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    • 2. 发明申请
    • SYNTHESIS OF PURE DIALLYL MORPHOLINIUM MONOMERS IN HIGH YIELDS AND USING ANTIBACTERIAL EFFECT OF THEIR SPIRO POLYMERS
    • 高效液相色谱法合成纯双螺旋单体和使用其SPIRO聚合物的抗菌效果
    • WO2015088464A1
    • 2015-06-18
    • PCT/TR2014/000507
    • 2014-12-15
    • BICAK, Tugrul Cem
    • BICAK, Tugrul CemINCE, AhmetBICAK, Niyazi
    • C08F26/06C08F126/06C08F226/06
    • A01N43/84A61K31/787C08F26/02C08F226/02
    • Herein, the synthesis of N,Ndiallyl morpholinium monomers and polymerization of the same to form rings at high yield and purity are explained. The process involves the synthesis of N,Ndiallyl morpholinium bromide and chloride and subsequently partially or completely exchanging their anions with borate, p-toluenesulfonate, oleate, and acetate anions. The cyclopolimerization of monomers yields water soluble polymers carrying quaternary ammonium groups in each repeated unit, whose aqueous solutions act as a bactericide solution. These solutions are advantageous in preparation of antibacterial formulations intended for domestic use. The polymer with bromide and borate anions is an efficient antibacterial which is able to kill "Pseudomonas Aeruginosa", the hardest hospital bacterium to cope with, as well as various common bacteria. These formulations are suitable for producing bactericide wet wipes and forming abacterial surfaces and, when combined with air conditioners, generating bacteria free air.
    • 本文中,解释了N,N,N,N,N,N,N,N,并且聚合以高产率和纯度形成环的方法。 该方法包括合成N,N,N,N'-二烯基吗啉鎓溴化物和氯化物,随后部分或完全交换其与硼酸盐,对甲苯磺酸盐,油酸盐和乙酸根阴离子的阴离子。 单体的环化聚合产生在每个重复单元中携带季铵基团的水溶性聚合物,其水溶液用作杀菌剂溶液。 这些溶液在制备用于家用的抗菌制剂方面是有利的。 具有溴化物和硼酸根阴离子的聚合物是一种有效的抗菌剂,能够杀死最难应对的医院细菌以及各种常见细菌的“铜绿假单胞菌”(Pseudomonas aeruginosa)。 这些制剂适用于生产杀菌剂湿巾和形成细菌表面,并且当与空调组合时产生无细菌的空气。
    • 3. 发明申请
    • POLY(HETEROAROMATIC) BLOCK COPOLYMERS WITH ELECTRICAL CONDUCTIVITY
    • 具有电导率的聚(偶氮)嵌段共聚物
    • WO2003018648A1
    • 2003-03-06
    • PCT/US2002/028064
    • 2002-09-03
    • TDA RESEARCH, INC.
    • LUEBBEN DEVITO, SylviaELLIOTT, BrianWILSON, Carolina
    • C08F126/06
    • C08G61/126C08F293/00C08F293/005C08F295/00C08F297/00C08F297/04C08G61/123C08G61/124C08L53/00C08L53/02C08L2666/24
    • The present invention provides block copolymers containing at least one block of a poly(heteroaromatic) polymer and at least two blocks of a non-conjugated polymer. The chemically different blocks of the copolymer are covalently bonded to each other in an alternating fashion through an appropriate linkage group. The poly(heteroaromatic) block may exist in its neutral or oxidized form, and when in the oxidized form, it associates with organic or inorganic counter-anions to balance the charge. The poly(heteroaromatic) polymer is an intrinsically conducting polymer (IPC), and when in the oxidized form it is electrically conducting. When the IPC block or blocks of the block copolymer are in the doped form, the block copolymer is electrically conducting. Preferably the conducting block copolymers have conductivities in the range 10 -6 -10 3 S/cm. Block copolymers of this invention are soluble or dispersible in water, one or more organic solvents, or in a mixture thereof at a level of at least about 0.1g/liter.
    • 本发明提供含有至少一个聚(杂芳族)聚合物嵌段和至少两个非共轭聚合物嵌段的嵌段共聚物。 共聚物的化学上不同的嵌段通过适当的连接基团以交替的方式彼此共价键合。 聚(杂芳族)嵌段可以其中性或氧化形式存在,并且当以氧化形式时,其与有机或无机反阴离子相结合以平衡电荷。 聚(杂芳族)聚合物是本征导电聚合物(IPC),当处于氧化形式时,它是导电的。 当嵌段共聚物的IPC嵌段或嵌段是掺杂形式时,嵌段共聚物是导电的。 优选地,导电嵌段共聚物的导电率在10 -6 -10 S / cm的范围内。 本发明的嵌段共聚物可以至少约0.1g /升的水溶性或分散于水,一种或多种有机溶剂或其混合物中。