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    • 2. 发明申请
    • PROCESSES OF PREPARING TABULAR GRAIN EMULSIONS
    • 制备颗粒细粒乳液的方法
    • WO1994022051A1
    • 1994-09-29
    • PCT/US1993002618
    • 1993-03-22
    • EASTMAN KODAK COMPANY
    • EASTMAN KODAK COMPANYHOUSE, Gary, LawrenceBRUST, Thomas, BrownellHARTSELL, Debra, LynnBLACK, Donald, LeeANTONIADES, Michael, GeorgeTSAUR, Allen, Keh-ChangCHANG, Yun, Chea
    • G03C01/005
    • G03C1/0053G03C1/015G03C1/047G03C1/07G03C2001/0055G03C2001/0151G03C2001/0156G03C2001/03558G03C2001/0478G03C2200/01G03C2200/43G03C2200/44
    • A process is disclosed of preparing silver halide emulsions containing tabular grains bounded by [100] major faces comprised of the steps of (1) introducing silver and halide salts into a dispersing medium and (2) maintaining conditions within the dispersing medium that promote the formation of tabular grains bounded by [100] major faces. The process is characterized in that of the tabular grains bounded by [100] major faces a portion accounting for 50 percent of total grain projected area selected on the criteria of adjacent major face edge ratios of less than 10 and thicknesses of less than 0.3 mu m internally at their nucleation site contain iodide and at least 50 mole percent chloride, at least the selected portion of the tabular grains being formed ty nucleation in a continuous double jet reaction in the presence of iodide with chloride accounting for at least 50 mole percent of the halide present in the dispersing medium and the pC1 of the dispersing medium being maintained in the range of from 0.5 to 3.5. Following nucleation tabular grain growth is undertaken in a reaction vessel which receives emulsion from the continuous double jet reactor until the tabular grains having a thickness of less than 0.3 mu m exhibit achieve a selected average aspect ratio.
    • 公开了一种制备包含由[100]主面界定的片状颗粒的卤化银乳剂的方法,其包括以下步骤:(1)将银盐和卤化物盐引入分散介质中,和(2)保持促进形成的分散介质内的条件 由[100]主面界定的片状颗粒。 该方法的特征在于,由[100]主面界定的平片状颗粒占相对主面积比小于10且厚度小于0.3μm的标准选择的占总颗粒投影面积的50%的部分 在其成核位置内部含有碘化物和至少50摩尔百分比的氯化物,至少所选择的片状颗粒部分在碘化物与氯化物存在下在连续双喷射反应中形成,占至少50摩尔% 存在于分散介质中的卤化物和分散介质的pCl保持在0.5至3.5的范围内。 在成核后,在从连续双喷射反应器接收乳液的反应容器中进行片状晶粒生长,直到厚度小于0.3μm的片状颗粒显示出选择的平均纵横比。