专利检索_..用双烯合成专利检索_..用双烯合成专利检索查询

序号	专利名	申请号	申请日	公开（公告）号	公开（公告）日	发明人
21	HIGHER ALIPHATIC TRIOL, PRODUCTION THEREOF, UNSATURATED CARBOXYLIC ESTERS THEREOF	JP8339095	1995-03-15	JPH07304701A	1995-11-21	KIKAWA HITOSHI; YAMAGISHI HIROSHI; SUZUKI NORIKO; ASAO YOSHIICHI
PURPOSE:To obtain a novel higher aliphatic triol which is useful as a starting substance for polyesters, polyurethanes, flexible crosslinking agents and other polymers. CONSTITUTION:A higher aliphatic triol having a chemical structure of an aliphatic hydrocarbon chain of at least 42 carbon atoms bearing three hydroxyl groups. This triol is obtained by oligomerizing a higher unsaturated fatty acid having at least 14 carbon atoms or a lower alkyl ester thereof, separating and recovering the trimers from the reaction mixture then reducing the trimers to convert the carboxyl or ester groups into -CH2OH. Otherwise, it is also obtained by oligomerizing a higher unsaturated aliphatic alcohol having at least 14 carbon atoms and separating and recovering the trimers. Further, the ester of the formula (R is an aliphatic hydrocarbon of at least 42 carbon atoms; R<4>-R<6> are H, residue of unsaturated carboxylic acid, respectively)is also novel.
22	PRODUCTION OF TETRAHYDROBENZYL ALCOHOL OR VINYLYSLOHEXENE	JP32821392	1992-12-08	JPH06172238A	1994-06-21	TANAKA YASUTAKA; SHIMADA GIICHI
PURPOSE:To obtain a method for producing tetrahydrobenzyl alcohol or vinylcyclohexene with minimized amount of by-produced butadiene polymer to a loss of a raw material. CONSTITUTION:This method for producing tetrahydrobenzyl alcohol or vinylcyclohexane comprises effecting the reaction in the coexistence of a metallic alkoxide in an amount of <1.0% based on the starting raw material under >=5kg/cm<2> pressure in synthesizing the tetrahydrobenzyl alcohol by the Diels- Alder reaction of butadiene with allyl alcohol or the vinylcyclohexene by the Diels-Alder reaction of the butadiene.
23	PRODUCTION OF DIENIC COMPOUND	JP22582992	1992-08-25	JPH0665111A	1994-03-08	ARAI ISAMU; SOEDA YUKIO
PURPOSE:To produce an alkyl-substituted dienic compound in good yield by reacting an olefin halide with an alkali metal in the presence of a tetrahydrofuran and subsequently reacting the reaction product with a fatty acid ester and water. CONSTITUTION:An halogenated olefin of formula: R<1>H=CX<2> (R<1>, R<2> are 1-5C alkyl; X is Cl, Br, I) is reacted with an alkali metal in the presence of tetrahydrofuran and/or hexamethylene oxide to produce an alkali metal olefin of formula: R<1>CH=CMR<2> (M is alkali metal). Two molecules of the compound is reacted with a fatty acid ester of formula I (R<3> is 1-5C alkyl; R<4> is alkyl) and subsequently with water to produce a chain-like dienic compound of formula II. The compound of formula II is subjected to a dehydrative ring-closing reaction to produce a cyclic dienic compound of formula III. Thereby the reaction can be advanced in good yield without employing diethyl ether which is low in ignition point, liable to form a peroxide in air, and apt to explode.
24	FLUORINE-SUBSTITUTED VICINAL GLYCOL, ITS PRODUCTION AND ITS USE	JP3866693	1993-02-26	JPH069463A	1994-01-18	YURUGEN KURUPE; HAINTSU SHIYUTORUTSU

25	CALCIUM-SENSING RECEPTOR-ACTIVE COMPOUNDS	PCT/EP2011070574	2011-11-21	WO2012069420A2	2012-05-31	VEDSOE PER; BLAEHR LARS KRISTIAN ALBERT
Compounds of general formula (I), their use as calcium receptor-active compounds for the prophylaxis, treatment or amelioration of physiological disorders or diseases associated with disturbances of CaSR activity, such as hyperparathyroidism, pharmaceutical compositions comprising said compounds, and methods of treating diseases with said compounds.
26	２，７－オクタジエン－１－オールの製造方法	PCT/JP2014/058663	2014-03-26	WO2014157402A1	2014-10-02	吉川　達也; 辻　智啓
高価なパラジウム触媒を高効率的に回収し、パラジウム１原子あたりの反応速度が向上する、簡便且つ工業的に有利な２，７－オクタジエン－１－オールの製造方法を提供する。具体的には、分子内に２つ以上のスルホナト基を有する水溶性トリアリールホスフィンおよびパラジウム化合物からなるパラジウム触媒、第３級アミンおよび二酸化炭素の存在下においてブタジエンと水をテロメリ化反応させることによる２，７－オクタジエン－１－オールの製造方法であって、テロメリ化反応によって得られたテロメリ化反応液を、２５℃における誘電率が２～１８の有機溶媒と混合した後、二酸化炭素の存在下で相分離させ、有機相から２，７－オクタジエン－１－オールを得、一方で、パラジウム触媒を含む水相を回収する工程を含む、２，７－オクタジエン－１－オールの製造方法を提供する。該製造方法によれば、２，７－オクタジエン－１－オールへの選択性が向上する。
27	METHOD FOR PRODUCING ALCOHOL SURFACTANTS AND ALCOHOL ETHER SURFACTANTS, THE PRODUCTS OBTAINED AND THEIR USE	PCT/EP2000/002416	2000-03-17	WO00056683A1	2000-09-28
The invention relates to a method for producing alcohol surfactants and alcohol ether surfactants which are inter alia suitable as surfactants or for producing surfactants. According to the inventive method, olefinic mixtures with a defined minimum content of linear hexene mixtures with a prevailing amount of branched dodecenes are produced which are converted to alcohol surfactants and are then optionally alkoxylated. The alcohol surfactant mixture obtained by the inventive method is characterized by a branching degree of 2.0 to 3.0 and has specifically advantageous properties in terms of its ecotoxicity and biodegradability. The invention further relates to the use of the alcohol surfactants and alcohol ether surfactants as surfactants by glycosidation or polyglycosidation, sulfation or phosphatization.
28	2,7−オクタジエン−1−オールの製造方法	JP2015508621	2014-03-26	JP6225170B2	2017-11-01	吉川達也; 辻智啓

29	FLUORINE-CONTAINING CYCLIC COMPOUND	JP2001059172	2001-03-02	JP2002255875A	2002-09-11	MIYAZAWA SATORU; OTANI MITSUTAKA; TSUTSUMI KENTARO; MAEDA KAZUHIKO
PROBLEM TO BE SOLVED: To obtain a new fluorine-containing cyclic compound useful as a raw material for a polymer, a functional material, a medicine, an agrochemical, etc. SOLUTION: This fluorine-containing cyclic compound is represented by general formula (1) (R<1> and R<2> are each independently a hydrogen atom or a monofunctional organic group; n is an integer of 0-5).
30	NOVEL ALCOHOL, (METH)ACRYLATE THEREOF, RESIN THEREOF, AND THEIR PRODUCTION METHOD	JP32283499	1999-11-12	JP2001139638A	2001-05-22	KAMON YOSHIHIRO; SONOBE HIROSHI
PROBLEM TO BE SOLVED: To provide a resin having a low moisture absorption and a good heat resistance, a (meth)acrylate used as a raw material monomer for the resin, a raw material alcohol for the (meth)acrylate, and efficient production methods for them. SOLUTION: 3-Hydroxymethyltetracyclo[4.4.0.12,5.17,10] dodecanes represented by formula I (wherein R1 is H or methuyl), (meth) acryloyloxymethyltetracyclo[4.4.0.12,5.17,10] dodecanes represented by formula II (wherein R1 and R2 are each H or methyl), and a resin prepared by (co) polymerizing a compound represented by formula II are provided.
31	METHOD FOR PRODUCING ALKADIENOL	JP31483699	1999-11-05	JP2001131103A	2001-05-15	MORI TOMOYUKI; KAMEO HIROSHI; ISOTANI SHINJI
PROBLEM TO BE SOLVED: To recycle a catalyst without deactivation in producing octadienol from butadiene and water in the presence of a catalyst containing palladium and an organophosphorus compound. SOLUTION: In recovering ocatadienol formed by distilling a reaction product solution and recycling a distillation residue containing the catalyst to a reactor, the distillation residue is subjected to steam distillation, a by-product is partially distilled, the distillation residue of steam distillation is extracted with an aqueous solution of an alkali, an organic acid as a by-product is removed and the resultant substance is recycled to the reactor.
32	PRODUCTION OF UNSATURATED ALCOHOL	JP15789195	1995-06-23	JPH0873389A	1996-03-19	SATO KEIICHI; SETO YOKO; NAKAJIMA IWAO
PURPOSE: To obtain an unsaturated alcohol which is a hydrated even number oligomer of a conjugated alkadiene useful as a raw material for cosmetics, etc., in high yield and selectivity by reacting the alkadiene with water in the presence of carbon dioxide using a pd compound and a specific phosphorus compound as catalysts. CONSTITUTION: This method for producing (E) an unsaturated alcohol having a skeleton obtained by polymerization of a conjugated alkadiene (e.g. 6- vinyl-2,8,13-tetradecatrien-1-ol) is to react (C) a conjugated alkadiene with (D) water in the presence of (B) carbon dioxide using (A) a pd compound and a phosphorus compound having one or more trivalent phosphorus-oxygen single bonds [e.g. a compound of formula I [A<1> is a (substituted)aryl or a (substituted) alkyl; A<2> and A<3> are each a (substituted)arylene; Q is O, S, CO, etc.; (x) and (y) are each 0 or1] or a compound of formula II[A<4> is A<1> ; A<5> and A<6> are each a (substituted)aryl] as catalysts.
33	PRODUCTION OF CONDENSED RING-CONTAINING COMPOUND	JP17539793	1993-07-15	JPH0725797A	1995-01-27	MIYAKE MASA; KIKUCHI HIROBUMI; MATSUMOTO MITSUO
PURPOSE:To obtain the compound useful as a raw material for polymeric compounds by reacting a butenediol diacetate compound with cyclopentadiene compound, distilling the reaction product, and further subjecting the distillation product to an esterification reaction and a hydrogenation reaction. CONSTITUTION:A compound of formula I (R<1>, R<2> are lower aliphatic groups) and/or a compound of formula II are reacted with cyclopentadiene or dicyclopentadiene in a solvent (e.g. methanol) at 150-260 deg.C, and the reaction mixture is subjected to a distillation separation. The residues are subjected to an ester exchange reaction with a lower aliphatic alcohol in the presence of an acid or alkali catalyst, and subsequently hydrogenated with hydrogen gas in the presence of a catalyst in a lower aliphatic alcohol as a solvent. The product is filtered and then distilled or sublimed to obtain the compound of formula III (n is 0, 1, 2). The compound of formula III is useful as a raw material for polymeric compounds used as various building materials and functional materials.
34	METHOD OF CYCLOOLIGOMERATING 3-HYDROXY-(1)-ALYKYNE	JP3064793	1993-02-19	JPH069459A	1994-01-18	FURIIDORIHIIBUIRUHERUMU KIYUTS; BUORUFUGANKU SHIYUREEDAA; HAINTSUUBUERUNAA FUOOGESU

35		JP12345178	1978-10-06	JPS625134B2	1987-02-03	IKAWA TSUNEO; MOROOKA YOSHIHIKO; SUZUKI HIROYA; MURATA ATSUO; TSUCHA SHUJI

36		JP32821392	1992-12-08	JP3342518B2	2002-11-11

37	PRODUCTION OF ALKADIENE TELOMER	JP16367599	1999-06-10	JP2000355561A	2000-12-26	MORI TOMOYUKI; KAMEO HIROSHI; ISOTANI SHINJI
PROBLEM TO BE SOLVED: To provide a method for producing the telomer from an alkadiene in the presence of a catalyst composed of palladium and an organophosphorus compound, which is recycled while avoiding its deactivation and loss. SOLUTION: This method supplies the reaction effluent liquid from the reaction step to the distillation tower 3, where it is distilled with heat of hot water also supplied to the distillation tower 3 as the heat source, the reaction solvent being distilled off from the tower top while the mixture of oil and water phases being discharged from the tower bottom. The mixture is separated into the oil and water phases, the water phase being heated and supplied to the distillation tower 6 as the heat source, while the oil phase being distilled under a vacuum to distill off the target telomer from the top and the residue containing the high-boiling point by-product and catalyst being discharged from the bottom. The catalyst is recycled back to the reaction step in such a way to keep high- boiling point by-product content in the oil phase, discharged from the oil/water separation step, at 10 wt.% or more.
38		JP9370992	1992-03-18	JP2885354B2	1999-04-19	MATSUMOTO MITSUO; KIKUCHI HIROBUMI

39		JP8339095	1995-03-15	JP2847210B2	1999-01-13	KIKAWA HITOSHI; YAMAGISHI HIROSHI; SUZUKI NORIKO; ASAO YOSHIICHI

40	PRODUCTION OF ALKADIENOLS	JP33700896	1996-12-17	JPH09227426A	1997-09-02	MORI TOMOYUKI; KAMEO HIROSHI; ISOTANI SHINJI
PROBLEM TO BE SOLVED: To industrially and advantageously obtain alkadienols without losing a phosphine compound by subjecting a changed material of phosphine produced with reaction to decomposition treatment to regenerate phosphines and recycling the phosphines to a reaction system. SOLUTION: When a conjugated alkadiene is reacted with water in the presence of a catalyst comprising (A) a palladium compound and (B) a phosphine compound and carbon dioxide, (C) at least a part of a changed material of phosphine compound in a reaction product liquid obtained by reaction is subjected to decomposition treatment in the presence of the component A to regenerate the component B and the regenerated component B is recycled to the reaction system. Furthermore, the component C is subjected to decomposition treatment by heating, hydrogenation or decomposition treatment by using a basic compound, and the component C is preferably a phosphonium salt of formula I or formula II [X is an alkyl; Y is H, an alkyl, an alkoxyl, etc.; (n) is 0-3; R1 to R3 are each a (substituted)1-14C hydrocarbon; (z) is OH, hydroxycarboxy, etc.].

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