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1. 发明申请

WO2010112372A3 MEMBRANES BASED ON POLYVINYL ALCOHOL 审中-公开
标题翻译：基于聚乙烯醇滤膜
公开(公告)号：WO2010112372A3
公开(公告)日：2010-11-25
申请号：PCT/EP2010053756
申请日：2010-03-23
申请人： WACKER CHEMIE AG , HOELZL MANFRED , BORTENSCHLAGER MARTIN , HECHER SUSANNE , SCHAUER FELICITAS
发明人： HOELZL MANFRED , BORTENSCHLAGER MARTIN , HECHER SUSANNE , SCHAUER FELICITAS
IPC分类号： C08F216/08 , B01D71/38
CPC分类号： C08F216/08 , B01D61/362 , B01D67/0006 , B01D71/38 , B01D71/70 , B01D2323/30 , C08F230/08
摘要： The invention relates to the use of silane-modified polyvinyl alcohols for producing membranes, characterized in that the silane-modified polyvinyl alcohols can be obtained by a) radically initiated copolymerization of one or more vinyl esters from unbranched or branched carboxylic acids having 1 to 15 C-atoms and one or more ethylenically unsaturated silane compounds selected from the group comprising compounds of the general formulae CR2=CR-B-Si(OR')3-n (R' ')n (1), or CR2=CRC (=0) -D-B-Si (OR')3-n (R' ')n (2), wherein B is an aryl, heteroaryl or (CR2) m residue, wherein one or more non-neighboring CR2 groups can be replaced by heteroatoms as applicable, D is a heteroatom, R is a hydrogen atom, an alkyl or aryl residue or a heteroatom that is substituted as applicable by a hydrogen atom or an alkyl, aryl residue, OR' is an alkoxy, alkylcarboxy or arylcarboxy residue, R' ' is an alkyl or aryl residue and n 0, 1 or 2 and in 0 to 15, and b) subsequent saponification of the silane-modified vinyl ester copolymerisate obtained in step a).
摘要翻译：本发明涉及使用硅烷改性的聚乙烯醇的用于生产膜，其特征在于，所述硅烷改性的聚乙烯醇可具有1至15个碳原子通过的无支链的一种或多种乙烯基酯的）共聚发起或支链羧酸和从包括通式I的化合物的组中的一种或多种烯键式不饱和硅烷化合物CR2 = CR-B-的Si（OR '）3-N（R'“）N（1），或CR 2 = CRC（= 0） -DB-的Si（OR '）3-N（R'“）N（2）其中B是芳基，杂芳基或（CR 2）M-基团，其中任选的一个或多个非相邻的CR2基团通过杂原子可以被替换，D是杂原子，R表示氢原子，烷基或芳基，或任选被氢原子或烷基取代的杂原子，芳基，OR“是烷氧基，烷基羧基 - 或Arylcarboxy- 基团，R“”是烷基或芳基，并且n是0,1或2和平均0至15，和b）在所述步骤a）获得的硅烷 - 改性的乙烯酯共聚物的皂化之后。

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