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    • 3. 发明申请
    • OXYGENATE CONVERSION TO OLEFINS WITH METATHESIS
    • 氧化物转化为具有METATHESIS的油脂
    • WO2008076675A1
    • 2008-06-26
    • PCT/US2007/086860
    • 2007-12-07
    • UOP LLCBOZZANO, Andrea, G.GLOVER, Bryan, K.
    • BOZZANO, Andrea, G.GLOVER, Bryan, K.
    • C07C6/04C07C11/06
    • C07C11/06C07C1/20C07C6/04Y02P30/42C07C11/02
    • Processing schemes and systems (10, 100, 200, 300, 400) for enhanced light olefin production, particularly for increased relative yield of propylene, involve oxygenate conversion to olefins and subsequent oxygenate conversion effluent stream treatment including cross metathesis of 1-butene with 2-butene, metathesis of 2-butene with ethylene, conversion or removal of at least a portion of the isobutene, and/or isomerization of at least a portion of 1-butene to 2- butene to produce additional propylene. The processing schemes and systems (10, 100, 200, 300, 400) may further involve a reaction with distillation column (162) for the metathesis of butenes with ethylene to produce propylene and/or a reaction with distillation column for the conversion of isobutenes with an oxygenate containing material to produce a tertiary ether or alcohol.
    • 用于增强轻烯烃生产的加工方案和系统(10,100,200,300,400),特别是用于增加丙烯的相对产率,涉及含氧化合物转化为烯烃和随后的含氧化合物转化流出物流处理,包括1-丁烯与2的交叉复分解 丁烯,2-丁烯与乙烯的复分解,至少一部分异丁烯的转化或除去,和/或至少一部分1-丁烯异构化成2-丁烯以产生另外的丙烯。 处理方案和系统(10,100,200,300,400)还可以包括与蒸馏塔(162)的反应,用于使乙烯与乙烯进行复分解以产生丙烯和/或与蒸馏塔反应以使异丁烯转化 含有含氧化合物的物质产生叔醚或醇。