
基本信息:
- 专利标题: PROCESS AND APPARATUS FOR THE POLYMERISATION OF OLEFINS
- 专利标题(中):烯烃聚合的方法和装置
- 申请号:US13988794 申请日:2011-12-14
- 公开(公告)号:US20130253148A1 公开(公告)日:2013-09-26
- 发明人: Andrew David Bell , Jean-Louis Chamayou , Kevin Peter Ramsay
- 申请人: Andrew David Bell , Jean-Louis Chamayou , Kevin Peter Ramsay
- 申请人地址: GB Hampshire
- 专利权人: Ineos Commercial Services UK Limited
- 当前专利权人: Ineos Commercial Services UK Limited
- 当前专利权人地址: GB Hampshire
- 优先权: EP10195898.1 20101220
- 国际申请: PCT/EP2011/072701 WO 20111214
- 主分类号: C08F2/34
- IPC分类号: C08F2/34
摘要:
The present invention relates to a process for the gas-phase polymerisation of olefins in a fluidised bed reactor, which process comprises: a) passing a fluidising gas comprising one or more olefin monomers through a fluidised bed of polymer particles in the presence of a polymerisation catalyst, b) withdrawing a first gaseous stream comprising solid particles from the top of the reactor, c) passing the first gaseous stream to a gas/solids separator, separating solid particles therefrom, and forming a second gaseous stream comprising residual solid particles, d) passing at least a portion of the second gaseous stream to one or more heat exchangers to remove the heat of reaction, and e) recycling at least a portion of the cooled stream from step (d) as the fluidising gas in step (a), characterised in that the rate of fouling of the one or more heat exchangers is such that i) the increase in pressure drop across the heat exchangers is equivalent to less than 5% per year, and/or ii) the decrease in heat transfer of the heat exchangers is equivalent to less than 5% per year.
摘要(中):
本发明涉及在流化床反应器中烯烃气相聚合的方法,该方法包括:a)在聚合反应存在下使包含一种或多种烯烃单体的流化气体通过聚合物颗粒的流化床 催化剂,b)从反应器顶部排出包含固体颗粒的第一气流,c)将第一气流送至气/固分离器,从其中分离固体颗粒,形成包含残留固体颗粒的第二气流 )将至少一部分第二气流引导至一个或多个热交换器以除去反应热,以及e)将步骤(d)中的冷却流的至少一部分循环为步骤(a)中的流化气体, 其特征在于,所述一个或多个热交换器的结垢速率使得i)所述热交换器上的压降的增加等于每年小于5%,和/或ii)所述d 热交换器的热传递相当于每年少于5%。
公开/授权文献:
- US09394382B2 Process and apparatus for the polymerisation of olefins 公开/授权日:2016-07-19
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F2/00 | 聚合工艺过程 |
--------C08F2/34 | .在气态中聚合 |