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    • 91. 发明公开
    • 석탄추출물 내의 황화합물 제거용 2차 용매 및 이를 이용한 황화합물 제거방법
    • 萃取煤脱硫的第二种溶剂和使用其的脱硫方法
    • KR1020130059073A
    • 2013-06-05
    • KR1020110125185
    • 2011-11-28
    • 한국에너지기술연구원
    • 김종남정태성김인백이광복이시훈범희태고창현박종호
    • C10L9/04C10L5/02B01D11/04
    • C10L9/04B01D11/04B01D2255/20753B01D2257/304C10L5/02C10L2290/54
    • PURPOSE: The secondary solvent for removing solvent compound and a removing method of sulfur compound using the same are provided to remove sulfur compound with high efficiency from coal extract of low class coal, and reduce cost of the whole procedure by showing high desulfurization efficiency from a small amount of secondary solvent. CONSTITUTION: The secondary solvent for removing solvent comprises deionized water, hydrogen peroxide, methanol, ethanol, phentanol, and one or the compound selected from PGMEA. A removal method comprises the step of introducing the secondary solvent which acts as hydrogen donor to coal extract and removes sulfide compound within coal extract obtained from the coal extracting process of low class in a form of hydrogen sulfide gas. The secondary solvent is also used with one selected from reforming catalyst of metal oxide, metal hydroxide, activated charcoal, and transition metal or desulfurizing agent composed of the mixture. The desulfurizing agent is Ni group reforming catalyst.
    • 目的:提供用于除去溶剂化合物的二次溶剂和使用其的硫化合物的除去方法,以从低级煤的煤提取物中高效地除去硫化合物,并且通过从低级煤的脱硫效率显示出高的脱硫效率来降低整个操作的成本 少量二次溶剂。 结构:用于除去溶剂的二次溶剂包括去离子水,过氧化氢,甲醇,乙醇,吩醇和一种或选自PGMEA的化合物。 除去方法包括将作为氢供体的二次溶剂引入到煤提取物中的步骤,并从硫化氢气体形式的低等级的提取煤中提取煤提取物中除去硫化物。 第二溶剂也可用于选自金属氧化物,金属氢氧化物,活性炭,过渡金属的重整催化剂或由该混合物组成的脱硫剂。 脱硫剂为Ni基重整催化剂。
    • 94. 发明公开
    • 수화된 금속염의 용융함침을 이용한 금속 또는 산화금속 촉매 담지체의 제조 방법 및 그 금속 또는 산화금속 촉매 담지체
    • 使用金属盐酸盐和金属或金属氧化物的熔融渗透过程的金属或金属氧化物负载型催化剂的制造方法
    • KR1020130013568A
    • 2013-02-06
    • KR1020110075280
    • 2011-07-28
    • 한국에너지기술연구원
    • 박지찬양정일양정훈고창현정헌이호태김학주천동현김병권김태완
    • B01J23/75B01J23/755B01J35/02B01J37/02
    • B01J37/0201B01J27/00B01J35/02B01J35/023B01J35/1004B01J37/08
    • PURPOSE: A manufacturing method for a metal- or metal oxide-supported catalyst using a melt-infiltration process with a metal hydrate salt and a metal- or metal oxide-supported catalyst thereof are provided to easily and quickly mass produce the metal- or metal oxide-supported catalyst by using a nitrate hydrate metal salt or a chloride hydrate metal salt with a low melting point. CONSTITUTION: A manufacturing method for a metal- or metal oxide-supported catalyst using a melt-infiltration process with a metal hydrate salt comprises the following steps: The metal hydrate salt is mixed with a metal substrate with a porous structure. After the mixing process, the mixture is melted at the melting point of the metal hydrate salt such that the metal hydrate salt infiltrates into the substrate. The metal hydrate salt infiltrated in the supporter is plasticized at a high temperature and chagrined to nanoparticles. The metal hydrate salt has a melting point within 35 - 120 deg. C. [Reference numerals] (a) Step of mixing metal hydrate salt and a support; (b) Step of carrying by melting impregnation; (c) Step of nanoparticulation by plasticizing
    • 目的:提供一种金属或金属氧化物负载的催化剂的制造方法,其使用金属水合物盐和金属或金属氧化物负载的催化剂进行熔融渗透,容易且快速地大量生产金属或金属 氧化物负载的催化剂,使用低熔点的硝酸盐水合物金属盐或氯化物水合物金属盐。 构成:使用具有金属水合物盐的熔融渗透方法的金属或金属氧化物负载的催化剂的制造方法包括以下步骤:金属水合物盐与具有多孔结构的金属基材混合。 在混合过程之后,混合物在金属水合物盐的熔点下熔化,使得金属水合物盐渗透到基材中。 渗透在支持体中的金属水合物盐在高温下增塑,并与纳米颗粒融合。 金属水合物盐的熔点在35-120度之内。 (a)将金属水合物盐和载体混合的步骤; (b)浸渍浸渍步骤; (c)通过塑化进行纳米颗粒的步骤
    • 97. 发明公开
    • 생물체에서 유래된 지질과 하이드로탈사이트를 이용하는 연속적인 탄화수소 생산 방법 및 장치
    • 使用氢化钙作为催化剂从生物原料制备碳氢化合物的连续方法和装置
    • KR1020120058241A
    • 2012-06-07
    • KR1020100119935
    • 2010-11-29
    • 한국에너지기술연구원
    • 고창현나정걸김종남박성열박종호범희태한상섭이보은
    • C10G3/00C07C1/213B01J21/00B01J38/50
    • Y02P20/584Y02P30/20C10G3/00B01J21/00B01J38/50C07C1/213
    • PURPOSE: Continuous method and apparatus for preparing hydrocarbon using biological originated lipid and hydrotalcite are provided to produce the hydrocarbon without using hydrogen, and to reduce the operational costs. CONSTITUTION: A continuous method for preparing hydrocarbon using biological originated lipid and hydrotalcite comprises the following steps: supplying raw materials selected from triglyceride, fatty acid, or fatty acid derivative into a first reactor(2); contacting the raw material in the first reactor with a hydrotalcite catalyst to obtain the hydrocarbon; recycling the used hydrotalcite after the termination of the reaction inside the first reactor; supplying the raw materials into a second reactor(3) during the recycling process of the hydrotalcite; contacting the raw materials in the second reactor with the hydrotalcite catalyst to obtain the hydrocarbon; and recycling the used hydrotalcite after the termination of the reaction inside the second reactor, and repeating previous steps.
    • 目的:提供使用生物来源的脂质和水滑石制备碳氢化合物的连续方法和设备,以生产不使用氢气的烃,并降低运行成本。 构成:使用生物来源的脂质和水滑石制备烃的连续方法包括以下步骤:将选自甘油三酯,脂肪酸或脂肪酸衍生物的原料供应到第一反应器(2)中; 使第一反应器中的原料与水滑石催化剂接触以获得烃; 在第一反应器内的反应结束后再循环使用的水滑石; 在水滑石的回收过程中将原料供应到第二反应器(3)中; 使第二反应器中的原料与水滑石催化剂接触以获得烃; 并且在第二反应器内部的反应结束后再循环使用的水滑石,并重复以前的步骤。