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    • 4. 发明申请
    • APPARATUS FOR CIRCULATING AN ELECTROLYTE IN AN ELECTROCHEMICAL CELL AND A BATTERY OF ELECTROCHEMICAL CELLS
    • 用于在电化学细胞和电化学电池电池中循环电解质的装置
    • WO1993000715A1
    • 1993-01-07
    • PCT/NL1992000111
    • 1992-06-26
    • NEDERLANDSE ORGANISATIE VOOR ...VAN DUIN, Pieter, JohannesSCHMAL, DirkSCHILLEMANS, Ronaldus, Adrianus, Albert
    • NEDERLANDSE ORGANISATIE VOOR ...
    • H01M02/38
    • H01M2/38
    • The invention provides an apparatus for circulating an electrolyte in an electrochemical cell whereby the cell is provided with a discharge (7) from the bottom to above the electrolyte level in the cell, causing that when a gas pressure is applied in the tank the electrolyte present therein flows into the space above the acid and that is further applied from a small opening at the bottom of the tank or of the discharge, which apparatus is characterized in that the tank (2) is provided with a float (3), coming on to the seating (4) when the tank is empty or substantially empty and thus limits the volume of the displaced liquid. Such an apparatus enables stirring the electrolyte by means of gas-supply (8) without the danger of bubbles. The apparatus according to the invention can excellently be used in electrochemical cells that are combined to batteries which enables a central gas-supply. This enables a simple and expedient circulation in the electrochemical cell.
    • 本发明提供了一种用于在电化学电池中循环电解质的装置,其中电池从底部提供到电池中的电解质水平以上的放电(7),导致当在罐中施加气体压力时存在电解质 其中流入酸的上方的空间,并进一步从罐的底部或排放口处的小开口施加,该装置的特征在于,罐(2)设置有浮子(3) 当罐是空的或基本上是空的时,到座(4),从而限制排出的液体的体积。 这样的装置能够通过气体供给(8)搅拌电解质而没有气泡的危险。 根据本发明的装置可以优异地用于组合到能够进行中央气体供应的电池的电化学电池中。 这使得电化学电池中的简单和便利的循环。
    • 9. 发明申请
    • BATTERY ELECTROLYTE CIRCULATION SYSTEM
    • 电池电解液循环系统
    • WO1995015586A1
    • 1995-06-08
    • PCT/US1993011698
    • 1993-12-01
    • TROJAN BATTERY COMPANYBRECHT, William, B.
    • TROJAN BATTERY COMPANY
    • H01M02/38
    • H01M2/40H01M10/342
    • A liquid electrolyte battery (10) comprises a number of electrolytic cells (12), an inlet port (22) extending into a first electrolytic cell (12-1), an electrolyte transport channel (30) residing within each electrolytic cell, a number of carry-over passages (40) hydraulically connecting adjacent electrolytic cells, an outlet port (50) extending from a last electrolytic cell (12-4), and a pump (58) for introducing an electrolyte solution or air into the electrolytic cells. The battery electrolyte is replenished by introducing an electrolyte solution (14) into the first electrolytic cell, causing the electrolyte level to rise and be hydraulically transported through the carry-over passages to fill each electrolytic cell. The electrolyte exiting the last electrolytic cell is collected and reintroduced back into the first electrolytic cell and circulated throughout the battery. The electrolyte exiting the battery may be collected in an electrolyte reservoir (72) and circulated through a temperature management device (78) to ensure a battery temperature within design parameters. The electrolyte level in each electrolytic cell is adjusted to a predetermined level by introducing air into the battery causing the hydraulic transport of an electrolyte volume residing above an inlet end (54) of the outlet port through the outlet port in the last electrolytic cell, and the electrolyte volume above an inlet end (42) of the carry-over passage through the carry-over passage in each other electrolytic cell. The air exiting the last electrolyte cell may be vented or treated for the removal of hazardous gases.
    • 液体电解质电池(10)包括多个电解池(12),延伸到第一电解池(12-1)中的入口(22),驻留在每个电解池内的电解质输送通道(30) 液压连接相邻电解槽的搬运通道(40),从最后一个电解槽(12-4)延伸的出口(50)和用于将电解质溶液或空气引入电解槽的泵(58)。 通过将电解质溶液(14)引入到第一电解槽中来补充电池电解质,使电解质水平升高并通过输送通道液压输送以填充每个电解池。 离开最后一个电解池的电解质被收集并重新引入第一电解槽并在整个电池中循环。 离开电池的电解质可以被收集在电解质储存器(72)中并通过温度管理装置(78)循环,以确保设计参数内的电池温度。 通过向电池中引入空气来调节电解液中的电解质量,使得位于出口端口的入口端(54)上方的电解质体液体通过最后的电解池中的出口进行液压输送,以及 在通过每个其他电解槽中的托运通道的移走通道的入口端(42)之上的电解质体积。 离开最后一个电解质电池的空气可以排放或处理以去除有害气体。
    • 10. 发明申请
    • ELECTRICAL STORAGE BATTERY CELL AND STORAGE BATTERY
    • 电储电池和储存电池
    • WO1990014692A1
    • 1990-11-29
    • PCT/DK1990000125
    • 1990-05-18
    • JENSEN, Vagn, BremerskovHENK, Peter, Olaf
    • JENSEN, Vagn, Bremerskov
    • H01M02/38
    • H01M2/38H01M10/342
    • A hermetically closed electrical storage battery cell with a metal salt containing electrolyte and with electrodes (1, 3 and 2) of the first order is provided with an expansion chamber (10, 11) with a compressible gas cushion (10), which can be open or closed (30). The expansion chamber (10, 11) is separated from the electrolyte-filled electrode space of the cell, but connectible with different zones of that space through oppositely directed one-way valve elements (5, 7). When the volume of the electrolyte expands during charge, electrolyte is displaced from the electrolyte-filled space into the expansion chamber (10, 11), and when the volume of the electrolyte is decreased during discharge, electrolyte is displaced from the expansion chamber (10, 11) into a different zone of the electrolyte-filled space. Hereby a step-wise circulation movement of the electrolyte is established, which counteracts the building-up of concentration differences in the electrolyte during charge and discharge. In a storage battery cell with horizontal electrodes and with the anode uppermost the one-way valve elements (5, 7) are so disposed and directed that the displacement of electrolyte takes place from the electrolyte-filled space to the expansion chamber (10, 11) adjacent the anode (1, 3) during charge, and from the expansion chamber (10, 11) to the electrolyte-filled space adjacent the cathode (2) during discharge. Instead of a single expansion chamber, a plurality of expansion chambers, distributed over the electrode area, may be used. A storage battery can be built up from a plurality of horizontally disposed cells, which are stacked on top of one another with a common cell closure (82) between each two successive cells.
    • 具有含有电解质的金属盐和第一级电极(1,3和2)的气密封闭的蓄电池单元设置有具有可压缩气垫(10)的膨胀室(10,11),其可以是 打开或关闭(30)。 膨胀室(10,11)与电池的电解质填充的电极空间分离,但是可以通过相反方向的单向阀元件(5,7)与该空间的不同区域连接。 当电解质膨胀时,电解质从充满电解质的空间移动到膨胀室(10,11)中,当放电期间电解液的体积减小时,电解质从膨胀室(10 ,11)进入电解质填充空间的不同区域。 因此建立了电解液的逐步循环运动,这抵消了在充放电期间电解质中浓度差异的增加。 在具有水平电极并且阳极最上面的蓄电池单元中,单向阀元件(5,7)被设置和指向,使得电解质的位移从电解质填充的空间发生到膨胀室(10,11 )在充电期间邻近阳极(1,3),并且在放电期间从膨胀室(10,11)到靠近阴极(2)的电解质填充空间。 代替单个膨胀室,可以使用分布在电极区域上的多个膨胀室。 可以从多个水平设置的单元构建蓄电池,所述多个水平布置的单元彼此堆叠,并且在每两个连续单元之间具有公共单元封闭件(82)。