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    • 7. 发明申请
    • METHOD OF MANUFACTURING PROTON-CONDUCTING MEMBRANES
    • 制造质子传导膜的方法
    • WO2011089521A3
    • 2011-10-27
    • PCT/IB2011000102
    • 2011-01-24
    • UNIV RAMOTPELED EMANUELBLUM ARNONAHARON ADI
    • PELED EMANUELBLUM ARNONAHARON ADI
    • H01M8/10
    • H01M4/96H01M4/9083H01M4/921H01M4/926H01M8/0202H01M8/0258H01M8/0271H01M8/186Y02E60/50Y02E60/521Y02E60/528Y02P70/56Y10T307/685
    • A process for producing proton-conducting membrane, the process comprising: mixing (i) 5% to 60% by volume of an electrically nonconductive inorganic powder having a good acid absorption capacity, the powder comprising essentially nanosize particles; (ii) 5% to 50% by volume of a polymeric binder that is chemically compatible with acid, oxygen and the fuel; and (iii) 10 to 90% by volume of an acid or aqueous acid solution, wherein the mixing is conducted at various rate steps, thereby producing a proton-conducting mixture; continuously casting the proton-conducting mixture on rolled paper, non-woven matrix or the like at ambient temperature; drying the casted proton-conducting mixture at a temperature of greater than 1000C for approximately 5 to 30 minutes, thereby forming a dry film; and laminating a plurality of the dry films together under pressure, and thereafter extracting pore- former out of pores of the dry films, thereby forming the proton-conducting membrane having an average pore size of less than 30 nanometers.
    • 一种生产质子传导膜的方法,该方法包括:混合(i)5%至60%体积的具有良好酸吸收能力的不导电无机粉末,该粉末基本上包含纳米尺寸颗粒; (ii)5体积%至50体积%的与酸,氧和燃料化学相容的聚合物粘合剂; 和(iii)10至90体积%的酸或酸水溶液,其中以各种速率步骤进行混合,由此产生质子传导混合物; 在环境温度下将质子导电混合物连续铸造在卷纸,无纺布基体等上; 在大于1000℃的温度下干燥铸造的导质子混合物大约5-30分钟,从而形成干膜; 在压力下将多个干膜层压在一起,然后从干膜的孔隙中提取成孔剂,从而形成平均孔径小于30纳米的质子传导膜。