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    • 1. 发明申请
    • VERTICALLY ALIGNED CARBON NANOTUBE ARRAYS AS ELECTRODES
    • 垂直排列的碳纳米管阵列作为电极
    • WO2017011052A3
    • 2017-02-23
    • PCT/US2016029184
    • 2016-04-25
    • UNIV RICE WILLIAM M
    • TOUR JAMES MRAJI ABDUL-RAHMAN OSALVATIERRA RODRIGO V
    • H01J1/63H01J17/49H01J63/04
    • H01M10/0525H01G11/06H01G11/28H01G11/36H01G11/68H01G11/86H01M4/045H01M4/587H01M4/625H01M4/66H01M4/661H01M4/663Y02E60/13
    • Embodiments of the present disclosure pertain to electrodes that include a plurality of vertically aligned carbon nanotubes and a metal associated with the vertically aligned carbon nanotubes. The vertically aligned carbon nanotubes may be in the form of a graphene-carbon nanotube hybrid material that includes a graphene film covalently linked to the vertically aligned carbon nanotubes. The metal may become reversibly associated with the carbon nanotubes in situ during electrode operation and lack any dendrites or mossy aggregates. The metal may be in the form of a non-dendritic or non-mossy coating on surfaces of the vertically aligned carbon nanotubes. The metal may also be infiltrated within bundles of the vertically aligned carbon nanotubes. Additional embodiments pertain to energy storage devices that contain the electrodes of the present disclosure. Further embodiments pertain to methods of forming said electrodes by applying a metal to a plurality of vertically aligned carbon nanotubes.
    • 本公开的实施例涉及包括多个垂直排列的碳纳米管和与垂直排列的碳纳米管相关联的金属的电极。 垂直排列的碳纳米管可以是石墨烯 - 碳纳米管混合材料的形式,其包括与垂直排列的碳纳米管共价连接的石墨烯膜。 在电极操作过程中,金属可能与碳纳米管原位可逆地结合,并且缺乏任何树突或苔状聚集体。 金属可以在垂直排列的碳纳米管的表面上呈非树枝状或非苔藓状涂层的形式。 金属也可以渗入垂直排列的碳纳米管束内。 另外的实施例涉及包含本公开的电极的能量存储装置。 其他实施例涉及通过将金属施加到多个垂直排列的碳纳米管来形成所述电极的方法。