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    • 2. 发明专利
    • Exhaust emission control device for internal combustion engine
    • 用于内燃机的排气排放控制装置
    • JP2013122179A
    • 2013-06-20
    • JP2011270325
    • 2011-12-09
    • Toyota Motor Corpトヨタ自動車株式会社Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • HAYASHI TAKAHIROMORIKAWA AKIRA
    • F01N3/08B01D53/94F01N3/24F01N3/28F02D41/14
    • Y02T10/24
    • PROBLEM TO BE SOLVED: To improve deterioration in fuel consumption for NOreduction in exhaust gas, in an exhaust emission control device for an internal combustion engine provided with a NOreduction catalyst device carrying a base metal catalyst and having low NOreduction performance.SOLUTION: An exhaust emission control device for an internal combustion engine includes: a first NOreduction catalyst device 40 carrying a base metal catalyst disposed at an exhaust passage 30; a second NOreduction catalyst device 50 disposed at the exhaust passage at a downstream side of the first NOreduction catalyst device and having ammonia storage capability; and a first NOsensor 80 disposed at the exhaust passage at a downstream side of the second NOreduction catalyst device. After a combustion air-fuel ratio of the internal combustion engine is made richer than a theoretical air-fuel ratio, the combustion air-fuel ratio of the internal combustion engine is made leaner than the theoretical air-fuel ratio. When the combustion air-fuel ratio of the internal combustion engine is made leaner than the theoretical air-fuel ratio, if NOis detected by the first NOsensor, the combustion air-fuel ratio of the internal combustion engine is made richer than the theoretical air-fuel ratio.
    • 要解决的问题:为了提高排气中的NO X 的燃料消耗的劣化,在内燃机的排气排放控制装置中, SB POS =“POST”> X 还原催化剂装置,其具有贱金属催化剂并且具有低NO X 还原性能。 解决方案:一种用于内燃机的废气排放控制装置,包括:承载设置在排气通道30处的贱金属催化剂的第一NOS SB POS =“X”SB“还原催化剂装置40; 设置在第一NO SB SB“还原催化剂装置的下游侧的排气通道处的第二NOS SB POS =”X“SB”还原催化剂装置“,以及 具有氨储存能力; 以及设置在第二NO ”> X“还原催化剂装置的下游侧的排气通道处的第一NO X 传感器80。 在内燃机的燃烧空燃比变得比理论空燃比更浓之后,使内燃机的燃烧空燃比比理论空燃比更稀。 当内燃机的燃烧空燃比比理论空燃比更精细时,如果通过第一NO X “> X 传感器,使内燃机的燃烧空燃比变得比理论空燃比更浓。 版权所有(C)2013,JPO&INPIT
    • 3. 发明专利
    • Exhaust emission control device for internal combustion engine
    • 用于内燃机的排气排放控制装置
    • JP2013122177A
    • 2013-06-20
    • JP2011270311
    • 2011-12-09
    • Toyota Motor Corpトヨタ自動車株式会社Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • HAYASHI TAKAHIROMORIKAWA AKIRA
    • F01N3/08B01D53/94F01N3/10F01N3/20F01N3/24
    • Y02T10/24
    • PROBLEM TO BE SOLVED: To improve deterioration in fuel consumption for NOreduction, in an exhaust emission control device for an internal combustion engine with a NOreduction catalyst device carrying a base metal catalyst and having low NOreduction performance.SOLUTION: A NOreduction catalyst device 40 carrying a base metal catalyst is disposed at a third exhaust passage 30 positioned at a downstream side of a confluence part 100 between a first exhaust passage 10 of a first cylinder group and a second exhaust passage 20 of a second cylinder group. A NOstorage device 50 is disposed at the second exhaust passage. A communication passage 60 communicating the second exhaust passage at a downstream side of the NOstorage device with the third exhaust passage at a downstream side of the NOstorage device is provided. When a combustion air-fuel ratio of the first cylinder group is made rich and when a combustion air-fuel ratio of the second cylinder group is made lean, exhaust gas flowing out from the NOstorage device passes through the communication passage. When the combustion air-fuel ratio of the second cylinder group is made rich, the exhaust gas flowing out from the NOstorage device passes through the NOreduction catalyst device.
    • 要解决的问题为了改善NO X 的燃料消耗的劣化,在具有NO X 还原性能的“X”SB“还原催化剂装置”。

      解决方案:承载贱金属催化剂的NOS SB POS =“POST”> X“还原催化剂装置40设置在位于汇合部100的下游侧的第三排气通道30之间,位于第一 第一气缸组的排气通道10和第二气缸组的第二排气通道20。 存储装置50设置在第二排气通道中。否则,将 X 存储装置50。 在NO X 存储装置的下游侧将第二排气通道与NO X 存储设备。 当第一气缸组的燃烧空燃比变浓时,当第二气缸组的燃烧空燃比变稀时,从NO X < SB>存储装置通过通信通道。 当第二气缸组的燃烧空燃比变浓时,从NO X 储存装置流出的废气通过NO X 还原催化剂装置。 版权所有(C)2013,JPO&INPIT

    • 4. 发明专利
    • Exhaust gas purification catalyst and method of producing the same
    • 排气净化催化剂及其生产方法
    • JP2013022507A
    • 2013-02-04
    • JP2011159102
    • 2011-07-20
    • Toyota Motor Corpトヨタ自動車株式会社Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • TAKAGI SHIGEJIWATABE GAOMORIKAWA AKIRAHIROSE TAKUTONAGAI YASUTAKA
    • B01J23/76B01D53/94B01J37/04B01J37/08F01N3/10
    • PROBLEM TO BE SOLVED: To provide an exhaust gas purification catalyst having excellent exhaust gas purification performance under a relatively low temperature condition and excellent heat endurance, and to provide a method of producing the exhaust gas purification catalyst.SOLUTION: The exhaust gas purification catalyst includes: at least one Group-XIII element oxide; at least either one of at least one lanthanoid oxide and at least one Group-IV element oxide; and particles including at least one base metal selected from a group comprising copper etc. An average particle size of the particles including the base metal is 1-1,000 nm. An average distance between the particles including the base metal and the Group-XIII element oxide nearest to the particles is 60 nm or less, and an average distance between the particles including the base metal and the lanthanoid oxide and/or the Group-IV element oxide nearest to the particles is 60 nm or less.
    • 解决的问题:提供一种在相对低的温度条件下具有优异的废气净化性能和优异的耐热性的废气净化催化剂,并提供一种生产废气净化催化剂的方法。 废气净化催化剂包括:至少一种第ⅩⅢ族元素氧化物; 至少一种镧系元素氧化物和至少一种IV族元素氧化物中的至少一种; 以及包含选自铜等的至少一种母体金属的粒子。包含母体金属的粒子的平均粒径为1-1000nm。 包括贱金属和最接近粒子的第ⅩⅢ族元素氧化物的粒子之间的平均距离为60nm以下,包含贱金属和镧系元素氧化物的粒子和/或IV族元素之间的平均距离 最接近粒子的氧化物为60nm以下。 版权所有(C)2013,JPO&INPIT
    • 9. 发明专利
    • Compound oxide and method for producing the same, and exhaust gas purifying catalyst
    • 化合物及其制造方法,以及排气净化催化剂
    • JP2013215651A
    • 2013-10-24
    • JP2012086825
    • 2012-04-05
    • Toyota Motor Corpトヨタ自動車株式会社Toyota Central R&D Labs Inc株式会社豊田中央研究所
    • KUMAGAI NAOKIMIURA MASAHIDEHONMA YUJIROTANABE TOSHITAKAMORIKAWA AKIRAYAMAMURA YOSHIE
    • B01J23/63B01D53/94B01J37/04F01N3/10
    • PROBLEM TO BE SOLVED: To provide a compound oxide in which a pyrochlore phase is stabilized by arranging a diffusion barrier around the pyrochlore phase and which is excellent in an oxygen storage capacity and is used for an exhaust gas purifying catalyst, and to provide an exhaust gas purifying catalyst including the compound oxide, and further, a method for producing the compound oxide.SOLUTION: A compound oxide is composed of an MgAlO-CeO-ZrOternary system compound oxide, and has a pyrochlore phase in which Ce and Zr are regularly arrayed. A method for producing the compound oxide includes: a step of adding a precipitant to a solution containing a cerium compound and a zirconium compound to form a first coprecipitate, firing it, and obtaining a first fired material; a step of adding a precipitant to a solution containing a magnesium compound and an aluminum compound to form a second coprecipitate, firing it, and obtaining a second fired material; and a step of producing the compound oxide which is composed of the MgAlO-CeO-ZrOternary system compound oxide, and has the pyrochlore phase in which Ce and Zr are regularly arrayed, by mixing, heating and reducing the first and second fired materials.
    • 要解决的问题:为了提供通过在烧绿石相周围设置扩散阻挡层来稳定烧绿石相的复合氧化物,其具有优异的储氧能力并且用于排气净化催化剂,并且提供排气 包括复合氧化物的气体净化催化剂,以及复合氧化物的制造方法。复合氧化物由MgAlO-CeO-Zr系复合氧化物构成,具有烧绿石相,其中Ce和Zr规则排列 。 复合氧化物的制造方法包括:将沉淀剂添加到含有铈化合物和锆化合物的溶液中,形成第一共沉淀物,烧成,得到第一烧成物的工序; 向含有镁化合物和铝化合物的溶液中添加沉淀剂以形成第二共沉淀物,烧制,得到第二烧成物的工序; 以及通过混合,加热和还原第一和第二烧制材料,制备由MgAlO-CeO-Zr复合氧化物组成的复合氧化物并具有规则排列Ce和Zr的烧绿石相的步骤。