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1. 发明申请

WO2013017496A1 USE OF A CATALYST COMPRISING A PHOSPHORUS MODIFIED ZEOLITE IN AN ALCOHOL DEHYDRATION PROCESS 审中-公开
标题翻译：在酒精脱水过程中使用包含磷酸改性沸石的催化剂
公开(公告)号：WO2013017496A1
公开(公告)日：2013-02-07
申请号：PCT/EP2012/064579
申请日：2012-07-25
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY , IFP Energies nouvelles , NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre , LOPEZ, Joseph , EUZEN, Patrick
发明人： NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre , LOPEZ, Joseph , EUZEN, Patrick
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
CPC分类号： C07C1/24 , B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C2527/14 , C07C2529/06 , C07C2529/40 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： The present invention relates, in a first embodiment, to the use of a catalyst to convert at least an alcohol into light olefins in a dehydration process to make an olefin having the same number of carbon atoms as the alcohol wherein said catalyst comprises a phosphorus modified zeolite and is made by a method comprising the following steps in this order, a) providing a zeolite comprising at least one ten members ring in the structure, optionally steaming said zeolite, b) mixing said zeolite of step a) with at least a component selected among one or more binders and shaping additives, then shaping said mixture, c) optionally making a ion-exchange, d) optionally steaming the shaped catalyst, optionally before step c), at least among said steaming of step d) and the steaming of step a) one is mandatory, e) introducing phosphorus on the catalyst to introduce at least 0.1 wt% of phosphorus, said introduction being made by dry impregnation or chemical vapor deposition, f) optionally introducing a metal, optionally simultaneously with step e), g) optionally washing the catalyst, h) optionally calcinating the catalyst, i) steaming the catalyst, also referred to as the equilibration step. In a second embodiment phosphorus can be introduced by any means and at step i) the steaming severity (X) is at least about 2. In said second embodiment the catalyst is advantageously steamed at a temperature above 625°C, preferably in the range 700 to 800°C. The metal of step f) is advantageously Calcium.
摘要翻译：在第一个实施方案中，本发明涉及在脱水方法中使用催化剂将至少一种醇转化为轻质烯烃，以制备具有与醇相同数目的碳原子的烯烃，其中所述催化剂包含磷改性沸石，并且通过包括以下步骤的方法制备：a）提供在该结构中包含至少一个十元环的沸石，任选地蒸汽所述沸石，b）将步骤a）的所述沸石与至少一种组分选自一种或多种粘合剂和成型添加剂，然后成型所述混合物，c）任选地进行离子交换，d）任选地在步骤c）之前蒸汽成型催化剂，至少在步骤d）的蒸汽和蒸的步骤a）一个是强制性的，e）在催化剂上引入磷以引入至少0.1重量％的磷，所述引入通过干浸渍或化学气相沉积制成，f）任选地引入任选地与步骤e）同时处理金属，g）任选地洗涤催化剂，h）任选地煅烧催化剂，i）蒸煮催化剂，也称为平衡步骤。在第二个实施方案中，磷可以通过任何方式引入，并且步骤i）蒸汽的苛刻度（X）至少约为2.在所述第二实施方案中，有利地，催化剂在高于625℃，优选在700℃ 至800°C。步骤f）的金属有利地是钙。

2. 发明申请

WO2013017498A1 CATALYST COMPRISING A PHOSPHORUS MODIFIED ZEOLITE AND HAVING PARTLY AN ALPO STRUCTURE 审中-公开
标题翻译：包含磷改性沸石的催化剂，具有ALPO结构
公开(公告)号：WO2013017498A1
公开(公告)日：2013-02-07
申请号：PCT/EP2012/064581
申请日：2012-07-25
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY , NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
发明人： NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
CPC分类号： C07C2/66 , B01J29/40 , B01J29/405 , B01J29/7049 , B01J29/85 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/10 , B01J37/28 , B01J2229/16 , B01J2229/183 , B01J2229/186 , B01J2229/36 , B01J2229/37 , B01J2229/40 , B01J2229/42 , C07C1/24 , C07C2/864 , C07C4/06 , C07C2529/40 , C07C2529/70 , C07C2529/80 , C07C2529/83 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： The present invention relates to a catalyst comprising a phosphorus modified zeolite, said phosphorus modified zeolite having partly an ALPOstructure, wherein, the catalyst comprises a P-modified zeolite and a binder, the zeolite comprises at least one ten members ring in the structure, optionally the catalyst comprises one or more metal oxides, the ALPO structure is determined by a signal between 35-45 ppm in 27 Al MAS NMR spectrum. The present invention also relates to the use of the above catalyst wherein said catalyst is operated in presence of steam at high temperature. "high temperature" means above 300°C and up to 800°C. By way of example one can cite, the alcohol dehydration to convert at least an alcohol into the corresponding olefin, the olefin cracking to make lighter olefins, the MTO and the alkylation of aromatic compounds with olefins and/or alcohols to produce, by way of example, paraxylene, ethylbenzene, cumene etc.
摘要翻译：本发明涉及包含磷改性沸石的催化剂，所述磷改性沸石部分具有ALPO结构，其中催化剂包含P-改性沸石和粘合剂，所述沸石包含至少一个结构中的十元环，任选地催化剂包含一种或多种金属氧化物，ALPO结构由27 Al MAS NMR光谱中的35-45ppm之间的信号确定。本发明还涉及上述催化剂的用途，其中所述催化剂在高温蒸汽存在下操作。 “高温”是指高于300℃和高达800℃。举例来说，可以列举醇脱水以将至少一种醇转化为相应的烯烃，烯烃裂解以制备较轻烯烃，MTO和芳族化合物与烯烃和/或醇的烷基化反应以通过例如对二甲苯，乙苯，枯烯等

3. 发明申请

WO2013017497A1 METHOD FOR MAKING A CATALYST COMPRISING A PHOSPHORUS MODIFIED ZEOLITE AND USE OF SAID ZEOLITE 审中-公开
标题翻译：制备包含磷改性沸石的催化剂的方法和使用ZEOLITE
公开(公告)号：WO2013017497A1
公开(公告)日：2013-02-07
申请号：PCT/EP2012/064580
申请日：2012-07-25
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY , NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
发明人： NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
CPC分类号： B01J29/85 , B01J29/40 , B01J29/65 , B01J29/7023 , B01J29/7026 , B01J29/7038 , B01J29/7042 , B01J29/7046 , B01J37/0009 , B01J37/10 , B01J37/28 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C1/24 , C07C2/08 , C07C2/66 , C07C2/864 , C07C4/06 , C07C2521/08 , C07C2527/14 , C07C2529/40 , C07C2529/65 , C10G3/49 , C10G29/205 , C10G29/22 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/46 , C07C15/08
摘要： The present invention relates, in a first embodiment, to a method to make a phosphorus modified zeolite comprising the following steps in this order, a) providing a zeolite comprising at least one ten members ring in the structure, optionally steaming said zeolite, b) mixing said zeolite of step a) with at least a component selected among one or more binders and shaping additives, then shaping said mixture, c) optionally making a ion-exchange, d) optionally steaming the shaped catalyst, optionally before step c), at least among said steaming of step d) and the steaming of step a) one is mandatory, e) introducing phosphorus on the catalyst to introduce at least 0.1 wt% of phosphorus, said introduction being made by dry impregnation or chemical vapor deposition, f) introducing a metal, optionally simultaneously with step e), g) optionally washing the catalyst, h) optionally calcinating the catalyst, i) steaming the catalyst, also referred to as the equilibration step. In a second embodiment phosphorus can be introduced by any means and at step i) the steaming severity (X) is at least about 2. In said second embodiment the catalyst is advantageously steamed at a temperature above 625°C, preferably in the range 700 to 800°C. The metal of step f) is advantageously Calcium. The present invention also relates to the use said catalyst in the alcohol dehydration, the olefin cracking to make lighter olefins, the MTO and the alkylation of aromatics by alcohols with olefins and/or alcohols.
摘要翻译：在第一个实施方案中，本发明涉及一种制备磷改性沸石的方法，该方法包括以下步骤：a）提供在该结构中包含至少一个十元环的沸石，任选地蒸煮所述沸石，b）将步骤a）的所述沸石与至少一种选自一种或多种粘合剂和成型添加剂的组分混合，然后将所述混合物成形，c）任选地进行离子交换，d）任选地在步骤c）之前蒸汽成型催化剂，至少在步骤d）的蒸汽和步骤a）的蒸汽中，一个是强制性的，e）在催化剂上引入磷以引入至少0.1重量％的磷，所述引入通过干浸渍或化学气相沉积，f ）任选地与步骤e）同时引入金属，g）任选地洗涤催化剂，h）任选地煅烧催化剂，i）蒸煮催化剂，也称为平衡步骤。在第二个实施方案中，磷可以通过任何方式引入，并且步骤i）蒸汽的苛刻度（X）至少约为2.在所述第二实施方案中，有利地，催化剂在高于625℃，优选在700℃ 至800°C。步骤f）的金属有利地是钙。本发明还涉及在醇脱水中使用所述催化剂，烯烃裂解以制备较轻烯烃，通过醇与烯烃和/或醇烷基化MTO和芳族化合物的烷基化。

4. 发明申请

WO2013017499A1 METHOD FOR MAKING A CATALYST COMPRISING A PHOSPHORUS MODIFIED ZEOLITE AND USE OF SAID ZEOLITE 审中-公开
标题翻译：制备包含磷改性沸石的催化剂的方法和使用ZEOLITE
公开(公告)号：WO2013017499A1
公开(公告)日：2013-02-07
申请号：PCT/EP2012/064582
申请日：2012-07-25
申请人： TOTAL RESEARCH & TECHNOLOGY FELUY , NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
发明人： NESTERENKO, Nikolai , MINOUX, Delphine , ADAM, Cindy , DATH, Jean-Pierre
IPC分类号： B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C1/20
CPC分类号： B01J29/85 , B01J29/40 , B01J29/65 , B01J29/7023 , B01J29/7026 , B01J29/7038 , B01J29/7042 , B01J29/7046 , B01J37/0009 , B01J37/10 , B01J37/28 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C1/24 , C07C2/08 , C07C2/66 , C07C2/864 , C07C4/06 , C07C2521/08 , C07C2527/14 , C07C2529/40 , C07C2529/65 , C10G3/49 , C10G29/205 , C10G29/22 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/08 , C07C15/46 , C07C15/08
摘要： The present invention relates, in a first embodiment, to a method to make a phosphorus modified zeolite comprising the following steps in this order, a) providing a zeolite comprising at least one ten members ring in the structure, optionally making an ion-exchange, b) steaming said zeolite, c) introducing phosphorus on the zeolite to introduce at least 0.1 wt% of phosphorus, said introduction being made by dry impregnation or chemical vapor deposition, d) mixing said zeolite of step c) with at least a component selected among one or more binders and shaping additives, e) shaping said mixture, f) introducing a metal, optionally simultaneously with step d), g) optionally washing the catalyst, h) optionally calcinating the catalyst, i) steaming the catalyst, also referred to as the equilibration step. In a second embodiment phosphorus can be introduced by any means and at step i) the steaming severity (X) is at least about 2. In said second embodiment the catalyst is advantageously steamed at a temperature above 625°C, preferably in the range 700 to 800°C. The metal of step f) is advantageously Calcium. The present invention also relates to the use said catalyst in the alcohol dehydration, the olefin cracking to make lighter olefins, the MTO and the alkylation of aromatics by alcohols with olefins and/or alcohols.
摘要翻译：在第一实施方案中，本发明涉及一种制备磷改性沸石的方法，其包括以下步骤：a）提供在该结构中包含至少一个十元环的沸石，任选进行离子交换， b）蒸煮所述沸石，c）在沸石上引入磷以引入至少0.1重量％的磷，所述引入通过干浸渍或化学气相沉积制备，d）将步骤c）的所述沸石与至少一种选自在一种或多种粘合剂和成型添加剂中，e）成型所述混合物，f）任选地与步骤d）同时引入金属，g）任选地洗涤催化剂，h）任选地煅烧催化剂，i）蒸发催化剂，作为平衡步骤。在第二个实施方案中，磷可以通过任何方式引入，并且步骤i）蒸汽的苛刻度（X）至少约为2.在所述第二实施方案中，有利地，催化剂在高于625℃，优选在700℃ 至800°C。步骤f）的金属有利地是钙。本发明还涉及在醇脱水中使用所述催化剂，烯烃裂解以制备较轻烯烃，通过醇与烯烃和/或醇烷基化MTO和芳族化合物的烷基化。

5. 发明申请

WO2012016788A1 PROCESS TO MAKE OLEFINS FROM METHANOL AND ISOBUTANOL 审中-公开
标题翻译：从甲醇和异丁醇制备油脂的方法
公开(公告)号：WO2012016788A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/061587
申请日：2011-07-08
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/20 , C07C4/06 , C07C11/06
CPC分类号： C07C1/22 , B01J29/40 , B01J2229/42 , C07C1/20 , C07C1/24 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/42 , C07C11/02 , C07C11/06 , C07C11/08 , C07C11/04
摘要： The present invention relates to a process for making essentially ethylene and propylene comprising : a) providing an alcohol mixture (A) comprising about 20 w% to 100% isobutanol, b) introducing in a reactor (A) a stream comprising the mixture (A) mixed with methanol or dimethyl ether or mixture thereof, optionally water, optionally an inert component, c) contacting said stream with a catalyst (A1) in said reactor (A), the MTO reactor, at conditions effective to convert at least a part of the alcohol mixture (A) and at least a part of the methanol and/or dimethyl ether to olefins, d) recovering from said reactor (A) an effluent comprising : ethylene, propylene, butene, water, optionally unconverted alcohols, various hydrocarbons, and the optional inert component of step b), e) fractionating said effluent of step d) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种基本上制备乙烯和丙烯的方法，其包括：a）提供包含约20重量％至100重量％异丁醇的醇混合物（A），b）在反应器（A）中引入包含混合物（A ）与甲醇或二甲醚或其混合物，任选的水，任选的惰性组分混合，c）使所述流与所述反应器（A）中的催化剂（A1），所述MTO反应器在有效地转化至少一部分的醇混合物（A）和至少一部分甲醇和/或二甲醚至烯烃，d）从所述反应器（A）回收包含乙烯，丙烯，丁烯，水，任选未转化的醇，各种烃和步骤b）的任选的惰性组分，e）将步骤d）的所述流出物分馏以产生至少一种乙烯流，丙烯料流，基本上由具有4个或更多个碳原子的烃组成的馏分，水和任选的惰性合作步骤a）的组分，任选地在反应器（A）的入口处全部或部分地回收乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分。

6. 发明申请

WO2012016787A1 PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 审中-公开
标题翻译：从ISOBUTANOL制造OLEFINS的过程
公开(公告)号：WO2012016787A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/061583
申请日：2011-07-08
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/20 , C07C4/06 , C07C11/06
CPC分类号： C07C1/24 , B01J29/40 , B01J2229/42 , C07C1/22 , C07C4/06 , C07C6/04 , C07C2529/40 , C08F10/02 , C10G3/42 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： The present invention relates to a process for the conversion of an alcohol mixture (A) comprising about 20 w% to 100% isobutanol to make essentially propylene, comprising : a)introducing in a reactor (A) a stream comprising the mixture (A), optionally water, optionally an inert component, b)contacting said stream with a catalyst (A1) at a temperature above 450°C in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c)recovering from said reactor (A) an effluent comprising : ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d)fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，，任选的水，任选的惰性组分，b）在有效使至少一部分异丁醇和其它醇脱水的条件下，在所述反应器（A）中在高于450℃的温度下将所述物流与催化剂（A1）接触，如果任何并且开裂，c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的混合物（A）的醇，各种烃和步骤a），d的任选的惰性组分的流出物）分馏步骤c）的所述流出物以产生至少一个乙烯流，丙烯流，基本上由具有4个碳原子或更多个碳原子的烃组成的馏分，水和步骤a）的任选的惰性组分，任选地将乙烯整体或部分在反应器（A）的入口，任选地在反应器（A）的入口处循环基本上由具有4个碳原子或更多碳原子的烃组成的馏分。

7. 发明申请

WO2012016786A1 PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 审中-公开
标题翻译：从ISOBUTANOL制造OLEFINS的过程
公开(公告)号：WO2012016786A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/061582
申请日：2011-07-08
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/20 , C07C4/06 , C07C11/06
CPC分类号： C07C1/24 , C07C1/20 , C07C1/22 , C07C2/12 , C07C4/06 , C07C11/06 , C07C29/00 , C07C2529/40 , C07C2529/85 , C08F210/02 , C08F210/06 , C12P7/16 , Y02P30/42
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w% to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), mixed with astream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 500°C in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising : ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，与包含具有4个或更多碳原子的烯烃（C 4 +烯烃），任选的水，任选的惰性组分的流动（D1）混合，b）在所述反应器（500℃）中使所述料流与催化剂（A1）在500℃以上接触 A）在有效使所述异丁醇和其它醇的至少一部分脱水的条件下（如果有的话）和破裂，c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的醇混合物（A），各种烃和步骤a）的任选的惰性组分，d）将步骤c）的所述流出物分馏以产生至少一种乙烯料流，丙烯料流，基本上由具有4个碳原子的烃组成的馏分或更多，水和th 任选地在反应器（A）的入口处全部或部分地循环乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分，。

8. 发明申请

WO2012016785A1 COMBINED PROCESS TO MAKE OLEFINS FROM ISOBUTANOL 审中-公开
标题翻译：从ISOBUTANOL制造OLEFINS的组合方法
公开(公告)号：WO2012016785A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/061581
申请日：2011-07-08
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/20 , C07C4/06 , C07C11/06 , C07C1/24
CPC分类号： C07C1/24 , B01J21/04 , B01J29/40 , B01J29/65 , C07C4/06 , C07C2521/04 , C07C2529/40 , C07C2529/65 , C07C2529/85 , C10G3/44 , C10G3/49 , C10G2300/1014 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C10G2400/22 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/20 , Y02P30/42 , C07C11/08 , C07C11/06
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w% to 100% isobutanol to make essentially propylene, comprising : a) introducing in a reactor (A) (also called the first reaction zone or low temperature reaction zone) a stream comprising the mixture (A), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1 ) in said reactor (A) at conditions effective to dehydrate : at least a portion of the isobutanol to essentially butenes, at least a portion of other alcohols, if any, to essentially olefins other than butene having the same carbon number as the alcohol precursor, c) recovering from said reactor (A) an effluent comprising : butenes, optionally olefins other than butene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to remove a portion or all the water, unconverted alcohols, optionally the inert component, and optionally the whole or a part of the various hydrocarbons to get a stream (D) comprising essentially olefins and optionally the inert component, e) introducing at least a part of said stream (D) in an OCP reactor (also called the second reaction zone or high temperature zone), f) contacting said stream comprising at least a part of (D), optionally in combination with a stream (D1 ) comprising olefins having 4 carbon atoms or more (C4+ olefins), in said OCP reactor with a catalyst which is selective towards light olefins in the effluent, to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, g) fractionating said effluent of step f) to produce at least an ethylene stream, a propylene stream and a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, optionally recycling ethylene in whole or in part at the inlet of the OCP reactor of step f), or at the inlet of the reactor (A) or at the inlet of both the OCP reactor of step f) and the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the OCP reactor.
摘要翻译：本发明涉及一种将包含约20W％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）（也称为第一反应区或低温反应区）包含混合物（A）的物流，任选的水，任选的惰性组分，b）在有效脱水的条件下使所述物流与所述反应器（A）中的催化剂（A1）接触：至少部分异丁醇至基本上丁烯，至少一部分其它醇（如果有的话）至具有与醇前体相同碳数的丁烯以外的基本上烯烃，c）从所述反应器（A）回收包含丁烯，任选烯烃除了丁烯，水，任选的未转化的混合物（A）的醇，各种烃和步骤a）的任选的惰性组分，d）分级步骤c）的所述流出物以除去未转化的部分或全部水醇，任选的惰性组分，以及任选的各种烃的全部或部分，以获得基本上含有烯烃和任选的惰性组分的流（D），e）将至少一部分所述流（D）引入OCP 反应器（也称为第二反应区或高温区），f）使包含至少一部分（D）的物流，任选与包含具有4个碳原子或更多个（C4 +烯烃）的烯烃的物流（D1）在所述OCP反应器中具有对流出物中的轻质烯烃具有选择性的催化剂，以产生具有比原料低的分子量的烯烃含量的流出物，g）将步骤f）的所述流出物分馏以产生至少一种乙烯流，丙烯料流和基本上由具有4个或更多碳原子的烃组成的馏分，任选地在步骤f）的OCP反应器的入口处全部或部分地回收乙烯，或在反应器的入口处（A）或在步骤f）的OCP反应器和反应器（A）的入口处，任选地在OCP反应器的入口处循环基本上由具有4个碳原子或更多个碳原子的烃组成的馏分。

9. 发明申请

WO2011161045A1 DEHYDRATION OF ALCOHOLS ON POISONED ACIDIC CATALYSTS 审中-公开
标题翻译：酒精在脱毒酸催化剂上的脱水
公开(公告)号：WO2011161045A1
公开(公告)日：2011-12-29
申请号：PCT/EP2011/060212
申请日：2011-06-20
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , MINOUX, Delphine , ADAM, Cindy , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre , VERMEIREN, Walter
发明人： MINOUX, Delphine , ADAM, Cindy , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre , VERMEIREN, Walter
IPC分类号： C07C1/24 , C07C11/04
CPC分类号： C07C1/24 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2529/40 , C07C2529/65 , C07C2529/82 , C07C2529/83 , C07C2529/85 , Y02P20/52 , C07C11/04
摘要： The present invention is a process for the dehydration of an alcohol having at least 2 carbon atoms to make the corresponding olefin, comprising: a) introducing in a reactor a stream (A) comprising at least an alcohol, optionally water, optionally an inert component, b) contacting said stream with an acidic catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, c) recovering from said reactor a stream (B) comprising : the inert component and at least an olefin, water and optionally unconverted alcohol, d) optionally fractionating the stream (B) to recover the unconverted alcohol and recycling said unconverted alcohol to the reactor of step a), e) optionally fractionating the stream (B) to recover the inert component, water and the olefin and optionally recycling said inert component and optionally a part of the water to the reactor of step a), wherein, f) an effective amount of a component capable to neutralize a part of the catalyst active site is introduced in stream (A) or directly in the dehydration reactor and g) optionally the temperature of the dehydration reactor is adjusted to increase the alcohol conversion or the olefin yield or both. In another embodiment at step f) an effective amount of a component capable to increase the selectivity for the desired corresponding olefin is introduced in stream (A) or directly in the dehydration reactor. The component introcuced at step f) can be chosen from the group consisting of ammonia, organic ammonium salts, hydrazine, nitriles, amines (including pyridines, pyrrols, pyrrolydones and pyrrolidines), amides, imines, di-imines, imides, cyanates, isocyanates, nitrites and nitroso compounds, aldehydes, ketones, carboxylic esters, and their corresponding thio-compounds (thiols, sulphides, disulfides).
摘要翻译：本发明是使具有至少2个碳原子的醇脱水以制备相应的烯烃的方法，其包括：a）在反应器中引入至少包含醇，任选的水，任选的惰性组分的流（A） b）使所述料流与所述反应器中的酸性催化剂接触，在有效使所述醇的至少一部分脱水以制备烯烃的条件下，c）从所述反应器回收流（B），其包含：惰性组分和至少一种烯烃，水和任选未转化的醇，d）任选地分馏流（B）以回收未转化的醇并将所述未转化的醇再循环到步骤a）的反应器中，e）任选地将流（B）分馏以回收惰性组分，水和烯烃，并且任选地将所述惰性组分和任选的一部分水再循环到步骤a）的反应器中，其中f）有效量的能够中和c的一部分反应器活性位点以流（A）或直接在脱水反应器中引入，并且g）任选地调节脱水反应器的温度以增加醇转化率或烯烃产率或两者。在步骤f）的另一个实施方案中，有效量的能够增加所需相应烯烃的选择性的组分被引入到流（A）中，或直接在脱水反应器中引入。在步骤f）中介导的组分可以选自氨，有机铵盐，肼，腈，胺（包括吡啶，吡咯，吡咯烷酮和吡咯烷），酰胺，亚胺，二亚胺，酰亚胺，氰酸酯，异氰酸酯，亚硝酸盐和亚硝基化合物，醛，酮，羧酸酯及其相应的硫代化合物（硫醇，硫化物，二硫化物）。

10. 发明申请

WO2011113834A1 SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS 审中-公开
标题翻译： ISOBUTANOL在酸性催化剂上的同时脱水和同位素同位素
公开(公告)号：WO2011113834A1
公开(公告)日：2011-09-22
申请号：PCT/EP2011/053902
申请日：2011-03-15
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
发明人： ADAM, Cindy , MINOUX, Delphine , NESTERENKO, Nikolai , VAN DONK, Sander , DATH, Jean-Pierre
IPC分类号： C07C1/24 , C07C11/00 , C07C11/08 , C07C11/09 , B01J29/06 , B01J29/40 , B01J29/85
CPC分类号： C07C1/24 , B01J29/85 , C07C5/2518 , C07C5/2775 , C07C11/08 , C07C11/09 , C07C2521/04 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/127
摘要： The present invention (in a first embodiment) relates to a process for the simu ltaneou s dehyd ration and skeletal isomerisation of isobuta nol to ma ke substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerise at least a portion of the isobutanol to make a mixture of n-butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, Wherein, the WHSV of the isobutanol is at least 1 h -1 or the temperature is from 200°C to 600°C and the catalyst is capable to make simultaneously the dehydration and skeletal isomerization of butene. The catalyst is a crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/AI higher than 10, or a dealuminated crystalline silicate of the group FER, MWW, EUO, MFS, ZSM- 48, MTT, MFI, MEL or TON having Si/AI higher than 10, or a phosphorus modified crystalline silicate of the group FER, MWW, EUO, MFS, ZSM-48, MTT, MFI, MEL or TON having Si/AI higher than 10, or a silicoaluminaphosphate molecular sieve of the group AEL, or a silicated, zirconated or titanated or fluorinated alumina. Advantageously the stream (B) is fractionated in a step d) to produce a n-butenes stream (N) and to remove the essential part of isobutene optionally recycled with stream (A) to the dehydration/isomerization reactor of step b).
摘要翻译：本发明（在第一个实施方案中）涉及一种用于将异丁醇与基本相应的烯烃进行脱水和骨架异构化的方法，其具有相同数目的碳并且基本上由正丁烯和异丁烯，所述方法包括：a）在反应器中引入包含异丁醇，任选的水，任选的惰性组分的物流（A），b）在有效脱水和骨架异构体的条件下，将所述物流与所述反应器中的催化剂接触，至少一部分异丁醇以制备正丁烯和异丁烯的混合物，c）从所述反应器回收料流（B），除去水，惰性组分（如果有的话）和未转化的异丁醇，以获得n 丁烯和异丁烯，其中，异丁醇的WHSV为至少1h-1，温度为200℃〜600℃，催化剂能够同时进行bu的脱水和骨架异构化拉登。该催化剂是具有Si / Al高于10的FER，MWW，EUO，MFS，ZSM-48，MTT，MFI，MEL或TON的结晶硅酸盐，或FER，MWW，EUO等的脱铝结晶硅酸盐，具有Si / Al大于10的MFS，ZSM-48，MTT，MFI，MEL或TON，或FER，MWW，EUO，MFS，ZSM-48，MTT，MFI，MEL或TON的磷改性结晶硅酸盐，其具有 Si / AI高于10，或AEL的硅铝磷酸盐分子筛，或硅化，锆化或钛酸化或氟化氧化铝。有利地，在步骤d）中将流（B）分馏以产生正丁烯料流（N），并除去任选与料流（A）一起循环的异丁烯的主要部分至步骤b）的脱水/异构化反应器。

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