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1. 发明申请

WO1998003520A1 METAL COMPLEXES CONTAINING BRIDGED, NON-AROMATIC, ANIONIC, DIENYL GROUPS AND ADDITION POLYMERIZATION CATALYSTS THEREFROM 审中-公开
标题翻译：含有桥接，非芳香，阴离子，二烯基的金属络合物及其加成聚合催化剂
公开(公告)号：WO1998003520A1
公开(公告)日：1998-01-29
申请号：PCT/US1997012650
申请日：1997-07-18
申请人： THE DOW CHEMICAL COMPANY , UNIVERSITY OF UTAH
发明人： THE DOW CHEMICAL COMPANY , UNIVERSITY OF UTAH , WILSON, David, R. , NICKIAS, Peter, N. , NEITHAMER, David, R. , ERNST, Richard, D.
IPC分类号： C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/659 , C08F4/65912 , C08F210/16 , Y10S526/943 , C08F4/6592 , C08F210/14 , C08F2500/07 , C08F2500/12
摘要： Novel Group 4 metal complexes wherein the metal is in the +2, +3, or +4 formal oxidation state containing two ligand groups bound by pi -electrons, at least one of which is a cyclic or non-cyclic, non-aromatic, anionic, dienyl ligand group and having a bridged ligand structure, catalytic derivatives of such complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型第4族金属络合物，其中金属为+2，+3或+4形式氧化态，其含有由π电子结合的两个配体基团，其中至少一种为环状或非环状，非芳族的，具有桥连配体结构的阴离子，二烯基配体基团，这种络合物的催化衍生物; 并且公开了其作为用于聚合加成聚合单体的催化剂的用途。

2. 发明申请

WO1997015582A1 SUPPORTABLE BISCYCLOPENTADIENYL METAL COMPLEXES 审中-公开
标题翻译：支持双金属二元金属复合物
公开(公告)号：WO1997015582A1
公开(公告)日：1997-05-01
申请号：PCT/US1996015074
申请日：1996-09-20
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , NICKIAS, Peter, N. , SPENCER, Lee
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F4/61927
摘要： Metal complexes corresponding to formula (I), wherein L independently each occurrence is a delocalized, pi -bonded group that is bound to M, containing up to 50 non-hydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula -(ER2)m-, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C1-20 hydrocarbyl, and C1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C1-20 hydrocarbyloxy, and m is an integer from 1 to 3; X' is a neutral Lewis base ligand having up to 20 non-hydrogen atoms; X" independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxyl, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X" groups together form a divalent hydrocarbadiyl or neutral hydrocarbon group; n is a number from 0 to 3; and p is an integer from 0 to 2.
摘要翻译：对应于式（I）的金属络合物，其中L独立地每次出现是与M结合的离域的π键合基团，其含有至多50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有式 - （ER 2）m - 的多达50个非氢原子的共价结合的二价取代基，其中E独立地为碳，硅或锗，R各自独立地选自C1 -20烃基和C 1-20烃氧基，条件是在至少一个出现中R是C 1-20烃氧基，m是1至3的整数; X'是具有至多20个非氢原子的中性路易斯碱配体; X“独立地为选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X” 一起形成二价烃基或中性烃基; n是从0到3的数字; p为0〜2的整数。

3. 发明申请

WO1996008497A1 METAL (III) COMPLEXES CONTAINING, NON-AROMATIC, ANIONIC, DIENYL GROUPS AND ADDITION POLYMERIZATION CATALYSTS THEREFROM 审中-公开
标题翻译：金属（III）复合物，非芳香族，阴离子型，二烯基和其加成聚合催化剂
公开(公告)号：WO1996008497A1
公开(公告)日：1996-03-21
申请号：PCT/US1995008466
申请日：1995-07-06
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , WILSON, David, R. , NEITHAMER, David, R. , NICKIAS, Peter, N. , KRUPER, W., Jack, Jr.
IPC分类号： C07F07/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00
摘要： Novel group 4, group 3 or lanthanide metal complexes wherein the metal is in the +3 formal oxidation state containing a cyclic or non-cyclic, non-aromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型第4族，第3族或镧系元素金属络合物，其中金属处于+3形式氧化态，其含有与M结合并具有桥连配体结构的环状或非环状，非芳族，阴离子，二烯基配体基团，催化衍生物的这种复合物; 并且公开了其作为用于聚合加成聚合单体的催化剂的用途。

4. 发明申请

WO1997041134A1 A METHOD FOR PRODUCING OCTAHYDROFLUORENYL METAL COMPLEXES 审中-公开
标题翻译：一种用于生产三氟甲磺酸金属络合物的方法
公开(公告)号：WO1997041134A1
公开(公告)日：1997-11-06
申请号：PCT/US1997004222
申请日：1997-03-18
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , NEWMAN, Thomas, H. , KLOSIN, Jerzy , NICKIAS, Peter, N.
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： Octahydrofluorenyl metal complexes, such as octahydrofluorenyltitaniumtrichloride, or ring-substituted octahydrofluorenyl metal complexes wherein the metal is in the +2, +3 or +4 formal oxidation state are prepared by reduction of tetra- or hexahydrofluorenyl metal complexes. The reduction reaction may be carried out at ambient pressure and temperature in the presence of a catalyst. The process of the present invention permits preparation of octahydrofluorenyltitanium metal complexes from a series of high yield reactions starting with fluorene. The resulting complexes are useful as catalysts in preparing polymers having a syndiotactic stereostructure.
摘要翻译：八氢芴基三氯化钛的八氢芴基金属络合物或其中金属处于+2，+3或+4形式氧化态的环取代的八氢芴基金属络合物是通过还原四或六氢芴基金属络合物来制备的。还原反应可以在环境压力和温度下在催化剂存在下进行。本发明的方法允许从芴开始的一系列高产率反应制备八氢芴基钛金属络合物。所得复合物可用作制备具有间同立构结构的聚合物的催化剂。

5. 发明申请

WO1997035894A3 ALLYL CONTAINING METAL COMPLEXES AND OLEFIN POLYMERIZATION PROCESS 审中-公开
公开(公告)号：WO1997035894A3
公开(公告)日：1997-10-02
申请号：PCT/US1997012821
申请日：1997-03-11
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , NICKIAS, Peter, N. , DEVORE, David, D. , TIMMERS, Francis, J.
IPC分类号： C08F04/64

6. 发明申请

WO1996008498A1 METAL COMPLEXES CONTAINING NON-AROMATIC, ANIONIC, DIENYL GROUPS AND ADDITION POLYMERIZATION CATALYSTS THEREFROM 审中-公开
标题翻译：包含非芳香族，阴离子型，二烯基和其添加聚合催化剂的金属络合物
公开(公告)号：WO1996008498A1
公开(公告)日：1996-03-21
申请号：PCT/US1995008489
申请日：1995-07-06
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , WILSON, David, R. , NEITHAMER, David, R. , NICKIAS, Peter, N. , KRUPER, W., Jack, Jr.
IPC分类号： C07F07/00
CPC分类号： C07F17/00 , C07F7/00 , C07F7/28 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F10/00
摘要： Novel group 4 metal complexes wherein the metal is in the +2 or +4 formal oxidation state containing a cyclic or noncyclic, non-aromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes including novel zwitterionic complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型4族金属络合物，其中金属处于+2或+4形式氧化态，其含有与M结合并具有桥连配体结构的环状或非环状，非芳族，阴离子，二烯基配体基团，这些络合物的催化衍生物包括新型两性离子复合物; 并且公开了其作为用于聚合加成聚合单体的催化剂的用途。

7. 发明申请

WO1994021693A1 PREPARATION OF ADDITION POLYMERIZATION CATALYSTS VIA LEWIS ACID MITIGATED METAL CENTER OXIDATION 审中-公开
标题翻译：通过LEWIS酸缓和金属中心氧化法制备添加聚合催化剂
公开(公告)号：WO1994021693A1
公开(公告)日：1994-09-29
申请号：PCT/US1994001647
申请日：1994-02-10
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , NICKIAS, Peter, N. , TIMMERS, Francis, J. , DEVORE, David, D. , ROSEN, Robert, K. , MUSSELL, Robert, D.
IPC分类号： C08F04/74
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/6592
摘要： Addition polymerization catalysts comprising a derivative of a titanium or zirconium in the +4 oxidation state prepared by metal center oxidation and cation complex formation of a reduced metal precursor complex via electron transfer in a single step by use of a neutral organic oxidant, optionally in the presence of a Lewis acid mitigator.
摘要翻译：包含通过金属中心氧化制备的+4氧化态的钛或锆的衍生物的加成聚合催化剂，并且通过使用中性有机氧化剂在一个步骤中通过电子转移形成还原金属前体络合物的阳离子络合物，任选地在存在路易斯酸缓释剂。

8. 发明申请

WO1998027103A1 FUSED RING SUBSTITUTED INDENYL METAL COMPLEXES AND POLYMERIZATION PROCESS 审中-公开
标题翻译：熔融取代的金属复合物和聚合方法
公开(公告)号：WO1998027103A1
公开(公告)日：1998-06-25
申请号：PCT/US1997021585
申请日：1997-11-21
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , MCADON, Mark, H. , NICKIAS, Peter, N. , PATTON, Jasson, T. , SHANKAR, Ravi, B. , TIMMERS, Francis, J. , VANDERLENDE, Daniel, D. , KOLTHAMMER, Brian, W., S. , UELIGGER, Steven, M.
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/02 , C08F210/16 , C08F210/18 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F212/08 , C08F2500/08 , C08F2500/12 , C08F210/14 , C08F210/06 , C08F236/20 , C08F2500/25
摘要： Group 4 metal constrained geometry complexes comprising a fused ring indenyl derivative ligand, catalytic derivatives thereof, processes for preparing the same and their use as components of olefin polymerization catalysts are disclosed.
摘要翻译：公开了包含稠环茚基衍生物配体的第4族金属约束几何配合物，其催化衍生物，其制备方法及其作为烯烃聚合催化剂组分的用途。

9. 发明申请

WO1998006760A1 SATURATED TRICYCLIC LIGAND CONTAINING METAL COMPLEXES AND OLEFIN POLYMERIZATION PROCESS 审中-公开
标题翻译：含饱和三元配位金属复合物和烯烃聚合工艺
公开(公告)号：WO1998006760A1
公开(公告)日：1998-02-19
申请号：PCT/US1997013560
申请日：1997-08-01
申请人： THE DOW CHEMICAL COMPANY , NORTHWESTERN UNIVERSITY
发明人： THE DOW CHEMICAL COMPANY , NORTHWESTERN UNIVERSITY , NICKIAS, Peter, N. , OBORA, Yasushi , MARKS, Tobin, J.
IPC分类号： C08F04/642
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/15
摘要： Bridged, group 4 Metal complexes useful as olefin polymerization catalyst components corresponding to the formula: L1ZL2MXmX'n or a dimer, solvated adduct, chelated derivative or mixture thereof, wherein: L1 is a partially salturated tricyclic group, especially octahydrofluorenyl, L2 is a substituted cyclopentadienyl group that is bound to M by means of delocalized pi -electrons, said cyclopentadienyl group being substituted at one and only one of its two distal positions with a bulky ligand group; Z is divalent bridging substituent; X each occurrence is a monovalent, anionic moiety having up to 40 non-hydrogen atoms, optionally, two X groups may be covalently bound together forming a divalent dianionic moiety having both valences bound to M, or, optionally 2 X groups may be covalently bound together to form a neutral, conjugated or nonconjugated diene that is bonded to M by means of delocalized pi -electrons (whereupon M is in the +2 oxidation state), or further optionally one or more X and one or more X' groups may be bonded together thereby forming a moiety that is both covalently bound to M and coordinated thereto; m is 1 or 2 and is equal to two less than the formal oxidation state of M, except when 2 X groups together form a neutral conjugated or non-conjugated diene that is pi -bonded to M, in which case m is equal to the formal oxidation state of M; X' is a neutral ligand having up to 20 non-hydrogen atoms, and n is a number from 0 to 3.
摘要翻译：第4族金属络合物，可用作对应于下式的烯烃聚合催化剂组分：L1ZL2MXmX'n或二聚体，溶剂化加合物，螯合衍生物或其混合物，其中：L1为部分饱和三环基团，特别是八氢芴基，L2为取代的通过离域π电子与M结合的环戊二烯基，所述环戊二烯基在其两个远端位置中的一个且仅一个被取代，具有庞大的配体基团; Z是二价桥连取代基; X每个出现是具有多达40个非氢原子的单价阴离子部分，任选地，两个X基团可以共价键合在一起形成具有与M结合的两个价键的二价二阴离子部分，或者任选地，2个X基团可共价结合一起形成通过离域π电子（因此M处于+2氧化态），或进一步任选地一个或多个X和一个或多个X'基团与M键合的中性，共轭或非共轭二烯结合在一起，从而形成共价结合M并与之配位的部分; m为1或2，并且等于小于M的形式氧化态的2，除了当两个X基团一起形成与M相连接的中性共轭或非共轭二烯时，其中m等于 M的正式氧化态; X'是具有至多20个非氢原子的中性配体，n是0至3的数。

10. 发明申请

WO1997015602A1 READILY SUPPORTABLE METAL COMPLEXES 审中-公开
标题翻译：易于支持的金属复合材料
公开(公告)号：WO1997015602A1
公开(公告)日：1997-05-01
申请号：PCT/US1996014608
申请日：1996-09-11
申请人： THE DOW CHEMICAL COMPANY
发明人： THE DOW CHEMICAL COMPANY , SPENCER, Lee , NICKIAS, Peter, N.
IPC分类号： C08F10/00
CPC分类号： C07F17/00 , C08F4/61908 , C08F4/6192 , C08F10/00
摘要： Metal complexes useful as olefin polymerization catalysts corresponding to formula (I), wherein L is a delocalized, pi -bonded group that is bound to M, containing up to 50 nonhydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula: -(ER2)m-, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C1-20 hydrocarbyl, and C1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C1-20 hydrocarbyloxy, and m is an integer from 1 to 3; Y is a divalent ligand group comprising nitrogen, phosphorus, oxygen or sulfur, said Y containing up to 20 nonhydrogen atoms; X' is a neutral Lewis base ligand having up to 20 non-hydrogen atoms; X'' independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X'' groups together form a divalent hydrocarbadiyl group; n is a number from 0 to 3; and p is an integer from 0 to 2.
摘要翻译：可用作对应于式（I）的烯烃聚合催化剂的金属络合物，其中L是与M结合的离域的π键合基团，其含有至多50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有下式的至多50个非氢原子的共价结合的二价取代基： - （ER 2）m - ，其中E独立地为碳，硅或锗，R各自独立地选自 C 1-20烃基和C 1-20烃氧基，条件是在至少一个出现中R是C 1-20烃基氧基，m是1至3的整数; Y是包含氮，磷，氧或硫的二价配体基团，所述Y含有至多20个非氢原子; X'是具有至多20个非氢原子的中性路易斯碱配体; X“独立地是选自氢化物，卤素，烃基，甲硅烷基，甲硅烷基，烃氧基，酰胺，甲硅烷氧基，卤代烃基，卤代甲硅烷基，甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分，或两个X 一起形成二价烃基; n是从0到3的数字; p为0〜2的整数。

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