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    • 2. 发明申请
    • COMPOSITION AND METHOD OF USE THEREOF FOR TREATING THERMOPLASTIC ARTICLES
    • 用于处理热塑性物品的组合物及其使用方法
    • WO1988000960A1
    • 1988-02-11
    • PCT/US1987000129
    • 1987-01-16
    • WILSON, Robert, B.
    • C09B67/10
    • C09B67/0083C09B67/0071D06P1/613D06P1/65125D06P1/928Y10S8/922Y10S8/924Y10S8/926Y10S8/927
    • A waterless treating composition for apparel and other articles, made from thermoplastic materials, comprises at least one high boiling ester, derived from at least one monohydric alcohol and one or more monocarboxylic acids; from at least one monocarboxylic acid and one more monohydric alcohols; from a glycol or polyol and one or more monocarboxylic acids; or from a dicarboxylic acid or polycarboxylic acid and one or more monohydric alcohols; and an organic colorant. When organic colorant is present in sufficient amounts, the composition comprises a waterless dye composition. A representative composition comprises an aliphatic polyester of a higher alkanoic acid and a polyol, of the formula (ACOO)2-6B, wherein A is alkyl of 8-22 carbon atoms and B is the residue of a polyhydric alcohol, other than glycerol, of 2-6 hydroxyl groups and an organic colorant. The compositions can further comprise an aromatic polyester of the formula C6Hz'-(COOR1)z, wherein z is 3, 4, 5, or 6; z' is 6-z; and R1 is higher alkyl; and/or a cycloaliphatic diester of formula (I), wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(CxHyO)nCxHy- or phosphated polyoxyalkylene of the formula (HO)2P(=O)O(CxH2xO)nCxH2x or a salt thereof, wherein (CxH2xO)n is (CH2CH2O)n, (C3H6O)n or (CH2CH2O)p(C3H6O)q, n is 2-22, and the sum of p + q is n. A process for treating apparel or other articles, fabricated from polyester, polyamide, polyurethane, acrylic, halogenated polyolefin or epoxy plastic, comprises exposing an article to the foregoing compositions, maintained at a temperature between 100 DEG C and the temperature at which the plastic is degraded, for a time adequate to achieve the desired degree of treatment.
    • 由热塑性材料制成的用于服装和其它制品的无水处理组合物包含至少一种衍生自至少一种一元醇和一种或多种单羧酸的高沸点酯; 从至少一种一元羧酸和一个以上的一元醇; 二醇或多元醇和一种或多种单羧酸; 或二羧酸或多元羧酸和一种或多种一元醇; 和有机着色剂。 当有机着色剂以足够的量存在时,组合物包含无水染料组合物。 代表性的组合物包含式(ACOO)2-6B的高级链烷酸和多元醇的脂族聚酯,其中A是8-22个碳原子的烷基,B是除甘油以外的多元醇的残基, 2-6个羟基和有机着色剂。 组合物还可以包含式C 6 H 6' - (COOR 1)z的芳族聚酯,其中z为3,4,5或6; z'为6-z; 且R1为高级烷基; 和(或)式(I)的脂环族二酯,其中R是取代或未取代的4-20个碳原子的直链或支链烷基,式HO(C x H y O)n C x H y - 或式(HO)2 P的磷酸化聚氧化烯的聚氧化烯 (= O)O(C x H x O)n C x H 2 x或其盐,其中(C x H 2 x O)n为(CH 2 CH 2 O)n,(C 3 H 6 O)n或(CH 2 CH 2 O)p(C 3 H 6 O)q,n为2-22, + q是n。 用于处理由聚酯,聚酰胺,聚氨酯,丙烯酸,卤化聚烯烃或环氧塑料制成的服装或其他制品的方法包括将制品暴露于前述组合物,保持在100℃和塑料的温度之间 退化一段时间,足以达到所需的治疗程度。
    • 3. 发明申请
    • DYE COMPOSITION AND METHOD OF USE THEREOF FOR COLORING THERMOPLASTIC ARTICLES
    • 染料组合物及其用于染色热塑性物品的方法
    • WO1988000607A1
    • 1988-01-28
    • PCT/US1986001484
    • 1986-07-11
    • WILSON, Robert, Buchanan
    • C09B67/40
    • D06P1/928C09B67/0083D06P1/613D06P1/65125
    • A waterless dye composition for apparel and other articles, made from thermoplastic materials, comprises an aliphatic polyester of a higher alkanoic acid and a polyol, of the formula (ACOO)2-6B, wherein A is alkyl of 8-22 carbon atoms and B is the residue of a polyhydric alcohol, other than glycerol, of 2-6 hydroxyl groups and an organic colorant. The compositions can further comprise an aromatic polyester of the formula C6Hz'-(COOR1)z, wherein z is 3, 4, 5, or 6; z' is 6-z; and R1 is higher alkyl; and/or a cycloaliphatic diester of formula (I), wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(CxHyO)nCxHy- or phosphated polyoxyalkylene of the formula (HO)2P(=O)O(CxH2xO)nCxH2x or a salt thereof, wherein (CxH2xO)n is (CH2CH2O)n, (C3H6O)n or (CH2CH2O)p(C3H6O)q, n is 2-22, and the sum of p + q is n. A process for coloring apparel or other articles, fabricated from polyester, polyamide, polyurethane, acrylic, halogenated polyolefin or epoxy plastic, comprises exposing an article to the foregoing compositions, maintained at a temperature between 100 C and the temperature at which the plastic is degraded, for a time adequate to achieve the desired degree of coloration. The compositions may further be diluted with water and used for textile finishing processes or as dyeing assistants in aqueous baths.
    • 由热塑性材料制成的用于服装和其它制品的无水染料组合物包含式(ACOO)2-6B的高级链烷酸和多元醇的脂族聚酯,其中A是8-22个碳原子的烷基和B 是除了甘油以外的2-6个羟基的多元醇的残基和有机着色剂。 组合物还可以包含式C 6 H 6' - (COOR 1)z的芳族聚酯,其中z为3,4,5或6; z'为6-z; 且R1为高级烷基; 和(或)式(I)的脂环族二酯,其中R是取代或未取代的4-20个碳原子的直链或支链烷基,式HO(C x H y O)n C x H y - 或式(HO)2 P的磷酸化聚氧化烯的聚氧化烯 (= O)O(C x H x O)n C x H 2 x或其盐,其中(C x H 2 x O)n为(CH 2 CH 2 O)n,(C 3 H 6 O)n或(CH 2 CH 2 O)p(C 3 H 6 O)q,n为2-22, + q是n。 用于着色由聚酯,聚酰胺,聚氨酯,丙烯酸,卤化聚烯烃或环氧塑料制成的服装或其他制品的方法包括将制品暴露于前述组合物,保持在100℃和 塑料会退化一段时间,以达到所需的着色程度。 组合物还可以用水稀释并用于纺织品整理过程或作为染色助剂在水浴中。
    • 5. 发明申请
    • INFUSION OF DYE USING A PLASTICIZER
    • 使用塑化剂输注染色体
    • WO01077212A1
    • 2001-10-18
    • PCT/US2001/011259
    • 2001-04-09
    • C08J7/02C08J7/06D06P1/00D06P1/651D06P1/92G02B1/04D06P1/90
    • D06P1/928C08J7/065D06P1/0004D06P1/65125D06P1/924G02B1/041
    • A method of infusing a dye into the surface of an article formed of a plastic material comprises contacting the surface with a solution including one or more solvents each aggressive to the plastic material, one or more dyes and one or more substances each capable of plasticizing the plastic material. If the plastic material is polycarbonate, then the aggressive solvent may be one or more chlorinated hydrocarbons. The dye may be a photochromic dye, a cosmetic tinting dye, dyes for absorbing infrared, laser and ultraviolet radiation, or combinations thereof. A wide range of plasticizers has been investigated. The article is contacted by the solution for ten seconds to one minute; and nearly all the infused solvent is then evaporated from the article by heating. The use of one or more plasticizers reduces or eliminates bubbling or hazing of the contacted surface during solvent evaporation. The dyed article comprises a surface layer having a depth of the order of magnitude of 100 microns containing one or more dyes, one or more plasticizers and, likely, a trace amount of the one or more aggressive solvents.
    • 将染料注入由塑料材料形成的制品的表面的方法包括使表面与包含一种或多种对塑料材料侵蚀的溶剂的溶液接触,一种或多种染料和一种或多种各自能够增塑的物质 塑料材料。 如果塑料材料是聚碳酸酯,则侵蚀性溶剂可以是一种或多种氯化烃。 染料可以是光致变色染料,化妆品着色染料,用于吸收红外线,激光和紫外线辐射的染料或其组合。 已经研究了各种增塑剂。 解决方案联系文章十秒钟至一分钟; 并且几乎所有输入的溶剂然后通过加热从制品中蒸发出来。 在溶剂蒸发期间使用一种或多种增塑剂减少或消除接触表面的起泡或起雾。 染色制品包括具有100微米量级的深度的表面层,其含有一种或多种染料,一种或多种增塑剂和可能的痕量的一种或多种腐蚀性溶剂。