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    • 9. 发明申请
    • AQUEOUS DISPERSIONS OF ORGANOPOLYSILOXANES
    • 有机聚硅氧烷的水分散体
    • WO1996037556A1
    • 1996-11-28
    • PCT/EP1996002227
    • 1996-05-23
    • WACKER-CHEMIE GMBHOBERNEDER, StefanBRAUNSPERGER, KarlHEINRICH, AlfredBRAUN, RudolfSOELLRADL, Herbert
    • WACKER-CHEMIE GMBH
    • C08L83/04
    • C09K3/1018B01F17/0071C08G77/14C08G77/16C08G77/18C08G77/20C08G77/24C08G77/26C08G77/28C08G77/46C08L83/04C09D183/04Y10S528/901C08L2666/44C08L83/00
    • Aqueous dispersions organopolysiloxanes which are free of organic transition metal compounds and of organic compounds of the metals of the main groups III, IV and V. These dispersions can be produced using the following starting compounds: (A) organopolysiloxane containing condensation-capable groups; (B) an organosilicon compound of the formula (II) {[(RO)3Si-R -]e R 1-e}aSi(OR)4-a, in which R can be identical or different and stands for a hydrogen atom or alkyl group with 1-6 carbon atoms, R can be identical or different and stands for SiC bonded hydrocarbon groups with 1-18 carbon atoms which are optionally substituted with halogen atoms, ether groups, ester groups, epoxy groups, mercapto groups, cyano groups or (poly)glycol groups, the latter being formed from oxyethylene- and/or oxypropylene units, and R can be identical or different and stands for bivalent hydrocarbon groups; a is 0 or 1, e is 0 or 1; and/or partial hydrolysates of the organosilicon compound with at most 8 Si-atoms; and (C) an organosilicon compound containing basic nitrogen.
    • 其不含选自有机过渡金属化合物和III,IV。,V.主族的金属的有机化合物的有机聚硅氧烷的水分散体使用含有可缩合基团,有机聚硅氧烷,(B)下式的有机硅化合物的起始物质(A)(ii)制备{[ (RO)3SI-R <3> - ]ë[R <2> 1-E}的aSi(OR)4-A,其中R可以相同或不同,并且是氢原子或具有碳原子数为1〜6的烷基,R <2> 可以是相同的或不同的,并且SiC键合的碳原子数为1〜18的烃基,任选地被卤素原子,醚基,酯基,环氧基,巯基,氰基或(聚)取代的二元醇的基团被取代,后者是氧化乙烯和/或氧化丙烯单元组成的, 且R <3>可以相同或不同,是二价烃基残基; a为0或1,e为0或1,和/或它们的最多具有8个Si原子,和(C)碱性氮的有机硅化合物的部分水解产物。