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序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
141	Production method of the oxidation catalyst and the oxidation reaction product	JP2013028790	2013-02-18	JP5552550B1	2014-07-16	穣人見; 沙知斉藤; 健吾荒川
【課題】高い選択性及び触媒回転数を可能とするｓｐ ³ Ｃ−Ｈ結合の酸化方法を提供する。【解決手段】本発明にかかるｓｐ ³ Ｃ−Ｈ結合の酸化方法は、下記一般式（１）で表される金属錯体触媒を酸化触媒としてｓｐ ³ Ｃ−Ｈ結合を酸化することを特徴とする。【化１】（式中、Ｍは鉄、マンガン又はコバルトであり、Ｌは任意の配位子であり、Ｘは対イオンであり、ｎは０、１又は２である。）【選択図】なし
142	Production method and fullerene derivatives of the fullerene derivative, proton conductor, and an electrochemical device	JP2000391777	2000-12-25	JP4848585B2	2011-12-28	ベルトルド・ヌーベル

143	Method for producing a poly-halogenated diamantane and derivatives thereof	JP2006528647	2005-06-20	JP4611984B2	2011-01-12	孝之前原; 真男山口

144	Penta cyclo tetra decane derivative and a method of manufacturing the same	JP3033999	1999-02-08	JP4466796B2	2010-05-26	武明光藤; 健司和田; 輝幸近藤; 俊彰鈴木; 一男飯田

145	内包フラーレン誘導体、プロトン伝導体、及び、燃料電池	JP2005515567	2004-10-26	JPWO2005049538A1	2007-06-07	泰彦笠間; 研次表; 工藤　昇; 昇工藤
固体高分子型燃料電池において、燃料電極と空気電極間でプロトンを伝導する電解質膜の材料としては、従来、C60などの空のフラーレンをプロトン解離性基で化学修飾した材料が使用されていたが、プロトン伝導度が低いため電池の内部抵抗が大きくなり、大電流を取り出すと起電力が低くなるという問題があった。電解質膜として、電気陰性度が3以上の原子を内包したフラーレンをプロトン解離性基で化学修飾した材料、あるいは、電気陰性度が1以下の原子を内包したフラーレンからなる材料を使用することにした。空のフラーレンをプロトン解離性基で化学修飾した材料にくらべ、プロトン伝導度の向上、燃料電池の内部抵抗低減に効果がある。
146	The photoresist composition comprising a diamond-like material derivative	JP2006534053	2004-09-29	JP2007507593A	2007-03-29	カールソン、ロバート、エム．; ダール、ジェレミー、イー．; リウ、シェンガオ
新規なポジティブ・ワーキング・フォトレジスト組成物が開示されている。該レジストの原樹脂のモノマーは、ポリマンタン系においてアダマンタンよりも高級なダイヤモンド状核含有側基、例えば、ジアマンタン、トリアマンタン、テトラマンタン、ペンタマンタン、ヘキサマンタン等を含有している。該ダイヤモンド状核含有側基は、水酸基のような親水性増進置換基を有することが出来、ラクトン基を含有することが出来る。本組成物の利点には、改良された解像度、感度、及び基体への接着性が含まれる。
147	Hetero atom-containing diamondoids transistor	JP2004523163	2003-07-17	JP2005533128A	2005-11-04	カールソン、ロバート、エム．; ダール、ジェレミー、イー．; リウ、ションガオ
新規なヘテロダイヤモンドイドが開示されている。これらのヘテロダイヤモンドイドは、ダイヤモンド格子構造中にヘテロ原子を含むダイヤモンドイドである。ヘテロ原子はｎ−型ヘテロダイヤモンドイドが形成されるように電子供与性とするか、又はｐ−型ヘテロダイヤモンドイドが形成されるように電子吸引性とすることができる。バルク材料は、これらのヘテロダイヤモンドイドから製造することができ、関係技術には、化学蒸着、重合体化、及び結晶凝集が含まれる。ｐ−型及びｎ−型ヘテロダイヤモンドイド系材料から接合を作ることができ、それらの接合を用いたマイクロエレクトロニックデバイスを作ることができる。それらデバイスには、ダイオード、バイポーラ接合トランジスタ、及び電界効果トランジスタが含まれる。
148	Polyacene compound and organic semiconductor thin film	JP2005051091	2005-02-25	JP2005272460A	2005-10-06	NARITA YOSHINORI; YAKEYAMA MASATOSHI; OSADA KAZUTO
PROBLEM TO BE SOLVED: To provide an organic semiconductor material exhibiting high mobility and excellent in oxidation resistance, to provide an organic semiconductor thin film having the high mobility, and to provide an organic semiconductor device excellent in electronic characteristics. SOLUTION: A transistor structure is obtained by forming a thin film of a pentacene compound in which halogen elements are introduced into the 6 position and the 13 position on a silicon substrate on which a gold electrode pattern is formed as a source/drain electrode. The polyacene compound exhibits the high mobility and is excellent in the oxidation resistance. Further, the organic semiconductor thin film has the high mobility. Furthermore, the organic semiconductor device has the excellent electronic characteristics. COPYRIGHT: (C)2006,JPO&NCIPI
149	ANTI-ALLERGIC AGENT CONTAINING SOYA SAPOGENOL B AS ACTIVE INGREDIENT	JP2000318735	2000-10-19	JP2002128663A	2002-05-09	YAMAGUCHI HITOMI; OGAWA YOSHIHIRO; KANAMORI TOMOKO; YOSHIMURA MINEKA; SAITO MINORU; UCHIDA RIICHIRO
PROBLEM TO BE SOLVED: To obtain a new anti-allergic agent, and a medicine, drink, food or cosmetic containing the same. SOLUTION: This anti-allergic medicine, drink, food or cosmetic, is characterized by containing soya sapogenol B (formula 1) or its derivative as an active ingredient, and the medicine, drink, food or the cosmetic is characterized by containing the anti-allergic agent.
150	OXIDATION OF POLYCYCLIC HYDROCARBON	JP12947297	1997-05-20	JPH10316601A	1998-12-02	NAKANO TATSUYA; ISHII YASUTAKA; HIRAI NARIHISA
PROBLEM TO BE SOLVED: To carry out oxidation reaction effectively at high conversion rate on an industrial scale while suppressing the adhesion of a sublimable polycyclic hydrocarbon on a reactor and on the internal walls of tubes by using a specific mixed solvent as a reaction solvent on the oxidation of the polycyclic hydrocarbon. SOLUTION: A sublimable polycyclic hydrocarbon (e.g. a bridged cyclic hydrocarbon having a methylidyne group, especially an adamantane) is oxidized in the presence of an oxidizing catalyst consisting of an imide compound expressed by the formula [R<1> and R<2> are each H, a halogen, an alkyl, etc., and they may be bonded to each other to form a double bond or a ring; X is oxygen or hydroxyl; (n)=1-3] in a mixed solvent consisting of (A) a non- sublimable aromatic compound (e.g. a benzene derivative) and (B) at least one compound (e.g. an organic compound such as a 1-4C aliphatic hydrocarbon) selected from acidic compounds and non-aromatic nitrile compounds [the component A/the component B=(25/75) to (95/5) by weight] under contact with oxygen to produce a polycyclic hydrocarbon which has a hydroxyl or oxo group.
151	OXIDIZING CATALYST SYSTEM AND OXIDIZING METHOD USING THE SAME	JP2363197	1997-02-06	JPH09327626A	1997-12-22	ISHII YASUTAKA; NAKANO TATSUYA
PROBLEM TO BE SOLVED: To obtain an oxide corresponding to a substrate at a high conversion ratio and a high selectivity by oxidizing the substrate with molecular oxygen under mild conditions. SOLUTION: Under the existence of an oxidizing catalyst consisting of an imide compound (N-hydroxyphthalimide and the like) represented by a formula (wherein R<1> and R<2> represent substituents such as hydrogen atom, halogen atom and the like, and R<1> and R<2> may be bonded with each other to form a double bond or an aromatic or nonaromatic 5-12 membered ring. X represents O or HO and n=1 to 3) and an auxiliary catalyst (excluding phosphovanado molybdic acid) containing elements selected from the group of 2A group in the periodic table, transition metals (3A group - 7A group, 8 group and 2B group in the periodic table) and 3B group in the periodic table, a substrate (cycloalkanes, polycyclic hydrocarbons and aromatic compounds having methyl group or methylene group adjacent aromatic ring) is oxidized to obtain oxides (ketones, alcohols, carboxylic acid and the like).
152	FULLEREN DERIVATIVE AS RADICAL TRAPPING AGENT	JP7732796	1996-03-29	JPH09136964A	1997-05-27	CHIANG LONG Y

153	ANION CHELATING AGENT	JP1124795	1995-01-27	JPH08199152A	1996-08-06	OZAWA OSAMU; YAMASHITA KOTARO; WATANABE YOSHIO
PURPOSE: To obtain an anion chelating agent useful as a transistor having anion selective electric field effect, suitable for catching an anion in an organic solvent, capable of forming a complex with the anion, comprising a specific repeating unit. CONSTITUTION: This chelating agent is a compound of formula I (R1 , R2 and R3 are each an alkyl) in which each OH in each repeating unit is OH bonded to a saturated alkyl. For example, an anion chelating agent is a compound of formula II. The compound of formula I is obtained by reducing the benzene ring of a cyclic condensed polymer from a 3,4,5-alkyl-substituted phenol and formaldehyde into a cyclohexyl ring by a catalytic hydrogenating method.
154	TETRACYCL(7.3.1.02.7.17.11)TETRADECANE DERIVATIVE	JP25785993	1993-09-09	JPH0782186A	1995-03-28	NAEMURA KOICHIRO; TOBE YOSHITO
PURPOSE:To provide a novel compound excellent in water resistance and hydrolysis resistance and useful as a physio1ogically active substance, afunctional substance or an intermediate for the substances. CONSTITUTION:A compound of formula I (R<1>, R<2>, R<3> are-COOH,-COOCH3,- COOC2H5,-CH2OH,-COCH3, H, 1-5C alkyl, etc.; R<4> is H,-OH, 1-5C alkyl, etc.,), e.g. The compound of formula I is obtained by subjecting a compound of formula II to a Koch-Haaf reaction for introducing the carboxyl group and subsequently esterifying the produced carboxylic acid. The compound of formula I is a compound in which the various substituent have been introduced to the tetracyclo[7.3.1.0<2>,<7>.1<7>,<11>] tetradecane skeleton that is more bulky than adamantane and extremely excellent in hydrophobicity. The skeleton has high selectivity that the substituents have been introduced to the 1,9,11 positions but not introduced to the other positions in all cases except a case in which a hyclroxyl group has been introduced to the 2 position.
155	PRODUCTION OF CONDENSED RING-CONTAINING COMPOUND	JP17539793	1993-07-15	JPH0725797A	1995-01-27	MIYAKE MASA; KIKUCHI HIROBUMI; MATSUMOTO MITSUO
PURPOSE:To obtain the compound useful as a raw material for polymeric compounds by reacting a butenediol diacetate compound with cyclopentadiene compound, distilling the reaction product, and further subjecting the distillation product to an esterification reaction and a hydrogenation reaction. CONSTITUTION:A compound of formula I (R<1>, R<2> are lower aliphatic groups) and/or a compound of formula II are reacted with cyclopentadiene or dicyclopentadiene in a solvent (e.g. methanol) at 150-260 deg.C, and the reaction mixture is subjected to a distillation separation. The residues are subjected to an ester exchange reaction with a lower aliphatic alcohol in the presence of an acid or alkali catalyst, and subsequently hydrogenated with hydrogen gas in the presence of a catalyst in a lower aliphatic alcohol as a solvent. The product is filtered and then distilled or sublimed to obtain the compound of formula III (n is 0, 1, 2). The compound of formula III is useful as a raw material for polymeric compounds used as various building materials and functional materials.
156		JP18878785	1985-08-28	JPH0680013B2	1994-10-12	KONO HIROYUKI; ODAJIMA TOSHIO

157		JP28866292	1992-10-27	JPH05294864A	1993-11-09	RON YON CHIYAN; RABINDORA BAROOANTO UPASANI; JIYON UIRAADO SUUIRUTSUEUSUKI

158		JP51069889	1989-10-02	JPH04501409A	1992-03-12

159	SCOPADULCIC ACID B DERIVATIVE	JP28483089	1989-11-02	JPH03148230A	1991-06-25	MORITA NAOMASA; TAKEGUCHI NORIAKI; HAYASHI TOSHIMITSU; ASANO SHINJI
NEW MATERIAL:A compound expressed by the formula (X is OH, =O or OCOR; Y is CH2OR, COOH or COOR; Z is OH, OCOR, OCOC6H5 or =O; R is 1-3C alkyl, except when X is =O and Y is COOH and Z is OCOC6H5) and base addition salt thereof. EXAMPLE:6beta-Benzoyl-9(12)a,9(12)b-dihomo-12-methyl-podocarpane-13bet a-al18-oic acid. USE:A remedy for gastric ulcer, duodenal ulcer, gastritis, esosphagitis, etc. PREPARATION:Scopadurcic acid B (a compound expressed by the formula wherein X is O and Y is COOH and Z is OCOC6H5) obtained from the crude drug Typycha Kuratu of Paraguay growth is reduced by NaBH4 to provide the compound expressed by the formula (X is OH) or reduced by LiAlH4 to provide the compound expressed by the formula (X and Z are OH and Y is CH2OH).
160		JP9519483	1983-05-30	JPS6345650B2	1988-09-12	NAKAMURA KOICHI; YAMAMURO AKIRA; MASUDA SHINICHI; TAKAISHI NAOTAKE; TO HISAO

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