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    • 3. 发明授权
    • Polyethylene and process for production thereof
    • 聚乙烯及其生产方法
    • US08507103B2
    • 2013-08-13
    • US13452197
    • 2012-04-20
    • Donna J. CrowtherDavid M. Fiscus
    • Donna J. CrowtherDavid M. Fiscus
    • B32B27/32C08F210/02C08F4/6592C08F4/642
    • C08F297/08C08F4/65912C08F4/65916C08F4/65925C08F210/16C08J5/18C08J2323/08Y10T428/1345Y10T428/31938
    • This invention relates to blown films produced from copolymer made by a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    • 本发明涉及由用于聚合烯烃的方法制备的共聚物制备的吹塑薄膜,其中在使用摩尔%三甲基铝为活化剂之前,将甲基铝氧烷溶液中的三甲基铝的量调节至1至25摩尔% 在与任何载体组合之前通过溶液的1 H NMR测定。 本发明还涉及一种聚合烯烃的方法,其中存在于甲基铝氧烷溶液中的未知物质的量在使用前调节为0.10至0.65个整合单元作为活化剂,其中未知物质的量由 在与任何载体组合之前进行的溶液的1 H NMR光谱。 优选地,甲基铝氧烷溶液存在于还包含茂金属过渡金属化合物的催化剂体系中。
    • 5. 发明申请
    • Polyethylene and Process for Production Thereof
    • 聚乙烯及其生产工艺
    • US20120200010A1
    • 2012-08-09
    • US13452197
    • 2012-04-20
    • Donna J. CrowtherDavid M. Fiscus
    • Donna J. CrowtherDavid M. Fiscus
    • B29C39/14
    • C08F297/08C08F4/65912C08F4/65916C08F4/65925C08F210/16C08J5/18C08J2323/08Y10T428/1345Y10T428/31938
    • This invention relates to blown films produced from copolymer made by a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    • 本发明涉及由用于聚合烯烃的方法制备的共聚物制备的吹塑薄膜,其中在使用摩尔%三甲基铝为活化剂之前,将甲基铝氧烷溶液中的三甲基铝的量调节至1至25摩尔% 在与任何载体组合之前通过溶液的1 H NMR测定。 本发明还涉及一种聚合烯烃的方法,其中存在于甲基铝氧烷溶液中的未知物质的量在使用前调节为0.10至0.65个整合单元作为活化剂,其中未知物质的量由 在与任何载体组合之前进行的溶液的1 H NMR光谱。 优选地,甲基铝氧烷溶液存在于还包含茂金属过渡金属化合物的催化剂体系中。