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1. 发明申请

WO2014076634A1 POLYMERIC PRECURSORS FOR PRODUCING GRAPHENE NANORIBBONS AND SUITABLE OLIGOPHENYLENE MONOMERS FOR PREPARING THEM 审中-公开
标题翻译：用于生产石墨纳米粒子的聚合物前体和适用的制备他们的二乙烯基单体
公开(公告)号：WO2014076634A1
公开(公告)日：2014-05-22
申请号：PCT/IB2013/060075
申请日：2013-11-12
申请人： BASF SE , MAX-PLANCK-GESELLSCHAFT ZUR FÖRDERUNG DER WISSENSCHAFTEN E.V. , BASF (CHINA) COMPANY LIMITED
发明人： MÜLLEN, Klaus , FENG, Xinliang , CAI, Jinming , RUFFIEUX, Pascal , FASEL, Roman , NARITA, Akimitsu
IPC分类号： C07C15/14 , C07C15/12 , C07C15/20 , C07C15/30 , C07C25/18 , C07C309/66 , C07C245/20 , C01B31/04 , C08G61/10
CPC分类号： C08G61/121 , B82Y40/00 , C01B32/182 , C01B32/184 , C01B2204/06 , C01B2204/22 , C07C25/18 , C08G61/10 , C08G2261/148 , C08G2261/312 , C08G2261/314 , C08G2261/414 , C08G2261/72 , C08G2261/91 , C08G2261/92 , C08G2261/95 , H01L51/102 , H01L51/441 , H01L51/5206 , H01L51/5221
摘要： The invention relates to oligophenylene monomers of general formula I, wherein R 1 is H, halogene, -OH, -NH 2 , -CN,-NO 2 , or a linear or branched, saturated or un-saturated C 1 -C 40 hydrocarbon residue, which can be substituted 1-to 5-fold with halogene (F, Cl, Br, I), -OH, -NH 2 , -CN and/or -NO 2 , and wherein one or more CH 2 -groups can be replaced by -O-, -S-, -C(O)O-, -O-C(O)-, -C(O)-, -NH-or – NR 3 -, wherein R 3 is an optionally substituted C 1 -C 40 hydrocarbon residue, or an optionally substituted aryl, alkylaryl, alkoxyaryl, alkanoyl or aroyl residue; R 2a and R 2b are H, or optionally one or more of the pairs of adjacent R 2a /R 2b is joined to form a single bond in a six-membered carbocycle; m is an integer of from 0 to 3; n is 0 or 1; and X is halogene or trifluoromethylsulfonate, and Y is H; or X is H, and Y is halogene or trifluoromethylsulfonate. The invention further relates to polymeric precursors as well as methods for preparing graphene nanoribbons from the oligophenylene monomers and the polymeric precur- sors.
摘要翻译：本发明涉及通式I的低聚苯乙烯单体，其中R 1是H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以是用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2 - 可以被-O - ， - S，-C（O）O-，-OC（O） - ， - C（O） - ， - NH-或-NR 3 - ，其中R 3是任选取代的C 1 -C 40烃残基或任选取代的芳基，烷基芳基，烷氧基芳基，烷酰基或芳酰基残基; R2a和R2b是H或任选的一对或多个相邻的R 2a / R 2b结合形成六元碳环中的单键; m为0〜3的整数; n为0或1; X为卤素或三氟甲基磺酸盐，Y为H; 或X为H，Y为卤素或三氟甲磺酸酯。本发明还涉及聚合物前体以及从低聚苯乙烯单体和聚合物前体制备石墨烯纳米带的方法。

2. 发明申请

WO2005095522A3 CATIONIC IMIDAZOLAZO DYES CONTAINING A 2, 5-DIAMINOPHENYL MOIETY 审中-公开
标题翻译：含有2,5-二氨基苯乙酸的咪唑咪唑染料
公开(公告)号：WO2005095522A3
公开(公告)日：2005-11-10
申请号：PCT/EP2005051323
申请日：2005-03-23
申请人： CIBA SC HOLDING AG , ELIU VICTOR PAUL , SAUDER THOMAS , KAUFFMANN DOMINIQUE , FROEHLING BEATE
发明人： ELIU VICTOR PAUL , SAUDER THOMAS , KAUFFMANN DOMINIQUE , FROEHLING BEATE
IPC分类号： C07C231/02 , C07C231/12 , C07C245/20 , C09B29/36 , C09B43/11 , C09B43/40 , C09B44/00 , C09B44/16 , A61K7/13
CPC分类号： C09B44/16
摘要： Disclosed are azo dyes of formula (1) , wherein R1 is hydrogen; C1-C14alkyl; hydroxy- C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a) -(CH2)n1-O-(CH2)n2-CH3; a radical of formula (1b) C10aryl; or C6-C10aryl-C1-C6alkyl; R3 is hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C6alkyl; or CO-R6; R4 is CO-R6; R5 is C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; R6 is hydrogen; C1-C14alkyl; C2-C14alkenyl; or C6-C10aryl; R7, R8, R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; m is 1; or 2; An is an anion; If m = 1, R2 is hydrogen; C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a); a radical of formula (1b) ; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; If m = 2, R2 is the direct bond; or C1-C14alkylene, which is optionally substituted by one or more C1-C4alkyl, or which is optionally interrupted by C5-C10arylene, -O- or -NR9R10-; R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair.
摘要翻译：公开了式（1）的偶氮染料，其中R 1是氢; C1-C 1-4烷基; 羟基-C 1 -C 14烷基; C2-C14alkenyl; （1a） - （CH2）n1-O-（CH2）n2-CH3的基团; 式（1b）的基团C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; R3是氢; C1-C 1-4烷基; C2-C14alkenyl; C6-C10芳基; C6-C10芳基，C1-C6烷基; 或CO-R6; R4是CO-R6; R5是C1-C14烷基; C2-C14alkenyl; C6-C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; R6是氢; C1-C 1-4烷基; C2-C14alkenyl; 或C 6 -C 10芳基; R 7，R 8，R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; m为1; 或2; 一种阴离子; 如果m = 1，则R2为氢; C1-C 1-4烷基; C2-C14alkenyl; 式（1a）的基团; 式（1b）的基团; C6-C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; 如果m = 2，则R2是直接键; 或C 1 -C 14亚烷基，其任选被一个或多个C 1 -C 4烷基取代，或任选地被C 5 -C 10亚芳基，-O-或-NR 9 R 10 - 取代; R9和R10彼此独立地是氢; 或C 1 -C 5烷基; 和n1，n2，n3和n4彼此独立地为0至5的数字。该化合物可用于染色有机材料，优选人发。

3. 发明申请

WO2020044348A1 CARBAZOLIUM SALT AND USE THEREOF IN ANION EXCHANGE MEMBRANES 审中-公开
公开(公告)号：WO2020044348A1
公开(公告)日：2020-03-05
申请号：PCT/IL2019/050975
申请日：2019-08-29
申请人： TECHNION RESEARCH & DEVELOPMENT FOUNDATION LIMITED
发明人： DIESENDRUCK, Charles Eliezer , DEKEL, Dario
IPC分类号： C08K5/19 , C07C209/60 , C07C211/64 , C07D209/88 , C07D209/96 , C07C245/20 , B01J41/09 , B01J41/12 , C08K5/3417
摘要： Compositions comprising a tetraaryl ammonium salt, a tetraaryl ammonium salt covalently bound to a polymer and methods for manufacturing the same are disclosed. The disclosed compositions are useful e.g., for an anion exchange membrane, or an anion conducting polymer, and may further be used in electrochemical devices such as alkaline fuel cells, and alkaline redox-flow batteries.

4. 发明申请

WO2017147145A1 MACROCYCLIC POLYPHENOLS FOR UNIVERSAL COATINGS 审中-公开
标题翻译：用于通用涂层的大环多酚
公开(公告)号：WO2017147145A1
公开(公告)日：2017-08-31
申请号：PCT/US2017/018867
申请日：2017-02-22
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
发明人： HEALY, Kevin , MESSERSMITH, Phillip B. , REESE, Willie Mae , BURCH, Patrick
IPC分类号： C07C217/94 , C07C59/72 , C07C245/20
CPC分类号： C07C39/23 , C07C217/94 , C07C245/20 , C07C2603/52 , C07C2603/54 , C09D5/00 , C09D7/65
摘要： The disclosure provides for coating compositions comprising macrocycles and salts in aqueous buffer and the use of the coating composition to prevent absorption of small molecules into polymeric surfaces.
摘要翻译：本公开提供了包含大环和盐在缓冲水溶液中的涂料组合物以及使用该涂料组合物防止小分子吸收到聚合物表面中的用途。

5. 发明申请

WO2008090555A3 MEDICAL DEVICES HAVING A MATRIX ADHERED THEREOF 审中-公开
标题翻译：具有其基质的医疗器械
公开(公告)号：WO2008090555A3
公开(公告)日：2009-01-08
申请号：PCT/IL2008000104
申请日：2008-01-22
申请人： ELUTEX LTD , DOMB ABRAHAM JACKOB , SHAULOV YULIA , LEVI YAIR , MANDLER DANIEL , TAL NOAM
发明人： DOMB ABRAHAM JACKOB , SHAULOV YULIA , LEVI YAIR , MANDLER DANIEL , TAL NOAM
IPC分类号： C09D5/44 , C07C245/20 , C25D11/00 , C25D13/04
CPC分类号： C09D5/44 , A61L31/10 , C08F2/58 , C08F285/00 , C08F291/00 , C08L51/003 , C09D5/4476 , C09D151/003 , C08L2666/02
摘要： Medical devices having a matrix comprising a pharmaceutically active agent, the matrix being adhered to a surface of the medical device via an adherence, are disclosed herein, as well as methods of utilizing the adherence to modulate a release of the pharmaceutically active agent.
摘要翻译：本文公开了具有包含药物活性剂的基质的医疗装置，所述基质通过粘附剂粘附到医疗装置的表面，以及利用粘附剂调节药物活性剂的释放的方法。

6. 发明申请

WO2008055927A1 VERFAHREN ZUR HERSTELLUNG AROMATISCHER DIAZONIUMSALZE 审中-公开
标题翻译：用于生产芳族重氮盐
公开(公告)号：WO2008055927A1
公开(公告)日：2008-05-15
申请号：PCT/EP2007/061999
申请日：2007-11-07
申请人： ZYLUM BETEILIGUNGSGESELLSCHAFT MBH & CO. PATENTE II KG , SCHMIDT, Bernd , HÖLTER, Frank
发明人： SCHMIDT, Bernd , HÖLTER, Frank
IPC分类号： C07C245/20
CPC分类号： C07C245/20
摘要： Beschrieben ist ein Verfahren zur Herstellung aromatischer Diazoniumsalze, wobei die Ausgangsverbindung ein aromatisches Amid ist und man die Amidbindung zunächst hydrolytisch spaltet und die so erhaltene Aminverbindung mit einem anorganischen Nitritsalz diazotiert. Die so erhaltenen Diazoniumsalze können in stabile Salze überführt werden und dann als Ausgangsstoffe für weitere Reaktionen wie der Heck-Reaktion dienen.
摘要翻译：描述了一种用于制备芳族重氮盐，其中起始化合物是芳族酰胺和酰胺键被裂解水解最初重氮化并因而与无机亚硝酸盐所得到的胺化合物的方法。由此获得的可转化为稳定的盐，然后将重氮盐作为起始其它反应材料如Heck反应。

7. 发明申请

WO02060812A2 PROCESS FOR DERIVATIZING CARBON NANOTUBES WITH DIAZONIUM SPECIES AND COMPOSITIONS THEREOF 审中-公开
标题翻译：用于制备具有重氮衍生物的碳纳米管的方法及其组合物
公开(公告)号：WO02060812A2
公开(公告)日：2002-08-08
申请号：PCT/US0202562
申请日：2002-01-29
申请人： UNIV RICE WILLIAM M , TOUR JAMES M , BAHR JEFFREY L , YANG JIPING
发明人： TOUR JAMES M , BAHR JEFFREY L , YANG JIPING
IPC分类号： C01B31/02 , C07C245/20 , C08K9/04 , C09C1/56 , C01B
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/36 , C01P2002/86 , C01P2002/88 , C01P2004/04 , C08K9/04 , C09C1/56 , C09C1/565
摘要： The invention incorporates new processes for the chemical modification of carbon nanotubes. Such processes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter ( ca . 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications and sensor devices. The methods of derivatization include electrochemical induced reactions thermally induced reactions (via in-situ generation of diazonium compounds or pre-formed diazonium compounds), and photochemically induced reactions. The derivatization causes significant changes in the spectroscopic properties of the nanotubes. The estimated degree of functionality is ca . 1 out of every 20 to 30 carbons in a nanotube bearing a functionality moiety. Such electrochemical reduction processes can be adapted to apply site-selective chemical functionalization of nanotubes. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes.
摘要翻译：本发明结合了碳纳米管化学修饰的新方法。这些过程涉及多壁和单壁碳纳米管的衍生，包括小直径（大约0.7纳米）单壁碳纳米管，以及重氮化合物。该方法允许将各种有机化合物化学连接到碳纳米管的侧面和端部。这些化学修饰的纳米管可用于聚合物复合材料，分子电子应用和传感器设备。衍生化方法包括电化学诱导反应热诱导反应（通过原位生成重氮化合物或预先形成的重氮化合物）和光化学诱导反应。衍生化引起纳米管的光谱性质的显着变化。估计的功能程度是ca。在带有功能性部分的纳米管中每20至30个碳中有1个。这种电化学还原过程可以适用于应用纳米管的位点选择性化学官能化。此外，当用合适的化学基团改性时，衍生化的纳米管与聚合物基体化学相容，从而允许纳米管的性质（例如机械强度或电导率）整体上转化为复合材料的性质。此外，当用合适的化学基团改性时，这些基团可以聚合形成包含碳纳米管的聚合物。

8. 发明申请

WO01012720A1 ONIUM GALLATES CATIONIC INITIATORS 审中-公开
标题翻译： ONIUM GALLATES阳离子发动机
公开(公告)号：WO01012720A1
公开(公告)日：2001-02-22
申请号：PCT/US2000/022084
申请日：2000-08-11
IPC分类号： C07F5/00 , C08F2/46 , C08F2/50 , C08G59/68 , C09D163/00 , G03F7/004 , G03F7/029 , C08L63/00 , C07C245/20 , C07F1/00 , C07F15/00 , C07F19/00
CPC分类号： C07F5/00 , C08F2/50 , C08G59/68 , C09D163/00 , G03F7/0045 , G03F7/029
摘要： An onium salt having an anion of the formula GaXaRb where X is a halogen atom or a hydroxy group, R is an aryl group, a and b represent integers of 0 to 4 and the sum of a and b is 4 and a cationically polymerizable composition containing the same.
摘要翻译：具有式GaXaRb阴离子的鎓盐，其中X是卤素原子或羟基，R是芳基，a和b表示0至4的整数，a和b的和为4，阳离子可聚合组合物含有相同的

9. 发明申请

WO00028983A1 NOVEL 4-DEDIMETHY LAMINOTETRA CYCLINE DERIVATIVES 审中-公开
标题翻译：新型4-DEDIMETHY LAMINOTETRA CYCLINE DERIVATIVES
公开(公告)号：WO00028983A1
公开(公告)日：2000-05-25
申请号：PCT/US1999/027304
申请日：1999-11-18
IPC分类号： C07D241/04 , A61K31/165 , A61K31/40 , A61K31/495 , A61K31/5375 , A61K31/65 , A61P1/02 , A61P1/18 , A61P3/10 , A61P7/00 , A61P7/04 , A61P9/14 , A61P11/00 , A61P13/12 , A61P17/00 , A61P19/02 , A61P19/10 , A61P27/02 , A61P29/00 , A61P31/04 , A61P35/00 , A61P37/02 , A61P37/06 , A61P39/02 , A61P43/00 , C07C235/82 , C07C237/26 , C07C237/32 , C07C237/34 , C07C237/36 , C07C237/38 , C07C245/20 , C07C247/18 , C07C329/20 , C07D207/00 , C07D295/00 , C07D295/13
CPC分类号： C07C235/82 , C07C237/26 , C07C245/20 , C07C247/18 , C07C329/20 , C07C2603/46 , C07D295/13
摘要： The present invention provides new chemically modified 4-dedimethylaminotetracycline compounds that can be substituted at the 7,8, and/or 9 positions and methods for preparing the 4-dedimethylamino tetracycline compounds. Other tetracycline compounds are the 4-dedimethylaminotetracycline derivatives with an oxime group, NH-Alkyl, or N-NH-Alkyl group at the C4 position. The present invention also provides a method of treating a mammal suffering from conditions or diseases by administering to the mammal an effective amount of the new chemically modified 4-dedimethylamino tetracycline compounds.
摘要翻译：本发明提供了可以在7,8和/或9位置被取代的新的化学修饰的4-脱二甲基氨基四环素化合物，以及制备4-脱二甲基氨基四环素化合物的方法。其他四环素化合物是在C4位置具有肟基，NH-烷基或N-NH-烷基的4-脱二甲基氨基四环素衍生物。本发明还提供了通过向哺乳动物施用有效量的新的化学改性的4-去二甲基氨基四环素化合物来治疗患有病症或疾病的哺乳动物的方法。

10. 发明申请

WO99006389A1 O-(PERFLUOROALKYL)DIBENZOFURANIUM SALT DERIVATIVES, INTERMEDIATES FOR THE PREPARATION OF THE SAME, PROCESS FOR THE PREPARATION OF THE INTERMEDIATES, PERFLUOROALKYLATING AGENTS, AND PROCESS FOR PERFLUOROALKYLATION 审中-公开
标题翻译： O-（全氟烷基）二苯并呋喃盐酸盐衍生物，其制备中间体，中间体的制备方法，全氟代醇衍生物，全氟代烷基化方法
公开(公告)号：WO99006389A1
公开(公告)日：1999-02-11
申请号：PCT/JP1998/003416
申请日：1998-07-30
IPC分类号： C07C217/80 , C07C245/20 , C07D307/91 , C07C213/08
CPC分类号： C07D307/91 , C07C217/80 , C07C245/20
摘要： O-(Perfluoroalkyl)dibenzofuranium salt derivatives represented by general formula (1) (wherein Rf is perfluoroalkyl being 1 to 10 carbon atoms; and X is a conjugate based of a Bronsted acid); intermediates for the preparation of the derivatives; a process for the preparation of the intermediates; perfluoroalkylating agents comprising the derivatives or the intermediates; and a process for perfluoroalkylation. The O-(perfluoroalkyl)dibenzofuranium salt derivatives are useful as perfluoroalkylating agents which permit high-yield perfluoroalkylation, and are applicable to a wide range of compounds and so inhibited in self-decomposition as to be relatively stable.
摘要翻译：通式（1）表示的O-（全氟烷基）二苯并ur鎓盐衍生物（其中，Rf是1-10个碳原子的全氟烷基; X是基于布朗斯台德酸的共轭物）; 制备衍生物的中间体; 制备中间体的方法; 包含所述衍生物或中间体的全氟烷基化剂; 和全氟烷基化方法。 O-（全氟烷基）二苯并anium盐衍生物可用作允许高产率全氟烷基化的全氟烷基化剂，并且适用于宽范围的化合物，因此被自分解抑制为相对稳定。

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