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    • 94. 发明授权
    • Cyclohexenone oxime ethers
    • 环己烯酮肟醚
    • US5604183A
    • 1997-02-18
    • US523682
    • 1995-09-05
    • Ulf MisslitzNorbert MeyerJuergen KastMatthias BratzAlbrecht HarreusHelmut WalterKarl-Otto WestphalenMatthias Gerber
    • Ulf MisslitzNorbert MeyerJuergen KastMatthias BratzAlbrecht HarreusHelmut WalterKarl-Otto WestphalenMatthias Gerber
    • A01N35/10A01N39/00C07C317/30C07C323/47C07D333/16C07D333/28C07C251/50C07C251/52
    • A01N39/00A01N35/10C07C317/30C07C323/47C07D333/16C07D333/28C07C2101/02C07C2101/14C07C2101/16
    • Cyclohexenone oxime ethers I ##STR1## where n is from 0 to 5, m is from 0 to 2, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl or benzyl, A is unsubstituted or substituted C.sub.1 -C.sub.6 -alkylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkenylene, unsubstituted or substituted C.sub.3 -C.sub.6 -alkynylene or an unsubstituted or substituted C.sub.3 -C.sub.6 -alkylene or C.sub.4 -C.sub.6 -alkenylene chain, where in each case a methylene group may be replaced with O, S, SO, SO.sub.2 or --N(R.sup.a)--, R.sup.a is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, Z is phenyl, a 5-membered heteroaromatic radical or a 6-membered heteroaromatic radical having from 1 to 4 nitrogen atoms, X is NO.sub.2, CN, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkoxy, COOH, C.sub.1 -C.sub.4 -alkoxycarbonyl, unsubstituted or substituted benzyloxycarbonyl, unsubstituted or substituted phenyl, unsubstituted or substituted pyridyl or --NR.sup.b R.sup.c, R.sup.b is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl and R.sup.c is H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or unsubstituted or substituted benzoyl, and the agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids are suitable as herbicides.
    • 环己烯酮肟醚I其中n为0至5,m为0至2,R 1为C 1 -C 6烷基,R 2为C 1 -C 4 - 烷基或苄基,A为未取代或取代的C 1 -C 6 - 亚烷基,未取代或取代的C 3 -C 6亚烯基,未取代或取代的C 3 -C 6亚炔基或未取代或取代的C 3 -C 6亚烷基或C 4 -C 6亚烯基链,其中在每种情况下亚甲基可以被O, S,SO,SO2或-N(Ra) - ,Ra是H,C1-C4-烷基,C3-C6-烯基或C3-C6-炔基,Z是苯基,5元杂芳族基团或6元 具有1至4个氮原子的杂芳族基团,X是NO 2,CN,卤素,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷氧基,COOH, C 1 -C 4烷氧基羰基,未取代或取代的苄氧基羰基,未取代或取代的苯基,未取代或取代的吡啶基或-NRbRc,Rb是H,C1-C4-烷基,C3-C6-烯基或C3-C6-炔基,Rc是H, C 1 -C 4 - 烷基,C 3 -C 6 - 烯基,C 3 -C 6炔基,C 1 -C 6 - 酰基或不饱和的 取代或取代的苯甲酰基,C1-C10-羧酸和无机酸的农业上有用的盐和酯适合作为除草剂。
    • 97. 发明授权
    • Herbicides containing substituted 2-aminothiophenes
    • US5422335A
    • 1995-06-06
    • US70389
    • 1993-06-07
    • Helmut HagenGerhard NilzHelmut WalterAndreas Landes
    • Helmut HagenGerhard NilzHelmut WalterAndreas Landes
    • A01N25/32A01N35/06A01N39/02A01N43/10C07D333/38C07D333/68C07D333/70C07D409/04C07D409/12C07D417/12A01N43/12A01N47/24C07D333/54
    • C07D409/04A01N25/32C07D333/38C07D333/68C07D409/12C07D417/12
    • A herbicidal composition containing one or more substituted 2-aminothiophenes of the formula I ##STR1## where R.sup.1 and R.sup.2 together from a C.sub.4 -alkylene chain to which a benzene ring may be fused,R.sup.3 is --CN or CX--R.sup.6, where R.sup.6 is hydroxyl, C.sub.1 -C.sub.4 -alkoxy or amino,R.sup.4 is hydrogen or a phenyl group which may carry one or two nitro radicals,--PO(OR.sup.8).sub.2, --CX--R.sup.9, --SO.sub.2 R.sup.10, --CX--N(H) --CO--R.sup.8 or --CX--N(R.sup.7)--SO.sub.2 --R.sup.11,whereR.sup.8 is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl groupR.sup.9 is C.sub.1 -C.sub.20 -alkyl, partially or completely halogenated C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.6 -cycloalkyl, or amino, C.sub.1 -C.sub.4 -alkylamino, C.sub.3 -C.sub.8 -cycloalkylamino, phenyl or phenylamino, where the aromatic moiety may carry at least one of nitro and halogen;R.sup.10 is C.sub.1 -C.sub.4 -alkyl or phenyl, which may carry one C.sub.1 -C.sub.4 -alkyl radical;R.sup.11 is pyrrolidin-1-yl, piperidin-1-yl, morpholin-4-yl or piperazin-1-yl, where the heterocyclic structures may carry one C.sub.1 -C.sub.4 -group;R.sup.5 is hydrogen;orR.sup.4 and R.sup.5 together form a group .dbd.CR.sup.12 R.sup.13 or --CO--W--CO--, where R.sup.12 is hydrogen, amino, C.sub.1 -C.sub.4 -alkylamino or C.sub.3 -C.sub.8 -cycloalkylamino;R.sup.13 is amino, C.sub.3 -C.sub.8 -cycloalkylamino, phenyl or pyridyl, where the two last mentioned substituents may carry at least one halogen or nitro radicals;W is an ethylene or ethenylene bridge, or a 6-membered 1,2-C-bonded aromatic bridge where these bridge members may carry, on each substitutable carbon atom, at least one halogena 5-membered or 6-membered 1,2-C-bonded cycloalkylene or cycloalkenylene bridge,and the basic salts of the compounds I in which R.sup.3 is hydroxycarbonyl or hydroxythiocarbonyl, and the acidic salts of the compounds I which contain a basic nitrogen atom, as antagonistic compoundsand one or more herbicidal active ingredients from the group consisting ofthe cyclohexenone derivatives of the formula III ##STR2##
    • 99. 发明授权
    • Dicarboximides and their use as herbicides
    • 二酰亚胺及其作为除草剂的用途
    • US5378680A
    • 1995-01-03
    • US931951
    • 1992-08-19
    • Volker MaywaldKlaus DitrichThomas KuekenhoehnerGerhard HamprechtWolfgang FreundKarl-Otto WestphalenMatthias GerberHelmut Walter
    • Volker MaywaldKlaus DitrichThomas KuekenhoehnerGerhard HamprechtWolfgang FreundKarl-Otto WestphalenMatthias GerberHelmut Walter
    • A01N43/76A01N43/78A01N43/80A01N43/90C07D498/04C07D499/04C07D513/04
    • C07D513/04A01N43/90
    • Dicarboximides of the formulae Ia, Ib and Ic ##STR1## where X is oxygen or sulfur,R.sup.1 is hydrogen, halogen, cyano, alkyl, cycloalkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, haloalkoxy, haloalkylthio, alkylsulfonyl, haloalkylsulfonyl, phenyl, phenylalkyl, phenoxy or phenylthio, a 5-membered or 6-membered saturated or aromatic heterocyclic radical containing one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, where the stated organic radicals may be further substituted, andR.sup.2 is hydrogen, hydroxyl, alkoxy, alkyl, cycloalkyl, alkenyl, alkynyl, di-C.sub.1 -C.sub.4 - alkylamino, a 5-membered or 6-membered heterocyclic saturated or aromatic radical having one or two hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, phenyl or naphthyl, where the stated organic radicals may be further substituted,and plant-tolerated salts of the dicarboximides I, except for 3-methylisoxazole-4,5-dicarboximide and thiazole-4,5-dicarboximides in which R.sup.2 is phenyl when R.sup.1 is methyl or 2-thiazolyl,and herbicides containing these compounds.
    • 其中X是氧或硫,R 1是氢,卤素,氰基,烷基,环烷基,烯基,炔基,烷氧基,烯氧基,炔氧基,烷氧基, 烷硫基,卤代烷氧基,卤代烷硫基,烷基磺酰基,卤代烷基磺酰基,苯基,苯基烷基,苯氧基或苯硫基,含有一个或两个选自氧,硫和氮的杂原子的5元或6元饱和或芳族杂环基团, 所述有机基团可以被进一步取代,并且R 2是氢,羟基,烷氧基,烷基,环烷基,链烯基,炔基,二-C 1 -C 4 - 烷基氨基,5元或6元杂环饱和或芳族基, 选自氧,硫和氮的两个杂原子,苯基或萘基,其中所述有机基团可以被进一步取代,以及二甲酰亚胺I的植物耐受盐,除了3-甲基异恶唑-4,5-二甲酰亚胺 de和噻唑-4,5-二羧酰亚胺,其中当R 1是甲基或2-噻唑基时,R 2是苯基,以及含有这些化合物的除草剂。