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    • 1. 发明申请
    • MOISTURE GENERATION METHOD AND MOISTURE GENERATOR
    • 水分生成方法和水分发生器
    • WO1997048640A1
    • 1997-12-24
    • PCT/JP1997002131
    • 1997-06-20
    • ULTRACLEAN TECHNOLOGY RESEARCH INSTITUTEOHMI, TadahiroNITTA, Takahisa
    • ULTRACLEAN TECHNOLOGY RESEARCH INSTITUTE
    • C01B05/00
    • C01B5/00
    • A moisture generation method and a moisture generator can efficiently generate high concentration moisture having high reactivity. A method of generating a moisture by reacting hydrogen and oxygen, comprises a mixed gas preparation step a1 of mixing hydrogen and oxygen to prepare a first mixed gas without diluting them with an inert gas, and a moisture generation step b1 of introducing the first mixed gas into a reaction tube incorporating a material having a catalytic function of reacting hydrogen with oxygen or made of such a material, and reacting hydrogen and oxygen inside the reaction tube to generate moisture. The moisture generator comprises a hydrogen source, means for controlling the hydrogen flow rate, an oxygen source, means for controlling the oxygen flow rate, a first mixing portion for mixing hydrogen and oxygen to prepare a first mixed gas, a reaction tube incorporating a material having a catalytic function of reacting hydrogen and oxygen constituting the first mixed gas or made of such a material, and means for introducing the first mixed gas into the reaction tube from the first mixing portion.
    • 水分产生方法和水分发生器可以有效地产生具有高反应性的高浓度水分。 通过氢和氧反应生成水分的方法包括:混合气体制备步骤a1,其中混合氢气和氧气,以制备第一混合气体,而不用惰性气体稀释;和产生第一混合气体的水分产生步骤b1 加入具有氢气与氧反应或由这种材料制成的催化功能的材料的反应管中,并使反应管内的氢和氧反应产生水分。 水分发生器包括氢源,用于控制氢气流量的装置,氧源,用于控制氧气流量的装置,用于混合氢气和氧气以制备第一混合气体的第一混合部分,并入材料的反应管 具有使构成第一混合气体的氢和氧反应或由这种材料制成的催化功能,以及用于将第一混合气体从第一混合部分引入反应管的装置。
    • 3. 发明申请
    • METHOD FOR GENERATING MOISTURE, REACTOR FOR GENERATING MOISTURE, METHOD FOR CONTROLLING TEMPERATURE OF REACTOR FOR GENERATING MOISTURE, AND METHOD FOR FORMING PLATINUM-COATED CATALYST LAYER
    • 用于产生水分的方法,用于产生水分的反应器,用于控制用于产生水分的反应器的温度的方法,以及形成铂包覆催化剂层的方法
    • WO1997028085A1
    • 1997-08-07
    • PCT/JP1997000188
    • 1997-01-27
    • FUJIKIN INCORPORATEDHITACHI, LTD.OHMI, TadahiroKAWADA, KojiTANABE, YoshikazuNITTA, TakahisaIKEDA, NobukazuMORIMOTO, AkihiroHIRAO, KeijiMOROKOSHI, HiroshiMINAMI, Yukio
    • FUJIKIN INCORPORATEDHITACHI, LTD.
    • C01B05/00
    • C01B5/00
    • The invention aims at further reducing the size and cost of a reactor for generating water from oxygen and hydrogen, providing high-purity water in an amount necessary for practical use safely, stably and continuously, and allowing a platinum-coated catalyst layer formed on the internal wall of the reactor body to maintain its high catalytic activity over a long period of time. Specifically, the reactor comprises a body made of a heat-resistant material and having an inlet and an outlet for water/moisture gas, a gas-diffusing member provided in the internal space of the body of the reactor, and a platinum coating provided on the internal wall surface of the body of the reactor, and hydrogen and oxygen fed from the inlet are diffused by means of the gas-diffusing member and then come into contact with the platinum coating to enhance the reactivity, thereby producing water from hydrogen and oxygen. The temperature of the reactor for generating moisture, wherein hydrogen is reacted with oxygen at a high temperature to generate moisture, is held to be below the ignition temperature of hydrogen or a hydrogen-containing gas to react hydrogen with oxygen while preventing explosive combustion of hydrogen and oxygen. The platinum-coated catalyst layer on the internal wall of the reactor body is formed by treating the surface of the internal wall of the body of a metallic reactor, cleaning the treated surface, forming a barrier coating of a nonmetallic material of an oxide or a nitride on the wall surface, and forming a platinum coating on the barrier coating.
    • 本发明旨在进一步降低用于从氧气和氢气产生水的反应器的尺寸和成本,提供安全,稳定和连续地实际使用所需量的高纯度水,并且允许形成在其上的铂涂覆的催化剂层 反应器主体的内壁在长时间内保持其高催化活性。 具体地,反应器包括由耐热材料制成的本体,具有用于水/湿气的入口和出口,设置在反应器主体的内部空间中的气体扩散部件和设置在反应器主体的内部的铂镀膜 反应器主体的内壁表面和从入口供给的氢气和氧气通过气体扩散构件扩散,然后与铂涂层接触以增强反应性,由此从氢气和氧气中产生水 。 用于产生水分的反应器的温度,其中氢气在高温下与氧气反应以产生水分,保持在低于氢气或含氢气体的点火温度以使氢气与氧气反应,同时防止氢气的爆炸性燃烧 和氧气。 反应器主体内壁上的铂包覆催化剂层是通过处理金属反应器主体内壁的表面,清洗处理过的表面,形成氧化物或非金属材料的非金属材料的阻挡层 在壁表面上形成氮化物,并在阻挡涂层上形成铂涂层。
    • 4. 发明申请
    • DEVICE FOR REMOVING HYDROGEN FROM A GAS MIXTURE AND ITS USE
    • 装置氢气与从气体混合物拆卸和应用设备的
    • WO1997023412A2
    • 1997-07-03
    • PCT/DE1996002418
    • 1996-12-16
    • FORSCHUNGSZENTRUM JÜLICH GMBHFÜRST, LeanderNEUMEISTER, HerbertFLUCHT, Reinhold
    • FORSCHUNGSZENTRUM JÜLICH GMBH
    • C01B05/00
    • B01D53/8671C01B3/58C01B5/00C01B2203/0435C01B2203/0465
    • The invention relates to a device for removing hydrogen from a gas mixture containing free hydrogen and oxygen, by the catalytic oxidation of the hydrogen in a reaction chamber (6), with a support (1) secured in the reaction chamber and coated on its surface (2) with catalytically active materials, serving to conduct reaction heat away, and an inlet (7) to the reaction chamber for the gas mixture and an outlet (10) for residual gas remaining after the oxidation of the hydrogen. A part (5) of the catalytically active surface (2) of the support (1) is immersed in a liquid bath (3), the temperature of which is below the condensation temperature of the water vapour formed in the reaction chamber (6). The inlet (7) for the liquid bath (3) also acts as the inlet for the gas mixture to be fed into the reaction chamber and the outlet (10) also acts as an outlet for the residual gas, and both the inlet (7) and the outlet (10) lie below the liquid level (8) in the reaction chamber (6) the pressure in the reaction chamber being controllable.
    • 本发明涉及一种用于从含有通过在反应空间(6)中的氢的催化氧化游离氢和氧的气体混合物与固定在反应空间具有催化活性材料涂覆的载体主体中除去氢气,它的表面(2)上 (1)服务于反应热的排出,并具有用于所述气体混合物的接入(7)到反应室和用于氢气的残留气体的氧化后剩下的输出(10),其中,所述承载体(1)与部件(5) 其催化活性表面(2)被浸没在液体浴(3),其具有下面的反应室的冷凝温度(6)形成的水蒸汽的温度,其中一个液体入口(7),用于在液体浴(3)在相同的时间访问在 被引入反应室的气体混合物,并在同一时间作为输出FO一个流体出口(10) r是残留气体,并且其中,两个液体入口(7)和下在反应室(6)中的液面(8)的液体出口(10)被布置,并且在所述反应空间中的压力可以被调节。
    • 5. 发明申请
    • WATER GENERATING METHOD
    • 水生产方法
    • WO1994007795A1
    • 1994-04-14
    • PCT/JP1993001430
    • 1993-10-05
    • OHMI, Tadahiro
    • C01B05/00
    • C01B5/00
    • A water generating method which is capable of providing a large quantity of water-mixed gas having an accurate concentration of water in a wide range from a low level of the order of ppt and ppb to a high level of the order of percentage, and a super-high cleanness, and which is quick to respond and simple to maintain. A method of generating water on reaction between hydrogen and oxygen consisting of the steps of generating a first mixed gas by mixing hydrogen, oxygen and an inert gas, and generating water by introducing the first mixed gas into a reaction tube, which is formed out of a material having a catalytic action capable of turning hydrogen and oxygen into radicals, and heating the interior of the reaction tube so as to cause a reaction between the hydrogen and oxygen contained in the first gas and produce water.
    • 一种水生成方法,其能够提供从ppt和ppb的量级的低水平到百分比量级的高水平的广泛范围内具有准确浓度的水的大量水混合气体,以及 超高的清洁度,快速响应和维护简单。 一种在氢气和氧气之间产生水的方法,包括以下步骤:通过混合氢气,氧气和惰性气体产生第一混合气体,并通过将第一混合气体引入反应管中而形成水,反应管由 具有能够将氢和氧转化为自由基的催化作用的材料,以及加热反应管的内部以引起第一气体中所含的氢和氧之间的反应并产生水。