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    • 91. 发明公开
    • 박리층을 갖는 성형용 금형 또는 전주용 모형 및 그들의 제조 방법
    • 用于电镀每个具有释放层的成型模具或主模式
    • KR1020090018216A
    • 2009-02-19
    • KR1020097001241
    • 2005-12-28
    • 닛뽕소다 가부시키가이샤
    • 히다카도모야나카모토노리후미후지타요시타카
    • B29C33/60B29C33/56C25D1/22
    • B29C33/64B29C33/56C25D1/22
    • A molding die or master pattern for electroforming characterized by comprising a die or master pattern and a release layer comprising a thin organic film formed on the surface of the die or pattern by bringing the die or pattern into contact with an organic-solvent solution containing a silane surfactant represented by the formula [1]: Rn-Si-X 4-n (1) (wherein R represents an optionally substituted C1-20 hydrocarbon group, an optionally substituted C1-20 halogenated hydrocarbon group, a C1-20 hydrocarbon group containing a connecting group, or C1-20 halogenated hydrocarbon group containing a connecting group; X represents hydroxy, halogeno, or C1-6 alkoxy or acyloxy; and n is an integer of 1-3) and a catalyst capable of interacting with the silane surfactant. The release layer is excellent in wearing resistance and release performance.
    • 一种用于电铸的成型模具或母版图案,其特征在于包括模具或主图案和释放层,所述剥离层包括通过使所述模具或图案与含有所述模具或图案的有机溶剂溶液接触而形成在所述模具或图案的表面上的薄的有机膜 由式[1]表示的硅烷表面活性剂:Rn-Si-X 4-n(1)(其中R表示任选取代的C 1-20烃基,任选取代的C 1-20卤代烃基,C 1-20烃基 含有连接基团或含有连接基团的C 1-20卤代烃基; X表示羟基,卤代或C 1-6烷氧基或酰氧基; n为1-3的整数)和能够与硅烷相互作用的催化剂 表面活性剂。 剥离层的耐磨损性和脱模性优异。
    • 95. 发明公开
    • 아크릴산계 중합체 및 그 제조 방법
    • 丙烯酸聚合物及其生产方法
    • KR1020080015006A
    • 2008-02-15
    • KR1020077029134
    • 2006-06-13
    • 닛뽕소다 가부시키가이샤
    • 구보히데오마츠모토히토시시모토리다케시가와베도오루
    • C08F20/06C08F220/06C08F2/40C08F297/02
    • C08F220/28C08F293/005C08F297/02C08F297/026
    • Disclosed is an acrylic acid polymer characterized by being a star polymer having a repeating unit derived from an (alpha-lower alkyl)acrylate represented by the formula (I) below in an arm. Also disclosed is an acrylic acid polymer characterized by containing a repeating unit derived from a poly(alpha-lower alkyl)acrylate and a repeating unit derived from an (alpha-lower alkyl)acrylate represented by the formula (I) below. Further disclosed is a method for producing a polymer wherein oligomers having a polymerization-active terminal and consisting of more than 1.0 and not more than 4.0 monomer units in average are formed from monomers, and a living polymerization is performed using the oligomers having a polymerization-active terminal as an initiating species. (I) (In the formula, R1 represents a hydrogen atom or a lower alkyl group, and R2 represents an organic group having a polar group.)
    • 公开了一种丙烯酸聚合物,其特征在于具有衍生自下述式(I)的(α-低级烷基)丙烯酸酯的臂的重复单元的星形聚合物。 还公开了一种丙烯酸聚合物,其特征在于含有衍生自聚(α-低级烷基)丙烯酸酯的重复单元和衍生自下式(I)表示的(α-低级烷基)丙烯酸酯的重复单元。 进一步公开了一种聚合物的制备方法,其中由单体形成平均具有多于1.0个且不超过4.0个单体单元的具有聚合活性末端的低聚物,并且使用具有聚合反应性的低聚物进行活性聚合, 活性终端作为起始物种。 (I)(式中,R1表示氢原子或低级烷基,R2表示具有极性基团的有机基团。)
    • 96. 发明公开
    • 신규한 다분기 고분자
    • 新型多分支聚合物
    • KR1020070119097A
    • 2007-12-18
    • KR1020077027726
    • 2004-11-25
    • 닛뽕소다 가부시키가이샤
    • 아오야기고이치로니이타니다케시
    • C08F12/16C08F212/14C08F4/06C08F20/22
    • C08F12/16C08F4/06C08G83/005
    • A hyperbranched polymer in which branch terminals can be easily modified and which has a high degree of branching and a narrow dispersion. A compound having two or more polymerization-initiation sites and polymerizable unsaturated bonds is polymerized by living radical polymerization using a metal catalyst. Thus, a hyperbranched polymer having a narrow dispersion and a high degree of branching can be produced which has repeating units represented by the formula (I): (I) wherein R1 to R3 each independently represents hydrogen or a hydrocarbon group, provided that R1 may be bonded to R3 to form a ring; X represents a connecting group having a valance of 3 or higher; Y's may be the same or different and each represents a functional group optionally terminated by halogeno; and a is an integer of 2 or larger.
    • 分枝末端可以容易地改性并具有高度支化度和窄分散性的超支化聚合物。 具有两个以上聚合引发位点和​​可聚合不饱和键的化合物通过使用金属催化剂的活性自由基聚合而聚合。 因此,可以制备具有窄分散性和高支化度的超支化聚合物,其具有由式(I)表示的重复单元:(I)其中R 1至R 3各自独立地表示氢或烃基,条件是R 1可以 与R3键合形成环; X表示3以上的连接基团; Y可以相同或不同,各自表示任选被卤素终止的官能团; a为2以上的整数。
    • 99. 发明公开
    • 유기 박막 형성 방법, 유기 박막 형성용 보조제 및 유기박막 형성용 용액
    • 유기박막형성방법,유기박막형성용보조제및유기박막형성용용액
    • KR1020070032819A
    • 2007-03-22
    • KR1020077003518
    • 2005-07-21
    • 닛뽕소다 가부시키가이샤
    • 기무라노부오후지타요시타카히다카도모야
    • C03C17/28C03C17/30B05D7/24
    • B05D7/24B05D1/185B82Y30/00B82Y40/00C03C17/28C03C17/30C03C2217/76
    • An organic thin film forming method for forming an organic thin film on a substrate surface comprising: contacting the substrate with a solution for forming an organic thin film obtained from an auxiliary agent for forming an organic thin film obtained by mixing a metal surfactant (1) having at least one hydrolytic group and a compound capable of interacting with the metal surfactant (1), and a metal surfactant (2) having at least one hydrolytic group, in an organic solvent, wherein a solution for forming an organic thin film is used in which the moisture content has been adjusted or maintained to be within a predetermined range; an organic thin film forming method for forming an organic thin film on a substrate surface comprising: contacting the substrate with an organic solvent solution obtained by mixing a metal surfactant having at least one hydrolytic group and a catalyst capable of interacting with the surfactant, wherein the organic solvent solution contains a predetermined amount of moisture, and contains 20 to 2000 ppm of a hydroxide group-containing compound which is a hydrolysis product of the metal surfactant; and, an auxiliary agent for forming an organic thin film and a solution for forming an organic thin film used in this method.
    • 1.一种有机薄膜形成方法,用于在基板表面上形成有机薄膜,所述方法包括:使所述基板与用于形成有机薄膜的溶液接触,所述有机薄膜由用于形成有机薄膜的辅助剂获得,所述辅助剂通过混合金属表面活性剂(1) 在有机溶剂中具有至少一个水解基团和能够与金属表面活性剂(1)相互作用的化合物和具有至少一个水解基团的金属表面活性剂(2),其中使用用于形成有机薄膜的溶液 其中水分含量已被调节或保持在预定范围内; 一种有机薄膜形成方法,用于在基板表面上形成有机薄膜,包括:使所述基板与通过混合具有至少一个水解基团的金属表面活性剂和能够与所述表面活性剂相互作用的催化剂而获得的有机溶剂溶液接触,其中所述 有机溶剂溶液含有规定量的水分,含有20〜2000ppm的作为金属系表面活性剂的水解物的含氢氧基的化合物, 以及用于形成有机薄膜的辅助剂和用于在该方法中使用的用于形成有机薄膜的溶液。