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    • 2. 发明申请
    • POLY(CYCLOSILOXANE) COMPOSIITON AND METHOD OF SYNTHESIS THEREOF
    • POLY(环硅氧烷)复合物及其合成方法
    • WO2004016670A2
    • 2004-02-26
    • PCT/US2003/025661
    • 2003-08-15
    • THE UNIVERSITY OF AKRONKENNEDY, Joseph, P.KURIAN, Pious
    • KENNEDY, Joseph, P.KURIAN, Pious
    • C08G
    • C08G77/50C07F7/21C08G77/04
    • A poly(cyclosiloxane) network comprises the hydrosilation reaction product of a cyclosiloxane of the formula (I) wherein R and R 2 are the same or different for each siloxane moiety and are selected from the group consisting of hydrogen, an alkyl group, an aryl group, and a cycloalkyl group, and wherein n is an integer from 3 to 8, wherein the cyclosiloxanes are joined by moieties selected from the group consisting of oxygen atoms, linear silanols, branched silanols, halosilanes, alkoxysilanes, vinyl silanes, allyl silanes, vinyl siloxanes, and allyl siloxanes, wherein the Si-O bonds of the cyclosiloxanes are substantially unrearranged compared to the cyclosiloxane precursors of the network. A process for the preparation of a poly(cyclosiloxane) network comprises providing a cyclosiloxane; providing a crosslinking group selected from the group consisting of linear silanols, branched silanols, halosilanes, alkoxysilanes, vinyl silanes, allyl silanes, vinyl siloxanes, and allyl siloxanes; contacting the cyclosiloxane and crosslinking group under condensation reaction conditions such that the crosslinking groups provide Si-O-Si linkages between the cyclosiloxane moieties to form a poly(cyclosiloxane) network composition.
    • 聚(环硅氧烷)网络包含式(I)的环硅氧烷的硅氢化反应产物,其中对于每个硅氧烷部分,R和R 2是相同或不同的,并且 选自氢,烷基,芳基和环烷基,并且其中n是3-8的整数,其中所述环硅氧烷通过选自以下的部分连接:氧原子,直链 硅烷醇,支链硅烷醇,卤代硅烷,烷氧基硅烷,乙烯基硅烷,烯丙基硅烷,乙烯基硅氧烷和烯丙基硅氧烷,其中环状硅氧烷的Si-O键与网络的环硅氧烷前体相比基本上未重排。 制备聚(环硅氧烷)网络的方法包括提供环硅氧烷; 提供选自直链硅烷醇,支链硅烷醇,卤代硅烷,烷氧基硅烷,乙烯基硅烷,烯丙基硅烷,乙烯基硅氧烷和烯丙基硅氧烷的交联基团; 在缩合反应条件下使环硅氧烷和交联基团接触,使得交联基团在环硅氧烷部分之间提供Si-O-Si键以形成聚(环硅氧烷)网络组合物。