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    • 1. 发明申请
    • SUPERCRITICAL HYDROCARBON CONVERSION PROCESS
    • 超临界碳氢转化过程
    • WO2005074440A2
    • 2005-08-18
    • PCT/US2004/037645
    • 2004-11-10
    • KELLOGG BROWN & ROOT, INC.McCALL, Thomas, F.RAMAMURTHY, PrithamSHAH, Kiran, V.SILVERMAN, Michael, A.VAN SICKELS, Martin, J.
    • McCALL, Thomas, F.RAMAMURTHY, PrithamSHAH, Kiran, V.SILVERMAN, Michael, A.VAN SICKELS, Martin, J.
    • C01G11/02C10G9/28C10G9/32C10G69/06
    • C10G9/28C10G9/32C10G69/06
    • Supercritical conversion of hydrocarbons (108,208) boiling above 538°C (1000°F) with a solvating hydrocarbon (106,206) at a weight ratio of solvating hydrocarbon to high-boiling hydrocarbons of at least 2:1 and at conditions above the critical temperature and pressure of the high-boiling hydrocarbons-solvent mixture, in the presence of hot fluidized solids (136,236). The hydrocarbons (108,208) are supplied to a reaction zone (114,214) at a temperature below that of the hot solids (136,236) supplied thereto, whereby the resulting hydrocarbons-solids suspension has a thermal equilibrium temperature corresponding to the reaction temperature. The conversion has high rates of sulfur, nitrogen and metals removal, nearly complete conversion to lower molecular weight products, high naphtha and distillate selectivity, and low coke formation. The supercritical conversion can replace crude distillation, vacuum distillation, solvent deasphalting, coking, hydrocracking, hydrotreating, and/or fluid catalytic cracking, and/or used in parallel with such unit operations for debottlenecking or increasing capacity.
    • 超临界转化沸点高于538°C(1000°F)的烃(108°C)与溶剂化烃(106,206)以溶剂化烃与高沸点烃的重量比至少为2:1和高于临界温度的条件,以及 在热流化固体存在下,高沸点烃 - 溶剂混合物的压力(136,236)。 在低于供给的热固体(136,236)的温度下,将烃(108,208)供应到反应区(114,214),由此得到的烃 - 固体悬浮液具有对应于反应温度的热平衡温度。 转化率高,硫,氮和金属去除率高,几乎完全转化为较低分子量产物,高石脑油和馏出物选择性,低焦炭形成。 超临界转化可以替代原油蒸馏,真空蒸馏,溶剂脱沥青,焦化,加氢裂化,加氢处理和/或流化催化裂化,和/或与这种单元操作并行地用于消除瓶颈或增加容量。
    • 4. 发明申请
    • SUPERCRITICAL HYDROCARBON CONVERSION PROCESS
    • 超临界油气转化工艺
    • WO2005074440A3
    • 2005-12-29
    • PCT/US2004037645
    • 2004-11-10
    • KELLOGG BROWN & ROOT INCMCCALL THOMAS FRAMAMURTHY PRITHAMSHAH KIRAN VSILVERMAN MICHAEL AVAN SICKELS MARTIN J
    • MCCALL THOMAS FRAMAMURTHY PRITHAMSHAH KIRAN VSILVERMAN MICHAEL AVAN SICKELS MARTIN J
    • C01G11/02C10G9/28C10G9/32C10G69/06
    • C10G9/28C10G9/32C10G69/06
    • Supercritical conversion of hydrocarbons (108,208) boiling above 538°C (1000°F) with a solvating hydrocarbon (106,206) at a weight ratio of solvating hydrocarbon to high-boiling hydrocarbons of at least 2:1 and at conditions above the critical temperature and pressure of the high-boiling hydrocarbons-solvent mixture, in the presence of hot fluidized solids (136,236). The hydrocarbons (108,208) are supplied to a reaction zone (114,214) at a temperature below that of the hot solids (136,236) supplied thereto, whereby the resulting hydrocarbons-solids suspension has a thermal equilibrium temperature corresponding to the reaction temperature. The conversion has high rates of sulfur, nitrogen and metals removal, nearly complete conversion to lower molecular weight products, high naphtha and distillate selectivity, and low coke formation. The supercritical conversion can replace crude distillation, vacuum distillation, solvent deasphalting, coking, hydrocracking, hydrotreating, and/or fluid catalytic cracking, and/or used in parallel with such unit operations for debottlenecking or increasing capacity.
    • 在溶剂化烃与高沸点烃的重量比为至少2:1的条件下和在高于临界温度的条件下,用溶剂化烃(106,206)超临界转化沸点高于538℃(1000°F)的烃(108,208)和 高沸点烃 - 溶剂混合物在热流化固体(136,236)存在下的压力。 在低于供给其中的热固体(136,236)的温度下将烃(108,208)供应到反应区(114,214),由此所得到的烃 - 固体悬浮液具有对应于反应温度的热平衡温度。 该转化具有高硫,氮和金属去除率,几乎完全转化为较低分子量产物,高石脑油和馏分选择性以及低焦炭形成。 超临界转化可以取代原油蒸馏,减压蒸馏,溶剂脱沥青,焦化,加氢裂化,加氢处理和/或流化催化裂化,和/或与用于消除瓶颈或增加容量的此类单元操作并行使用。
    • 5. 发明申请
    • VERFAHREN ZUR HOCHTEMPERATUR-KURZZEIT-DESTILLATION VON RÜCKSTANDSÖL
    • PROCESS渣油蒸馏的高温短时间
    • WO2004056942A1
    • 2004-07-08
    • PCT/EP2003/007377
    • 2003-07-09
    • LURGI AGWEISS, Hans-JürgenZENTNER, UdoHEURICH, Helmut
    • WEISS, Hans-JürgenZENTNER, UdoHEURICH, Helmut
    • C10G9/28
    • C10G9/28C10G70/043C10G2300/107C10G2300/1077C10G2300/301C10G2400/02C10G2400/06
    • Ein Verfahren zur Hochtemperatur-Kurzzeit-Destillation von Rückstandsölen wird dahingehend verbessert, dass von dem Gas/Öldampf-Gemisch aus dem Mischwerk (1) eine kleine Rückstandsfraktion auf technisch einfache Weise gewonnen wird, in der die unerwünschten Katalysator-Schadstoffe (CCR, Ni, V, Asphaltene) weitgehend aufkonzentriert sind. Hierzu wird das in einem Mischreaktor (1) erzeugte Gas/Öldampf-Gemisch in einer Kolonne (17) soweit mit Gas oder Wasserdampf verdünnt, dass bei unter 450°C eine schwer siedende schadstoffhaltige Fraktion mit einem Siedebeginn über 450°C kondensiert und abgezogen wird in der die Schadstoffe weitgehend aufkonzentriert sind. Nach einer weiteren Verbesserung wird das nicht kondensierte Produktöl aus Kolonne (17) einer Fraktionier-Kolonne (19) zugeführt, in der es in eine schadstoffarme Vakuum Gasöl sowie in eine Benzin/Gasöl-Fraktion zerlegt wird.
    • 一种用于剩余油的高温短期蒸馏方法进行了改进,即从混合器中的气/油蒸气混合物的(1)在技术上简单的方式获得小的残余馏分,其中所述不希望的催化剂污染物(CCR,镍, V,沥青质)在很大程度上浓缩。 为了这个目的,在(1)中产生的柱(17)稀释气体/油蒸气混合物,只要气体或水蒸汽的混合反应器,是在低于450℃的高沸点污染馏分的初始沸点冷凝以上450℃,汽提 在其中污染物在很大程度上浓缩。 根据本发明的分馏塔的进一步改进,从塔(17)的不凝结油产物(19)供入,其被分解成低污染物的真空瓦斯油并进入燃料/瓦斯油馏分。
    • 10. 发明申请
    • PLASTIC-TO-OIL PLANT, ACCORDING CRACKING REACTOR, AND RELATED METHODS FOR CONVERTING PLASTIC WASTE INTO PETROCHEMICAL PRODUCTS
    • WO2020212403A1
    • 2020-10-22
    • PCT/EP2020/060558
    • 2020-04-15
    • PRUVIA GMBH
    • MASTELLONE, Maria Laura
    • C10G1/10C10G9/28
    • A plastic-to-oil plant for converting plastics into petrochemical products shall be easy to build, to operate, and to maintain. Operation shall be energy- and resource-efficient. To reach this aim, the inventions suggests a plastic-to-oil plant, comprising a cracking reactor (V.1) for a pyrolysis reaction, wherein plastics, in particular polyolefins, are converted into at least gasified pyrolysis products and char, and further comprising a separate combustor (V.2), the cracking reactor (V.1) comprising a plastics inlet port, in particular a plastic melt flow inlet port (5), a particles inlet port (23), a pyrolysis products outlet port (6), and a char and particles outlet port (24), the combustor (V.2) comprising a char and particles inlet port (26), a combustion air inlet port (28), and a combustion products and particles outlet port (29), the char and particles outlet port (24) of the cracking reactor (V.1 ) being connected to the char and particles inlet port (26) of the combustor (V.2), and the combustion products and particles outlet port (29) of the combustor (V.2) being connected to the particles inlet port (23) of the cracking reactor (V.1), the cracking reactor (V.1) and the combustor (V.2) therefore being part of a parti- cles loop (94) which contains a multitude of solid particles, such that during opera- tion the particles are cycled from the cracking reactor (V.1) to the combustor (V.2) and back, wherein the cracking reactor (V.1) is designed such that mixing in the cracking reactor (V.1) is mainly promoted by a flow of said particles fed at the top of the cracking reactor (V.1) essentially in counter-current with a flow of the pyrolysis products, without need of mechanical mixing devices.