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    • 6. 发明申请
    • Method of preventing surface roughening during hydrogen pre-bake of SiGe substrates using chlorine containing gases
    • 在使用含氯气体的SiGe衬底的氢预烘烤期间防止表面粗糙化的方法
    • US20050148162A1
    • 2005-07-07
    • US10751207
    • 2004-01-02
    • Huajie ChenDan MocutaRichard MurphyStephen BedellDevendra Sadana
    • Huajie ChenDan MocutaRichard MurphyStephen BedellDevendra Sadana
    • C30B25/02C30B29/52H01L21/20H01L21/205H01L21/306H01L21/36H01L21/44
    • H01L21/02046C30B25/02C30B29/52H01L21/02052H01L21/02381H01L21/0243H01L21/02532H01L21/02658H01L21/02661
    • The invention forms an epitaxial silicon-containing layer on a silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface and avoids creating a rough surface upon which the epitaxial silicon-containing layer is grown. In order to avoid creating the rough surface, the invention first performs a hydrofluoric acid etching process on the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. This etching process removes most of oxide from the surface, and leaves only a sub-monolayer of oxygen (typically 1×1013-1×1015/cm2 of oxygen) at the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. The invention then performs a hydrogen pre-bake process in a chlorine containing environment which heats the silicon germanium, strained silicon, or thin silicon-on-insulator surface sufficiently to remove the remaining oxygen from the surface. By introducing a small amount of chlorine containing gases, the heating processes avoid changing the roughness of the silicon germanium, patterned strained silicon, or patterned thin silicon-on-insulator surface. Then the process of epitaxially growing the epitaxial silicon-containing layer on the silicon germanium, patterned strained silicon, or patterned silicon-on-insulator surface is performed.
    • 本发明在硅​​锗,图案化的应变硅或图案化的绝缘体上硅表面上形成外延含硅层,并避免产生外延含硅层生长的粗糙表面。 为了避免产生粗糙表面,本发明首先对硅锗,图案化应变硅或图案化的绝缘体上硅表面进行氢氟酸蚀刻工艺。 该蚀刻工艺从表面除去大部分氧化物,并且仅留下氧气的亚单层(通常为1×10 13/1×10 15 / cm 2以上) 的氧),图案化的应变硅或图案化的绝缘体上硅表面。 然后,本发明在含氯环境中进行氢预烘烤过程,其中充分加热硅锗,应变硅或薄的绝缘体上硅表面以从表面除去剩余的氧。 通过引入少量的含氯气体,加热过程避免改变硅锗,图案化的应变硅或图案化的绝缘体上硅表面的粗糙度。 然后进行外延生长硅锗,图案化应变硅或图案化硅绝缘体表面上的外延硅含量层的工艺。
    • 7. 发明授权
    • Method for improving CVD film quality utilizing polysilicon getterer
    • 利用多晶硅吸收器提高CVD膜质量的方法
    • US06749684B1
    • 2004-06-15
    • US10250181
    • 2003-06-10
    • Huajie ChenDan MocutaRichard J. MurphyPaul RonsheimDavid Rockwell
    • Huajie ChenDan MocutaRichard J. MurphyPaul RonsheimDavid Rockwell
    • C30B2504
    • C30B29/06C30B25/02C30B29/08C30B29/52
    • A method is disclosed for forming an epitaxial layer on a front side of a substrate formed of a monocrystalline material, using a chemical vapor deposition system. In this method, a plurality of gettering wafers formed of a gettering material are arranged in the CVD system, such that the front side of each substrate is facing one of the gettering wafers. Impurities present in the CVD system during formation of the epitaxial layer are gettered by the gettering wafers. Alternatively, a layer of a gettering material is deposited on a back side of each of the plurality of substrates, and the substrates are arranged such that the front side of each substrate is facing the backside of another of the substrates. In another embodiment, a layer of a gettering material is deposited on an interior surface of the CVD system. Impurities removed from the CVD system during epitaxial formation include oxygen, water vapor and other oxygen-containing contaminants.
    • 公开了一种使用化学气相沉积系统在由单晶材料形成的基板的正面上形成外延层的方法。 在该方法中,在CVD系统中配置由吸气材料形成的多个吸气晶片,使得每个基板的前侧面对吸气晶片之一。 在形成外延层期间存在于CVD系统中的杂质被吸杂晶片吸收。 或者,在多个基板的每一个的背面上沉积吸气材料层,并且将基板布置成使得每个基板的前侧面对另一个基板的背面。 在另一个实施例中,吸气材料层沉积在CVD系统的内表面上。 在外延形成期间从CVD系统中除去的杂质包括氧,水蒸气和其它含氧污染物。
    • 8. 发明申请
    • Method of forming thin sgoi wafers with high relaxation and low stacking fault defect density
    • 形成具有高松弛和低堆垛缺陷缺陷密度的薄sgoi晶片的方法
    • US20070128840A1
    • 2007-06-07
    • US10597066
    • 2004-01-16
    • Huajie ChenStephen BedellDevendra SadanaDan Mocuta
    • Huajie ChenStephen BedellDevendra SadanaDan Mocuta
    • H01L21/20
    • H01L21/76256H01L21/02381H01L21/0245H01L21/02532H01L21/02664H01L21/31658H01L21/84H01L29/1054H01L29/78687
    • A method of forming a silicon germanium on insulator (SGOI) structure. A SiGe layer is deposited on an SOI wafer. Thermal mixing of the SiGe and Si layers is performed to form a thick SGOI with high relaxation and low stacking fault defect density. The SiGe layer is then thinned to a desired final thickness. The Ge concentration, the amount of relaxation, and stacking fault defect density are unchanged by the thinning process. A thin SGOI film is thus obtained with high relaxation and low stacking fault defect density. A layer of Si is then deposited on the thin SGOI wafer. The method of thinning includes low temperature (550° C.-700° C.) HIPOX or steam oxidation, in-situ HCl etching in an epitaxy chamber, or CMP. A rough SiGe surface resulting from HIPOX or steam oxidation thinning is smoothed with a touch-up CMP, in-situ hydrogen bake and SiGe buffer layer during strained Si deposition, or heating the wafer in a hydrogen environment with a mixture of gases HCl, DCS and GeH4.
    • 一种形成绝缘体上硅锗(SGOI)结构的方法。 SiGe层沉积在SOI晶片上。 进行SiGe和Si层的热混合以形成具有高松弛和低堆垛层错缺陷密度的厚SGOI。 然后将SiGe层变薄至所需的最终厚度。 稀释过程,Ge浓度,松弛量和堆垛层错缺陷密度均不变。 因此获得了具有高松弛和低堆垛层错缺陷密度的薄SGOI膜。 然后在薄SGOI晶片上沉积一层Si。 稀释方法包括低温​​(550℃-700℃)HIPOX或蒸汽氧化,在外延室中进行原位HCl蚀刻或CMP。 由HIPOX或蒸汽氧化稀化产生的粗糙SiGe表面在应变Si沉积期间用接触式CMP,原位氢气烘烤和SiGe缓冲层进行平滑,或者在氢气环境中用HCl,DCS混合气体加热晶片 和GeH 4。
    • 9. 发明申请
    • DIFFERENTIAL SPACER FORMATION FOR A FIELD EFFECT TRANSISTOR
    • 场效应晶体管的差分空间形成
    • US20070249112A1
    • 2007-10-25
    • US11308686
    • 2006-04-21
    • Brian GeeneDan MocutaGaku Sudo
    • Brian GeeneDan MocutaGaku Sudo
    • H01L21/8238
    • H01L21/823807H01L21/823864H01L29/7843
    • A method for manufacturing an integrated circuit includes providing one or more n-type field effect transistor and one or more p-type field effect transistor on a semiconductor substrate. Each of the transistors separated by a trench isolation structure. Each of the transistors has a source and drain regions formed in the semiconductor layer and a gate electrode formed above the semiconductor layer. An oxide liner is deposited across the upper surface of the integrated circuit and onto each of the one or more n-type field effect transistors and one or more p-type field effect transistors. A nitride liner depositing is deposited the oxide liner. At least a portion of the nitride liner on each of the one or more p-type field effect transistor is removed to form nitride sidewall spacers. Additional source and drain regions are implanted into the one or more p-type field effect transistors. The integrated circuit is annealed. The nitride liner is removed from the one or more n-type field effect transistors. The exposed oxide liner is removed from the semiconductor substrate and the one or more n-type field effect transistors and the one or more p-type field effect transistors whereby each of the one or more p-type field effect transistor has greater silicide proximity than each of the one or more n-type field effect transistors, thereby allowing increased performance of each of the one or more p-type field effect transistors without adversely affecting performance of each of the one or more n-type field effect transistors.
    • 一种用于制造集成电路的方法包括在半导体衬底上提供一个或多个n型场效应晶体管和一个或多个p型场效应晶体管。 每个晶体管由沟槽隔离结构分开。 每个晶体管具有形成在半导体层中的源极和漏极区域以及形成在半导体层上方的栅电极。 在集成电路的上表面和一个或多个n型场效应晶体管和一个或多个p型场效应晶体管中的每一个上沉积氧化物衬垫。 氮化物衬垫沉积沉积氧化物衬垫。 去除一个或多个p型场效应晶体管中的每一个上的氮化物衬垫的至少一部分,以形成氮化物侧壁间隔物。 另外的源极和漏极区域被注入到一个或多个p型场效应晶体管中。 集成电路退火。 从一个或多个n型场效应晶体管去除氮化物衬垫。 暴露的氧化物衬垫从半导体衬底和一个或多个n型场效应晶体管和一个或多个p型场效应晶体管中去除,由此,一个或多个p型场效应晶体管中的每一个与硅化物接近, 每个一个或多个n型场效应晶体管,从而允许增加一个或多个p型场效应晶体管中的每一个的性能,而不会不利地影响一个或多个n型场效应晶体管中的每一个的性能。