins. This invention further relates to the hydrosilane-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及官能化聚烯烃的方法，包括使茂金属催化剂与氢硅烷和一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制备的氢硅烷官能化的聚烯烃。

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