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1. 发明授权

US07833932B1 Compositions and methods for treating exhaust gases 有权
标题翻译：用于处理废气的组合物和方法
公开(公告)号：US07833932B1
公开(公告)日：2010-11-16
申请号：US12702010
申请日：2010-02-08
申请人： Chris E. DiFrancesco , Kozo Iida
发明人： Chris E. DiFrancesco , Kozo Iida
IPC分类号： B01J23/46 , B01J35/00
CPC分类号： F01N3/2066 , B01D53/8628 , B01D53/9477 , B01D2251/2062 , B01D2255/1026 , B01D2255/20776 , B01D2255/9022 , B01J23/6527 , B01J23/8993 , B01J27/053 , B01J35/0006 , F01N13/009 , F01N2610/02 , Y02T10/24
摘要： The present invention provides compositions, systems, and methods for achieving high efficiencies of nitrogen oxide (NOx) removal from exhaust gases while minimizing ammonia slip and sulfur dioxide oxidation. In one embodiment, a method of removing nitrogen oxides from an exhaust gas comprises providing a first catalyst layer, adding an ammonia-containing compound to the exhaust gas upstream of the first catalyst layer in excess of the stoichiometric equivalent of the nitrogen oxides in the exhaust gas, flowing the exhaust gas through the first catalyst layer, selectively catalytically decomposing ammonia in excess of the stoichiometric reaction equivalent of the nitrogen oxides in the exhaust gas, and catalytically reducing the nitrogen oxides by reaction with ammonia not selectively catalytically decomposed.
摘要翻译：本发明提供了用于实现从废气中除去氮氧化物（NOx）的高效率同时使氨滑脱和二氧化硫氧化最小化的组合物，系统和方法。在一个实施方案中，从废气中除去氮氧化物的方法包括提供第一催化剂层，向第一催化剂层的上游排气中加入超过化学计量当量的排气中的氮氧化物的含氨化合物气体，使废气流过第一催化剂层，选择性地催化分解超过废气中的氮氧化物的化学计量反应当量的氨，并且通过与未经选择性催化分解的氨反应催化还原氮氧化物。

2. 发明授权

US08137633B2 Compositions and methods for treating exhaust gases 有权
标题翻译：用于处理废气的组合物和方法
公开(公告)号：US08137633B2
公开(公告)日：2012-03-20
申请号：US12944154
申请日：2010-11-11
申请人： Chris E. DiFrancesco , Kozo Iida
发明人： Chris E. DiFrancesco , Kozo Iida
IPC分类号： B01D53/86
CPC分类号： F01N3/2066 , B01D53/8628 , B01D53/9477 , B01D2251/2062 , B01D2255/1026 , B01D2255/20776 , B01D2255/9022 , B01J23/6527 , B01J23/8993 , B01J27/053 , B01J35/0006 , F01N13/009 , F01N2610/02 , Y02T10/24
摘要： The present invention provides compositions, systems, and methods for achieving high efficiencies of nitrogen oxide (NOx) removal from exhaust gases while minimizing ammonia slip and sulfur dioxide oxidation. In one embodiment, a method of removing nitrogen oxides from an exhaust gas comprises providing a first catalyst layer, adding an ammonia-containing compound to the exhaust gas upstream of the first catalyst layer in excess of the stoichiometric equivalent of the nitrogen oxides in the exhaust gas, flowing the exhaust gas through the first catalyst layer, selectively catalytically decomposing ammonia in excess of the stoichiometric reaction equivalent of the nitrogen oxides in the exhaust gas, and catalytically reducing the nitrogen oxides by reaction with ammonia not selectively catalytically decomposed.
摘要翻译：本发明提供了用于实现从废气中除去氮氧化物（NOx）的高效率同时使氨滑脱和二氧化硫氧化最小化的组合物，系统和方法。在一个实施方案中，从废气中除去氮氧化物的方法包括提供第一催化剂层，向第一催化剂层的上游排气中加入超过化学计量当量的排气中的氮氧化物的含氨化合物气体，使废气流过第一催化剂层，选择性地催化分解超过废气中的氮氧化物的化学计量反应当量的氨，并且通过与未经选择性催化分解的氨反应催化还原氮氧化物。

3. 发明申请

US20110172090A1 COMPOSITIONS AND METHODS FOR TREATING EXHAUST GASES 有权
标题翻译：用于处理排气的组合物和方法
公开(公告)号：US20110172090A1
公开(公告)日：2011-07-14
申请号：US12944154
申请日：2010-11-11
申请人： Chris E. DiFrancesco , Kozo Iida
发明人： Chris E. DiFrancesco , Kozo Iida
IPC分类号： B01J23/46 , B01J35/02
CPC分类号： F01N3/2066 , B01D53/8628 , B01D53/9477 , B01D2251/2062 , B01D2255/1026 , B01D2255/20776 , B01D2255/9022 , B01J23/6527 , B01J23/8993 , B01J27/053 , B01J35/0006 , F01N13/009 , F01N2610/02 , Y02T10/24
摘要： The present invention provides compositions, systems, and methods for achieving high efficiencies of nitrogen oxide (NOx) removal from exhaust gases while minimizing ammonia slip and sulfur dioxide oxidation. In one embodiment, a method of removing nitrogen oxides from an exhaust gas comprises providing a first catalyst layer, adding an ammonia-containing compound to the exhaust gas upstream of the first catalyst layer in excess of the stoichiometric equivalent of the nitrogen oxides in the exhaust gas, flowing the exhaust gas through the first catalyst layer, selectively catalytically decomposing ammonia in excess of the stoichiometric reaction equivalent of the nitrogen oxides in the exhaust gas, and catalytically reducing the nitrogen oxides by reaction with ammonia not selectively catalytically decomposed.
摘要翻译：本发明提供了用于实现从废气中除去氮氧化物（NOx）的高效率同时使氨滑脱和二氧化硫氧化最小化的组合物，系统和方法。在一个实施方案中，从废气中除去氮氧化物的方法包括提供第一催化剂层，向第一催化剂层的上游排气中加入超过化学计量当量的排气中的氮氧化物的含氨化合物气体，使废气流过第一催化剂层，选择性地催化分解超过废气中的氮氧化物的化学计量反应当量的氨，并且通过与未经选择性催化分解的氨反应催化还原氮氧化物。

4. 发明授权

US07658898B2 Compositions and methods for treating exhaust gases 有权
公开(公告)号：US07658898B2
公开(公告)日：2010-02-09
申请号：US11888640
申请日：2007-08-01
申请人： Chris E. DiFrancesco , Kozo Iida
发明人： Chris E. DiFrancesco , Kozo Iida
IPC分类号： B01D53/56 , B01D53/58 , B01D53/94
CPC分类号： F01N3/2066 , B01D53/8628 , B01D53/9477 , B01D2251/2062 , B01D2255/1026 , B01D2255/20776 , B01D2255/9022 , B01J23/6527 , B01J23/8993 , B01J27/053 , B01J35/0006 , F01N13/009 , F01N2610/02 , Y02T10/24
摘要： The present invention provides compositions, systems, and methods for achieving high efficiencies of nitrogen oxide (NOx) removal from exhaust gases while minimizing ammonia slip and sulfur dioxide oxidation. In one embodiment, a method of removing nitrogen oxides from an exhaust gas comprises providing a first catalyst layer, adding an ammonia-containing compound to the exhaust gas upstream of the first catalyst layer in excess of the stoichiometric equivalent of the nitrogen oxides in the exhaust gas, flowing the exhaust gas through the first catalyst layer, selectively catalytically decomposing ammonia in excess of the stoichiometric reaction equivalent of the nitrogen oxides in the exhaust gas, and catalytically reducing the nitrogen oxides by reaction with ammonia not selectively catalytically decomposed.

5. 发明授权

US08703080B2 Method for removing mercury in exhaust gas and system therefor 有权
标题翻译：废气中汞的去除方法及其系统
公开(公告)号：US08703080B2
公开(公告)日：2014-04-22
申请号：US12459023
申请日：2009-06-25
申请人： Shintaro Honjo , Toru Takashina , Kozo Iida , Susumu Okino , Yasuhiro Takeuchi
发明人： Shintaro Honjo , Toru Takashina , Kozo Iida , Susumu Okino , Yasuhiro Takeuchi
IPC分类号： B01D47/00 , B01D53/46 , B01D53/56 , B01D53/86 , C01B17/00 , C01B17/74 , C01B17/48
CPC分类号： B01D53/501 , B01D53/8665 , B01D2257/602 , F23J15/006 , F23J2215/60 , F23J2219/40
摘要： The present invention provides a method for removing mercury in exhaust gas, in which mercury in exhaust gas discharged from combustion equipment is removed, characterized by including a mercury oxidation process in which mercury in the exhaust gas is converted to mercury chloride in the presence of a catalyst; a contact process in which the exhaust gas is brought into contact with an absorbing solution in a scrubber to absorb and remove mercury components from the exhaust gas; and a control process in which blowing of air or addition of an oxidizing agent into the scrubber is accomplished, and the amount of blown air or the added amount of oxidizing agent is regulated to control the oxidation-reduction potential of the absorbing agent, and a system for removing mercury in exhaust gas. According to the mercury removing method in accordance with the present invention, a phenomenon that mercury chloride is reduced into metallic mercury by SO2 etc. and the metallic mercury scatters in the exhaust gas can be prevented, and mercury in the exhaust gas can be decreased effectively.
摘要翻译：本发明提供了一种去除废气中排出的废气中的汞的方法，其中废气中排出的废气中的汞被除去，其特征在于包括一种汞氧化法，其中废气中的汞转化为氯化汞，催化剂; 接触方法，其中废气与洗涤器中的吸收溶液接触以从废气中吸收和去除汞组分; 以及控制方法，其中完成吹入空气或将氧化剂加入到洗涤器中，并且调节吹入空气量或氧化剂的添加量以控制吸收剂的氧化还原电位，并且废气中汞去除系统。根据本发明的水银除去方法，可以防止将二氧化氯还原成金属汞，并且可以防止金属汞在排气中飞散的现象，从而可以有效地降低废气中的汞。

6. 发明申请

US20080176742A1 Method For Producing Catalyst For Treating Exhaust Gas 审中-公开
标题翻译：生产废气处理催化剂的方法
公开(公告)号：US20080176742A1
公开(公告)日：2008-07-24
申请号：US11576041
申请日：2005-03-04
申请人： Katsumi Nochi , Masanao Yonemura , Kozo Iida , Yoshiaki Obayashi , Shigeru Nojima , Toshiyuki Onishi
发明人： Katsumi Nochi , Masanao Yonemura , Kozo Iida , Yoshiaki Obayashi , Shigeru Nojima , Toshiyuki Onishi
IPC分类号： B01J37/02 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/50 , B01J23/52 , B01J23/58 , B01J23/63 , B01J23/648 , B01J23/652 , B01J23/656 , B01J23/89 , B01J27/185
CPC分类号： B01J35/0013 , B01D53/864 , B01D53/8668 , B01D2257/708 , B01J21/04 , B01J23/38 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/462 , B01J23/464 , B01J23/468 , B01J23/48 , B01J23/50 , B01J23/52 , B01J23/58 , B01J23/63 , B01J23/6482 , B01J23/652 , B01J23/6562 , B01J23/89 , B01J37/0211 , B01J37/0213 , B01J37/0242 , B01J37/16
摘要： An object of the present invention is to provide a method for producing a catalyst for treating exhaust gas, enabling a smaller amount of a noble metal to be supported and reducing the production cost thereof. There is provided a method for producing a catalyst for treating an exhaust gas containing carbon monoxide and volatile organic compounds, wherein the method comprises: preparing, as a pH buffer solution, an aqueous metal salt solution in which at least one metal salt is dissolved; reductively-treating the aqueous metal salt solution while keeping the pH constant to prepare a metal colloid solution; and immersing a carrier in the metal colloid solution to support the metal on the carrier. The supported amount of metal may be 0.7 g/L or less per one of the metals.
摘要翻译：本发明的目的在于提供一种废气处理用催化剂的制造方法，能够减少贵金属的负载量，降低其制造成本。提供了一种用于处理含有一氧化碳和挥发性有机化合物的废气的催化剂的方法，其中所述方法包括：制备溶解有至少一种金属盐的金属盐水溶液作为pH缓冲溶液; 在保持pH恒定的同时还原性处理金属盐水溶液以制备金属胶体溶液; 并将载体浸渍在金属胶体溶液中以将金属支撑在载体上。每个金属的金属的负载量可以为0.7g / L以下。

7. 发明申请

US20070021299A1 Catalyst for reacting hydrocarbon with steam and process for producing hydrogen from hydrocarbon 审中-公开
标题翻译：用于使烃与蒸汽反应的催化剂和从烃生产氢气的方法
公开(公告)号：US20070021299A1
公开(公告)日：2007-01-25
申请号：US11525873
申请日：2006-09-25
申请人： Katsuomi Takehira , Tetsuya Shishido , Hiroyuki Morioka , Naoya Kobayashi , Tsutomu Katamoto , Tomoyuki Imai , Kozo Iida , Toshinobu Yasutake
发明人： Katsuomi Takehira , Tetsuya Shishido , Hiroyuki Morioka , Naoya Kobayashi , Tsutomu Katamoto , Tomoyuki Imai , Kozo Iida , Toshinobu Yasutake
IPC分类号： B01J23/00
CPC分类号： B01J23/755 , B01J23/007 , B01J23/78 , B01J35/0013 , B01J35/006 , B01J35/1014 , B01J35/1019 , B01J37/03 , C01B3/40 , C01B2203/0233 , C01B2203/1052 , C01B2203/1082 , C01B2203/1235 , Y02P20/52
摘要： A catalyst for reacting hydrocarbon with steam according to the present invention, has a specific surface area of 40 to 300 m2/g, and comprises: a porous composite oxide carrier containing magnesium and aluminum; and nickel metal in the form of fine particles carried on the porous composite oxide carrier, and having a magnesium content of 5 to 55% by weight, calculated as Mg, based on the weight of the catalyst, an aluminum content of 5 to 35% by weight, calculated as Al, based on the weight of the catalyst, a nickel content of 1.2 to 60% by weight, calculated as Ni, based on the weight of the catalyst, and a total amount of magnesium, aluminum and nickel of 50 to 85% by weight, calculated as a sum of Mg, Al and Ni, based on the weight of the catalyst, the fine nickel metal particles having an average particle diameter of not more than 10 nm.
摘要翻译：根据本发明的用于使烃与蒸汽反应的催化剂的比表面积为40至300m 2 / g，并且包括：含有镁和铝的多孔复合氧化物载体; 以及承载在多孔复合氧化物载体上的微粒形式的镍金属，镁含量为5〜55重量％，以催化剂重量为基准计，Mg为5〜35重量％，铝含量为5〜35重量％，以Al为基准，以催化剂的重量计，镍含量为1.2至60重量％，以Ni计，以催化剂的重量计，镁，铝和镍的总量为50 至85重量％，基于催化剂的重量计算为Mg，Al和Ni的总和，细镍金属颗粒的平均粒径不大于10nm。

8. 发明申请

US20060051263A1 Apparatus for treatment cos for gas produced by gasification and method for treating cos 有权
标题翻译：用于气化产生的气体处理cos的装置和用于处理cos的方法
公开(公告)号：US20060051263A1
公开(公告)日：2006-03-09
申请号：US10522604
申请日：2003-08-06
申请人： Masahiro Harada , Shintaro Honjo , Makoto Susaki , Kazuo Ishida , Hajime Nagano , Susumu Okino , Kozo Iida , Akira Johana
发明人： Masahiro Harada , Shintaro Honjo , Makoto Susaki , Kazuo Ishida , Hajime Nagano , Susumu Okino , Kozo Iida , Akira Johana
IPC分类号： B01J8/02
CPC分类号： B01J23/866 , B01D53/885 , C10K1/34
摘要： There is disclosed a COS treatment apparatus for a gasified gas, in which an O2 removal catalyst and a COS conversion catalyst located on the downstream side of a gasified gas flow with respect to the O2 removal catalyst are provided. Also, there is disclosed a COS treatment apparatus containing a TiO2 catalyst that carries Cr2O3 or NiO. Further, there is disclosed a COS treatment method including a first step in which O2 is removed by the reaction with H2S and CO, and a second step in which COS is converted to H2S.
摘要翻译：公开了一种用于气化气体的COS处理装置，其中位于气化气体的下游侧的O 2 H 2除去催化剂和COS转化催化剂相对于O 2 提供了除去催化剂。

9. 发明授权

US06395665B2 Methods for the regeneration of a denitration catalyst 有权
标题翻译：脱硝催化剂再生方法
公开(公告)号：US06395665B2
公开(公告)日：2002-05-28
申请号：US09263709
申请日：1999-03-05
申请人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi
发明人： Shigeru Nojima , Kozo Iida , Yoshiaki Obayashi
IPC分类号： B01J3864
CPC分类号： B01J38/60 , B01D53/8625 , B01D53/96 , B01J23/92 , B01J38/62 , B01J38/64 , B01J38/66 , B01J38/68 , Y02C20/30
摘要： This invention provides a method for the regeneration of a denitration catalyst which comprises cleaning a denitration catalyst having reduced denitration power with an aqueous alkaline solution to remove the substances deposited thereon, and subjecting the catalyst to an activation treatment with an aqueous acid solution; a method for the regeneration of a denitration catalyst which comprises cleaning a denitration catalyst having reduced denitration power with a cleaning fluid comprising an aqueous solution containing sulfuric acid or ammonia at a concentration of 0.05 to 20% by weight and maintained at a temperature of 10 to 90°C.; and a method for the regeneration of a denitration catalyst which comprises cleaning a denitration catalyst having reduced denitration power under the above-described conditions, and impregnating the denitration catalyst with a catalytically active component so as to support it on the catalyst.
摘要翻译：本发明提供了一种用于再生脱硝催化剂的方法，其包括用碱性水溶液清洗具有降低的脱硝功率的脱硝催化剂以除去其上沉积的物质，并用酸水溶液进行活化处理; 一种用于再生脱硝催化剂的方法，其包括用包含浓度为0.05至20重量％的硫酸或氨的水溶液的清洁流体清洗具有降低的脱硝功率的脱硝催化剂，并保持在10至 90°C。以及脱硝催化剂的再生方法，该方法包括在上述条件下清洗具有降低的脱硝功率的脱硝催化剂，并用催化活性组分浸渍脱硝催化剂以便将其支持在催化剂上。

10. 发明授权

US5869419A Nitrogen oxide removal catalyst 失效
标题翻译：氧化氮去除催化剂
公开(公告)号：US5869419A
公开(公告)日：1999-02-09
申请号：US871520
申请日：1997-06-09
申请人： Yoshiaki Obayashi , Kozo Iida , Shigeru Nojima , Atsushi Morii , Osamu Naito
发明人： Yoshiaki Obayashi , Kozo Iida , Shigeru Nojima , Atsushi Morii , Osamu Naito
IPC分类号： B01D53/86 , B01D53/94 , B01D53/96 , B01J23/30 , B01J37/02 , B01J38/00 , B01J23/00 , B01J8/00 , B01J23/16
CPC分类号： B01J38/00 , B01D53/8628 , B01D53/8631 , B01J23/30 , B01J37/0244
摘要： This invention effectively utilizes a solid type honeycomb-shaped NO.sub.x removal catalyst which has been used in a catalytic ammonia reduction process and hence reduced in NO.sub.x removal power, and thereby provides an inexpensive catalyst having NO.sub.x removal power equal to that of a fresh catalyst. The nitrogen oxide removal catalyst of this invention, which is useful in a process wherein ammonia is added to exhaust gas and nitrogen oxides present in the exhaust gas are catalytically reduced, has a two-layer structure composed of a lower layer comprising a spent solid type nitrogen oxide removal catalyst and an upper layer comprising a fresh TiO.sub.2 -WO.sub.3 -V.sub.2 O.sub.5 ternary or TiO.sub.2 -WO.sub.3 binary catalyst powder which has been applied to the lower layer so as to give a coating thickness of 100 to 250 .mu.m. Moreover, the catalyst power constituting the upper layer is a catalyst powder obtained by pulverizing a spent solid type nitrogen oxide removal catalyst.
摘要翻译：本发明有效地利用了催化氨还原方法中使用的固体型蜂窝状NOx去除催化剂，从而降低了NOx去除能力，从而提供了具有等于新鲜催化剂的NOx去除功率的便宜的催化剂。本发明的氮氧化物去除催化剂可用于将排放气体中存在氨和排出气体中存在的氮氧化物的方法进行催化还原的方法中，具有由下层构成的二层结构，该下层由废固体型氮氧化物去除催化剂和上层，其包含新的TiO 2 -WO 3-V 2 O 5三元或TiO 2 -WO 3二元催化剂粉末，其被施加到下层以使涂层厚度为100-250μm。此外，构成上层的催化剂功率是通过粉碎废固体型氮氧化物去除催化剂而获得的催化剂粉末。

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