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1. 发明申请

WO2007120173A3 N-HALAMINE/QUATERNARY AMMONIUM POLYSILOXANE COPOLYMERS 审中-公开
标题翻译： N-山梨糖醇/季铵盐聚对苯二甲酸乙二醇酯共聚物
公开(公告)号：WO2007120173A3
公开(公告)日：2008-08-28
申请号：PCT/US2006030909
申请日：2006-08-08
申请人： UNIV AUBURN , WORLEY SHELBY D , CHEN YONGJUN , LIANG JIE , BARNES PAUL KEVIN
发明人： WORLEY SHELBY D , CHEN YONGJUN , LIANG JIE , BARNES PAUL KEVIN
IPC分类号： C07D233/00
CPC分类号： C08G77/388 , C08G77/26 , C08G77/452 , C09D183/10
摘要： Precursor N-halamine/quaternary ammonium random copolymers which are soluble in water for the purpose of functionalizing surfaces or materials so as to render them biocidal upon exposure to oxidative halogen solutions. The biocidal function can be imparted to the precursor N-halamine moiety either before or after siloxane bonding or adhesion to the surface or material. The biocidal surfaces and materials can then be used to inactivate pathogenic microorganisms such as bacteria, fungi, and yeasts, as well as virus particles, that can cause infectious diseases and those microorganisms that cause noxious odors and unpleasant coloring such as mildew. Examples of surfaces and materials which can be rendered biocidal include, but are not limited to, cellulose, chitin, chitosan, synthetic fibers, glass, ceramics, plastics, rubber, cement grout, latex caulk, porcelain, acrylic films, vinyl, polyurethanes, silicon tubing, marble, metals, metal oxides, and silica.
摘要翻译：前体N-卤代胺/季铵无规共聚物，其可溶于水以使表面或材料功能化，以便在暴露于氧化性卤素溶液时使其具有杀菌活性。在硅氧烷键合或粘附到表面或材料之前或之后，可将杀生物功能赋予前体N-卤胺部分。然后杀生物表面和材料可用于灭活致病微生物，如细菌，真菌和酵母，以及病毒颗粒，其可引起感染性疾病，以及引起有害气味和不愉快着色如微生物的微生物。具有杀菌功能的表面和材料的实例包括但不限于纤维素，壳多糖，壳聚糖，合成纤维，玻璃，陶瓷，塑料，橡胶，水泥浆，乳胶填料，瓷，丙烯酸膜，乙烯基，聚氨酯，硅胶管，大理石，金属，金属氧化物和二氧化硅。

2. 发明申请

WO2005058814A2 BIOCIDAL SILOXANE COATING MATERIAL CONTAINING N-HALOGENATED AMINE AND AMIDE FUNCTIONAL GROUPS 审中-公开
标题翻译：含有N-羟基化胺和酰胺官能团的生物硅氧烷涂料
公开(公告)号：WO2005058814A2
公开(公告)日：2005-06-30
申请号：PCT/US2004038558
申请日：2004-11-17
申请人： UNIV AUBURN , WORLEY SHELBY D , CHEN YONGJUN , LIANG JIE , WU RONG , BARNES KEVIN , BROUGHTON ROYALL M , CHO UNCHIN , LEE JAEWOONG
发明人： WORLEY SHELBY D , CHEN YONGJUN , LIANG JIE , WU RONG , BARNES KEVIN , BROUGHTON ROYALL M , CHO UNCHIN , LEE JAEWOONG
IPC分类号： A61K31/785 , C07D20060101 , C07D487/10 , C07F7/02 , C07F7/18 , D06M13/325 , D06M15/643 , D06M16/00 , C07D
CPC分类号： D06M13/325 , C07D487/10 , C07F7/1836 , D06M13/352 , D06M13/355 , D06M13/513 , D06M15/6436 , D06M16/00
摘要： N-halamine compounds which contain hindered amine and amide functional groups. Compounds include structure (TTDD); wherein X, X', and X'' independently are H, CI, or Br, wherein no more than two of X, X', and X'' are H and structure (I) wherein R, R', and R'' are independently alkyl groups containing (1) to (4) carbon atoms or hydrogen, and X and X' are independently H, CI, or Br. Compositions comprising the compounds are also described. The compounds and/or compositions can be used, for example, for the purpose of constructing biocidal coatings and materials. The biocidal activity can inactivate pathogenic microorganisms such as bacteria, fungi, and yeasts, as well as, virus particles, which can cause infectious diseases, and those microorganisms which cause noxious odors and unpleasant coloring, such as mildew.
摘要翻译：含有受阻胺和酰胺官能团的N-卤代胺化合物。化合物包括结构（TTDD）; 其中X，X'和X“独立地为H，Cl或Br，其中X，X'和X”中不超过2个为H，结构（I）其中R，R'和R' 独立地为含有（1） - （4）个碳原子的烷基或氢，X和X'独立地为H，Cl或Br。还描述了包含化合物的组合物。化合物和/或组合物可以用于例如用于构建杀生物剂的涂料和材料的目的。杀生物活性可以灭活细菌，真菌和酵母等致病微生物，以及可能引起传染病的病毒颗粒，以及引起有害气味和不愉快着色如微生物的微生物。

3. 发明申请

WO03053142A3 HIGHLY CROSSLINKED BIOCIDAL POLYSTYRENE HYDANTOIN PARTICLES 审中-公开
标题翻译：高度交联的生物聚苯乙烯HYDANTOIN颗粒
公开(公告)号：WO03053142A3
公开(公告)日：2003-10-16
申请号：PCT/US0227417
申请日：2002-08-26
申请人： UNIV AUBURN , WORLEY SHELBY D , CHEN YONGJUN
发明人： WORLEY SHELBY D , CHEN YONGJUN
IPC分类号： A61F13/49 , A01N59/00 , A61F13/15 , A61F13/472 , A61K31/785 , C08F8/30 , C08F8/44 , C08F257/02 , C08F265/10 , C08F267/10 , A01N43/76 , A61L15/46
CPC分类号： A01N59/00 , A61K31/785 , C08F257/02 , C08F265/10 , C08F267/10
摘要： Method for preparing biocidal halogenated polystyrene hydantoins. The biocidal polymers poly-1,3-dichloro-5-methyl-(4'-vinylphenyl)hydantoin, poly-1,3-dibromo-5-methyl-5-(4'-vinylphenyl)hydantoin, and their monohalogenated alkali metal salts and protonated derivatives have been prepared as porous beads by use of highly crosslinked polystyrene beads as starting materials. The porous beads will be useful in water and air disinfection applications when employed in cartridge filters and carafe (for water), as well as for controlling noxious odor when mixed with absorbent materials in items such as disposable diapers, incontinence pads, bandages, sanitary napkins, pantiliners, mattress covers, shoe inserts, sponges, animal litter, carpets, fabrics, and air filters or the like.
摘要翻译：杀生物卤化聚苯乙烯乙内酰脲的制备方法聚-1,3-二氯-5-甲基 - （4'-乙烯基苯基）乙内酰脲，聚-1,3-二溴-5-甲基-5-（4'-乙烯基苯基）乙内酰脲及其单卤代碱金属盐和质子化衍生物已经通过使用高度交联的聚苯乙烯珠作为起始材料制备为多孔珠粒。当用于滤筒过滤器和瓶盖（用于水）时，多孔珠可用于水和空气消毒应用，以及用于在与诸如一次性尿布，失禁垫，绷带，卫生巾等物品中的吸收材料混合时控制有害气味内裤衬垫，床垫套，鞋垫，海绵，动物垃圾，地毯，织物和空气过滤器等。

4. 发明申请

WO2004040978A2 BIOCIDAL PARTICLES OF METHYLATED POLYSTYRENE 审中-公开
标题翻译：甲基化聚苯乙烯的杀菌颗粒
公开(公告)号：WO2004040978A2
公开(公告)日：2004-05-21
申请号：PCT/US0334298
申请日：2003-10-30
申请人： UNIV AUBURN , WORLEY SHELBY D , CHEN YONGJUN
发明人： WORLEY SHELBY D , CHEN YONGJUN
IPC分类号： A01N59/00 , C08F8/00 , A01N25/00
CPC分类号： A01N59/00 , C08F8/30 , C08F8/24 , C08F112/08
摘要： Methylated polystyrene having pendant N-halamine and N-halamine precursor groups. Biocidal particles have been prepared by reacting highly crosslinked methylated polystyrene beads as starting materials with various N-halamine precursor compounds. The resulting polymer beads are halogenated with chlorine or bromine. The porous beads will be useful in disinfection applications, as well as for sanitization and controlling noxious odor when mixed with absorbent materials in items such as disposable diapers, infant swimwear, incontinence pads, bandages, sanitary napkins, pantiliners, mattress covers, shoe inserts, sponges, animal litter, carpets, and fabrics.
摘要翻译：具有侧链N-卤胺和N-卤素前体基团的甲基化聚苯乙烯。已经通过使高度交联的甲基化聚苯乙烯珠粒作为起始材料与各种N-卤胺前体化合物反应来制备杀生物粒子。所得聚合物珠粒用氯或溴卤化。多孔珠粒在消毒应用中是有用的，并且当与诸如一次性尿布，婴儿游泳衣，失禁垫，绷带，卫生巾，内裤衬垫，床垫罩，鞋插入物等物品中的吸收材料混合时用于消毒和控制有害气味。海绵，动物垃圾，地毯和织物。

5. 发明申请

WO0206579A3 BIOCIDAL POLYAMIDES AND METHODS 审中-公开
标题翻译：生物聚酰胺和方法
公开(公告)号：WO0206579A3
公开(公告)日：2002-05-16
申请号：PCT/US0119219
申请日：2001-06-15
申请人： UNIV AUBURN , LIN JIAN , WORLEY SHELBY D , BROUGHTON ROYALL M
发明人： LIN JIAN , WORLEY SHELBY D , BROUGHTON ROYALL M
IPC分类号： A01N25/10 , A01N59/00 , D06M11/09 , D06M13/127 , D06M13/35 , D06M13/352 , D06M13/355 , D06M13/358 , D06M13/364 , D06M16/00
CPC分类号： D06M16/00 , A01N25/10 , A01N59/00 , D06M11/09 , D06M13/127 , D06M13/35 , D06M13/352 , D06M13/355 , D06M13/358 , D06M13/364 , D06M2101/34 , D06M2101/36 , A01N25/34 , A01N2300/00
摘要： Biocidal polyamide materials such as deodorant and/or biocidal Nylon3 polyamide fibers, fabrics and surfaces and biocidal Aramid (such as Kevlar3 and Nomex3) fibers, fabrics and surfaces, and methods of preparation. Heterocyclic N-halamine precursor moieties are covalently linked to the polyamide material. The fabrics and/or fibers thereafter obtain antimicrobial activity after washing with a halogenated solution to convert the heterocyclic precursor moieties into heterocyclic N-halamines. The antimicrobial activity against pathogenic microorganism can be repeatedly regenerated by washings with a halogenated solution.
摘要翻译：杀生物聚酰胺材料如除臭和/或杀生物尼龙3聚酰胺纤维，织物和表面和杀生物芳族聚酰胺（如Kevlar3和Nomex3）纤维，织物和表面以及制备方法。杂环N-卤胺前体部分与聚酰胺材料共价连接。然后织物和/或纤维在用卤化溶液洗涤后获得抗微生物活性，以将杂环前体部分转化为杂环N-卤胺。抗病原微生物的抗微生物活性可以通过用卤化溶液的洗涤反复再生。

6. 发明申请

WO0230477A8 USE OF N-HALAMINE BIOCIDAL POLYMER FOR ODOR CONTROL 审中-公开
标题翻译： N-HALAMINE BIOCIDAL POLYMER用于气味控制的应用
公开(公告)号：WO0230477A8
公开(公告)日：2002-09-06
申请号：PCT/US0131641
申请日：2001-10-09
申请人： UNIV AUBURN , HALOSOURCE CORP
发明人： WORLEY SHELBY D , BROUGHTON ROYALL M , WILLIAMS JEFFREY F
IPC分类号： A01N59/00 , A61L2/00 , A61L9/014 , A61L9/00 , A61L9/01 , A61L9/04 , A61L11/00
CPC分类号： A61L9/014 , A01N59/00 , A61L2/0082 , Y10T442/2525 , A01N25/34 , A01N25/10 , A01N2300/00
摘要： The present invention is a method of using a polymeric N-halamine biocidal material as an agent preferably used in conjunction with a matrix material for the reduction of noxious odors caused by the decomposition of organic compounds. In a preferred embodiment of the method according to the present invention, the biocidal N-halamine polymer is provided in a comminuted form and mixed with super absorbent polymer to provide a treatment composition. The treatment composition is emplaced within an article to provide intimate contact between the composition and a microorganism-containing fluid. The fluid is absorbed by the super absorbent polymer thereby providing a surface for the biocidal polymer to contact the microorganism.
摘要翻译：本发明是一种使用聚合N-卤胺杀生物材料作为优选与基质材料结合使用以减少由有机化合物分解引起的有害气味的试剂的方法。在根据本发明的方法的优选实施方案中，杀生物N-卤代胺聚合物以粉碎形式提供并与高吸收性聚合物混合以提供处理组合物。处理组合物置于制品内以提供组合物和含微生物的流体之间的紧密接触。流体被高吸收性聚合物吸收，从而提供杀生物聚合物与微生物接触的表面。

7. 发明申请

WO0230477B1 USE OF N-HALAMINE BIOCIDAL POLYMER FOR ODOR CONTROL 审中-公开
标题翻译： N-胺盐杀菌聚合物在气味控制中的应用
公开(公告)号：WO0230477B1
公开(公告)日：2002-07-04
申请号：PCT/US0131641
申请日：2001-10-09
申请人： UNIV AUBURN , HALOSOURCE CORP
发明人： WORLEY SHELBY D , BROUGHTON ROYALL M , WILLIAMS JEFFREY F
IPC分类号： A01N59/00 , A61L2/00 , A61L9/014 , A61L9/00 , A61L9/01 , A61L9/04 , A61L11/00
CPC分类号： A61L9/014 , A01N59/00 , A61L2/0082 , Y10T442/2525 , A01N25/34 , A01N25/10 , A01N2300/00
摘要： The present invention is a method of using a polymeric N-halamine biocidal material as an agent preferably used in conjunction with a matrix material for the reduction of noxious odors caused by the decomposition of organic compounds. In a preferred embodiment of the method according to the present invention, the biocidal N-halamine polymer is provided in a comminuted form and mixed with super absorbent polymer to provide a treatment composition. The treatment composition is emplaced within an article to provide intimate contact between the composition and a microorganism-containing fluid. The fluid is absorbed by the super absorbent polymer thereby providing a surface for the biocidal polymer to contact the microorganism.
摘要翻译：本发明是一种使用聚合N-卤胺杀生物材料作为优选与基质材料一起使用的试剂以减少有机化合物分解引起的有害气味的方法。在根据本发明的方法的优选实施方案中，杀生物N-卤胺聚合物以粉碎形式提供并与超吸收聚合物混合以提供处理组合物。处理组合物被放置在制品内以提供组合物和含微生物的流体之间的紧密接触。流体被超吸收性聚合物吸收，从而为杀生物聚合物提供接触微生物的表面。

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