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    • 1. 发明申请
    • METHOD AND APPARATUS FOR REMOVING UNDESIRABLE METALS FROM IRON-CONTAINING MATERIALS
    • 从含铁材料中去除不可燃金属的方法和装置
    • WO0050649A3
    • 2001-02-08
    • PCT/IB0000379
    • 2000-02-23
    • HYLSA SA
    • SALINAS-FERNANDEZ MARIO AGUERRA-REYES MARIA TAPARICIO-ARRANZ JOSE MVILLARREAL-TREVINO JUAN APEDROZA-CONTRERAS MIGUEL ANGEL
    • C21B13/00C21B13/04C22B1/24C22B5/12C22B7/02C22B19/30C22B1/20C22B1/216C22B1/22C22B13/02C22B17/02C22B19/00
    • C22B1/2406C21B13/0046C21B13/04C22B5/12C22B7/02C22B19/30Y02P10/122Y02P10/136Y02P10/216
    • The present invention relates to a method and apparatus for separating undesired toxic metals, such as Zn, Pb and Cd, from iron-containing materials by: sintering a mixture of such materials (typically including EAF dust and mill scale) with carbonaceous particles to form sturdy sinter lumps; preheating such lumps in a non-reducing atmosphere, if needed, to achieve an elevated temperature generally above the vaporization temperature of the undesired metals, but below the sticking temperature of said iron-containing lumps (which is typically below the vaporization temperatures of such undesired metals in their oxide form), feeding the lumps at such elevated temperature into a reduction reactor; flowing hot reducing gas through said lumps to volatilize said undesired reduced metals and carry the volatilized metals out of said reduction reactor leaving the iron-containing lumps largely stripped of the undesired metals and ready for discharge and safe and/or useful disposal or re-use, and finally cooling the off gas from the reactor to separate out the resulting solidified unwanted metals (typically in their oxide form resulting from a water quench cooling).
    • 本发明涉及通过以下方法从铁含量分离不需要的有毒金属如Zn,Pb和Cd的方法和装置:将这种材料(通常包括EAF粉尘和磨尺)的混合物与碳质颗粒烧结以形成 坚固的烧结块; 如果需要,在非还原性气氛中预热这样的块,以达到通常高于不需要的金属的蒸发温度但低于所述含铁块的粘附温度的升高温度(其通常低于这种不希望的金属的汽化温度 以其氧化物形式的金属),将这些升高的温度的块体送入还原反应器中; 流过热还原气体通过所述块状物以挥发所述不期望的还原金属并将挥发的金属从所述还原反应器中排出,留下含铁块大部分剥离不需要的金属并准备排出,并且安全和/或有用的处理或再利用 ,并最终冷却来自反应器的废气以分离所得到的固化的不需要的金属(通常以由水淬火冷却得到的氧化物形式)。
    • 3. 发明申请
    • RETORT
    • 反驳
    • WO01038455A1
    • 2001-05-31
    • PCT/AU2000/001427
    • 2000-11-23
    • C10B1/04C10B27/02C10B47/20C10B53/08C21B13/04F27D17/00C10B47/18C21B11/00F27B5/06
    • F27D17/004C10B1/04C10B27/02C10B47/20C10B53/08C21B13/04
    • A retort (10) including a thermally insulated casing (12) defining a furnace chamber (14) therein; one or more columns (15) provided within said chamber (14), each column (15) comprising a plurality of vertically orientated, vertically spaced, heat resistant tubes (16, 18, 20, 22), wherein the cross-sectional area of each tube is smaller than that of an adjacent, lower tube, and wherein the ends of adjacent tubes are arranged so as to provide an annular space (24, 26, 28) therebetween, an inlet (17) through which a combustible charge is fed into the uppermost tube (16), an outlet (30) from which reacted charge is removed from the lowermost tube (22); and a fluid conduit (36) for conveying combustible volatiles evolved by heating said charge to a gas burning means (31, 32) for combustion, to thereby provide heat to said retort (10).
    • 一种包括在其中限定炉室(14)的绝热壳体(12)的蒸馏器(10) 设置在所述腔室(14)内的一个或多个柱(15),每个柱体(15)包括多个垂直取向的,垂直间隔开的耐热管(16,18,20,22),其中横截面积 每个管小于相邻的下管的管,并且其中相邻管的端部被布置成在其间提供环形空间(24,26,28),入口(17),可燃物质通过所述入口 进入最上管(16),从最下管(22)除去反应的电荷的出口(30)。 以及用于输送可燃挥发物的流体导管(36),其通过将所述电荷加热到用于燃烧的气体燃烧装置(31,32)而放出,从而向所述蒸馏器(10)提供热量。
    • 5. 发明申请
    • PRODUCTION OF IRON USING ENVIRONMENTALLY-BENIGN RENEWABLE OR RECYCLED REDUCING AGENT
    • 使用环保型可再生或再循环还原剂生产铁
    • WO2007108984B1
    • 2008-11-27
    • PCT/US2007006175
    • 2007-03-12
    • UNIV MICHIGAN TECH
    • EISELE TIMOTHY CKAWATRA SURENDRA K
    • C22B1/244C22B11/00
    • C21B13/0066C21B13/0006C21B13/008C21B13/04C21C2007/0031C22B1/244C22B1/245C22B5/10Y02P10/136Y02P10/216
    • To produce metallic iron from iron ore, a composition comprising a mass of material formed from a mixture of iron ore particles and particles of a reductant that is either a biomass material in particulate form or a plastic resinous material in particulate form is used. The reductant can also be a mixture of biomass material and resin in any proportions. The mass of material comprises at least one body having a shape adapted for smelting such as pellets, briquettes, pieces or lumps. The pellets have sufficient cohesion to maintain the shape into which they have been formed. The invention also provides a new method for smelting iron from its ore which comprises subdividing the ore into particles of a selected size, mixing the subdivided ore particles with particles of a biomass material or particles of a plastic resinous material or with mixtures thereof, forming a mass of the mixture into at least one body with a shape that is suited for smelting in a furnace and placing the body in a furnace and exposing it to sufficient heat to bring the iron therein to smelting temperature within the furnace to thereby produce metallic iron directly from the ore.
    • 为了从铁矿石生产金属铁,使用包含由铁矿石颗粒和作为颗粒形式的生物质材料或颗粒形式的塑性树脂材料的还原剂颗粒的混合物形成的大量材料的组合物。 还原剂也可以是任何比例的生物质材料和树脂的混合物。 材料块包括具有适于熔炼的形状的至少一个主体,例如丸粒,煤饼,块或团块。 颗粒具有足够的内聚力来维持它们形成的形状。 本发明还提供了一种从其矿石中冶炼铁的新方法,其包括将矿石细分成选定尺寸的颗粒,将细分矿石颗粒与生物质材料颗粒或塑性树脂材料颗粒或其混合物混合,形成 将所述混合物的质量转换成适合于在炉中熔炼并将所述炉体置于熔炉中并将其暴露于足够的热量以使其中的所述熔炼炉内的所述熔炼炉内的熔炼温度由此直接生产金属铁的形状的至少一个本体 来自矿石。
    • 6. 发明申请
    • PRODUCTION OF IRON USING ENVIRONMENTALLY-BENIGN RENEWABLE OR RECYCLED REDUCING AGENT
    • 使用环境可再生能源或回收还原剂生产铁
    • WO2007108984A2
    • 2007-09-27
    • PCT/US2007006175
    • 2007-03-12
    • UNIV MICHIGAN TECH
    • EISELE TIMOTHY CKAWATRA SURENDRA K
    • C21C7/04
    • C21B13/0066C21B13/0006C21B13/008C21B13/04C21C2007/0031C22B1/244C22B1/245C22B5/10Y02P10/136Y02P10/216
    • To produce metallic iron from iron ore, a composition comprising a mass of material formed from a mixture of iron ore particles and particles of a reductant that is either a biomass material in particulate form or a plastic resinous material in particulate form is used. The reductant can also be a mixture of biomass material and resin in any proportions. The mass of material comprises at least one body having a shape adapted for smelting such as pellets, briquettes, pieces or lumps. The pellets have sufficient cohesion to maintain the shape into which they have been formed. The invention also provides a new method for smelting iron from its ore which comprises subdividing the ore into particles of a selected size, mixing the subdivided ore particles with particles of a biomass material or particles of a plastic resinous material or with mixtures thereof, forming a mass of the mixture into at least one body with a shape that is suited for smelting in a furnace and placing the body in a furnace and exposing it to sufficient heat to bring the iron therein to smelting temperature within the furnace to thereby produce metallic iron directly from the ore.
    • 为了从铁矿石生产金属铁,使用包含由铁矿石颗粒和作为颗粒形式的生物质材料的还原剂颗粒或颗粒形式的塑料树脂材料的混合物的混合物形成的大量材料的组合物。 还原剂也可以是任何比例的生物质材料和树脂的混合物。 材料的质量包括至少一个具有适于冶炼的形状的主体,例如颗粒,团块,块或块。 颗粒具有足够的内聚力以保持它们已经形成的形状。 本发明还提供了一种从其矿石中熔炼铁的新方法,其中包括将矿石细分成选定尺寸的颗粒,将细分矿石颗粒与生物质材料或塑料树脂材料颗粒或其混合物混合,形成 混合物的质量至少一个具有适于在炉中冶炼的形状并将本体放置在炉中并使其暴露于足够的热量以将铁中的铁熔化到炉内的熔炼温度的至少一个主体中,从而直接产生金属铁 从矿石。
    • 8. 发明申请
    • METHOD AND APPARATUS FOR REMOVING UNDESIRABLE METALS FROM IRON-CONTAINING MATERIALS
    • 从含铁材料中去除不可燃金属的方法和装置
    • WO00050649A2
    • 2000-08-31
    • PCT/IB2000/000379
    • 2000-02-23
    • C21B13/00C21B13/04C22B1/24C22B5/12C22B7/02C22B19/30C21D
    • C22B1/2406C21B13/0046C21B13/04C22B5/12C22B7/02C22B19/30Y02P10/122Y02P10/136Y02P10/216
    • The present invention relates to a method and apparatus for separating undesired toxic metals, such as Zn, Pb and Cd, from iron-containing materials by: sintering a mixture of such materials (typically including EAF dust and mill scale) with carbonaceous particles to form sturdy sinter lumps; preheating such lumps in a non-reducing atmosphere, if needed, to achieve an elevated temperature generally above the vaporization temperature of the undesired metals, but below the sticking temperature of said iron-containing lumps (which is typically below the vaporization temperatures of such undesired metals in their oxide form), feeding the lumps at such elevated temperature into a reduction reactor; flowing hot reducing gas through said lumps to volatilize said undesired reduced metals and carry the volatilized metals out of said reduction reactor leaving the iron-containing lumps largely stripped of the undesired metals and ready for discharge and safe and/or useful disposal or re-use, and finally cooling the off gas from the reactor to separate out the resulting solidified unwanted metals (typically in their oxide form resulting from a water quench cooling).
    • 本发明涉及通过以下方法从铁含量分离不需要的有毒金属如Zn,Pb和Cd的方法和装置:将这种材料(通常包括EAF粉尘和磨尺)的混合物与碳质颗粒烧结以形成 坚固的烧结块; 如果需要,在非还原性气氛中预热这样的块,以达到通常高于不需要的金属的蒸发温度但低于所述含铁块的粘附温度的升高温度(其通常低于这种不希望的金属的汽化温度 以其氧化物形式的金属),将这些升高的温度的块体送入还原反应器中; 流过热还原气体通过所述块状物以挥发所述不期望的还原金属并将挥发的金属从所述还原反应器中排出,留下含铁块大部分剥离不需要的金属并准备排出,并且安全和/或有用的处理或再利用 ,并最终冷却来自反应器的废气以分离所得到的固化的不需要的金属(通常以由水淬火冷却得到的氧化物形式)。
    • 9. 发明申请
    • DEVICE AND METHOD FOR THE DIRECT REDUCTION OF IRON OXIDES
    • 直接还原铁氧化物的装置和方法
    • WO00036157A1
    • 2000-06-22
    • PCT/IB1999/001941
    • 1999-12-06
    • C21B13/02C21B13/04
    • C21B13/04C21B13/02C21B2100/22Y02P10/136
    • Device and method for the direct reduction of iron oxides, comprising a reactor defining in its middle-upper part a reduction zone (110) inside which the reaction takes place, means (15) to introduce the load from above the reactor, means to introduce the gassy current into at least a section of the reactor in correspondence with the reduction zone (110), means to remove the reduced material, and means (20) to discharge the exhaust fumes, the reactor including an upper mouth (12) communicating with said reduction zone (110) for the introduction of the mineral iron and a lower aperture (13) through which the reduced iron exits, wherein said reduction zone (110) has a truncated cone conformation tapering downwards.
    • 用于直接还原铁氧化物的装置和方法,包括反应器,其中部在其中间部分限定发生反应的还原区(110),用于从反应器上方引入负载的装置(15) 与还原区(110)相对应的至少一部分反应器的气流,用于去除还原材料的装置,以及用于排出废气的装置(20),所述反应器包括与所述还原区(110)连通的上口(12) 用于引入矿物铁的所述还原区(110)和还原铁离开的下孔(13),其中所述还原区(110)具有向下锥形的截锥形构造。